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The Strength Properties Activated Granulated Ground Blast Furnace Slag with Aluminum Potassium Sulfate and Sodium Hydroxide (칼륨명반과 수산화나트륨으로 활성화된 고로슬래그 미분말의 강도 특성)

  • Kim, Taw-Wan;Hahm, Hyung-Gil
    • Journal of the Korea Concrete Institute
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    • v.27 no.2
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    • pp.95-102
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    • 2015
  • In this paper, the effects of sodium hydroxide (NaOH) and aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) dosage on strength properties were investigated. For evaluating the property related to the dosage of alkali activator, sodium hydroxide (NaOH) of 4% (N1 series) and 8% (N2 series) was added to 1~5% (K1~K5) dosage of aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) and 1% (C1) and 2% (C2) dosage of calcium oxide (CaO). W/B ratio was 0.5 and binder/ fine aggregate ratio was 0.5, respectively. Test result clearly showed that the compressive strength development of alkali-activated slag cement (AASC) mortars were significantly dependent on the dosage of NaOH and $AlK(SO_4)_2{\cdot}12H_2O$. The result of XRD analysis indicated that the main hydration product of $NaOH+AlK (SO_4)_2{\cdot}12H_2O$ activated slag was ettringite and CSH. But at early ages, ettringite and sulfate coated the surface of unhydrated slag grains and inhibited the hydration reaction of slag in high dosage of $NaOH+AlK(SO_4)_2{\cdot}12H_2O$. The $SO_4{^{-2}}$ ions from $AlK(SO_4)_2{\cdot}12H_2O$ reacts with CaO in blast furnace slag or added CaO to form gypsum ($CaSO_4{\cdot}2H_2O$), which reacts with CaO and $Al_2O_3$ to from ettringite in $NaOH+AlK(SO_4)_2{\cdot}12H_2O$ activated slag cement system. Therefore, blast furnace slag can be activated by $NaOH+AlK(SO_4)_2{\cdot}12H_2O$.

Does $N_2O$ react over oxygen vacancy on $TiO_2$(110)?

  • Kim, Bo-Seong;Kim, Yu-Gwon;Li, Z.;Dohnalek, Z.;Kay, B.D.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.196-196
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    • 2011
  • Molecular $N_2O$ has bee known to react over oxygen vacancy on a reduced rutile $TiO_2$(110)-1${\times}$1 surface to desorb as molecular $N_2$ leaving oxygen atom behind. In the present study, we investigated the reaction of $N_2O$ on rutile $TiO_2$(110) using temperature-programmed desorption (TPD). Our results indicate that $N_2O$ does not react over the oxygen vacancy under a typical UHV experimental condition. On a rutile $TiO_2$(110)-1${\times}$1 with a well-defined oxygen vacancy concentration of 5% ($2.6{\times}10^{13}/cm^2$), $N_2O$ desorption features show a monolayer peak maximum at 135 K followed by a small peak maximum at 170 K. When the oxygen vacancy is blocked with $H_2O$, the $N_2O$ peak at 170 K disappears completely, indicating that the peak is due to molecular $N_2O$ interacting with oxygen vacancy. The integrated amount of desorbed $N_2O$ plotted against the amount of adsorbed $N_2O$ however shows a straight line with no offset indicating no loss of $N_2O$ during our cycles of TPD measurements. In addition, our $N_2O$ uptake measurements at 70~100 K showed no $N_2$ (as a reaction product) desorption except contaminant $N_2$. Also, $H_2O$ TPD taken after $N_2O$ scattering up to 350 K indicates no change in the vacancy-related $H_2O$ desorption peak at 500 K showing no change in the oxygen vacancy concentration after the interaction with $N_2O$.

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Oxygen Ring Formation Reaction of Mono-Oxo Bridged Binudear Molybdenum (Ⅴ) Complex (Ⅲ). Reaction of $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ with solvent Water in Binary Aqueous Mixtures (한개의 산소다리를 가진 몰리브덴(V) 착물의 산소고리화 반응 (제 3 보). 2 성분 혼합용매에서 용매물과 $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$의 반응)

  • Sang Oh Oh;Huee Young Seok
    • Journal of the Korean Chemical Society
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    • v.32 no.6
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    • pp.528-535
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    • 1988
  • The rates of oxygen ring formation of $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ have been investigated spectrophotometric method in binary aqueous mixtures. Temperature was $20^{\circ}C$ to $40^{\circ}C$ and pressure was varied up to 1500 bar. The observed rate constants are increased by hydrogen ion and decreased by thiocyanate. The more increasing of co-solvents dielectric constant, the more stable intermediate is formed. The observed rate constant is given by, $k_{obs}^{-1} = k^{-1} (1 + K^{-1}[H_2O]^{-1}) All activation parameters are positive values. The oxygen ring formation of [Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ is believed to be a interchange-dissociative mechanism..

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Removal CO2 Using Na2CO3, K2CO3 and Li2CO3 Impregnated Activated Carbon -Characteristics of CO2 Adsorption in Fixed Bed Reactor- (Na2CO3, K2CO3 및 Li2CO3 첨착활성탄을 이용한CO2 제거 -고정층 반응기에서의 CO2 흡착특성-)

  • Choi, Won-Joon;Jung, Jong-Hyeon
    • Journal of Environmental Health Sciences
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    • v.34 no.3
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    • pp.240-246
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    • 2008
  • The purpose of this study was to gain basic information on the characteristics of $CO_2$ adsorption in relation to $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon in a Fixed Bed Reactor. From the results of this study the following conclusions were made: $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon had a longer breakthrough time and more enhanced adsorption capacity than activated carbon alone. When tested with isothermal adsorption and tested for $CO_2$ adsorption the amount of $CO_2$ adsorbed varied with temperature, $CO_2$ inlet concentration, gas flow rate, aspect ratio, etc. Based on the results, when Langmuir, Freundlich and Dubinin-Polanyi adsorption isotherms were used for linear regression of isothermal adsorption data, Langmuir adsorption isotherm was the most suitable. And, the optimum condition for $Na_2CO_3$ and $K_2CO_3$ impregnated activated carbon make-up was 1N and $Li_2CO_3$ was 0.1N. It could be concluded that adsorption capacity was decreased with adsorption temperature and increased gas concentration. When the aspect ratio (L/D) was varied 0.5, 1.0 and 2.0, the significant drop of adsorption amount was observed below 1.0 and breakthrough time was shortened with gas flow rate.

Measurement of Melting Temperatures of $UO_2,\;(U,Gd)O_2\;and\;(U,Er)O_2$ Fuels

  • Kang Ki Won;Yang Jae Ho;Kim Keon Sik;Kim Jong Hun;Lee Young Woo;Song Kun Woo
    • Nuclear Engineering and Technology
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    • v.36 no.1
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    • pp.104-111
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    • 2004
  • The melting temperatures of $UO_2,\;UO_2-6wt\%Gd_{2}O_3,\;UO_2-12wt\%Gd_{2}O_3,\;UO_2-2wt\%Er_{2}O_3,\;and\;UO_2-4wt\%Er_{2}O_3$ fuels were measured. Fuel materials were loaded in a tungsten capsule of which shape met the black body condition. The melting temperature was measured by the thermal arrest method during heating of the capsule in an induction furnace. The measured melting temperature of $UO_2$ fuel was $2815{\pm}20^{\circ}C$. The solidus and liquidus temperatures of $UO_2-Gd_{2}O_3\;and\;UO_2-Er_{2}O_3$ had also been measured, and it was observed that the solidus temperatures of them were lower than the liquidus temperature by $15{\sim}25^{\circ}C$. Measured melting temperatures of $UO_2,\;UO_2-Gd_{2}O_3\;and\;UO_2-Er_{2}O_3$ fuels were as follows:

Fabrication of engineered tunnel-barrier memory with $SiO_2/HfO_2/Al_2O_3$ tunnel layer ($SiO_2/HfO_2/Al_2O_3$ 적층구조 터널링 절연막을 적용한 차세대 비휘발성 메모리의 제작)

  • Oh, Se-Man;Park, Gun-Ho;Kim, Kwan-Su;Jung, Jong-Wan;Jeong, Hong-Bae;Cho, Won-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.129-130
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    • 2009
  • The P/E characteristics of $HfO_2$ CTF memory capacitor with $SiO_2/HfO_2/Al_2O_3$(OHA) engineered tunnel barrier were investigated. After a growth of thermal oxide with a thickness of 2 nm, 1 nm $HfO_2$ and 3 $Al_2O_3$ layers were deposited by atomic layer deposition (ALD) system. The band offset was calculated by analysis of conduction mechanisms through Fowler-Nordheim (FN) plot and Direct Tunneling (DT) plot. Moreover the PIE characteristics of $HfO_2$ CTF memory capacitor with OHA tunnel barrier was presented.

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A PRELIMINARY STUDY FOR STANDARDIZATION OF THE MAYSI-2K (MASSACHUSETTES YOUTH SCREENING INSTRUMENT-2 KOREAN) IN KOREAN DELINQUENT YOUTHS (한국형 비행 청소년 정신병리 선별척도인 MAYSI-2K (Massachusettes Youth Screening Instrument-2 Korean)의 표준화를 위한 예비연구)

  • Yi, Ji-Hyun;Lee, Hae-Kook;Lee, Chung-Tai;Kim, Sun-Kyung;Kweon, Yong-Sil
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.14 no.2
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    • pp.238-246
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    • 2003
  • Objectives:Mental health problems have been found to be more common among juvenile delinquents. This report assessed the reliability, and validity of the MAYSI-2K(Massachusettes Youth Screening Instrument-2 Korean) in Korean delinquents to examine the utility as a screening measure. Methods:The study consisted of 119 male juvenile youths(mean age 16) who admitted in the probation & detention office. They completed an assessment battery including MAYSI-2K and K-YSR(Korean-Youth Self Report) upon entry. Factor analysis, reliability test, and validity test were conducted. Results:The results of factor analysis represented 14 factors which showed more factor structures in comparison with published factor loadings of 7 in the MAYSI. In factor analysis according to the each subscale of the MAYSI, the internal coefficients of 7 subscales ranged from .142 to .756. Test-retest reliability revealed significant correlations(r= .84). There were significant correlations among subscales of MAYSI-2K and K-YSR. Conclusion:Our findings suggested that MAYSI-2K might be a useful screening measure. But further studies with extended number of subjects and culturally appropriate items are required for clinical utility of the MAYSI-2K in Korean delinquents.

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Topological Properties of Recursive Circulants : Disjoint Cycles and Graph Invariants (재귀원형군의 위상 특성 : 서로소인 사이클과 그래프 invariant)

  • Park, Jeong-Heum;Jwa, Gyeong-Ryong
    • Journal of KIISE:Computer Systems and Theory
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    • v.26 no.8
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    • pp.999-1007
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    • 1999
  • 이 논문은 재귀원형군 G(2^m , 2^k )를 그래프 이론적 관점에서 고찰하고 정점이 서로소인 사이클과 그래프 invariant에 관한 위상 특성을 제시한다. 재귀원형군은 1 에서 제안된 다중 컴퓨터의 연결망 구조이다. 재귀원형군 {{{{G(2^m , 2^k )가 길이 사이클을 가질 필요 충분 조건을 구하고, 이 조건하에서 G(2^m , 2^k )는 가능한 최대 개수의 정점이 서로소이고 길이가l`인 사이클을 가짐을 보인다. 그리고 정점 및 에지 채색, 최대 클릭, 독립 집합 및 정점 커버에 대한 그래프 invariant를 분석한다.Abstract In this paper, we investigate recursive circulant G(2^m , 2^k ) from the graph theory point of view and present topological properties of G(2^m , 2^k ) concerned with vertex-disjoint cycles and graph invariants. Recursive circulant is an interconnection structure for multicomputer networks proposed in 1 . A necessary and sufficient condition for recursive circulant {{{{G(2^m , 2^k ) to have a cycle of lengthl` is derived. Under the condition, we show that G(2^m , 2^k ) has the maximum possible number of vertex-disjoint cycles of length l`. We analyze graph invariants on vertex and edge coloring, maximum clique, independent set and vertex cover.

Slow-Cooling Calcination Process to Potassium Tetratitanate and Potassium Hexatitanate Fibers (서냉소성법에 의한 사티탄산칼륨 및 육티탄산칼륨 섬유의 합성)

  • 최진호;한양수;송승완
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.664-670
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    • 1993
  • Potassium tetratitanate (K2Ti4O9) and Potassium hexatitanate (K2Ti6O13) fibers have been prepared by the slow-cooling calcination process in a temperature range from 125$0^{\circ}C$ to 95$0^{\circ}C$ using the K2CO3 and TiO2 as the starting materials. Optimum fiber growth conditions have been also investigated by changing the physical parameters, such as calcination time and temperature, and cooling rate. Relatively long K2Ti4O9 fibers ( 1.2mm) have been grown with quite a high aspect ratio (c/a 500)when the starting material with a nominal composition of K2O and TiO2 with 1:4 was calcined at 115$0^{\circ}C$ for 4h, and then was slowly cooled to 95$0^{\circ}C$ with a rate of 2$0^{\circ}C$/h. In case of a K2O.6TiO2 composition, acicular shaped K2Ti6O13 fibers with 20~300${\mu}{\textrm}{m}$ long and low aspect ratio (c/a 10~15) have been formed irrespective of the coolign rate. The growth condition of fibers have been discussed based upon the phase diagram of K2O-TiOa2.

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