• Title/Summary/Keyword: KCL-2

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Preparation of $Pb(Sc_{1/2}Nb_{1/2})O_3$ powders by the molten salt synthesis method (용융염 합성법에 의한 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 분말의 제조)

  • 박경봉
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.400-405
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    • 1997
  • Lead scandium niobate powders were prepared by a molten salt synthesis method using KCl as a flux. Variations in phase formation and particle morphology were investigated for the temperature range $700^{\circ}C$ to $850^{\circ}C$. Pure $Pb(Sc_{1/2}Nb_{1/2})O_3$ perovskite phase was formed at $850^{\circ}C$ after 2hrs and the average particle size of powder was below 0.5 $\mu\textrm{m}$. The results are discussed with respect to DTA, X-ray diffraction, and microstructural characterization data.

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Combustion Synthesis of YAG:Ce Phosphor with Teflon (Teflon을 이용한 YAG:Ce 형광체 합성)

  • Yeon, Jung Woon;Won, Chang Whan;Won, Hyung Il;Nersisyan, H.H.
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.439-443
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    • 2012
  • YAG:Ce phosphor were prepared in a self-propagating high-temperature synthesis (SHS) using a $1.5Y_2O_3+2.5Al_2O_3+0.116CeO_2+3.0KClO_3+kCO(NH_2)_2+m(C_2F_4)_n$ precursor mixture. The heat for the combustion propagation was provided by the reaction of a $KClO_3+CO(NH_2)_2+(C_2F_4)n$ mixture. Pure-phase YAG phosphor was synthesized at the combustion temperature of $1210^{\circ}C$ from k=3.6 mole and m=0.3 mole. The as-prepared YAG:Ce phosphor had a particle size of $2-10{\mu}m$. The addition of Teflon to the precursor mixture increased the YAG particle size and its luminescent intensity. The emission peak of the YAG phosphor was blue-shifted with an increase of Teflon concentration.

Characterization of the Morphology and Corrosion Resistance in Electroless Ni-P-TiO2 Composite Coating Prepared by TiO2 Contents (TiO2 함량에 따르는 무전해 Ni-P-TiO2 복합도금층 특성 연구)

  • Byoun, Young-Min;Kim, Ho-Young;lee, Jae-Woong;Hwang, Hwan-il
    • Journal of the Korean institute of surface engineering
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    • v.52 no.4
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    • pp.187-193
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    • 2019
  • Electroless Ni-P coatings are widely used in the chemical, mechanical, and electronic industries because of their excellent wear and abrasion resistance. In this study, the effect of $TiO_2$ particles of composite coating was investigated. To improve the corrosion resistance, electroless $Ni-P-TiO_2$composite coating was studied by varying the $TiO_2$ content. The morphology and phase structure of $Ni-P-TiO_2$ composite coatings were analyzed by scanning electron microscopy(SEM), X-ray diffractometry(XRD) and X-ray photoelectron spectroscopy(XPS). The result showed that $Ni-P-TiO_2$composite coating is composed of Ni, P, Ti and O. It exhibits an amorphous structure, high hardness and good corrosion resistance to the substrate. $Ni-P-TiO_2$ composite coatings have higher open circuit potential than that of the substrate, which obtained at $TiO_2$ content of 5.0 g/L optimal integrated properties.

Characterization of Concrete Composites with Mixed Plastic Waste Aggregates (복합 폐플라스틱 골재 치환 콘크리트의 기초 물성 평가)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.317-324
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    • 2020
  • Plastic wastes generated from domestic waste are separated by mixed discharge with foreign substances, and the cost of the separation and screening process increases, so recycling is relatively low. In this study, as a fundamental study for recycling mixed plastic wastes generated from domestic waste into concrete aggregates, changes in concrete properties according to the plastic waste types and the substitution rate were evaluated experimentally. The mixed plastic waste aggregate(MPWA) was found to have a lower density and a higher absorption rate compared to the coarse aggregate with good particle size distribution. On the other hand, the single plastic waste aggregate(SPWA) was composed of particles of uniform size, and both the density and the absorption rate were lower than that of the fin e aggregate. It was found that the MPWA substitution concrete did not cause a material separation phenomenon due to a relatively good particle size distribution even with the largest amount of plastic waste substitution, and the amount of air flow increased little. The compressive strength and flexural strength of the PWA substitution concrete decreased as the amount of substitution of the PWA increased due to the low strength of the PWA, the suppression of the cement hydration reaction due to hydrophobicity, and the low adhesion between the PWA and the cement paste. It was found that the degree of deterioration in compressive strength and flexural strength of concrete substituted with MPWA having good particle size distribution was relatively small.

Effects of pH and Potassium Chloride in Solvent System of High-Speed Countercurrent Chromatography (pH 및 염화칼륨 첨가가 고속역류크로마토그래피의 용매시스템에 미치는 영향)

  • Lee, Chang-Ho;Lee, Boo-Yong;Lee, Hyun-Yu;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1222-1227
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    • 1997
  • Effects of the physical properties of solvent system such as pH and polarity change by salt addition in solvent system were investigated by using high speed countercurrent chromatography apparatus (Model CCC-1000, Pharm-Tech Research Corp. USA). The changes of pH and interfacial tension in solvent system of high speed countercurrent chromatography did not significantly affect on retention of stationary phase, but induced remarkable changes in the partition coefficient of ginkgo flavonoids, kaempferol, quercetin and isorhamnetin. The partition coefficients of ginkgo flavonoid standard increase with an increased pH of solvent system and quercetin sharply increased at pH 10.0. Retention of stationary phase decreases with an increased concentration of KCl in butanol of solvent system. Interfacial tension between two phase in solvent system of hexane increases with an increased concentration of KCl. The polarity of solvent system significantly changes the partition coefficients of ginkgo flavonoid.

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Characterization of Cement Mortar with Plastic Fine Aggregates (플라스틱 잔골재에 의한 시멘트 모르타르 기초 물성 평가)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.383-388
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    • 2019
  • The present study evaluated experimentally the effects of the type and content of plastic fine aggregates on cement mortar in order to utilize waste platics as raw materials of concrete. The two kinds of plastics, LLDPE and HDPE were used, and the mixing rate of plastic fine aggregates was increased 0, 25, 50, 75, 100%. The mortar of LLDPE fine aggregate and HDPE fine aggregate showed similar tendency in flow and material separation resistance, density and water absorption, compressive strength and flexural strength by age. The flowability of mortar mixed with plastic fine aggregates was increased up to 50% but decreased at 75% or more. The material separation resistance of mortar with plastic fine aggregates was also dramatically decreased. On the other hand, due to the low density of plastics, the density of mortar decreased with the mixing of plastic fine aggregates. Due to the low adhesion between plastic fine aggregates and cement, the compressive strength by age was decreased in proportion to the mixing ratio of plastic aggregate, but the flexural strength of each age decreased with maintaining a certain level at 50% or more of plastic fine aggregate content.

A Study on the Stability of Langmuir-Blodgett(LB) Films of L-${\alpha}$-Phosphatidylethanolamine Monolayer (L-${\alpha}$-Phosphatidylethanolamine 단분자층 LB막의 안정성에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.44-49
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    • 2014
  • We were investigated by cyclic voltammetry to the stability through the electrochemical characteristics of phospholipid(L-${\alpha}$-phosphatidylethanolamine, LAPE) monolayer LB films. LAPE monolayer LB films was deposited by the LB method on the indium tin oxide(ITO) glass. The electrochemical properties was measured by cyclic voltammetry with a three-electrode system in 0.5 N, 1.0 N, 1.5 N and 2.0 N $KClO_4$ solution. The measuring range is continuously oxidized to 1650 mV, with an initial potential of -1350 mV was reduced. Scanning rates of 50, 100, 150, 200, and 250 mV/s was set. As a result, LB monolayer films of LAPE was appeared on irreversible processes by the oxidation current from the cyclic voltammogram. Diffusion coefficient (D) of LAPE was calculated 195, 15.9, 5.75, 1.38 and $0.754cm^2s^{-1}{\times}10^{-9}$ at 0.01 N, 0.05 N, 0.10 N, 0.15 N and 0.20 N $KClO_4$ solutions, respectively.

Characterization of the Small Cryptic Plasmid, pGD2, of Klebsiellia sp. KCL-2.

  • Yoo, Ju-Soon;Kim, Hae-Sun;Chung, Soo-Yeol;Lee, Young-Choon;Cho, Young-Soo;Choi, Yong-Lark
    • BMB Reports
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    • v.34 no.6
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    • pp.584-589
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    • 2001
  • One of the cryptic plasmids from the oil degrading bacterium Klebsiella sp. KCL-2, the small plasmid pGD2, has been identified and characterized. This plasmid has a size of 3.6 kb with unknown functions. We constructed the recombinant plasmid pMGD2. The nucleotide sequences of the plasmid were determined and two open reading frames were detected. ORF1 encodes a replication initiator protein (RepA), which has a high degree of homology with the protein of ColE2 plasmid. The product encoded by ORF2 showed a high similarity with the transposase protein of IS5. IS5 is 1195 by long and contains an inverted terminal repetition of 16 bp with one mismatch. Stem-loop structures in the 5'untranslated region of the repA suggest that a putative gene, incA, is located in a complementary strand to the leader region of the repA mRNA.

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