• Title/Summary/Keyword: J-V characteristics

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Electrical Properties by different method of metal complex of G4-48PyP Dendrimer (금속이온 착체방법에 의한 G4-48PyP 덴드리머의 전기적 특성)

  • Kim, S.U.;Jung, S.B.;Kim, C.;Park, J.C.;Chang, J.S.;Kwon, Y.S.
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1532-1534
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    • 2003
  • We attempted to fabricate a dendrimer Langmuir-Blodgett(LB) films containing 48 pyridinepropanol functional end group. As the pyridinepropanol functional group could form a complex structure with metal ions. In this study the samples for electrical measurement were fabricated to two types metal complexes with $Pt^{4+}$ ions by LB method. And we have investigated the surface activity at the air-water interface as well as the electrical properties for the monolayers of G4-48PyP dendrimer complex with metal ions($Pt^{4+}$ ions) by different method. In the surface pressure-area(${\pi}$-A) isotherms of the dendrimers, the stable condensed films formed at the air-water interface and the different method of metal complex showed the difference on molecular behavior. We have studied the electrical properties of the ultra thin dendrimer LB films investigated by the current-voltage (I-V) characteristics of metal/dendrimer LB films/metal(MIM) structure. In conclusion, it is demonstrated that the metal ion around G4-48PyP dendrimer can contribute to make formation of network structure among dendrimers and it result from the change of electrical properties.

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Poly(p-phenylenevinylene)s Derivatives Containing a New Electron-Withdrawing CF3F4Phenyl Group for LEDs

  • Jin, Young-Eup;Kang, Jeung-Hee;Song, Su-Hee;Park, Sung-Heum;Moon, Ji-Hyun;Woo, Han-Young;Lee, Kwang-Hee;Suh, Hong-Suk
    • Bulletin of the Korean Chemical Society
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    • v.29 no.1
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    • pp.139-147
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    • 2008
  • New PPV derivatives which contain electron-withdrawing CF3F4phenyl group, poly[2-(2-ethylhexyloxy)-5-(2,3,5,6-tetrafluoro-4-trifluoromethylphenyl)-1,4-phenylenevinylene] (CF3F4P-PPV), and poly[2-(4-(2-etylhexyloxy)-phenyl)-5-(2,3,5,6-tetrafluoro-4-trifluoromethylphenyl)-1,4-phenylenevinylene] (P-CF3F4P-PPV), have been synthesized by GILCH polymerization. As the result of the introduction of the electron-withdrawing CF3F4phenyl group to the phenyl backbone, the LUMO and HOMO energy levels of CF3F4P-PPV (3.14, 5.50 eV) and P-CF3F4P-PPV (3.07, 5.60 eV) were reduced. The PL emission spectra in solid thin film are more red-shifted over 50 nm and increased fwhm (full width at half maximum) than solution conditions by raising aggregation among polymer backbone due to electron withdrawing effect of 2,3,5,6-tetrafluoro-4-trifluoromethylphenyl group. The EL emission maxima of CF3F4P-PPV and P-CF3F4P-PPV appear at around 530-543 nm. The current density-voltage-luminescence (J-V-L) characteristics of ITO/PEDOT/polymer/Al devices of CF3F4P-PPV and P-CF3F4P-PPV show that turn-on voltages are around 12.5 and 7.0 V, and the maximum brightness are about 82 and 598 cd/m2, respectively. The maximum EL efficiency of P-CF3F4P-PPV (0.51 cd/A) was higher than that of CF3F4P-PPV (0.025 cd/A).

Double Layer Anti-reflection Coating for Crystalline Si Solar Cell (결정질 실리콘 태양전지를 위한 이층 반사방지막 구조)

  • Park, Je Jun;Jeong, Myeong Sang;Kim, Jin Kuk;Lee, Hi-Deok;Kang, Min Gu;Song, Hee-eun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.1
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    • pp.73-79
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    • 2013
  • Crystalline silicon solar cells with $SiN_x/SiN_x$ and $SiN_x/SiO_x$ double layer anti-reflection coatings(ARC) were studied in this paper. Optimizing passivation effect and optical properties of $SiN_x$ and $SiO_x$ layer deposited by PECVD was performed prior to double layer application. When the refractive index (n) of silicon nitride was varied in range of 1.9~2.3, silicon wafer deposited with silicon nitride layer of 80 nm thickness and n= 2.2 showed the effective lifetime of $1,370{\mu}m$. Silicon nitride with n= 1.9 had the smallest extinction coefficient among these conditions. Silicon oxide layer with 110 nm thickness and n= 1.46 showed the extinction coefficient spectrum near to zero in the 300~1,100 nm region, similar to silicon nitride with n= 1.9. Thus silicon nitride with n= 1.9 and silicon oxide with n= 1.46 would be proper as the upper ARC layer with low extinction coefficient, and silicon nitride with n=2.2 as the lower layer with good passivation effect. As a result, the double layer AR coated silicon wafer showed lower surface reflection and so more light absorption, compared with $SiN_x$ single layer. With the completed solar cell with $SiN_x/SiN_x$ of n= 2.2/1.9 and $SiN_x/SiO_x$ of n= 2.2/1.46, the electrical characteristics was improved as ${\Delta}V_{oc}$= 3.7 mV, ${\Delta}_{sc}=0.11mA/cm^2$ and ${\Delta}V_{oc}$=5.2 mV, ${\Delta}J_{sc}=0.23mA/cm^2$, respectively. It led to the efficiency improvement as 0.1% and 0.23%.

Vegetation Change and Growing Characteristics of Abies koreana Population by Altitude in Georim Valley of Mt. Jiri (지리산 거림계곡 구상나무 개체군의 고도별 식생변화와 생장특성)

  • Kim, Chang-Hwan;Jo, Min-Gi;Kim, Jong-Kab;Choi, Myung-Suk;Chung, Jae-Min;Kim, Ji-Hong;Moon, Hyun-Shik
    • Journal of agriculture & life science
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    • v.46 no.1
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    • pp.63-70
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    • 2012
  • To provide the basic information for preservation and reasonable management plan of Abies koreana population, vegetation structure and growing condition by altitude were analyzed. Six sites($400m^2$) were set up along the Georim valley in Mt. Jiri from 1,000m to 1,500m. The importance value of A. koreana in tree layer was the highest at 1,400m(site V) and 1,500m(site VI), and that of Quercus mongolica in the other site was high. In subtree layer, the importance value of A. koreana was the highest at site VI which located at 1,500m above the level of the sea. In DBH distribution, A. koreana population distributed evenly at all DBH class(below 10cm, 11-20cm, 21-30cm, above 31cm). Since 2000, the amount of tree-ring growth of A. koreana at site I, II, III, IV, V, and VI were 1.002, 0.996, 1.752, 1.850, 1.198, 0.984 mm/yr, which has decreased slowly in time for 2000, except site III.

Free-Surface Effects on a Fin Attached to a Submerged Body (잠수체 벽에 부착된 핀의 자유표면 효과에 관한 실험적 연구)

  • Kim, S.M.;Lee, S.J.;Lee, C.M.
    • Journal of the Society of Naval Architects of Korea
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    • v.33 no.1
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    • pp.27-39
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    • 1996
  • The effects of free surface and a strut on the lifting characteristics on a fin attached at the mid-chord of the strut are investigated experimentally in a circulating water channel. Variation of lift force on the fin is investigated with respect to free stream velocity(V), angle of attack of the fin(${\alpha}$) and ratio of the submergence depth of the fin to the chord of the fin(H/C). Attentions are focused on the lifting characteristics of the fin at shallow depths of submergence. Visualization of the free surface deformation along the strut and of the streamline about the fin is made in order to examine the inflow angle to the fin. Lift force on the fin alone i.e. in absence of the strut is also measured to investigate the difference in lifting characteristics of the fin caused by the strut. The results show that lift forces over the fin are largely affected by a free surface in the case of small submergence ratios(HiC<3.0). For HiC>5.0, the effects of the free surface are negligibly small. The inflow angle to the fin is significantly influenced by the strut and flow speed at the shallow depths of submergence. The deformation of the free surface is largely governed by the waves generated by the strut. However, for small submergence depths, the effects of the fin are found also significant.

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Discharge Characteristics of Surface Discharge Type FFL for LCD Backlighting (LCD 백라이트용 면방전형 FFL의 방전 특성)

  • Lim, M.S.;Yun, S.H.;Shin, Y.S.;Jung, D.Y.;Kwon, S.S.;Lim, K.J.
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1786-1788
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    • 1999
  • In this paper, we studied Surface Discharge Type Flat Fluorescent Lamp with High Luminance for LCD Backlighting, Liquid Crystal display(LCDs) demand the use of fluorescent lamp as the backlighting source. This lamp is Surface Discharge Type structure with a pair of Sodalime glass, insulator layer, phosphor layer, and Xe gas gap. In spite of its simple structure, the lamp has uniform and stable discharge over entire volume. Till now, we measured the current-voltage(V-I), Firing Voltage, Sustain Voltage for 0.5mm, 1mm electrode gap. In experiment result, long gap cell structure cause high firing voltage. The rising in firing voltage in long gap structure could not be explained by paschen's law because of non-uniform electric field.

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Effects of Doping in Organic Electroluminescent Devices Doped with a Fluorescent Dye

  • Kang, Gi-Wook;Ahn, Young-Joo;Lee, Chang-Hee
    • Journal of Information Display
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    • v.2 no.3
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    • pp.1-5
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    • 2001
  • The effect of doping on the energy transfer and charge carrier trapping processes has been studied in organic light-emitting diodes (OLEDs) doped with a fluorescent laser dye. The devices consisted of N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1-biphenyl-4,4'-diamine (TPD) as a hole transporting layer, tris(8-hydroxyquinoline) aluminum ($Alq_3$) as the host, and a fluorescent dye, 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1 H,5H-benzo[i,j]quinolizin-8-yl) vinyl]-4H-pyran) (DCM2) as the dopant. Temperature dependence of the current-voltage-luminescence (I-V-L) characteristics, the electroluminescence (EL) and photoluminescence (PL) spectra are studied in the temperature ranging between 15 K and 300 K. The emission from DCM2 was seen to be much stronger compared with the emission from $Alq_3$, indicative of efficient energy transfer from $Alq_3$ to DCM2. In addition, the EL emission from DCM2 increasd with increasing temperature while the emission from the host $Alq_3$ decreased. The result indicates that direct charge carrier trapping becomes efficient with increasing temperature. The EL emission from DCM2 shows a slightly sublinear dependence on the current density, implying the enhanced quenching of excitons at high current densities due to the exciton-exciton annihilation.

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Carcass and Meat Quality Traits in an Embden×Toulouse Goose Cross Raised in Organic Dehesa

  • Sole, M.;Pena, F.;Domenech, V.;Clemente, I.;Polvillo, O.;Valera, M.;Verona, J.C.;Rubi, M.;Molina, A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.6
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    • pp.838-844
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    • 2016
  • This study assessed the influence of genetic type (Embden-Anser anser, EE; Toulouse-Anser anser, TT and F1 cross, ET) for meat characteristics (carcass, meat quality and fatty acid (FA) profiles), of domestic geese "Anser anser domesticus" raised in dehesa as an alternative, organic feeding system. Carcass and breast muscle weight (p<0.01) were greater for the ET group at the same live weight. None of the groups showed differences in the production of fatty liver with this type of feeding. Higher values were found for maximum Warner-Bratzler shear force (between 7.62 and $8.87kg/cm^2$), which implies the improvement of this parameter. High levels of oleic FAs were obtained, especially for the TT group. The polyunsaturated/saturated FA ratio was highest for the ET group (p<0.001), reflecting the optimum nutritional values as a component of a healthy consumer diet.

The Spray Behavior Analysis and Space Distribution of Mixture in Transient Jet Impinging on Piston Cavity (비정상 충돌 분류의 Cavity형상에 따른 공간 농도 분포 및 거동해석)

  • Lee, S.S.;Kim, K.M.;Kim, B.G.;Chang, S.S.;Ha, J.Y.
    • Journal of ILASS-Korea
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    • v.1 no.2
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    • pp.16-23
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    • 1996
  • In case of a high-speed D.I. diesel engine. the injected fuel spray is unavoidable that the impinging on the wall of piston cavity and in this case the geometry of piston cavity has a great influence on the atomization structure and air flow fields. In the field of combustion and in many other spray applications, there are clear evidence of correlation between spray structure and emission of pollutants. Ordinary, the combustion chamber of driving engine have unsteady turbulent flow be attendant on such as the change of temperature, velocity and pressure. So the analysis of spray behavior is difficult. In this study, a single spray was impinged on each cavity wall at indicated angle in a quiescent atmosphere at room temperature and pressure, as being the simplest case, and 3 types of piston cavity such as Dish, Toroidal and Re-entrant type was tested for analyzing the influence of cavity geometry. And hot wire probe was used for analyze non-steady flow characteristics of impinging spray, and to investigate the behavior of spray, the aspects of concentration c(t), standard deviation $\sigma(t)$ and variation factor (v.f.) was measured with the lapse of time.

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A Study on the Decision Method for CM Organization of Skyscraper Projects in Korea using the Pugh-Matrix (의사결정 매트릭스를 활용한 국내 초고층 프로젝트의 CM 조직 구성 결정방법에 관한 연구)

  • Lim, Jae-Bok;Choi, Won-Cheol;Kim, Jae-Jun
    • Journal of The Korean Digital Architecture Interior Association
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    • v.10 no.2
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    • pp.39-47
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    • 2010
  • In this study, there should be a debation on the methods, such as considerations on the CM organization of skyscraper project for the client's side, process and impact factors need to be taken, and suggesting the evaluation and selection criteria, which may lead strategic decision-making by the client. Owner of the CM organizational decision to establish a variety of alternatives, the range of CM performance characteristics of the project, considering the weight and also by evaluating the effectiveness of appropriate alternative is selected. Domestic skyscraper project, decisions about the CM organization for 'S Tower' prior to the proposed decision and the criteria was applied. As a result, domestic CM/PM companies and overseas CM/PM companies were doing business as J/V, Supervision of the integration work order types showed the highest performance levels. when they ordered CM services. The project cost reduced and organizational improvements, the results of applying alternative way, improve on-site construction plans, sharing key technologies, process improvement plan could benefit from such expectations.