• Title/Summary/Keyword: Isothermal characteristics

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Moisture Absorption Characteristics of Pt/Nafion Membrane for PEMFC Prepared by a Drying Process (건식법에 의해 제조한 PEMFC용 Pt/나피온 막의 흡습 특성)

  • Lee, Jae-Young;Lee, Hong-Ki
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.4
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    • pp.310-315
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    • 2012
  • A simple drying process was developed for the preparation of a Pt/Nafion self-humidifying membrane to be used for a proton-exchange membrane fuel cell (PEMFC). Platinum (II) bis (acetylacetonate), $Pt(acac)_2$ was sublimed, penetrated into the surface of a Nafion film and then reduced to Pt nanoparticles simultaneously without any support of a reducing agent in a glass reactor at $180^{\circ}C$ for 15 min. The process was carried out in $N_2$ atmosphere to prevent the oxidation of Pt nanoparticles at high temperature. The morphology and distribution of the Pt nanoparticles were observed by transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS), and we found that the average Pt particle size was ca. 3.7 nm, the penetration depth was ca. $17{\mu}m$. Almost all Pt nanoparticles were formed just beneath the surface and the number density decreased rapidly as the penetration depth increased. To estimate water absorption characteristics of the Nafion membranes, water uptake at an isothermal condition was measured by dynamic vapor sorption (DVS), and it was found that water uptake of the Pt/Nafion membrane was higher than that of the neat Nafion membrane.

THD Lubrication Analysis of a Surface-Textured Parallel Thrust Bearing with Rectangular Grooves: Part 1 - Effect of Film-Temperature Boundary Condition (사각형 그루브로 Surface Texturing한 평행 스러스트 베어링의 열유체윤활 해석: 제1보 - 유막온도경계조건의 영향)

  • Park, TaeJo;Kang, JeongGuk
    • Tribology and Lubricants
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    • v.38 no.6
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    • pp.267-273
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    • 2022
  • Surface texturing is the latest technology for processing grooves or dimples on the friction surface of a machine. When appropriately applied, it can reduce friction and significantly increase durability. Despite many studies over the past 20 years, most are isothermal (ISO) analyses in which the viscosity of the lubricant is constant. In practice, the viscosity changes significantly owing to the heat generated by the viscous shear of the lubricant and film-temperature boundary condition (FTBC). Although many thermohydrodynamic (THD) analyses have been performed on various sliding bearings, only few results for surface-textured bearings have been reported. This study investigates the effects of the FTBC and groove number on the THD lubrication characteristics of a surface-textured parallel thrust bearing with multiple rectangular grooves. The continuity, Navier-Stokes, and energy equations with temperature-viscosity-density relations are numerically analyzed using a commercial computational fluid dynamics code, FLUENT. The results show the pressure and temperature distributions, variations of load-carrying capacity (LCC), and friction force with four FTBCs. The FTBCs greatly influence the lubrication characteristics of surface-textured parallel thrust bearings. A groove number that maximizes the LCC exists, which depends on the FTBC. ISO analysis overestimates the LCC but underestimates friction reduction. Additional analysis of various temperature boundary conditions is required for practical applications.

THD Lubrication Analysis of a Surface-Textured Parallel Thrust Bearing with Rectangular Grooves: Part 2 - Effect of Groove Depth (사각형 그루브로 Surface Texturing한 평행 스러스트 베어링의 열유체윤활 해석: 제2보 - 그루브 깊이의 영향)

  • TaeJo Park;JeongGuk Kang
    • Tribology and Lubricants
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    • v.39 no.1
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    • pp.21-27
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    • 2023
  • Surface texturing is widely applied to friction surfaces of various machine elements. Most of the theoretical studies have focused on isothermal (ISO) analyses which consider constant lubricant viscosity. However, there have been limited studies on the effect of oil temperature increase owing to viscous shear. Following the first part of the present study that investigated the effects of film-temperature boundary condition (FTBC) and groove number on the thermohydrodynamic (THD) lubrication characteristics of a surface-textured parallel thrust bearing with multiple rectangular grooves, this study focuses on the effect of groove depths. Current study numerically analyzes the continuity, Navier-Stokes, and energy equations with temperature-viscosity-density relations using a commercial computational fluid dynamics (CFD) software, FLUENT. The results of variation in temperature, velocity, and pressure distributions as well as load-carrying capacity (LCC) and friction force indicate that groove depth and FTBC significantly influence the temperature distribution and pressure generation. The LCC is maximum near the groove depth at which the vortex starts, smaller than the ISO result. For intense grooves, the LCC of THD may be larger than that from ISO. The frictional force decreases as the groove becomes deeper, and decreases more significantly in the case of THD. The study shows that groove depth significantly influences the THD lubrication characteristics of surface-textured parallel thrust bearings.

Change in Microstructure with the Gas Quenching Rate during Austempering Treatment of SAE 1078 Steel (SAE 1078 강의 오스템퍼링 열처리시 가스 퀜칭 속도에 따른 미세조직의 변화)

  • Gi-Hoon Kwon;Hyunjun Park;Kuk-Hyun Yeo;Young-Kook Lee;Sang-Gweon Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.3
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    • pp.121-127
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    • 2023
  • When high carbon steel is heated in an appropriate austenizing temperature range and subjected to austempering, the size and shape of lamellar structure can be controlled. The high carbon steel sheet having the pearlite structure has excellent elastic characteristics because it has strong restoring force when properly rolled, and is applied in a process known as patenting-process using lead bath. In the case of isothermal treatment using lead-medium, it is possible to quickly reach a uniform temperature due to high heat transfer characteristics, but it is difficult to replace it with process technology that requires treatment to remove harmfulness lead. In this study, we intend to develop fluidization technology using garnet powder to replace the lead medium. After heating the high-carbon steel, the cooling rate was changed by compressed air to the vicinity of the nose of the continuous cooling curve, and then maintained for 90 s and then exposed to room temperature. The microstructure of the treated specimens were analyzed and compared with the existing products treated with lead bath. The higher the flow rate of compressed air, the faster the cooling rate to the pearlite transformation temperature, so lamellar spacing decreases and the hardness tends to increase.

Characteristics of the Co-Combustion of Coal and Bio-Solid Fuel using Biomass as an adjunct (석탄과 보조제로 바이오매스를 사용한 바이오 고형연료의 혼소 특성)

  • Hyeon, Wan-Su;Jin, Yong-Gyun;Jo, Eun-Ji;Han, Hyun-Goo;Min, Seon-Ung;Yeo, Woon-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.2
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    • pp.49-57
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    • 2020
  • Due to the sewage sludge's characteristics of high water content and low calorific value, it is hard to use sewage sludge as an energy source. In this study, we investigated production of bio-solid fuel which is mixed both sewage sludge and woody biomass in order to improve the sewage sludge's characteristics and replace fossil fuels. A thermogravimetric analysis was used to investigate the co-combustion characteristics of the mixed coal and bio-solid fuel of 5%, 10%, 15%, respectively. The analysis was carried out under non-isothermal conditions by raising the internal temperature of 25℃ to 900℃ with an increment of 10℃/min. In the case of comparing single coal sample and mixture sample of coal and bio-solid fuel, the initiation combustion temperature has slightly changed. However, both the maximum combustion temperature and the termination start combustion temperature were hardly noticeable. The initiation combustion was occurred between 200~315℃ and the thermal decomposition causing a significant weight change occurred between 350~700℃. As a result of the kinetic analysis of the co-combustion, the activation energy was decreased as the mixing rate was higher. Therefore, it is able to co-combust the mixed coal and bio-solid fuel in power plants.

Permeability Aftereffect in FeCuNbSiB Alloy (FeCuNbSiB 합금의 투자율 여효)

  • Lee, Yong-Ho;Sin, Yong-Dol;No, Tae-Hwan;Gang, Il-Gu
    • Journal of the Korean Magnetics Society
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    • v.2 no.3
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    • pp.216-221
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    • 1992
  • Annealing effects on the permeability aftereffect(disaccommodation) of liquid quenched single strip $Fe_{73.5}Cu_1Nb_3Si_{16}B_{6.5}$ alloys were investigated with pulse method. The initial susceptibility X, $B_{10},$ (the flux density at 10 Oe) and disaccommodation intensity D (D = [X(1 s)-X(64 s)]/X(1 s), where X(1 s) and X(64 s) are the susceptibility of 1 and 64 s of rest time after A. C. demagnetization) were about 800, 0.8 T and 16 %, respectively. The soft magnetic properties were improved with isothermal annealing for 1 hour at $300{\sim}600^{\circ}C.$ X, $B_{10},$ and D at $570^{\circ}C$ of optimum annealing temperature were 15000, 1.2 T and 1.1 %, respectively. The origin of the change of characteristics were examined with fine crystalline structure and magnetostriction.

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A Study on Cure Behavior of an Epoxy/Anhydride System and Silica Filler Effects (에폭시-산무수물 조성물의 경화거동 및 실리카 첨가에 따른 특성변화 연구)

  • Lee, Chung Hee;Kim, Kyoung-Mahn
    • Journal of Adhesion and Interface
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    • v.10 no.3
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    • pp.117-126
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    • 2009
  • Epoxy/anhydride systems with silica filler were studied to improve the cure behavior and characteristics. To study the curing process of epoxy/anhydride using DSC and a stress rheometer, it was observed that gelation temperature increased by increasing the thermal rate or in high isothermal conditions, while it was observed that the degree of cure at gelation decreased. Thermal stability of the epoxy/anhydride system showed any increment by increasing silica contents, except slight decrease of weight by containing humidity. The epoxy resin cured with 30% of silica filler decreased coefficient thermal expansion (CTE) about 33% to show $40ppm/^{\circ}C$. Specimens filled with 30 wt% of silica showed 60% increase in storage modulus at $30^{\circ}C$ to show 3909 MPa compared with neat resin to 2,377 MPa. Epoxy/anhydride systems with surface treated silica by silane coupling agent decreased storage modulus.

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Studies on the Environmental Factors for Sap Extraction of Acer mono and the Resource Development of Its Community / Habitat Environment and Community Structure (고로쇠나무(Acer mono)의 수액출수에 미치는 환경요인과 그 군락의 자원화에 관한 연구: 생육지 환경과 군락의 구조)

  • 김철수;강애경
    • The Korean Journal of Ecology
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    • v.17 no.3
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    • pp.333-344
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    • 1994
  • Community structure and habitat characteristics of Acer mono stands were studied in Mt. Giri $(127{\circ}35'E.,\;35{\circ}18'N)$ and Mt. $Baekun(127{\circ}38'E.,\;35{\circ}05'N)$. The vegetation was investigated by the Braun-Blanquet's phytosociological method. Distribution of Acev mono was most abundant on eastern and western slopes in valley side. The community structure was composed of 4 layers and average number of species appeared in each quadrat was 24. Habitats were almost covered with exposed rocks and the surface soil was classified to clay loam. The isothermal date lines of Mt. Giri and Baekun were 130 and 120 days, respectively, which is the number of days with mean daily minimum temperature below zero during the year. The daily range of temperature was compared at 4 regions during sap extraction.

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Heat Transfer Characteristics During Gas Cooling Process of Carbon Dioxide in a Horizontal Tube (수평관내 초임계 영역의 Co2 냉각 열전달 특성)

  • Son, Chang-Hyo;Lee, Dong-Gun;Oh, Koo-Kyu;Jeong, Si-Young;Kim, Young-Lyoul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.3
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    • pp.289-295
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    • 2004
  • The heat transfer coefficient and pressure drop during gas cooling process of carbon dioxide in a horizontal tube were investigated. The experiments were conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flowmeter, an evaporator, and a gas cooler(test section). The main components of the water loop consist of a variable-speed pump, an isothermal tank, and a flowmeter. The gas cooler is a counterflow heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus. The test section consists of smooth, horizontal stainless steel tube of the outer diameter of 9.53mm and of the inner diameter of 7.75mm. The length of the test section is 6m. The refrigerant mass fluxes were 200∼300kg/(m2$.$s) and the inlet pressure of the gas cooler varied from 7.5㎫ to 8.5㎫. The main results were summarized as follows : Pressure drop of CO2 increases with increasing gas cooler pressure. The friction factors of CO2 in a horizontal tube show a relatively good agreement with the correlation by Blasius. The heat transfer coefficient of CO2 in transcritical region increases with decreasing gas cooler pressure and decreasing mass flux of CO2. Most of correlations proposed in a transcritical region showed significant deviations with experimental data except for those predicted by Gnielinski.

Natural Convection in Tilted Square Enclosure with Inner Circular Cylinder at Different Vertical Locations (내부 원형 실린더의 위치 변화에 따른 기울어진 사각 밀폐계 내부의 자연대류 현상)

  • Jeong, Seung Jae;Yoon, Hyun Sik;Choi, Changyoung;Ha, Man Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.12
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    • pp.1113-1120
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    • 2013
  • A numerical analysis of the effect of the position of a circular cylinder in a $45^{\circ}$ tilted enclosure on natural convection in the enclosure is presented. The location of the cylinder is changed between -0.4 and 0.4. The Rayleigh number is varied between $10^3$ and $10^5$. The effect of the location of the cylinder on natural convection in the enclosure is analyzed by the isothermal line, stream line, and surface-averaged Nusselt number. The flow and heat transfer characteristics are independent of time in the range of the Rayleigh number and cylinder location that is considered in this study. The surface-averaged Nusselt number of the cylinder and enclosure increases as the cylinder gets closer to the wall of the enclosure.