• Title/Summary/Keyword: J$_{}$ c/degradation

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Theoretical studies on the stabilization and diffusion behaviors of helium impurities in 6H-SiC by DFT calculations

  • Obaid Obaidullah;RuiXuan Zhao;XiangCao Li;ChuBin Wan;TingTing Sui;Xin Ju
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.2879-2888
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    • 2023
  • In fusion environments, large scales of helium (He) atoms are produced by a radical transformation along with structural damage in structural materials, resulting in material swelling and degradation of physical properties. To understand its irradiation effects, this paper investigates the stability, electronic structure, energetics, charge density distribution, PDOS and TDOS, and diffusion processes of He impurities in 6HSiC materials. The formation energy indicates that a stable, favorable position for interstitial He is the HR site with the lowest energy of 2.40 eV. In terms of vacancy, the He atom initially prefers to substitute at pre-existing Si vacancy than C vacancy due to lower substitution energy. The minimum energy paths (MEPs) with migration energy barriers are also calculated for He impurity by interstitial and vacancy-mediated diffusion. Based on its calculated energy barriers, the most possible diffusion path includes the exchange of interstitial and vacancy sites with effective migration energies ranging from 0.101 eV to 1.0 eV. Our calculation provides a better understanding of the stabilization and diffusion behaviors of He impurities in 6H-SiC materials.

EFFECT OF HARDNESS CHANGES AND MICROSTRUCTURAL DEGRADATION ON CREEP BEHAVIOR OF A Mod.9Cr-1Mo STEEL

  • PARK K. S.;CHUNG H. S.;LEE K. J.;JUNG Y. G.;KANG C. Y.;ENDO T.
    • International Journal of Automotive Technology
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    • v.6 no.1
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    • pp.45-52
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    • 2005
  • Interrupted creep tests for investigating the structural degradation during creep were conducted for a Mod.9Cr-1Mo steel in the range of stress from 71 to 167 MPa and temperature from 873 to 923 K. The change of hardness and tempered martensitic lath width was measured in grip and gauge parts of interrupted creep specimens. The lath structure was thermally stable in static conditions. However, it was not stable during creep, and the structural change was enhanced by creep strain. The relation between the change in lath width and creep strain was described quantitatively. The change in Vickers hardness was expressed by a single valued function of creep LCR(life consumption ratio). Based on the empirical relation between strain and lath width, a model was proposed to describe the relation between change in hardness and creep LCR. The comparison of the model with the empirical relation suggests that about 65% of hardness loss is due to the decrease of dislocation density accompanied by the movement of lath boundaries. The role of precipitates on subboundaries was discussed in connection with the abnormal subgrain growth appearing in low stress regime.

Impact of gamma radiation on 8051 microcontroller performance

  • Charu Sharma;Puspalata Rajesh;R.P. Behera;S. Amirthapandian
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4422-4430
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    • 2022
  • Studying the effects of gamma radiation on the instrumentation and control (I&C) system of a nuclear power plant is critical to the successful and reliable operation of the plant. In the accidental scenario, the adverse environment of ionizing radiation affects the performance of the I&C system and it leads to inaccurate and incomprehensible results. This paper reports the effects of gamma radiation on the AT89C51RD2, a commercial-off-the-shelf 8-bit high-performance flash microcontroller. The microcontroller, selected for the device under test for this study is used in the remote terminal unit for a nuclear power plant. The custom circuits were made to test the microcontroller under different gamma doses using a 60Co gamma source in both ex-situ and in-situ modes. The device was exposed to a maximum dose of 1.5 kGy. Under this hostile environment, the performance of the microcontroller was studied in terms of device current and voltage changes. It was observed that the microcontroller device can operate up to a total absorbed dose of approximately 0.6 kGy without any failure or degradation in its performance.

The Effects of Reaction Conditions and NOM on Persulfate Oxidation of RDX (Persulfate에 의한 RDX 산화시 반응조건과 NOM의 영향)

  • Wu, Dabo;Bae, Bum-Han
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.10
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    • pp.723-730
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    • 2011
  • In this experiment, persulfate, a strong oxidant for ISCO (In-Situ Chemical Oxidation) was used to degraded RDX in artificial ground water at ambient temperature. Results of RDX degradation by persulfate in a batch reactor showed that the oxidation reaction was pseudo first order with estimated Ea (activation energy) of $1.14{\times}10^2kJ/mol$ and the rate was increased with the increase of reaction temperature. The oxidation of RDX by persulfate increased slightly with the increase of initial solution pH from 4 to 8. The RDX oxidation rate increased 13 times at pH 10 compared with that at pH 4, however, alkaline hydrolysis was found to be the main reaction of RDX degradation rather than oxidation. The study also showed that the oxidation rate of RDX by persulfate was linearly dependent upon the molar ratios of persulfate to RDX from 5 : 1 up to 100 : 1, with a proportion constant of $4{\times}10^{-4}$ ($min^{-1}$/molar ratio) at $70^{\circ}C$. While NOM (Natural Organic Matter) exerted negative effects on the oxidation rate of RDX by persulfate, with a proportion constant of $1.21{\times}10^{-4}$ ($min^{-1}{\cdot}L/mg-NOM$) at $70^{\circ}C$ and persulfate/NOM molar ratio of 10/1. The decrease in RDX oxidation rate was linearly dependent upon the added NOM concentration. However, the estimated activation energy in the presence of 20 mg-NOM/L was within 3.3% error compared to that without NOM, which implies the addition of NOM does not alter intrinsic oxidation reaction.

EFFECT OF SOYBEAN EXTRUSION ON NITROGEN METABOLISM, NUTRIENT FLOW AND MICROBIAL PROTEIN SYNTHESIS IN THE RUMEN OF LAMBS

  • Ko, J.Y.;Ha, J.K.;Lee, N.H.;Yoon, C.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.5 no.3
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    • pp.571-582
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    • 1992
  • Soybeans were dry extruded at three different temperatures (125, 135 and $145^{\circ}C$) for 30 s. Four lambs fitted with cannulae in the rumen and abomasums were used in a balanced $4{\times}4$ Latin square design. Lambs were fed at 2 h intervals for 12 times a day with automatic feeder to maintain steady state conditions in digestive tract. A dual-phase marker system was used to estivate ruminal flow rate of both liquid and solid digesta. Objectives of this study were to determine the effect of extrusion temperature of raw soybean on the ruminal liquid and solid dilution rate, nitrogen digestion and flow at the abomasum and availability of amino acid in lambs. There were no significant effects of extrusion on liquid and solid dilution rate, and liquid volume. Ruminal liquid flow rate was not influenced by extrusion and ranged from 389 to 435 ml/hr. Extrusion had no influence on ruminal OM digestion and flow rate to the abomasums. Dietary N flow to the abomasums increased (p < 0.05) as extruding temperature increased. Extruding temperature had a significant effect (p < 0.05) on flow of N escaping ruminal degradation and ranged from 34.91 to 57.38%. Microbial N synthesized/kg OMTDR ranged from 27 to 37 g and highest with $145^{\circ}C$ ESB diet. Extrusion decreased the amount of degradable amino acid in the rumen and increased the supply of amino acid to the lower gut, especially with 135 and $145^{\circ}C$ ESB diets.

Effects of LCFA on the Gas Production, Cellulose Digestion and Cellulase Activities by the Rumen Anaerobic Fungus, Neocallimastix frontalis RE1

  • Lee, S.S.;Ha, J.K.;Cheng, K.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.8
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    • pp.1110-1117
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    • 2001
  • Responses of the rumen fungus, Neocallimastix frontalis RE1, to long chain fatty acid (LCFA) were evaluated by measuring gas production, filter paper (FP) cellulose digestion and polysaccharidase enzyme activities. LCFA (stearic acid, $C_{18:0}$; oleic acid, $C_{18:1}$; linoleic acid, $C_{18:2}$ and linolenic acid, $C_{18:3}$) were emulsitied by ultrasonication under anaerobic condition, and added to the medium. When N frontalis RE1 was grown in culture with stearic, oleic and linoleic acid, the cumulative gas production, gas pool size, FP cellulose digestion and enzymes activities significantly (p<0.05) increased at some incubation times(especially, exponential phases of fungal growth, 48~120 h of incubation) relative to that for control cultures. However, the addition of linolenic acid strongly inhibited all of the investigated parameters up to 120 h incubation, but not after 168 and 216 h of incubation. These results indicated that stearic, oleic and linoleic acids tended to have great stimulatory effects on fungal cellulolysis, whereas linolenic acid caused a significant (p<0.05) inhibitory effects on the cellulolysis by the rumen fungus. These results are the first report of the effect of LCFAs on the ruminal fungi. Further research is needed to identify the mode of action of LCFAs on fungal strains and to verify whether or not ruminal fungi have ability to hydrate unsaturated LCFAs to saturated FAs. There was high correlation between cumulative in vitro gas production and fungal growth (94.78%), FP cellulose degradation (96.34%), CMCase activity(90.86%) or xylanase activity (87.67%). Thus measuring of cumulative gas production could be a useful tool for evaluating fungal growth and/or enzyme production by ruminal fungi.

Purification and Properties of the Polyvinyl alcohol oxidase from Xanthomonas campestris J2Y (폴리비닐 알콜 분해균 Xanthomonas campestris J2Y의 Polyvinyl alcohol oxidase 정제 및 성질)

  • Kwoen, Dae-Jun;Jo, Youl-Lae
    • Applied Biological Chemistry
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    • v.39 no.5
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    • pp.349-354
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    • 1996
  • The Polyvinyl alcohol(PVA) oxidase involved in PVA degradation by microorganism has been purified to homogeneity from culture broth of Xanthomonas campestris J2Y grown in a minimal medium containing PVA as a sole carbon source. The enzyme was purified by DEAE-cellulose chromatograpy and Sephadex G-150 gel filtration. The purified PVA oxidase was electrophoretically homogeneous both in the absence and presence of SDS. The molecular weight of the enzyme was estimated to be about 55,000 daltons by SDS-polyacrylamide gel electrophoresis and Sephadex G-150 gel filtration. The native enzyme existed as a monomer. The optimal pH and temperature was shown to be pH 7 and $37^{\circ}C$ respectively. The activity of enzyme was stable below $55^{\circ}C$ and between pH range of $5{\sim}11$. The enzyme activity was significantly inhibited by metal compounds such as $Ag^{2+},\;Hg^{2+}$. While, metal ions such as $Mn^{2+},\;and\;Cu^{2+}$ stimulated the reaction. Km value of the enzyme for PVA was $7.04{\times}10^{-2}mmol/{\ell}$.

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Investigation on Characteristics of Swine Manure of Optimum Volume for Escalator Reversing Composting Facility (돼지분뇨 특성에 따른 기계교반 퇴비화시설의 적정용적 산정 연구)

  • Kwag, J.H.;Choi, D.Y.;Park, C.H.;Jeong, K.H.;Kim, J.H.;Yoo, Y.H.;Youn, C.K.;Ra, C.S.
    • Journal of Animal Environmental Science
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    • v.14 no.2
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    • pp.105-112
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    • 2008
  • This study was carried out to investigate evaporation rate of moisture per surface area and degradation rate of organic matter in full scale escalator reversing composting facility were analyzed to develope a computer program for the computation of an optimum volume of composting facility according to handling methods of swine farm, moisture levels of manure, degradation rate of organics and evaporation rate of moisture during composting. The obtained results can be followed as bellow; The temperature in full scale escalator reversing composting facility during composting reached $70^{\circ}C$ in 4 days and maintained until 11 days. Reduction rate of moisture and density was average 1.20% and 29.7%, respectively. Annual degradation rate of organic matter was 3.53%, showing lowest rate in winter as 3.23%. These seasonal degradation rate could be a factor to be considered for proper management and installation of composting facility. When computed with the amount of feces, urine, slurry and manure plus wastewater produced, the optimum volumes of composting facility for slurry and manure plus wastewater including each 95% moisture was $229m^3$ and $277m^3$, respectively, showing 21% ($48m^3$) difference.

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A Study of Bearing Strength on Composite Pinned-Joint at Low Temperature (저온환경에서 복합재료 핀 연결부의 Bearing 강도에 관한 연구)

  • Her, N.I.;Lee, S.Y.;Kim, J.H.;Lee, Y.S.;Sa, J.W.;Cho, S.;Im, K.H.;Oh, Y.K.;Choi, C.H.;Do, C.J.;Kwon, M.;Lee, G.S.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.413-418
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    • 2001
  • Fundamental failure mode in a laminated composite pinned-joint is proposed to assess damage resulting from stress concentration in the plate. The joint area is a region with stress concentrations thus a complicated stress state exists. The modeling of damage in a laminated composite pinned-joint presents many difficulties because of the complexity of the failure process. In order to model progressive from initial to final, finite element methods are used rather than closed form stress analyses. Failure analysis must be a logical combination of suitable failure criteria and appropriate material properties degradation rules. In this study, the material properties which were obtained in previous study, the preparing process of the bearing strength test for a pinned joint CFRP composite plate subjected to in-plane loading at low temperature, and the FEM result of progressive damage model using ANSYS program are summarized to assess the structural safety of CFRP plate used in the magnetic supporting post of KSTAR(Korea Superconducting Tokamak Advanced Research).

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Correlation between pr1 and pr2 Gene Content and Virulence in Metarhizium anisopliae Strains

  • Rosas-Garcia, Ninfa M.;Avalos-de-Leon, Osvaldo;Villegas-Mendoza, Jesus M.;Mireles-Martinez, Maribel;Barboza-Corona, J.E.;Castaneda-Ramirez, J.C.
    • Journal of Microbiology and Biotechnology
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    • v.24 no.11
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    • pp.1495-1502
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    • 2014
  • Metarhizium anisopliae is a widely studied model to understand the virulence factors that participate in pathogenicity. Proteases such as subtilisin-like enzymes (Pr1) and trypsin-like enzymes (Pr2) are considered important factors for insect cuticle degradation. In four M. anisopliae strains (798, 6342, 6345, and 6347), the presence of pr1 and pr2 genes, as well as the enzymatic activity of these genes, was correlated with their virulence against two different insect pests. The 11 pr1 genes (A, B, C, D, E, F, G, H, I, J, and K) and pr2 gene were found in all strains. The activity of individual Pr1 and Pr2 proteases exhibited variation in time (24, 48, 72, and 96 h) and in the presence or absence of chitin as the inductor. The highest Pr1 enzymatic activity was shown by strain 798 at 48 h with chitin. The highest Pr2 enzymatic activity was exhibited by the 6342 and 6347 strains, both grown with chitin at 24 and 48 h, respectively. Highest mortality on S. exigua was caused by strain 6342 at 48 h, and strains 6342, 6345, and 6347 caused the highest mortality 7 days later. Mortality on Prosapia reached 30% without variation. The presence of subtilisin and trypsin genes and the activity of these proteases in M. anisopliae strains cannot be associated with the virulence against the two insect pests. Probably, subtilisin and trypsin enzyme production is not a vital factor for pathogenicity, but its contribution is important to the pathogenicity process.