• Title/Summary/Keyword: Isotopic ages

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SHRIMP Zircon U-Pb Geochronology, Geochemistry and Sr-Nd Isotopic Study of the Cheongju granitoid rocks (청주 화강암의 SHRIMP 저어콘 U-Pb 연대, 지구화학 및 Sr-Nd 동위원소 연구)

  • Cheong, Won-Seok;Kim, Yoon-Sup;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
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    • v.20 no.4
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    • pp.191-206
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    • 2011
  • The emplacement ages, whole-rock geochemistry and Sr-Nd isotopic compositions of granitoid rocks from Cheongju area, South Korea, were investigated for delineating their petrogenetic link to the Jurassic Daebo granitoid rocks. Zircon crystals were collected from the diorite, biotite granite and acidic dyke samples in a single outcrop. Cross-cutting relationships show that the emplacement of diorite was postdated by the intrusion of biotite granite. Both rocks have been subsequently intruded by acidic dyke. The U-Pb isotopic compositions of zircon from the diorite, biotite granite, and acidic dyke were measured using a SHRIMP-II ion microprobe, yielding the crystallization ages of $174{\pm}2Ma$, $170{\pm}2Ma$, and $170{\pm}5Ma$, respectively, with 95% confidence limits ($t{\sigma}$). The emplacement ages are consistent with those determined from the above relative ages. The major and trace element patterns of the rocks are consistent with those of the Jurassic Daebo granitoid rocks, possibly suggesting a subduction-related I-type granite. The geochemical signature is, however, betrayed by the Sr and Nd isotopic compositions of these rocks. The isotopic signatures suggest that the rocks were produced either by the partial melting of lower-crust or by the mantle-derived magma contaminated by the basement rocks during its ascent and/or emplacement. In addition, the inherited ages of zircons of the rocks (ca. 2.1, 1.8, 0.8 and 0.4 Ga) suggest a possible assimilation with crustal rocks from the Gyeonggi massif and Ogcheon metamorphic belt.

Petrologic Study on the Busan Migmatitic Gneiss in the northeastern Margin of the Ogcheon Zone (옥천대(沃川帶) 북동변(北東邊)에 분포(分布)하는 부산혼성편마암(婦山混成片麻岩)에 대(對)한 암석학적(岩石學的) 연구(硏究))

  • Na, Ki-Chang
    • Economic and Environmental Geology
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    • v.20 no.4
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    • pp.235-246
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    • 1987
  • Busan migmatitic gneisses in the northeastern margin of the Ogcheon zone have been studied petrologically in order to clarify their origin. Petrochemical and mineralogical studies show that the gneisses are Precambrian basemental paragneisses and the rocks were migmatized more intensively than the Bagdalryeong gneisses which have been known to constitute the basemental gneisses of Ogcheon zone. K-Ar biotite isotopic ages are $150.79{\pm}3.37Ma$ in Busan migmatitic gneiss and $191{\pm}4.27Ma$ in Bagdalryeong gneisses. These ages seem to be isotopic homogenised ages. Progressive regional metamorphisms are predominent in the studied area showing greenschist facies, epidote amphibolite facies and amphibolite facies toward N-W direction.

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Rb-Sr Isotopic Ages of Biotite in the Weathering Profile of Granodiorite, Yecheon (예천지역 화강섬록암 풍화대내 흑운모의 Rb-Sr 동위원소연대 변화)

  • Jeong Gi Young;Cheong Chang-Sik;Lee Bong Ho
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.1
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    • pp.53-59
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    • 2005
  • Rb-Sr isotopic ages of oxidized biotite in the weathering profile of granodiorite, Yecheon area, were measured by thermal ionization mass spectrometry, and compared with their K-Ar ages. A decrease of Rb-Sr isotopic age is well correlated with iron oxidation, and consistent with K-Ar age. Octahedral and interlayer cations including Rb and Sr were partly released from the oxidizing biotite by excess positive charge from iron oxidation. Divalent /sup 87/Sr decayed from monovalent /sup 87/Rb was more easily released from biotite, resulting in the reduction of Rb-Sr isotopic age. Weathered biotite is not suitable for the age dating of parent rocks, but behaviour of radiogenic isotopes provides useful information on the geochemical and structural changes of biotite during weathering.

The Age of the Okcheon Metamorphic Belt-How Much Do We Know? (옥천 변성대의 시기-우리는 얼마만큼 알고 있나?)

  • Kwon, Sung-Tack
    • The Journal of the Petrological Society of Korea
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    • v.17 no.2
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    • pp.51-56
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    • 2008
  • The geologic age of the Okcheon metamorphic belt, used to be a longstanding puzzle, has been settled down to Neoproterozoic to Paleozoic with discovery of fossils and isotopic age dating of metavolcanic rocks. As isotopic ages become accumulated, there appeared a controversy over the age of peak metamorphism in the Okcheon metamorphic belt, i.e., a single late Permian-early Triassic metamorphism (CHIME allanite age and U-Pb age of metamorphic zircon), or earlier independent presence of early Permian metamorphism (U-Pb age of allanite within garnet porphyroblast). If we compare the isotopic ages that can represent metamorphism, the data for the latter have much larger error than those of the former with some overlap considering the error limits. It means that, the former, supported by two independent ages, is considered a better representation for the age of metamorphism of the Okcheon metamorphic belt. Therefore, I propose the idea of early Permian metamorphism should better be reserved until conclusive evidence appears. The late Permian-early Triassic metamorphic age suggest that the effect of continental collision influenced much of the middle part of Korean Peninsula, namely, the Imjingang belt, the Gyeonggi massif and the Okcheon belt.

Sr, Nd and Pb isotopic investigations of ultramafic xenoliths and their host basalts from Jeju Island, Baekryeong Island, Boeun and Ganseong, Korea: Implications for a large-scale difference in the source mantle beneath East Asia

  • Park, Seong-Hee;Kwon, Sung-Tack;Hee Sagong;Cheong, Chang-Sik
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.75-75
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    • 2001
  • We report Sr, Nd and Pb isotope data of clinopyroxene separates from ultramafic xenoliths and their host basaltic rocks in Jeju Island, Baekryeong Island, Boeun and Ganseong, Korea. The isotopic data of the xenoliths and host basalts are distinctly different from those of Korean basement rocks. Except for two xenoliths from Ganseong, all samples in this study have isotopic ratios within the combined range of MORB-OIB data. All basaltic rocks have Nd-Sr-Pb isotope compositions different from those of xenoliths, indicating that the host basaltic magma did not derive from the lithospheric mantle where the xenoliths originated. The range of isotopic composition of xenoliths is much greater than that observed in host basalts, which reflects small-scale heterogeneity of the lithospheric mantle. The greater isotopic heterogeneity of the lithospheric mantle probably reflects its long-term stability. The spinel peridotite xenolith data of Jeju Island, Baekryeong Island and Boeun display mixing hyperbolas between DMM and EM II end members. Since Jeju basalts have EM II-like isotopic signature, the mixing relationship shown by the isotopic data of the Jeju xenoliths can be interpreted as the result of infiltration of metasomatic fluid or melt derived from basaltic magma into DMM-like lithospheric mantle. In contrast to other xenolith sites, the Ganseong xenoliths are dominantly clinopyroxene megacryst and pyroxenite. Clinopyroxene megacrysts have different isotopic ratios from their host basalt, reflecting its exotic origin. Two Ganseong xenoliths (wherlite and clinopyroxenite) have much enriched Sr and Nd isotopic ratios and Nd model ages of 2.5-2.9 Ga, and plot in an array away from the MORB-OIB field. The mantle xenoliths from Korean Peninsula have similar $\^$87/Sr/$\^$86/Sr,$\^$143/Nd/$\^$144/Nd and $\^$207/Pb/$\^$204/Pb ratios to, but higher $\^$208/Pb/$\^$204/Pb ratios than, those from eastern China, indicating that Korean xenoliths are derived from the lithospheric mantle with higher Th/U ratio compared with Chinese ones. The isotopic data of xenolith-bearing basalts of Baekryeong Island and Ganseong, along with Ulreung and Dok Islands, show a mixing trend betlveen DMM and EM I in Sr-Nd-Pb isotopic correlation diagrams, which is also observed in tile northeastern Chinese basalts. However, the Jeju volcanic rocks show an EM II signature that is observed in southeastern Chinese basalts. The isotopic variations in volcanic rocks from the northern and southern portions of the East Asia reflect a large-scale isotopic heterogeneity in their source mantle.

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Sr Isotopic Composition of Apatite from the Yeongju and Andong Granites: Isotopic Distinction between the Two Granites and Location of the Boundary (영주화강암과 안동 화강암의 인회석 Sr 동위원소 조성: 두 암체의 동위원소적 구분과 경계의 위치)

  • Yoon, Rina;Lee, Seung-Gu;Park, Kye-Hun;Song, Yong-Sun
    • The Journal of the Petrological Society of Korea
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    • v.25 no.1
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    • pp.89-93
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    • 2016
  • Yeongju and Andong granites, located in the northeastern Yeongnam massif, reveal very similar emplacement ages but distinct initial isotopic compositions of strontium. However, previous studies used different boundaries to distinguish these batholiths. In this study, we determined Sr isotopic compositions of apatite separated from the granites of the area to find out the proper boundary and propose the location of such boundary based upon analysis.

Geochemical and Isotopic Study of the Onjeongri Granite in the Northern Gyeongsang Basin, Korea : Comparison with Cretaceous to Tertiary Granitic Rocks in the Other Part of the Gyeongsang Basin and the Inner Zone of Southwest Japan (경상분지 북부에 분포하는 온정리 화강암에 대한 암석화학적, 동위원소 지구화학적 연구 : 경상분지 다른 지역과 서남 일본 내대에 분포하는 백악기-제 3기 화강암류와의 비교 고찰)

  • 정창식;권성택;김정민;장병욱
    • The Journal of the Petrological Society of Korea
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    • v.7 no.2
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    • pp.77-97
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    • 1998
  • We analyzed geochemical and radiogenic isotope data to investigate the genesis and source characteristics of the Onjeongri granite in the northern part of the Gyeongsang Basin. Field observation and K-Ar ages confirm late Cretaceous intrusion (ca. 87 Ma) of the Onjeongri granite. The hornblende geobarometery gives less than 2 kbar for the emplacement pressure of the Onjeongri granite. Geochemical and isotopic compositions suggest that the Onjeongri granite was formed in a relatively immature arc system. $SiO_2$ contents show a negative linear relationship with initial $^{87}Sr/^{86}Sr$ ratios, and an apparent positive correlation with $^{207}Pb/^{204}Pb$ ratios, suggesting an incomplete mixing or assimilation. However, the isotopic data known for any exposed rocks of the study area do not fit as an endmember, implying that the contaminant might reside in the lower crust. A review of published isotopic ages, geochemical, and Sr and Nd isotopic data for the Cretaceous to Tertiary granites in the Gyeongsang Basin indicates the followings. 1) Granitic magmatism in the Gyeongsang Basin were episodic. 2) Granitic rocks in the basin were derived from young (< 0.9 Ga) lower crust, and their isotopic signatures reflect heterogeneous source region. Geochemical and isotopic signatures of granitic rocks in the basin are difficult to explain by upper crustal contamination. 3) Granites in the Gyeongsang Basin have closely related to those in the San in Belt of the Inner Zone of Southwest Japan in terms of age, petrography, and isotopic and geochemical composition. 4) Sr-Nd isotopic signatures of the Onjeongri granite are relatively primitive compared with granitic rocks in the other parts of the Gyeongsang Basin and in the Inner Zone of Southwest Japan.

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Geochronology and Cooling history of the Mesozoic Granite Plutons in the Central Part of the Ogcheon Fold Belt, South Korea (남한 습곡대 중앙부의 중생대 화강암 질암의 생선년대와 냉각사)

  • Myung-Shik JIN
    • The Journal of the Petrological Society of Korea
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    • v.4 no.2
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    • pp.153-167
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    • 1995
  • Emplacement ages for the granite plutons of the Jurassic and the Cretaceous times in the central Ogcheom Fold Belt were determined by Rb-Sr whole rock and mineral isocheon methods. In addition mineral ages for the plutons were determined by K-Ar and fission track methods. In turn, thermal histories and uplifting rates of the granitic bodies are elucidated from the isotopic ages. The Jecheon(~203 Ma) and Mungyeong(at lest~200 Ma) granites of the Jurassic and the Muamsa, Wolagsan and Daeyasan granites(~110 Ma) of the Cretaceous show high strontium initial ratios [$(^{87}Sr/^{86}Sr)_1$0.7100],suggesting that the granitic magmas have been generated by partial melting of crustal materials (S-type), or by mixing of mantle and crustal materials. Only mineral ages of the Sogrisan and Hyeongjebong granites (~90 Ma) were determined by K-Ar method, and petrogenesis of them were not defined yet. The two Jurassic granite plutons were cooled rapidly down to $300^{\circ}C$, right after the plutons were slowly cooled down since then, due to their deep emplacment. During the Middle Cretaceous period, the Jurassic Mungyeong granitic pluton was intruded and thermally affected much by the surrounding Wolagsan and Daeyasan granites. Accordingly the Rb-Sr mineral age, K-Ar hornblende and biotite ages of the Mungyeong granite appear to be reduced or reset due to the thermal effects above their blocking temperatures. All the cretaceous granites have been cooled much ore simply and rapidly down than the Jurassic ones below $300^{\circ}C$, owing to their shallow emplacement.

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Petrogenesis of Mesozoic granites at Garorim Bay, South Korea: evidence for an exotic block within the southwestern Gyeonggi massif?

  • Kim, Ji In;Choi, Sung Hi;Yi, Keewook
    • Geosciences Journal
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    • v.23 no.1
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    • pp.1-20
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    • 2019
  • We present data from the Mesozoic Keumkang, Palbong, and Baekhwa granites in Garorim Bay, in the southwestern part of the Gyeonggi massif, South Korea. Using major and trace element concentrations, Sr-Nd-Pb isotopic compositions, and sensitive high-resolution ion microprobe (SHRIMP) zircon U-Pb ages, we aim to constrain the petrogenesis of the granites and explain their origin within a broader regional geological context. SHRIMP U-Pb zircon ages of $232.8{\pm}3.2$, $175.9{\pm}1.2$, and $176.8{\pm}9.8$ Ma were obtained from the Keumkang, Palbong and Baekhwa granites, respectively. The Late Triassic Keumkang granites belong to the shoshonite series and show an overall enrichment in large ion lithophile elements (LILE), a depletion in high field strength elements (HFSE) relative to primitive mantle, compared with neighboring elements in the primitive mantle-normalized incompatible trace element diagram with notable high Ba and Sr contents, and negligible Eu anomalies. The Keumkang granites are typified by highly radiogenic Sr and unradiogenic Nd and Pb isotopic compositions: $(^{87}Sr/^{86}Sr)_i=0.70931-0.70959$, $(^{143}Nd/^{144}Nd)_i=0.511472-0.511484$ [$({\varepsilon}_{Nd})_i=-17.0$ to -16.7], and $(^{206}Pb/^{204}Pb)=17.26-17.27$. The Middle Jurassic Palbong and Baekhwa granites belong to the medium- to high-K calc-alkaline series, and show LILE enrichment and HFSE depletion similar to the Keumkang granites, but exhibit significant negative anomalies in Ba, Sr, and Eu. Furthermore, they have elevated Y and Yb contents at any given $SiO_2$ content compared with other Jurassic granitoids from the Gyeonggi massif. The Palbong and Baekhwa granites have slightly less radiogenic Sr and more radiogenic Nd and Pb isotopic compositions [$(^{87}Sr/^{86}Sr)_i=0.70396-0.70908$, $(^{143}Nd/^{144}Nd)_i=0.511622-0.511660$, $({\varepsilon}_{Nd})_i=-15.4$ to -14.7, $(^{206}Pb/^{204}Pb)=17.56-17.76$] relative to the Keumkang granites. The Keumkang granites are considered to have formed in a post-collisional environment following the Permo-Triassic Songrim orogeny that records continent-continent collision between the North and South China blocks, and may have formed by fractional crystallization of metasomatized lithospheric mantle-derived mafic melts. The Palbong and Baekhwa granites may have been produced from a gabbroic assemblage at pressures of less than ~15 kbar, associated with subduction of the paleo-Pacific (Izanagi) plate at the Eurasian continental margin. Elevated ${\varepsilon}_{Nd}(t)$ values in the granitoids from the southwestern part of the Gyeonggi massif relative to those of the central and northern parts, together with the comparatively shallow depth of origin, imply the presence of an exotic block in the Korean lithosphere.