• Title/Summary/Keyword: Janus Particles

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Generation of Janus particles smaller than 10-${\mu}$m in diameter (직경 10-${\mu}$m 이하의 야누스 입자 생성)

  • Ahn, Sang-Hoon;Yoo, Jung-Yul
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.679-682
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    • 2008
  • The particle which has two different characteristics on both sides is called Janus particle which is emerging as a key material in microscale transport systems. For example, if one hemisphere has polarity and the other does not, then nonpolar sides would attract each other so that a complex cluster is formed. Thus, this fascinating material can be used as an element of twisting ball panel display, complex micro-scale clusters, drug delivery unit, and active detecting beads. The keywords in developing Janus particle are size and uniformity. Former researches solved uniformity but downsizing still remains a problem. There are three methods to generate small size particles in microchannels: co-flowing, cross-flowing, and elongational flows. In this research, we generate Janus particles smaller than 10-${\mu}$m in diameter using elongational flow in microchannels. And we use UV initiator with Hydrogen UV source to solidify micro size particles. One hemisphere of the particle is coated with rhodamin for visualization.

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Attachment Energy of Janus Particles at Fluid-Fluid Interfaces (유체 계면에서 야누스 입자의 흡착 에너지)

  • Park, Bum Jun
    • Korean Chemical Engineering Research
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    • v.51 no.6
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    • pp.655-660
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    • 2013
  • In this review, I present the configuration behaviors of various Janus particles at fluid-fluid interfaces. As a model system, Janus spheres, Janus ellipsoids, and Janus dumbbells are selected to investigate the effect of shape, size, and wettability on their configurations. In particular cases, Janus ellipsoids can adopt two distinct configurations (i.e., upright and tilted configurations) due to the presence of two energy minima in the attachment energy profile. On the contrary, a single energy minimum is found in the case of Janus dumbbells such that they adopt either the upright or tilted configuration. Interestingly, the geometric and chemical asymmetry and anisotropy in the characteristic properties of Janus dumbbells lead to an intermediate state in which the particles can rotate freely in a certain range of orientation angles.

Synthesis of Shape Reconfigurable Janus Particles by External pH Stimuli (산세기 조절을 통해 모양 변형이 가능한 야누스 입자의 제조)

  • Eom, Naye;Kim, Jongmin;Kang, Sung-Min;Lee, Chang-Soo
    • Clean Technology
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    • v.20 no.3
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    • pp.226-231
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    • 2014
  • This study presents a micromolding for the synthesis of Janus particles with reconfigurable shape by pH stimuli. First, we use acrylic acid (AA) as pH responsive monomer in the hydrophilic part and trimethylolpropane triacylate (TMPTA) in the hydrophobic part, respectively. The change of acidity in solvent induces the swelling of hydrophilic part in the Janus particles. The pH-responsive Janus particles show different swelling ratio of hydrophilic part in according to composition of acrylic acid in diverse range (0-70% v/v) and pH (3-11). As the concentration of acrylic acid in the hydrophilic part and environmental pH increase, the hydrophilic part in the Janus particles is proportionally swelled. Second, we fabricate novel type of Janus particles with two different hydrophilicities. As a proof of concept, we have applied acrylic acid (AA) and 2-(dimethylamino)ethyl methacrylate (DAEMA) into each part because the monomers provide reverse responsive activity. As expected, these Janus particles show different shape anisotropies with reconfigurable property in accordance with the polarity of each part at same acidity of environmental solvent. We envision that the stimuli responsive Janus particles have a wide application from fundamental science to diagnostic apparatus.

Direct Simulation of the Magnetic Interaction of Elliptic Janus Particles Suspended in a Viscous Fluid (점성유체에 분산된 타원형 야누스 입자의 자성 상호작용에 관한 직접수치해석)

  • Kim, Hei Eun;Kang, Tae Gon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.7
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    • pp.455-462
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    • 2017
  • The magnetic interaction between elliptic Janus magnetic particles are investigated using a direct simulation method. Each particle is a one-to-one mixture of paramagnetic and nonmagnetic materials. The fluid is assumed to be incompressible Newtonian and nonmagnetic. A uniform magnetic field is applied externally in a horizontal direction. A finite-element-based fictitious domain method is employed to solve the magnetic particulate flow in the creeping flow regime. In the magnetic problem, the magnetic field in the entire domain, including the particles and the fluid, is obtained by solving the governing equation for the magnetic potential. Then, the magnetic forces acting on the particles are calculated via a Maxwell stress tensor formulation. In a single particle problem, it is found that the orientation angle at equilibrium is affected by the aspect ratio of the particle. As for the two-particle interaction, the dynamics and the final conformation of the particles are significantly influenced by the aspect ratio, the orientation, and the spatial positions of the particles. For the given positions of the particles, the fluid flow is also influenced by the orientation of each particle. The self-assembly structure of the particles is not a fixed one, but it varies with the above-mentioned factors.

Analysis of Phagocytosis and Birefringence in the Peritoneal Cells of the Rat, with Special Regard to the Mast Cells (흰쥐의 복강내 세포, 특히 비만세포의 식작용 및 복굴절성에 관한 분석)

  • Yung Keun Oh;Hyun Sam Shin;Hyuck Bang
    • The Korean Journal of Zoology
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    • v.12 no.3
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    • pp.69-76
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    • 1969
  • The phagocytic petencies and birefringences of peritoneal mast cells of rats treated with particular dyes (neutral red, toluidine blue, pyronin, methylene blue, alcian blue, trypan blue, carmine, orange G, aniline blue, Janus green B, and India ink) were analyzed by means of phase contrast microscopy and polarizing microscopy. In addition, cytomorphic effects of the dyes on the peritoneal mast cells were also discussed. Phagocytic activities or ingestion of the dye particles were not observed in most cases, except for the India ink group. Hardly a macrophage appeared without some dark particles which were ingested or phagocytosed. Trypan blue and aniline blue produced very weak birefringence in the cytoplasm of mast cells but the rest did not produce even in the acid medium (neutral red and toluidine blue). The short and slender ectoplasmic processes of the mast cells and the leucocytes were also found in certain groups. The cytomorphic effects of the dyes on the mast cell were slight and variable.

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