• 제목/요약/키워드: Isothermal analysis

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유동 해석을 이용한 평판형 고체 산화물 연료전지의 성능 특성 분석 (II) - 비등온 모델 - (Performance Predictions of the Planar-type Solid Oxide Fuel Cell with Computational Flow Analysis (II) - Non-isothermal Model -)

  • 현희철;손정락;이준식;노승탁
    • 대한기계학회논문집B
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    • 제27권7호
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    • pp.963-972
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    • 2003
  • Performance characteristics of the planar-type solid oxide fuel cell (SOFC) are investigated by the analysis of flow fields coupled with heat and mass transfer phenomena in anode and cathode channels. For these purposes, performance analysis of the SOFC is conducted based on electrochemical reaction phenomena in electrodes and electrolyte coupled with flow fields in anode and cathode channels. In the present study, the isothermal model adopted in the previous paper prepared by the same authors is extended to the non-isothermal model by solving energy equation additionally with momentum and mass transfer equations using CFD technique. It is found that the difference between isothermal and non-isothermal models come from non-uniform temperature distribution along anode and cathode electrodes by solving energy equation in non-isothermal model. Non-uniform temperature distribution in non-isothermal model contributes to the increase of average temperature of the fuel cell and influences its performance characteristics.

변온 하중하에 있는 재료의 이력거동 예측을 위한 다층 모델에 관한 연구 (A Study on the Overlay Model for Description of Hysteresis Behavior of a Material under Non-isothermal Loading)

  • 김상호;서동훈;여태인
    • 한국자동차공학회논문집
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    • 제18권3호
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    • pp.133-142
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    • 2010
  • The present work focuses on the characterization of material parameters of the Overlay(multilinear hardening) model for analyzing the non-isothermal cyclic deformation. In the previous study, all the parameters were especially based on the Overlay theories, and a simple method was suggested to find out the best material parameters for the isothermal cyclic deformation analysis. Based on the previous research this paper f dther improves the isothermal parameters and suggests how to apply the isothermal parameters to the non-isothermal conditions especially for the description of TMF(Thermo-Mechanical Fatigue) hysteresis behavior. The parameters are determined and calibrated using 400 series stainless steel test data in the reference papers. For the implementation into ABAQUS, a user subroutine is developed by means of ABAQUS/UMAT. The finite element results show good agreement with test for the case of uniaxial non-isothermal cyclic loading, signifying the proposed method can be used in the TMF analysis of the converter-inserted heavy duty muffler system and the stainless steel exhaust-manifold system which are to be done in our future research.

알루미늄 합금박판 비등온 성형공정의 유한요소 해석 및 실험적 연구 (제2부:해석) (Finite Element Analysis and Experimental Investigation of Non-isothermal Forming Processes for Aluminum-Alloy Sheet Metals (Part2:Analysis))

  • 김성민;구본영;금영탁;김종호
    • 소성∙가공
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    • 제8권3호
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    • pp.252-261
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    • 1999
  • The 3-dimensional finite element program is developed to analyze the non-isothermal forming processes of aluminum-alloy sheet metals. Bishop's method is introduced to solve the heat balance and force equilibrium equations. Also, Barlat's non-quadratic anisotropic yield function depicts the planar anisotropy of the aluminum-alloy sheet. To find an appropriate constitutive equation, four different forms are reviewed. For the verification of the reliability of the developed program, the computational try-outs of the non-isothermal cylindrical cupping processes of AL5052-H32 and Al1050-H16 are carried out. As results, the constitutive equation relating to strain and strain-rate, in which the constants are represented by the 5th-degree polynomials of temperature, is in good agreement with measurement. The computational try-outs can predict optimal forming conditions in non-isothermal forming processes.

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Pyrolysis Properties of Lignins Extracted from Different Biorefinery Processes

  • Lee, Hyung Won;Jeong, Hanseob;Ju, Young-Min;Youe, Won-Jae;Lee, Jaejung;Lee, Soo Min
    • Journal of the Korean Wood Science and Technology
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    • 제47권4호
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    • pp.486-497
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    • 2019
  • The non-isothermal and isothermal pyrolysis properties of H lignin and P lignin extracted from different biorefinery processes (such as supercritical water hydrolysis and fast pyrolysis) were studied using thermogravimetry analysis (TGA) and pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). The lignins were characterized by ultimate/proximate analysis, FT-IR and GPC. Based on the thermogravimetry (TG) and derivative thermogravimetry (DTG) curves, the thermal decomposition stages were obtained and the pyrolysis products were analyzed at each thermal decomposition stage of non-isothermal pyrolysis. The isothermal pyrolysis of lignins was also carried out at 400, 500, and $600^{\circ}C$ to investigate the pyrolysis product distribution at each temperature. In non-isothermal pyrolysis, P lignin recovered from a fast pyrolysis process started to decompose and produced pyrolysis products at a lower temperature than H lignin recovered from a supercritical water hydrolysis process. In isothermal pyrolysis, guaiacyl and syringyl type were the major pyrolysis products at every temperature, while the amounts of p-hydroxyphenyl type and aromatic hydrocarbons increased with the pyrolysis temperature.

Kinetics of Thermal Degradation of Polypropylene/Nanoclay/Wood Flour Nanocomposites

  • Mohan, D. Jagan;Lee, Sun-Young;Kang, In-Aeh;Doh, Geum-Hyun;Park, Byung-Dae;Wu, Qinglin
    • 한국응용과학기술학회지
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    • 제24권3호
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    • pp.278-286
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    • 2007
  • As a part of enhancing the performance of wood-plastic composites (WPC), polypropylene (PP)/ nanoclay (NC)/ wood flour (WF) nanocomposites were prepared using melt blending and injection molding process to evaluate their thermal stability. Thermogravimetric analysis (TGA) was employed to investigate thermal degradation kinetics of the nanocomposites both dynamic and isothermal conditions. Dynamic scans of the TGA showed an increased thermal stability of the nanocomposites at moderate wood flour concentrations (up to 20 phr, percentage based on hundred percent resin) while it decreased with the addition of 30 phr wood flour. The activation energy $(E_a)$ of thermal degradation of nanocomposites increased when nanoclay was added and the concentration of wood flour increased. Different equations were used to evaluate isothermal degradation kinetics using the rate of thermal degradation of the composites, expressed as weight loss (%) from their isothermal TGA curves. Degradation occurred at faster rate in the initial stages of about 60 min., and then proceeded in a gradual manner. However, nanocomposites with wood flour of 30 phr heated at $300^{\circ}C$ showed a drastic difference in their degradation behavior, and reached almost a complete decomposition after 40 min. of the isothermal heating. The degree of decomposition was greater at higher temperatures, and the residual weight of isothermal degradation of nanocomposites greatly varied from about 10 to 90%, depending on isothermal temperatures. The isothermal degradation of nanocomposites also increased their thermal stability with the addition of 1 phr nanoclay and of wood flour up to 20 phr. But, the degradation of PP100/NC1/MAPP3/WF30 nanocomposites with 30 phr wood flour occurs at a faster rate compared to those of the others, indicating a decrease in their thermal stability.

국토환경계획 정도(精度) 향상 목적의 지형고도속성을 반영한 한반도 등온분포도 작성 (Isothermal Distribution Map on the Korean Peninsula to Improve the Accuracy of the Environmental Planning)

  • 김원주;이관규
    • 한국환경복원기술학회지
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    • 제11권3호
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    • pp.87-93
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    • 2008
  • In order to manage national environment effectively, one has to understand its ecological traits. The difference of temperature determines ecological traits of each respective region. In other words, temperature differentials on surface make a great impact on botanical structure. Currently, isothermal data-produced by meteorological stations based upon time series analysis-are widely used to plan and manage national environment. Nonetheless, the isothermal data do not reflect real surface temperature of regions. Because of numerous mountainous terrains in the Korean peninsula where temperature varies widely according to altitude, the range of temperature distribution-that reflects altitudinal change-has to be paid special attention. This study aims at expressing in space isothermal distribution that is necessary to plan and manage national environment effectively. In addition, not just South Korea, but also North Korea was included for isothermal distribution. As a result, this study corrected established isothermal lines up to date and demonstrated that altitude, latitude, and distance from coastal lines greatly influence temperature distribution of the Korean peninsula.

A Study on Transformation of Dynamic DSC Results into Isothermal Data for the Formation Kinetics of a PU Elastomer

  • Ahn, WonSool
    • Elastomers and Composites
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    • 제53권2호
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    • pp.52-56
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    • 2018
  • The present study examines the transformation of dynamic DSC data into the equivalent isothermal data for the formation kinetics of a polyurethane elastomer. The reaction of 2'-dichloro-4,4'-methylenedianiline (MOCA) with a PTMG/TDI-based isocyanate prepolymer was evaluated. DSC measurement was performed in the dynamic scanning mode with several different heating rates to obtain the reaction thermograms. Then, the data was transformed into the isothermal data through a procedure based on Ozawa analysis. The main feature of this procedure was the transformation of $({\alpha}-T)_{\beta}$ curves from dynamic DSC into $({\alpha}-t)_T$ curves using the isoconversional $(t-T)_{\alpha}$ diagram. Validity was discussed for the relationship between the dynamic DSC data and the transformed isothermal results.

저온의 순수물속에 잠겨있는 등온수직 원기둥에 의한 자연대류 열전달에 종횡비가 미치는 영향 (Effects of aspect ratio on natural convective heat transfer from a vertical isothermal cylinder immersed in cold pure water)

  • 유갑종;엄용균;이성진
    • 대한기계학회논문집
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    • 제15권2호
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    • pp.677-684
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    • 1991
  • A numerical analysis is performed about the effects of aspect ratio on natural convective heat transfer from a vertical isothermal cylinder of 0.deg. C immersed in cold pure water. The results of analysis include velocity profiles, temperature profiles and mean Nusselt number of the steady flow region. As aspect ratio of vertical cylinder increases, the flow and heat transfer characteristics of vertical isothermal cylinder approach to those of vertical isothermal flat plate. Numerical solutions obtained for Rayleigh number and aspect ratio indicate the cylinders can be classified as short cylinder and long cylinder. In the cases of short cylinder and long cylinder, new heat transfer correlations are presented. Here, the coefficient values C of new heat transfer correlations are presented as the function of density extremum parameter $R^*/. Numerical results show that theoretical results are in close agreement with experimental results.ts.

등온 열처리에 따른 중탄소 베이나이트강의 미세조직과 기계적 특성 (Effect of Isothermal Heat Treatment on the Microstructure and Mechanical Properties of Medium-Carbon Bainitic Steels)

  • 이지민;이상인;임현석;황병철
    • 한국재료학회지
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    • 제28권9호
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    • pp.522-527
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    • 2018
  • This study investigates the effects of isothermal holding temperature and time on the microstructure, hardness and Charpy impact properties of medium-carbon bainitic steel specimens. Medium-carbon steel specimens with different bainitic microstructures are fabricated by varying the isothermal conditions and their microstructures are characterized using OM, SEM and EBSD analysis. Hardness and Charpy impact tests are also performed to examine the correlation of microstructure and mechanical properties. The microstructural analysis results reveal that granular bainite, bainitic ferrite, lath martensite and retained austenite form differently in the specimens. The volume fraction of granular bainite and bainitic ferrite increases as the isothermal holding temperature increases, which decreases the hardness of specimens isothermally heat-treated at $300^{\circ}C$ or higher. The specimens isothermally heat-treated at $250^{\circ}C$ exhibit the highest hardness due to the formation of lath martensite, irrespective of isothermal holding time. The Charpy impact test results indicate that increasing isothermal holding time improves the impact toughness because of the increase in volume fraction of granular bainite and bainitic ferrite, which have a relatively soft microstructure compared to lath martensite for specimens isothermally heat-treated at $250^{\circ}C$ and $300^{\circ}C$.

지하대수층을 이용한 축열시스템의 설계 (I) : 등온해석 (Design of an Aquifer Thermal Energy Storage System (I) : Isothermal Analysis)

  • 송영길;이관수;이태희;김양현
    • 설비공학논문집
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    • 제5권2호
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    • pp.102-110
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    • 1993
  • An isothermal analysis was conducted to develop the design tool of an aquifer thermal energy storage system. Taejeon aquifer was chosen for the analysis, and the variation of FRE(Fluid Recovery Efficiency) with respect to the aquifer natural velocity and thermal load were investigated. The analysis results were compared with those of ATESSS(Aquifer Thermal Energy Storage System Simulator) and agreed within 2% of discrepancy. It is recommended, based on the result of this study, that the system may be suitable for a large volume of hot or chill thermal energy storage system, such as for district heating or cooling.

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