• Title/Summary/Keyword: Isotope analysis

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Marine Terraces of the Eastern Coast of Korean Peninsula

  • Park, Seong-Gil
    • The Korean Journal of Quaternary Research
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    • v.17 no.2
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    • pp.15-15
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    • 2003
  • In South Korea, marine terraces have been well developed along the eastern coastal zone, and previous researches on the marine terraces have also been focused on to this coastal zone. The marine terraces of the eastern coast of South Korea had been classified into three terrace groups, that is, the higher, middle, and lower surface ones, according to the heights of marine terraces by previous studies(Oh, 1981 ;Chang, 1987 ;Yoon et. al, 1999, 2003 ; Hwang and Yoon, 1996 etc.). Recently, however, it tends to classify the marine terraces based on the concept of geomorphic surface units(Lee, 1987 ; Kim, 1990 ; Choi, S. 2003; Choi S. et. al 2003a,b, etc). For example, it was proposed that the marine terrace surfaces of Eupcheon coast of the southeastern coastal area of Korea could be classified into 16 geomorphic surfaces, i.e., Eupcheon 1terrace(former shoreline height of 160m), 2(153m), 3(140m), 4(130m), 5(124m), 6(115m), 7(100m), 8(92m), 9(82m), 10(71m), 11(62m), 12(53m), 13(43m), 14(35m), 15(18m) and 16(10m) surfaces, in descending order, according to the former shoreline heights(Choi, S, 2003 ; Choi, S. et. al, 2003a,b). Among these terraces, Eupcheon 1, 2, 4, 5 and 7 surfaces had not been reported in previous works. Among the above mentioned marine terraces, Eupcheon 15 terrace, the most widely and continuously distributed marine terrace have been identified as marine terrace of the Last Interglacial culmination period(oxygen isotope stage 5e) which was based on amino acid dates(124∼125ka BP) and geomorphological features such as red soil, pollen analysis, fossil cryogenic structures and crossing terrace concept. Eupoheon 15 terrace surfaces have also been proposed as the key surface for the identification and correlation of the so-called '5e' marine terrace in the eastern coast of South Korea. This terrace was reconfirmed as the Last Interglacial culmination period, which was based on the identification of Ata tephra, one of the wide-spread marker tephra which indicates the Last Interglacial culmination period in Japan by Sasaki et. al(2002). It was thought that marine terraces of the eastern coast of South Korea had been formed by the steady-state uplifting during the Quaternary glacio-eustatic sea level changes(Choi, 1997). The uprift rate of 10cm/1,000years had been proposed in the eastern coast of South Korea based on the former shoreline altitude(18m) of the above Eupcheon 15 terrace. Therefore, it can be estimated that Eupcheon 1 terrace had been formed in the early Pleistocene from the above uprift rate. The OSL dating for the samples of Eupcheon 7, 9, 13, 15 and 16 terraces and identification of marker tephra in the terrace deposits are in progress. It is expected that more elaborate chronology on themarine terraces of the eastern coast of South Korea could be established by these absolute dates and marker-tephra.

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An Analysis of Phenolic Compounds, Carbon Isotopes, and Sugar Components of Whiskys Based on the Period of Maturation (위스키의 종류와 숙성기간에 따른 페놀성 화합물, 탄소동위원소비 및 당 성분 분석)

  • Cho, Eun-Ah;Lee, Young-Sang
    • The Korean Journal of Food And Nutrition
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    • v.25 no.1
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    • pp.57-63
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    • 2012
  • This paper analyzes phenolic compounds, carbon isotopes, and sugar components of whiskys based on the maturation period. For this, the paper considers a total of 40 whiskys(mainly imports) distributed in Korea. It is important to analyze the presence phenolic compounds(e.g., furfural, syringaldehyde, vanillin, syringic acid, and vanillic acid) because these are found only in whiskys ripened in oak. The results indicate that the total content of phenolic compounds increased with the increase in the storage period regardless of the type of whisky. In terms of vanillin/syringaldehyde(V/S), Scotch whiskys had 0.4~0.5; American whiskies, 0.30~0.34; and Canadian whiskies, 0.31~0.33. In terms of Scotch whiskys, Macallan had 0.25~0.34, making it unique among Scotch whiskys. In terms of the ratio of carbon isotopes, there were clear differences between malt Scotch whiskys, blended Scotch grain whiskys, American whiskys, and Canadian whiskys: -23.4~ -24.3, -16.8~-21.0, -11.0~-11.5 and -9.5~13.9, respectively. In addition, malt Scotch whiskys contained 40~230 $mg/{\ell}$ of fructose; blended Scotch whiskys, 20~120 $mg/{\ell}$; American whiskys, 50~70 $mg/{\ell}$; and Canadian whiskys, 20~100 $mg/{\ell}$, demonstrating that the fructose content of single-malt whiskys was twice the average fructose content. On the other hand, malt Scotch whiskys contained 30~170 $mg/{\ell}$ of glucose; blended Scotch whiskys, 20~120 $mg/{\ell}$; American whiskys, 20~30 $mg/{\ell}$; and Canadian whiskys, 10~110 $mg/{\ell}$, demonstrating that the glucose content of single-malt whiskys exceeded the average glucose content. This study's results can be used as a database of classification for whiskys based on the fermentation of raw ingredients and the period of maturation for distinguishing between different types of whiskys. In addition, the results can facilitate the verification of genuine whiskys by allowing for the identification of different types of whiskys based on the period of maturation.

Invasion of Korean Pine Seedlings Originated from Neighbour Plantations into the Natural Mature Deciduous Broad-leaved Forest in Gwangneung, Korea (광릉 천연활엽수 성숙림에서 주변 인공림으로부터 잣나무 치수의 침입 정착)

  • Kang, Ho Sang;Lim, Jong-Hwan;Chun, Jung Hwa;Lee, Im Kyun;Kim, Young Kul;Lee, Jae Ho
    • Journal of Korean Society of Forest Science
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    • v.96 no.1
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    • pp.107-114
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    • 2007
  • Establishments of the seedlings inside the natural forest from adjacent artificial forests would be an important factor in forest stand dynamics. This study was conducted to see the invasion of Korean pine (Pinus koraiensis) seedlings which is not native in this region, into the natural deciduous broad-leaved forest in Gwangneung, Korea. There is no mother tree at the I ha study site while the number of naturally regenerated P. koraiensis seedlings was 345 trees and 56% of them were clumped with more than two seedlings at each point. Applying the image segmentation method to IKONOS satellite image of January, 2003, the distance from the center of 1 ha study site to the nearest mother tree and plantation of Korean pine were 200 m and 270 m, respectively. The average height and root-collar diameter of the seedlings were 34 em and 7 mm, respectively and the age of 207 seedlings (60%) were below 5 years old. Most abundant range of soil moisture gradient and LAl (leaf area index) were from 16 to 20% and those of LAI were from 3.1 to 3.5. To understand the dynamics and seed dispersal pattern of Korean pine in the Gwangneung natural deciduous broad-leaved forests, additional studies not only long-term monitoring of growth and mortality of naturally regenerated Korean pine seedlings but also application of stable isotope analysis and molecular genetic techniques was recommended.

Effect of Rare Earth Elements on Proliferation and Fatty Acids Accumulation of 3T3-L1 Cells

  • He, M.L.;Yang, W.Z.;Hidari, H.;Rambeck, W.A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.1
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    • pp.119-125
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    • 2006
  • The present study including two experiments was designed to determine the effect of media containing different rare earth elements (REE) on proliferation and fatty acids accumulation in 3T3-L1 cell cultures. In Experiment 1, 3T3-L1 preadipocytes in 96-well plates ($1.5{\times}10^4cells/ml$) were cultured with Dulbecco's modified Eagle's medium (DMEM) containing 10% fetal bovine serum (FBS) for 24 h. Then the media were changed to the following 10 different media for 48 h: DMEM containing 10% FBS for the control; the above media containing $5{\mu}M$, $10{\mu}M$ or $15{\mu}M$ of $LaCl_3$, $CeCl_3$ or the mixture of these REE chlorides. The proliferation rate of the cells was measured and compared by a non-isotope method-XTT method. In Experiment 2 the cells in 24-well plates ($1.5{\times}10^4cells/ml$) were cultured in DMEM containing 10% FBS for 7 days until confluent and then were changed to above DMEM containing dexamethasone, methyl-isobutylxanthine and insulin (DMI) for two days. Afterwards the media were changed to the 10 different media with REE supplements as in Experiment 1 and cultured for 6 days. The cells were then harvested for fatty acids analysis by gas chromatography. It was found that supplementation of La (5, 10 and $15{\mu}M$), Ce ($5{\mu}M$ and $15{\mu}M$) and the mixture REE (5, 10 and $15{\mu}M$) stimulated (p<0.05) the proliferation of 3T3-L1 preadipocytes (Experiment 1). In the differentiating 3T3-L1 cells supplementation of La ($5{\mu}M$ and $10{\mu}M$), Ce ($5{\mu}M$) and the mixture REE ($5{\mu}M$ and $15{\mu}M$) decreased (p<0.05) the concentration of monounsaturated fatty acids (MUFA) per $10^5cells$, while the supplementation of La ($5{\mu}M$), Ce ($5{\mu}M$) and the mixture REE ($15{\mu}M$) increased (p<0.05) the ratio of saturated fatty acids (SFA) to MUFA. These results indicate that the supplementation of REE to the media may affect proliferation, differentiation and lipogenesis rates of 3T3-L1 cells. However, the effect may depend upon the level or type of REE applied.

Holocene Environments of the Buyeo Area Choongnam Province: Reconstructed from Carbon Isotopic and Magnetic Evidences from Alluvial Sequences (충남 부여지역의 홀로세 기후변화 -탄소동위원소분석과 대자율분석을 이용하여-)

  • Park, Kyeong;Park, Ji-Hoon
    • Journal of the Korean Geographical Society
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    • v.46 no.4
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    • pp.396-412
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    • 2011
  • Multi-proxy analysis was used to produce a high-resolution paleoclimatic record from a thick section of the Holocene alluvial fan deposit in Gatap-ri, Buyeo. According to ${\delta}^{13}C$ analyses, five minor climate fluctuations can be determined. From the stage I to stage VI, climate changes are as follows: cool-dry, warm-humid, cool-dry, warm humid, drier than stage IV, and finally more humid environment than stage V. According to magnetic susceptibility records, four different stages can be identified, among which stage ii shows the highest susceptibility. Stage-i deposit is derived from sediments of back marsh-type wetland. Stage-ii and stage-iii deposits, however, show higher magnetic susceptibility because magnetite-enriched soil from weathered upland was transported to the area to form an alluvial fan deposits. Stage-iv deposit is comparable to the modern plow horizon.

The Characteristic and Origin of Organic Matter in the ODP Leg 204 Site 1249C and Site 1251B (ODP Leg 204 Site 1249C와 Site 1251B 퇴적물의 유기물 기원 및 지화학적 특성)

  • Shim, Eun-Hyoung;Yun, Hye-Su;Lee, Young-Joo;Han, Sang-Young
    • Economic and Environmental Geology
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    • v.47 no.1
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    • pp.71-85
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    • 2014
  • To study biogeochemical characteristics and origin organic matter, sediment samples were taken from Site of 1249C and Stie 1251B of ODP Leg 204. Data of Rock-Eval, isotope, and element analysis generally indicate dominance of marine organic matter in sediments deposited under marine sedimentary environment. Only Rock-Eval data are somewhat different from those of others owing to under-maturation of organic matter. Samples of Site 1249C show high content of gas hydrate, whereas Site 1251B low content of gas hydrate in some intervals of the core. This result may be accounted to different location of two cores and presence of transportation passage (Horizon A, BSR 2) of thermogenic gas in the core, 1249 C. However, Site 1251B Located in the basin of low accumulation of gas hydrate is presumed to be limited in the gas hydrate production. Because not only transportation passage is limited to move thermogenic gas from the core, but also gas supply was not enough. Therefore, the biogenic gas that resulted from diagenesis of there sediment is superior.

Metallurgical study of bronze bells excavated from the Miruksa (temple) site in Iksan (익산 미륵사지 출토 동종의 금속학적 연구)

  • Cho, Nam-chul;Huh, Il-kwon;Kang, Hyung-tae
    • 보존과학연구
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    • s.27
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    • pp.5-22
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    • 2006
  • Mireuksa is a temple that was established in the Baekjea Period and continued around to the 16thcentury. The sites of the temple throughout diverse periods such as the United Shilla Period, KoryuPeriod, and Chosun Period including the one of the early temple in the late Baekjea Period were discovered. In those temple sites, there were lots of diverse artifacts discovered including artifacts in the Bronze Age. In this study, the compositions of four bronze bells excavated from Mireuksa site in Iksan were analyzed and the manufacturing technique of bronze bells was studied through the observation of microstructure. Also, the analytical cases of ancient bronze bells were collected and compared. Furthermore, the provenance study of the bronze bells site was attempted with the Pbisotope ratio. The results aim to offer crucial keys for discovering the aspect of society as well as information about the origin, development, and the route of propagation of ancient technologies. Bronze bell No. 1 showed an unexpected composition as Cu was found 98.5% in it. There were shown twins which were created by annealing and an even phase in the fine grains. It was also shown that bronze bell No. 2 and 4 had a high content of Pb although they showed a similar composition with general bronze bells in terms of Sn content. As shown in the analysis characteristics table of Korean bronze bell of this study, the ancient bronze bell used Pb of which content was limited to 2.12% in general, however, the results showed 15.5% and 13.2% respectively, which is an excessive amount. Asa result of analyzing inclusion in the microstructure of bronze bell No. 2, it was found that sulfide group mineral was used since there appeared S(14.55%). Also, it was proven that $CuFeS_2$ or$Cu_5FeS_4$ was used as a raw material because there was a small amount of Fe. As a result of analyzing inclusion of bronze bell No. 4, the bronze bell sample contained S(13.43%) and it is thought that sulfide group mineral was used, however, it had no Fe. Therefore, it is not connected to $CuFeS_2$ which is the main mineral of Korea. In addition, a strain line was shown with processing in bronze bell No. 2 and 4. As a result of provenance study of bronze bell No. 2 and 4 using the Pb isotope ratio, they or their raw materials are estimated to come from the southern China. Bronze bell No. 3 showed only Cu and Sn, and it is featured with a relatively low amount of Sn(6.63%). The microstructure has only phase, andintergranular corrosion was highly in progress.

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Hydro-Biogeochemical Approaches to Understanding of Water and Carbon Cycling in the Gwangneung Forest Catchment (수문생지화학적 접근을 통한 광릉 산림 유역의 물과 탄소 순환 이해)

  • Kim, Su-Jin;Lee, Dong-Ho;Kim, Joon;Kim, Sung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.2
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    • pp.109-120
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    • 2007
  • The information on flowpath, storage, residence time, and interactions of water and carbon transport in a catchment is the prerequisite to the understanding and predicting of water and carbon cycling in the mountainous landscapes of Korea. In this paper, along with some up-to-date results, we present the principal methods that are currently used in HydroKorea and CarboKorea research to obtain such information. Various catchment hydrological processes have been examined on the basis of the water table fluctuations, the end-member mixing model, the cross correlation analysis, and cosmogenic radioactive isotope activity. In the Gwangneung catchment, the contribution of surface discharge was relatively large, and the changes in the amount, intensity and patterns of precipitation affected both the flowpath and the mean residence time of water. Particularly during the summer monsoon, changes in precipitation patterns and hydrological processes in the catchment influenced the carbon cycle such that the persistent precipitation increased the discharge of dissolved organic carbon (DOC) concentrated in the surface soil layer. The improved understanding of the hydrological processes presented in this report will enable a more realistic assessment of the effects of climate changes on the water resource management and on the carbon cycling in forest catchments.

The Relationship among the Indicator PCBs in Breast Milk and Dietary Habits and Demographic Factors in Women Living in Urban Areas (대도시에 거주하는 여성의 모유 중 Indicator PCBs와 식이습성 및 인구통계학적 인자간의 관계)

  • We, Sung-Ug;Kim, Ki-Ho;Cho, Bong-Hui;Cho, Yu-Jin;Yoon, Cho-Hee;Min, Byung-Yoon
    • Journal of Environmental Health Sciences
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    • v.36 no.3
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    • pp.199-207
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    • 2010
  • In this study, breast milk levels of indicator polychlorinated biphenyls (PCBs) were estimated, and statistics drawn, for 22 Koreans in the general population, aged 26-38, who had resided in metropolitan areas for more than 5 years without occupational exposure to organochlorine pollutants. Concentrations of indicator PCBs were measured using the isotope dilution method with a high resolution gas chromatograph/high resolution mass detector, which provided accurate and precise data for investigation of trends, and international comparisons. The geometric mean of total indicator PCB levels was 22.3 ng/g lipid, which is significantly lower than the level in individuals from European countries. Overall, the geometric mean and 95th percentile of the most abundant congener PCB 153 were 8.04 ng/g lipid and 16.4 ng/g lipid, respectively. PCB congeners 138, 153 and 180 together accounted for about 75% of the indicator congeners analyzed. Breast milk total indicator PCB concentrations were significantly associated with age and parity, but not with body mass index (BMI), rate of body weight increase, or smoking habits. The geometric mean level of PCB 153 in breast milk from mothers with a pre-pregnant BMI < $21\;kg/m^2$ was significantly higher than in pre-pregnant women with a BMI of ${\geqslant}\;21\;kg/m^2$ (p<0.05). Women who ate more fish, meat, and milk products did not have significantly higher total indicator PCB levels than those who ate less of these products, but a significant difference in PCB 153 levels was demonstrated between the subjects consuming higher (11.45 ng/g lipid) and lower (6.79 ng/g lipid) amounts of fish (p<0.05), after adjusting for confounders. These results suggest that age, parity and fish intake are the important factors affecting the concentrations of indicator PCBs in these subjects.

Metallic Mineralogical Characteristics of Forged Iron Axe from the Wood-framed Tomb at the Hwangseongdong, Gyeongju, Korea (경주 황성동 목곽묘 출토 단조 철부의 금속광물학적 특성)

  • Kim, Jeong-Hun;Yi, Ki-Wook;Lee, Chan-Hee
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.231-245
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    • 2007
  • The forged iron axe of the middle 3rd Century found in the No. 2 wood-framed tomb from the Hwangseongdong site, Gyeongju is rectangular on the plane level. The iron axe shines in met-allic luster, which is light grey with pale creamy tint. The result of X-ray diffraction analysis shows that the axe consists of magnetite and geothite, which can explain why the composition and texture of the original ore has been kept intact. There are fine-grained quartz, calcite, mica, magnetite, amphibole, unknown tungsten minerals, pyroxene and olivine inside the axe. Those must be the impurities that they failed to remove in the thermal treatment process. Generally, the iron axe consists mainly of pearlite texture coexisting ferrite and cementite, and show high carbon contents with homogeneous distribution. It can be interpreted the axe was carburized after the material was made to resemble pure iron. The decarbonization work didn't go well along the process marks. Crude ores of the iron axe are possible utilized by magnetite from the Ulsan mine on the basis of the occurrences and inclusions. It's estimated that the original ore was bloom produced in low-temperature reduction and formed around in $727^{\circ}C$, which is eutetic temperature.