• Title/Summary/Keyword: K feldspar

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Polymetamorphism of the Odesan Gneiss Complex in the Northeastern area of the Kyonggi Massif, Korea (경기육괴 북동부지역에 분포하는 오대산편마암복합체의 다변성작용)

  • 권용완;김형식;오창환
    • The Journal of the Petrological Society of Korea
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    • v.6 no.3
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    • pp.226-243
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    • 1997
  • The Odesan Gneiss Complex consists of mainly migmatitic gneiss and porphyroblastic gneiss with locally intercated quartzite, amphibolite, marble and leucocratic gneiss. At least two different regional metamorphisms are recognized in the study area. Metamorphic grade of the first metamorphism increases from the K-feldspar-muscovite zone(in which biotite-muscovite-plagioclase-quartz and garnet-biotite-muscovite-K-feldspar-plagioclase-quartz assemblages occur) in the east and southwestern part of the study area to the K-feldspar-garnet zone(in which garnet-biotite-K-feldspar-plagioclase-quartz, biotite-K-feldspar-plagioclase-quartz, garnet-biotite-K-feldspar-plagioclase-sillimanite-spinel-quartz assemblages occur) in the northwestern part. Kyanite is found as inclusions in plagioclase. The second metamorphism is characterised by occurrence of cordierite. The metamorphic grade of 2nd metamorphism decreases radically from the central-western part near Gaeinsan in which cordierite-garnet-sillimanite-biotite-muscovite-quartz, cordierite-garnet-spinel-sillimanite-biotite-muscovite-quartz assemblages representing the garnet-cordierite zone are observed. The garnet-cordierite zone is surrounded by the sillimanite-cordierite zone which shows cordierite-sillimanite-biotite-plagioclase, cordierite-muscovite-biotite-plagioclase and sillimanite-muscovite-biotite-plagioclase assemblages. The peak metamorphic P-T conditions of the first metamorphism calcuted from garnet-biotite-sillimanite-K-feldspar-plagioclase-spinel assemblage are 5.4~7.4 kb and $776-789^{\circ}C$. Real P-T condition of the first metamorphism might be higher than the calcuated P-T condition according to the study based on the phase equilibria. P-T conditions calcuated from the garnet-biotite in plagioclase are 12.5kb and $650^{\circ}C$ which indicate that the P-T path of the first metamorphism had passed a high pressure condition before the peak metamorphic temperature condition. The peak metamorphic P-T conditions of the second metamorphism calcuated from garnet-biotite-cordierite-spinel-quartz assemblage are $680~750^{\circ}C$ at pressures lower than 6 kb. In the Odesan Gneiss Complex, the first metamorphism of medium pressure and high temperature had occurred after the high pressure condition and fast uplift and then the second metamorphism of low pressure condition occurred after sedimentation of the Kuryong Group.

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A Study on the Hydrothermal Synthesis of Clay Mineral(I) Hydrothermal Treatment of the Weathered Two-Mica Granite in Kang Wha district of Korea (수열반응에 의한 인공점토의 합성연구(I) 강화도산 백운모질 풍화 화강암의 수열처리)

  • 이응상;이상훈
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.71-82
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    • 1995
  • The weathered two-mica granite is widely distributed in Korea and called a kind of ground rock for kaolin. The major minerla compositions are consist of this quartz, feldspar, mica and clay mineral. At present, only a small portion of this granite is used as the material for the low-grade tile industry due to the low S.K. value and the high contents of impurities such as Fe2O3 and FeO. The low S.K. value is caused by feldspars not weathered to clay minerals. The refinement of this thus has been required for the recent shortage of the resources of high-grade one. This paper concerns an optimum hydrothermal treatment condition to refine the low-grade weathered two-mica granite of which impurities are feldspar mineral and Fe2O3. FeO components in using for the main material of ceramic industry. And then, from this result, we tried to fine out the basic formation mechanism of clay mineral from feldspar etc and develope the effectual utilization method of this.

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Impact deformation of Feldspar in Achondrite: NWA 2727, NWA 3117, NWA 856 Meteorite

  • LEE, Jaeyong;FAGAN, Timothy J.
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.73.1-73.1
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    • 2018
  • We investigated shock history of three achondrite meteorites: NWA 3117, a howardite from asteroid Vesta, NWA 2727, a breccia from the Moon, and NWA 856, a shergottite from Mars. Shock histories were evaluated from deformation of plagioclase feldspars. Feldspar grains were classified based on observations in cross-polarized light as undulatory, mosaic, mosaic-recrystallized or maskelynite. This sequence represents increasing deformation of original feldspar crystals. Undulatory crystals have wavy extinction, mosaic crystals have patchy extinction, and mosaic-recrystallized grains appear as if they were originally coarse-grained and have recrystallized to mosaics of small equant crystals. Maskelynite grains are isotropic, indicating transformation to glass. Based on feldspar deformation, the degrees of impact processing are NWA 856 > NWA 3117 > NWA 2727. The high deformation of NWA 856 is expected because this sample is from Mars, which is a large parent body and requires a powerful impact to accelerate a rock to escape velocity. In contrast, the parent body of NWA 3117 (Vesta) is smaller than that of NWA 2727 (the Moon), yet NWA 3117 appears more highly deformed than NWA 2727. One possible explanation is that NWA 2727 is from a relatively young part of the Moon, which has not been exposed to impacts as long as the surface of Vesta.

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Synthesis of Analcime by Treating of Domestic Feldspar (국산 장석으로부터의 Analcime합성)

  • 김면섭
    • Journal of the Korean Ceramic Society
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    • v.14 no.1
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    • pp.7-11
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    • 1977
  • Domestic Anyang feldspar was treated in autoclave with 1N sodium hydroxide solution for 1-6 hrs at 100-20$0^{\circ}C$ By X-ray diffraction patterns and cation exchange capacity, the products were examined. The following concecutive reaction was valid. AlbitelongrightarrowAmorphous aluminosilicatelongrightarrowAnalcime The reaction rate constants, k1 and k2, were 0.20 and 0.15(1/hr) at 20$0^{\circ}C$ respectively. The activiation energy from albite to amorphous aluminosilicate was 10 kcal/mol, and from amorphous aluminosilicate to analcine 13 kcal/mol. The analcime obtained was excellent in cation exchange capacity, amounting to 210meq./100g.

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Study on Fluid Inclusion and Genetic Modelling of Pegmatites at the Maewol Feldspar Mine (매월장석광산(梅月長石鑛山)의 페그마타이트내(內) 유체포유물(流體包有物)과 그 성인(成因)에 관한 모델 연구)

  • Moon, Kun Joo
    • Economic and Environmental Geology
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    • v.21 no.4
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    • pp.381-387
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    • 1988
  • Maewol Feldspar Mine produces feldspar ore from pegmatites. K-Rb Age of muscovite is 137.7Ma. Fluid inclusions in quartz crystal of the pegmatite show bimodal distribution of homogenization temperatures. The high homogenization temperatures range from 290 to $302^{\circ}C$ while low homogenization temperatures range from 157 to $195^{\circ}C$. Three phases liquid $CO_2$ bearing inclusions indicate $CO_2$ gases were abundantly mixed with granitic melt until the pegmatic magma melt cooled to $290^{\circ}C$. Low density of the magmatic melt relative to the same volume of granitic magma is due to mixture of volatiles(mainly $CO_2$ gases) with the melt and larger space and slow cooling allowed to grow crystals of the pegmatic magma.

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An Experimental Study for Strength Improvement of Soft Ground using Hardening Agent and Silicate Mineral Power (수용성 고화재와 규산염광물 결합재를 활용한 지반개량재의 실험적 연구)

  • Kim, Sung-Wook;Choi, Eun-Kyeong;Cho, Jinwoo;Lee, JuHyung;Lee, Kyu-Hwan
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.4
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    • pp.8-15
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    • 2015
  • The demand for environmental consideration is on the increase in civil engineering. This study focuses on the development of technology to reduce the use of carbonate cement and improve its performance by using a silicate mineral and hardening agents, and presents the test results for the demonstrative evaluation of the properties of the raw material. Highly active feldspar was used as a binder to augment the bonding of the carbonate cement, and their change in strength was observed after test piece construction with the addition of soluble hardening agent. The uniaxial compression strength of the test piece of the general Portland cement with the addition of 0.5% soluble hardening agent, showed an increase by 33% and that of the test piece of cement with the addition of 70% substituted with feldspar increased by 28%. The strength of viscous soil; classified as soft ground, showed an increase of a maximum of 1.7 times when it was mixed with cement and solidifier depending on the curing period. These tests confirmed that a soluble solidifier is effective for improving the strength of a cement binder and that the highly active feldspar can be used as a binder.

Petrogeochemistry of Granitic Rocks Distributed in the Geumsan District, Korea (금산지역에 분포하는 화강암류의 암석지구화학)

  • Chin, Ho-Ill;Min, Kyoung-Won;Chon, Hyo-Taek;Park, Young-Seog
    • Economic and Environmental Geology
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    • v.28 no.2
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    • pp.123-137
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    • 1995
  • The Mesozoic Geumsan granitic rocks of various composition are distributed in the Geumsan district, the central part of the Ogcheon Fold Belt. About 40 ore deposits of $CaF_2{\pm}Au{\pm}Ag{\pm}Cu{\pm}Pb{\pm}Zn$ are widely distributed in this district and are believed to be genetically related to the granitic rocks. Based on their petrography and geochemistry, the granitic rocks in this district can be classified into two groups ; the Group I( equigranular leucocratic granite, porphyritic biotite granite, porphyritic pink-feldspar granite, seriate leucocratic granite) and the Group II(seriate pinkfeldspar granite, equigranular alkali-feldspar granite, equigranular pink-feldspar granite, miarolitic pink-feldspar granite, equigranular biotite granite). Interpreted from their isotopic dating data and geochemical characteristics, the Group I and the Group II are inferred to be emplaced during the Jurassic(~184Ma), and the Cretaceous to the early Tertiary period(~59Ma), respectively. Both Group I and Group II generally belong to magnetite-series granitoids. The Cretaceous granitic rocks of Group II are more highly evolved than those of the Jurassic Group I. The Rb-Sr variation diagram suggests that the granitic rocks of the Jurassic Group I and of the Cretaceous Group II be evolved mainly during the processes of fractional crystallization and partial melting, respectively.

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The Micostructural Change During the Mylonitzation of Cheongsan Granite, Korea (청산화강암의 압쇄암화작용 동안에 미구조 변화)

  • Kang, Ji-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.24 no.2
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    • pp.125-139
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    • 2015
  • Rock structural and microstructural analyses on the deformed Cheongsan granite, which is characterized by abundant feldspar megacrystals, have been carried out to understand the microstructural change during the mylonitization by ductile shear deformation. In K-feldspars, the characteristic microstructures are recognized as microkinks, microfractures, myrmekites, flame perthites, and core-and-mantle structures without the development of subgrains in outer core-zone. Microkinks are observed in both the microfractured and unmicrofractured K-feldspars and the directions of their axes are generally extended across the adjacent K-feldspar fragments bounded by microfractures. Myrmekites and flame perthites are found on the strain-localized boundaries of the microfractured K-feldspars. In plagiclases, microfractures, deformation twins and kink bands are predominant. Grain size reduction of plagioclase megacrysts also occurs by microfracturing but the core-and-mantle structures like the case of K-feldspars are uncommon in the microfractured plagioclases. The deformation twins, which overlap the igneous zoning structures, are often found in less deformed rocks. The twin lamellae in more deformed rocks generally bisect the obtuse angles of conjugate kink-band boundaries, and are microfractured or microfaulted and randomly oriented. From such characteristic microstructures, thus, it can be suggested that the micostructures during the mylonitzation of Cheongsan granite was developed as follows: production of microkinks in the K-feldspar megacrysts and of deformation twins and kink bands in the plagioclase megacrysts, and then grain-size reduction of the feldspar megacrysts through microfracturing, and then production of core-and-mantle structures (grain-size reduction of the microfractured K-feldspars through grain boundary migration), myrmekites and flame perthites in the microfractured K-feldspars.

Leucite Synthesis from Solid-State Sintering (고상법에 의한 Leucite 합성)

  • Yoon, Dong-Sup;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.282-286
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    • 2005
  • Leucite crystal has been utilized for dental porcelain due to its high thermal expansion coefficient to meet its counter metal side. Many industrial applications of leucite from the incongruently melting of potassium feldspar are used and its minimum temperature of crystallization is $1150^{\circ}C$. This study aimed to get leucite crystal from lower temperature through congruently melting, and the starting materials are taken from K-feldspar mainly, and aluminum hydroxide and potassium carbonate are additionally supplied to meet stoichiometry of leucite. We report that the leucite crystal can be synthesized in congruently melting from the temperature $950^{\circ}C$ through solid-state sintering with k-feldspar, potassium carbonate and aluminum hydroxide.

Antirapakivi Mantled Feldspars from Sanbangsan Trachyte Lava Dome, Jeju Volcanic Field, Korea (산방산용암돔 조면암에서 산출되는 장석의 안티라파키비 조직)

  • Yun, Sung-Hyo
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.2
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    • pp.87-97
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    • 2020
  • The compositions of the phenocrystic feldspars of the Sanbangsan trachyte range from labradorite(An53.6) to andesine(An35.4), and of the microphenocrysts and laths range from andesine(An31.2) to oligoclase(An18.7). Mantled feldspar which forms a thin rim around the phenocrysts and microphenocrysts, is anorthoclase(Or20.5An9.4) to sanidine(Or49.2An1.4). Phenocrystic plagioclase, which shows a distinct zonal structure, represents an oscillatory zoning in which the An content of the zone repeatedly increases or decreases between andesine (An39.3) and labradorite (An51.3) from the core toward the rim, and the rim of the phenocrysts is surrounded by alkali feldspar(Or31.9-39.4Ab63.2-57.0An4.9-3.7), showing the antirapakivi texture. Microphenocryst which does not represent the antirapakivi texture, shows the normal zoning with a decreasing An content (An36.4→An25.6) as it moves outward from the center of a crystal. As a result of X-ray mapping of K, Ca, and Na elements for the feldspar phenocrysts representing the typical zonal structure, shows the oscillatory zoning that six zones show the distinctive compositional differences, and the rims are mantled by alkali feldspar to indicate the antirapakivi texture. The groundmass is composed of K-enriched, Ca-poor alkali feldspar. The antirapakivi texture of feldspar which appears in Sanbangsan trachyte, may have been formed in mixing systems as a result of the juxtaposition of near liquidus melt, rich in alkali feldspar components(trachytic magma), with plagioclase phenocrysts and microphenocrysts already crystallized in a more mafic system.