• Journal of Korean Society of Environmental Engineers
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• v.32 no.5
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• pp.443-454
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• 2010

Phthalate compounds are widely used as plasticizers in polyvinyl chlororide (PVC) resins and other industrial consumer products, and some of them are known to be endocrine disruptors. In Korea, a number of studies have been carried out for the measurement of phthalates in consumer products and drinking water. However, no data are available for those compounds in the ambient air where the general public are routinely exposed. In this study, we evaluated sampling and analytical methods for the determination of phthalates in the ambient atmosphere. A wide range of phthalates compounds were included in the target analytes, which are dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), butyl benzyl phthalate (BBP), di(2-ethylhexyl) phthalate (DEHP), and di-n-octyl phthalate (DOP). Most of samples were collected using a high volume sampler with a PUF/XAD-2 column/quartz fiber filter and then analyzed by GC/MS. Some of samples were simultaneously collected on XAD-2 using a low-volume sampler, together with high-volume samples. The analytical method applied in this study showed good repeatability and linearity. Quantitative detection limits were estimated from 0.60 to 17.84 ng/$m^3$ in air, depending on individual compounds. The field measurements were carried out at 3 sites located in Sihwa- Banwall industrial areas and a suburban area from January 2007 to November 2007. From the field experiments, DEHP, DMP and DBP appeared to be the most abundant compounds in the ambient air. It was also found that DMP, DEP and DBP were mainly distributed in the vapor phase, while BBP, DEHP and DOP were predominantly associated with the particulate phase. The concentrations of DEHP and DMP in the industrial areas ranged from 45.7 to 1,012.7 ng/$m^3$ and from 7.7 to 375.1 ng/$m^3$, respectively. Overall, the high-volume sampling method was demonstrated to be superior to the low-volume method for the determination of phthalates in the ambient atmosphere.

• Membrane Journal
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• v.27 no.5
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• pp.458-467
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• 2017

In this study, we prepared PVDF membranes via TIPS for water treatment applications. PVDF was used for its excellent chemical and mechanical properties. The effect of coagulation bath composition, temperature, and heat capacity on the overall membrane morphology was studied and observed using SEM. A mixture of DOP and DBP was used as the diluent, and silica was used as an additive. It was observed that as the heat capacity of the coagulation bath increased, the crystallization rate of PVDF decreased yielding larger pores. Also, as the heat capacity of the coagulation bath decreased, the crystallization rate of PVDF increased yielding smaller pores.

• Microbiology and Biotechnology Letters
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• v.36 no.2
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• pp.128-134
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• 2008

In order to examine efficient L-threo-2,3-Dihydroxyphenylserine (L-threo-DOPS) synthesis process using whole cell biocatalyst, a thermostable L-threonine aldolase (L-TA), which cloned from Streptomyces coelicolor A3(2) and improved for stability, was expressed in a Corynebacterium glutamicum R strain. The constructed Corynebacterium expression vector, pCG-H44(1) successfully expressed L-TA in C. glutamicum R strain, but showed very low expression level. In order to improve the expression level, the expression vector named pCG-H44(2) was reconstructed by eliminating 1 nucleotide between SD sequence and start codon of L-TA. The pCG-H44(2) vector plasmid was able to overexpress L-TA approximately 3.2 times higher than pCG-H44(1) in C. glutamicum R strain (CGH-2). When the whole cell of CGH-2 was examined in a repeated batch system, L-threo-DOPS was successfully synthesized with a yield of 4.0 mg/ml and maintain synthesis rate constantly after 30 repeated batch reactions for 130 h.

• Korean Chemical Engineering Research
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• v.45 no.4
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• pp.410-413
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• 2007

The effect of internal donor(ID) in the heterogeneous Ziegler-Natta catalyst on the ethylene-1-butene copolymerization and the molecular structure of the resulting copolymer was investigated. $SiO_2$-supported $TiCl_4$ catalysts having ID/Ti molar ratio of 0.5 were prepared with ethyaluminium dichloride, magnesium alkyl, 2-ethyl-1-hexanol and $TiCl_4$. Three different IDs were employed such as ethylbenzoate(EB), diisobuylphthalate(DIBP) and dioctylphthalate(DOP). ID-added catalyst showed a larger fraction of Ti(+3) compared to that of no ID-added catalyst. The EB-added catalyst showed the highest activity in copolymerization. Xylene soluble value decreased by more than 50 % with ID-added catalysts compared to that of no ID-added catalyst. Crystaf analysis showed the chemical compositional distribution of PE copolymer was improved in the case of DIBP-added catalyst significantly. It could be explained that the presence of ID could make more even active sites and block the non-stereospecific active sites.

• Archives of Pharmacal Research
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• v.21 no.6
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• pp.782-784
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• 1998

Ginseng total saponin (GTS) can modulate dopaminergic activity at both presynaptic and postsynaptic dopamine receptors (Kim et al, 1998). The present study investigated t he effect of GTS on the bovine adrenal tyrosine hydroxylase (TH), which catalyze L/tyrosine to DOP. GTS inhibited the bovine adrenal TH by 42.4, 51.5 and 55.3% at concentrations of 40, 80 and 100${\mu}g$/ml, respectively. The IC50 value of GTS was 77.5${\mu}g$/ml. GTS exhibited noncompetitive inhibition with a substrate L-tyrosine. The Ki value was 155${\mu}g$/ml.

• Proceedings of the Korea Information Processing Society Conference
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• 2017.11a
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• pp.275-278
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• 2017

과거의 가장 흔한 공격이었던 코드 삽입 공격은 방어 기법이 발전함에 따라 점점 어려워지고 있다. 공격자는 코드를 삽입하지 않고도 공격할 수 있는 방법을 찾기 시작하였고, 공격 대상에 존재하는 코드를 연결하여 원하는 동작을 실행하게 만드는 코드 재사용 공격을 하기 시작했다. 코드 재사용 공격을 막는 방어 기법 역시 제안되었지만, 다시 이를 우회하는 발전된 코드 재사용 공격들도 나오면서 공격과 방어를 거듭하고 있다. 본 논문에서는 코드 재사용 공격의 전신인 return into libc 부터 Data Oriented Programming (DOP)까지의 공격과 방어를 정리하고, 코드 재사용 공격이 발전되는 과정을 살펴보는 것을 목표로 한다.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.1015-1017
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• 2003

Recently, DGPS or RTK-GPS techniques enable us to use satellite based positioning systems with high accuracy. But in urban area, navigation systems suffer from problems such as signal blockage by high-rise buildings, multi-path problems, and so on. So we have to know numbers of visible satellites and quality of signals received at the ground level in urban area as accurate as possible. In this paper, we developed a simulation system called LoQAS [Location service Quality Assessment System, 2002, the University of Tokyo] which can simulate numbers of visible satellites and DOP values using accurate satellite orbital data and 3-D digital map. In this time, we evaluated this system and extended it to deal with reflected signals to assess multi-path problems.

• Textile Coloration and Finishing
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• v.17 no.2 s.81
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• pp.40-45
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• 2005

Electret filter is good enough to protect health and environment from air pollution. The reason why is gathering particles not only by mechanical mechanism but also by electrostatic attraction. Especially this filter is shown lower pressure drop than general mechanical filters as glass fiber. For making electret filter media using polypropylene meltblown(M/B) nonwoven, the nonwoven is charged with corona which was supplied high voltage DC, AC, and pulse with DC power. The electret filter media is tested with $0.3{\mu}m$ sodium chloride and dioctyl phthalate(DOP) aerosol. Results revealed that filtration performance of electret filter media increased as corona was applied with higher voltage and with AC power rather than DC, and fiber diameter was fine and uniform.

• 제어로봇시스템학회:학술대회논문집
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• 2000.10a
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• pp.476-476
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• 2000

This paper deals with an estimation method far sideslip angle by using an unknown input observation technique in 4WS passenger car systems. Firstly, a 4WS vehicle model with 3DOP is derived under the constant velocity and same tyre's properties. The induced model is transformed into the linear state space model with considering the external disturbance. Secondly, an unknown input observer is introduced and its property which estimating the states of system without any disturbance information is shown. Lastly, the estimated sideslip angle of the 4WS system is verified through numerical simulation.

• Proceedings of the IEEK Conference
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• 2002.07c
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• pp.1610-1613
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• 2002

This paper analyses the performance of PE-IPDL technique fer the wireless mobile position location, which have been considered as a major candidate for 3GPP position location due to its capability in mitigating the hearability problem and DOP problem. To improve the location performance of PE-IPDL, this paper introduces the high-resolution estimation technique for the first arrival multipath delay, and simulation results verify its superiority. For a systematic analysis of above location method, its performances are exploited by obeying the CODIT channel model specially bad urban channel environment. Simulation results verify its efficiency of enhancing the degree of accuracy in positioning.