• Title/Summary/Keyword: J-lead

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Lead Effects among Secondary Lead Smelter Workers with Blood Lead Levels below $80{\mu}g/100\;ml$

  • Lilis Ruth;Fischbein Alf;Diamond Sidney;Anderson Henry A.;Selikoff Irving J.;Blumberg William E.;Eisinger Josef
    • 대한예방의학회:학술대회논문집
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    • 1994.02a
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    • pp.549-559
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    • 1994
  • A subgroup or workers from a secondary lead smelter was defined to include those with blood lead levels not exceeding $80{\mu}g/100\;ml$ and with no pest history of elevated blood lead. Central nervous system symptoms (tiredness, sleeplessness, irritability, headache) were reported by 55% of the group and muscle and joint pain by 39%. Zinc proteporphyrin (ZPP) levels were elevated in 71% or cases. Low hemoglobin levels (less than 14 gm/l00 ml) were round in more than a third of the workers. While BUN and creatinine were mostly in the normal range, there - nevertheless n correlation between ZPP and both BUN and creatinine. Reduced nerve-conduction velocities were present in 25% or the group; this was not significantly different from findings in Ii control group. The data indicate that n blood level of $80{\mu}g/100\;ml$ is an inappropriate biological guide in the prevention or lead disease.

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Utility of solid phase extraction for colorimetric determination of lead in waters, vegetables, biological and soil samples

  • Al-Mallah, Zakia;Amin, Alaa S.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.461-468
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    • 2018
  • A highly sensitive, selective and rapid method for the determination of lead based on the reaction of lead (II) with 5-(4'-chlorophenylazo)-6-hydroxypyrimidine-2,4-dione (CPAHPD) and the solid phase extraction of the Pb(II)-CPAHPD complex with Amberlite XAD-2000 was developed, in the presence of pH 5.6 buffer solution and Triton X-114 medium. CPAHPD reacts with lead to form a violet complex with a molar ratio of 2:1 (CPAHPD to lead). This complex was enriched by the solid phase extraction with Amberlite XAD-2000. An enrichment factor of 500 was obtained by elution of the complex from the resin with a minimal amount of isopentyl alcohol(0.2 mL). In isopentyl alcohol medium,the molar absorptivity of the complex is $1.13{\times}10^6L\;mol^{-1}cm^{-1}$ at 647 nm. Beer's law is obeyed in the range of $5.0-160ng\;mL^{-1}$ in the measured solution. The relative standard deviation for 10 replicate samples of $50ng\;mL^{-1}$ level is 1.26%. The detection and quantification limits reaches 1.5 and $4.7ng\;mL^{-1}$ in the original samples. The presented procedure was successfully applied for determination of lead content in real samples such as vegetables, waters, biological and soil samples with satisfactory results.

Validation of the neutron lead transport for fusion applications

  • Schulc, Martin;Kostal, Michal;Novak, Evzen;Czakoj, Tomas;Simon, Jan
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.959-964
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    • 2022
  • Lead is an important material, both for fusion or fission reactors. The cross sections of natural lead should be validated because lead is a main component of lithium-lead modules suggested for fusion power plants and it directly affects the crucial variable, tritium breeding ratio. The presented study discusses a validation of the lead transport libraries by dint of the activation of carefully selected activation samples. The high emission standard 252Cf neutron source was used as a neutron source for the presented validation experiment. In the irradiation setup, the samples were placed behind 5 and 10 cm of the lead material. Samples were measured using a gamma spectrometry to infer the reaction rate and compared with MCNP6 calculations using ENDF/B-VIII.0 lead cross sections. The experiment used validated IRDFF-II dosimetric reactions to validate lead cross sections, namely 197Au(n, 2n)196Au, 58Ni(n,p)58Co, 93Nb(n, 2n)92mNb, 115In(n,n')115mIn, 115In(n,γ)116mIn, 197Au(n,γ)198Au and 63Cu(n,γ)64Cu reactions. The threshold reactions agree reasonably with calculations; however, the experimental data suggests a higher thermal neutron flux behind lead bricks. The paper also suggests 252Cf isotropic source as a valuable tool for validation of some cross-sections important for fusion applications, i.e. reactions on structural materials, e.g. Cu, Pb, etc.

Development of Progressive Die CAD/CAM System for Manufacturing Lead Frame, Semiconductor (반도체 리드 프레임 제조를 위한 프로그레시브 금형의 CAD/CAM 시스템 개발)

  • Choi, J.-C.;Kim, B.-M.;Kim, C.;Kim, J.-H.;Kim, C.-B.
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.12
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    • pp.230-238
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    • 1999
  • This paper describes a research work of developing computer-aided design of lead frame, semiconductor, with blanking operation which is very precise for progressive working. Approach to the system is based on the knowledge-based rules. Knowledge for the system is formulated from plasticity theories, experimental results and the empirical knowledge of field experts. This system has been written in AutoLISP on the AutoCAD using a personal computer and in I-DEAS Drafting Programming Language on the I-DEAS Master Series Drafting with Workstation, HP9000/715(64) and tool kit on the ESPRIT. Transference of data among AutoCAD, I-DEAS Master Series Drafting, and ESPRIT is accomplished by DXF(drawing exchange format) and IGES(initial graphics exchange specification) methods. This system is composed of six modules, which are input and shape treatment, production feasibility check, strip-layout, die-layout, modelling, and post-processor modules. The system can design process planning and Die design considering several factors and generate NC data automatically according to drawings of die-layout module. As forming process of high precision product and die design system using 2-D geometry recognition are integrated with technology of process planning, die design, and CAE analysis, standardization of die part in die design and process planning of high pression product for semiconductor lead frame is possible to set. Results carried out in each module will provide efficiencies to the designer and the manufacturer of lead frame, semiconductor.

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Optimal Communication Channel Scheduling for Remote Control of Lead Vehicle in a Platoon (군집 선행차량의 원격제어를 위한 통신 채널의 최적 스케줄링)

  • 황태현;최재원
    • Journal of Institute of Control, Robotics and Systems
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    • v.9 no.12
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    • pp.969-976
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    • 2003
  • A remote control strategy for vehicles in Intelligent Vehicle Highway System (IVHS) is considered. An optimal scheduling of a limited communication channel is proposed for lead vehicle control in a platoon. The optimal scheduling problem is to find the optimal communication sequence that minimizes the cost obtained inherently by an optimal control without the communication constraint. In this paper, the PID control law which guarantees the string stability is used for the lead vehicle control. The fact that the PID control law is equivalent to the approximately linear quadratic tracker allows to obtain the performance measure to find an optimal sequence. Simulations are conducted with five maneuvering platoons to evaluate the optimality of the obtained sequence.

Study of Multi-Step Current Lead (다단 전류도입선 해석)

  • Moon, J.S.;Seol, S.Y.
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.379-384
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    • 2000
  • High-Tc superconducting current leads with multi-step and continually varied cross-sectional area are studied to reduce heat leak into cryostat and material use. Assuming conduction-cooled lead the cross-sectional area is reduced along the heat flow direction according to the increase of critical current density which increases with decreasing temperature. In this study, we also analyze the multi-step cross-sectional area High-Tc current leads. The multi-st데 current leads changes the cross-sectional area to have constant safety-factor at changed section. The heat leak into cryostat, total voume, safety-factor and the temperature profiles are compared to those of the constant safety-factor current leads. The developed methods are applied to the Bi-2223 superconductor sheathed with Ag-Au alloy.

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Effects of the nonlinear behavior of lead-rubber bearings on the seismic response of bridges

  • Olmos, B.A.;Roesset, J.M.
    • Earthquakes and Structures
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    • v.1 no.2
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    • pp.215-230
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    • 2010
  • The main objectives of this work were to investigate the effects of the nonlinear behavior of the isolation pads on the seismic response of bridges with rubber bearings, and to identify when base isolation improved their seismic performance. To achieve these objectives a parametric study was conducted designing a set of bridges for three different soil types and varying the number of spans, span lengths, and pier heights. The seismic responses (accelerations, displacements and pier seismic forces) were evaluated for three different structural models subjected to three earthquakes with different dynamic characteristics. The first represented bridges without base isolation; the second corresponded to the same bridges including now rubber bearings as an isolation system, with linear elastic behavior that shifted the natural period of the bridge by a factor of 2 to 4. In the third model the seismic response of bridges supported on lead-Rubber bearings was studied accounting for the nonlinear behavior of the lead. The results show clearly the importance of the nonlinear behavior on the seismic performance of the bridges.

Estimation of Lead Exposure Intensity by Industry Using Nationwide Exposure Databases in Korea

  • Koh, Dong-Hee;Park, Ju-Hyun;Lee, Sang-Gil;Kim, Hwan-Cheol;Jung, Hyejung;Kim, Inah;Choi, Sangjun;Park, Donguk
    • Safety and Health at Work
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    • v.12 no.4
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    • pp.439-444
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    • 2021
  • Background: In a previous study, we estimated exposure prevalence and the number of workers exposed to carcinogens by industry in Korea. The present study aimed to evaluate the optimal exposure intensity indicators of airborne lead exposure by comparing to blood lead measurements for the future development of the carcinogen exposure intensity database. Methods: Data concerning airborne lead measurements and blood lead levels were collected from nationwide occupational exposure databases, compiled between 2015 and 2016. Summary statistics, including the arithmetic mean (AM), geometric mean (GM), and 95th percentile level (X95) were calculated by industry both for airborne lead and blood lead measurements. Since many measurements were below the limits of detection (LODs), the simple replacement with half of the LOD and maximum likelihood estimation (MLE) methods were used for statistical analysis. For examining the optimal exposure indicator of airborne lead exposure, blood lead levels were used as reference data for subsequent rank correlation analyses. Results: A total of 19,637 airborne lead measurements and 32,848 blood lead measurements were used. In general, simple replacement showed a higher correlation than MLE. The results showed that AM and X95 using simple replacement could be used as optimal exposure intensity indicators, while X95 showed better correlations than AM in industries with 20 or more measurements. Conclusion: Our results showed that AM or X95 could be potential candidates for exposure intensity indicators in the Korean carcinogen exposure database. Especially, X95 is an optimal indicator where there are enough measurements to compute X95 values.