• Archives of Pharmacal Research
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• v.20 no.3
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• pp.288-290
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• 1997

An efficient synthesis of 3-(E)-hydroxy- and 3-(E)-acetoxypropenylcephem derivatives, key intermediates for the synthesis of 3-(E)-propenylcephalosporins was achieved via Stille coupling reaction of 3-trifloxycephem with 3-(E)-tributylstannylallylic alcohol.

• Korean Journal of Remote Sensing
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• v.39 no.6_1
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• pp.1389-1399
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• 2023

KOMPSAT-3/3A (K3/K3A) absolute radiometric calibration study was conducted based on a Field Line of sight Automated Radiance Exposure (FLARE) system. FLARE is a system, which has been developed by Labsphere, Inc. adopted a SPecular Array Radiometric Calibration (SPARC) concept. The FLARE utilizes a specular mirror target resulting in a simplified radiometric calibration method by minimizing other sources of diffusive radiative energies. Several targeted measurements of K3/3A satellites over a FLARE site were acquired during a field campaign period (July 5-15, 2021). Due to bad weather situations, only two observations of K3 were identified as effective samples and they were employed for the study. Absolute radiometric calibration coefficients were computed using combined information from the FLARE and K3 satellite measurements. Comparison between the two FLARE measurements (taken on 7/7 and 7/13) showed very consistent results (less than 1% difference between them except the NIR channel). When additional data sets of K3/K3A taken on Aug 2021 were also analyzed and compared with gain coefficients from the metadata which are used by current K3/K3A, It showed a large discrepancy. It is assumed that more studies are needed to verify usefulness of the FLARE system for the K3/3A absolute radiometric calibration.

• BMB Reports
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• v.47 no.12
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• pp.685-690
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• 2014

The Ras/Raf/MEK/Erk signaling pathway is important for regulation of cell growth, proliferation, differentiation, survival, and apoptosis in response to a variety of extracellular stimuli. Lack of Erk MAPK activation is observed in several cancer cells despite active activation of Ras. However, little is known about the modulation of Erk1/2 activity by active Ras. Here, we show that overexpression of active H-Ras (H-RasG12R) in NIH3T3 fibroblasts impaired FGF2-induced Erk1/2 phosphorylation, as compared to wild-type cells. Northern blot analysis revealed that prolonged expression of active Ras increased MAP kinase phosphatase 3 (MKP3) mRNA expression, a negative regulator of Erk MAPK. Inhibition of the phosphatidylinositol 3-kinase (PI3K)/Akt pathway abrogated active Ras-induced up-regulation of MKP3 expression, leading to the rescue of Erk1/2 phosphorylation. Our results demonstrated that the Ras/Raf/MEK/Erk signaling cascade is negatively regulated by the PI3K/Aktdependent transcriptional activation of the MKP3 gene.

• Korean Journal of Materials Research
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• v.5 no.4
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• pp.433-444
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• 1995

BaCe$O_{3}$를 첨가하여 용융공정으로 제조한 단결정형 Y$Ba_{2}$$Cu_{3}$$O_{x}$(1-2-3) 초전도체의 온도에 대한 자화특성을 연구하였다. 고상반응법과 용융공정으로 0에서 30wt% BaCe$O_{3}$를 1-2-3 결정내에 미세 분산시켰다. 초전도체의 자화특성은 VSM(vibrating sample magnetometer)을 사용하여 77K, 60K, 40K와 20K, 2 Tesla 자장범위에서 측정하였다. BaCe$O_{3}$를 첨가하지 않은 겨우나 5wt% BaCe$O_{3}$를 첨가한 1-2-3 결정의 경우, 77K, 외부자장이 증가시 자화율 차이가 증가하는 비정상 자화특성이 관찰된다. 측정온도가 60K에서는 제2차 최대점이 나타나는 자장값이 고자장쪽으로 이동한다. 20K와 40K의 저온에서는 비정상자화특성이 2 T의 자장범위까지 관찰되지 않았다. 15wt%와 20wt% BaCe$O_{3}$첨가한 시편에서는 자장이 증가하면 자화율차이가 단순히 감소한다. Y-Ba-Cu-O의 flux pinning 기구를 BaCe$O_{3}$첨가에 의한 미세조직변화로 설명하였다.

• Korean Journal of Crystallography
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• v.3 no.1
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• pp.31-36
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• 1992

6, 9-Difluoro-11, 21-dihydroxyl-16, 17-[(1methylehtylidene)bis(oxy)]-pregna-1, 4-diene-3, 20-dione (fluorocinolone acetonide) , C24H3OF106, trigonal, R3 (defined as a hexagonal lattice), a =b = 17.896 k, c: 18.365 k, V=5094.3 A', Z=9, 1 (MoK a) =0.7107 A, D=1.31 g/cm3, D.: 1.328 g/cm3 T=298 K, final R=0.050 for 1101 unique observed reflections. The molecule has conformational features in common with other corticosteroids. Three molecules related by 3-fold symmetry are involved in hydrogen bonding, forming a layer of molecules perpendicular to the c-axis.

• Proceedings of the KIPE Conference
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• 2002.07a
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• pp.119-123
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• 2002

실제의 브러시리스 직류 전동기의 역기전력 파형은 고가의 정밀 서보 전동기를 제외했을 때, 이상적인 사다리꼴이나 정현파의 형태가 아닌 그 형태에 근접한 모양을 갖는다. 하지만 브러시리스 직류 전동기의 운전은 역기전력 파형을 이상적이라고 가정하여 사다리꼴인 경우는 3상 2여자 직류 제어를 하고, 정현파인 경우에는 3상 3여자 교류 제어를 하는 것이 일반적이다. 일반적인 3상 3여자 운전은 3상 2여자 운전에 비해 공간 자계의 높은 분해능을 제공하고, 3상 2여자 운전에서 구조적으로 나타날 수밖에 없는 정류 시의 토크 리플도 발생하지 않는 장점을 갖는다. 따라서 본 논문에서는 위의 두 측면을 고려하여, 즉 이상적인 형태의 역기전력 형태를 갖지 않는 실제 전동기의 특성과 3상 3여자 운전의 특성을 적용하여, 역기전력의 형태에 상관없이 적용할 수 있는 3상 3여자 직류 제어 방법을 제안하고 이에 대한 센서리스 운전을 제안한다.

• Proceedings of the Korean Institute of Communication Sciences Conference
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• 2006.07a
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• pp.280-280
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• 2006

• Journal of KIISE:Computer Systems and Theory
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• v.34 no.5_6
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• pp.176-186
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• 2007

An interconnection network can be represented as a graph where a vertex corresponds to a node and an edge corresponds to a link. The diameter of an interconnection network is the maximum length of the shortest paths between all pairs of vertices. The fault diameter of an interconnection network G is the maximum length of the shortest paths between all two fault-free vertices when there are $_k(G)-1$ or less faulty vertices, where $_k(G)$ is the connectivity of G. The fault diameter of an R-regular graph G with diameter of 3 or more and connectivity ${\tau}$ is at least diam(G)+1 where diam(G) is the diameter of G. We show that the fault diameter of a 2-dimensional $m{\times}n$ torus with $m,n{\geq}3$ is max(m,n) if m=3 or n=3; otherwise, the fault diameter is equal to its diameter plus 1. We also show that in $d({\geq}3)$-dimensional $k_1{\times}k_2{\times}{\cdots}{\times}k_d$ torus with each $k_i{\geq}3$, there are 2d mutually disjoint paths joining any two vertices such that the lengths of all these paths are at most diameter+1. The paths joining two vertices u and v are called to be mutually disjoint if the common vertices on these paths are u and v. Using these mutually disjoint paths, we show that the fault diameter of $d({\geq}3)$-dimensional $k_1{\times}k_2{\times}{\cdots}{\times}k_d$ totus with each $k_i{\geq}3$ is equal to its diameter plus 1.

• Korean Journal of Materials Research
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• v.22 no.6
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• pp.316-320
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• 2012

$Co_3O_4$, $Al_2O_3$ and $Co_3O_4$/$Al_2O_3$ mesoporous powders were prepared by a sol-gel method with starting matierals of aluminum isopropoxide and cobalt (II) nitrate. A P123 template is employed as an active organic additive for improving the specific surface area of the mixed oxide by forming surfactant micelles. A transition metal cobalt oxide supported on alumina with and without P123 was tested to find the most active and selective conditions as a heterogeneous catalyst in the reaction of styrene epoxidation. A bBlock copolymer-P123 template was added to the staring materials to control physical and chemical properties. The properties of $Co_3O_4$/$Al_2O_3$ powder with and without P123 were characterized using an X-ray diffractometer (XRD), a Field-Emission Scanning Electron Microscope (FE-SEM), a Bruner-Emmertt-Teller (BET) surface analyzer, and $^{27}Al$ MAS NMR spectroscopy. Powders with and without P123 were compared in catalytic tests. The catalytic activity and selectivity were monitored by GC/MS, $^1H$, and $^{13}C$-NMR spectroscopy. The performance for the reaction of epoxidation of styrene was observed to be in the following order: [$Co_3O_4$/$Al_2O_3$ with P123-1173 K > $Co_3O_4$/$Al_2O_3$ with P123-973 K > $Co_3O_4$-973 K>$Co_3O_4$/$Al_2O_3$-973 K > $Co_3O_4$/$Al_2O_3$ with P123-1473 K > $Al_2O_3$-973 K]. The existence of ${\gamma}$-alumina and the nature of the surface morphology are related to catalytic activity.

• Korean Journal of Materials Research
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• v.11 no.1
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• pp.34-38
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• 2001

Intermetallics of Fe-28%Al($Fe_3Al$) and Fe-28%Al-4%Cr($Fe_3Al-4Cr$) were oxidized at 1073, 1273 and 1473k in air for up to 17 days. The oxidation resistance of$Fe_3Al-4Cr$ was basically similar to or better than that of $Fe_3Al$. The oxide scales formed on $Fe_3Al$ consisted essentially of pure ${\alpha}-AL_2O_3$, while those formed on $Fe_3Al-4Cr$ consisted of ${\alpha}-AL_2O_3$ having dissolved iron and chromium ions. The preferential outward diffusion of substrate elements to form the outer oxide layer led to the formation of Kirkendall voids at the oxide-matrix interface. The scales formed on $Fe_3Al(-4Cr)$ were thin and dense up to 1273K, but they spalled easily at 1473K, accompanied by more weight gains.