• Title/Summary/Keyword: Isothermal Model

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Numerical Study of Land/Channel Flow-field Optimization in Polymer Electrolyte Fuel Cells (PEFCs) (I) -The Effects of Land/Channel Flow-field on Current Density and HFR Distributions- (고분자전해질형연료전지의 가스 채널 최적화를 위한수치적연구(I) -가스 채널 치수가 전류밀도와 HFR 분포에 미치는영향성-)

  • Ju, Hyun-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.9
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    • pp.683-694
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    • 2008
  • The performance and durability of Polymer Electrolyte Fuel Cells (PEFCs) are strongly influenced by the uniformity of current density, temperature, species distributions inside a cell In order to obtain uniform distributions in them, the optimal design of flowfield must be a key factor. In this paper, the numerical study of land/channel flowfield optimizations is performed, using a multi-dimensional, multi-phase, non-isothermal PEFC model. Numerical simulations reveal more uniform current density and HFR(High Frequency Resistance) distributions and thus better PEFC performance with narrower land/channel width where the less severe oxygen depletion effect near the land region and more uniform contact resistance variation along the in-plane direction are achieved. The present study elucidates detailed effects of land/channel width and assist in identifying optimal flow-field design strategies for the operation of PEFCs.

Sorption Isotherms and KocS Estimation of Pyrethroids in Sediments

  • Lee, Sang-Jin;Shin, Hyun-Moo
    • Journal of Environmental Science International
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    • v.12 no.11
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    • pp.1173-1179
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    • 2003
  • Laboratory sorption isotherm batch studies have been attempted to elucidate interaction of synthetic pyrethroids (bifenthrin and permethrin) with sediments and their fractions. As a nonlinear isothermal model, the Freundlich equation was applied to sorption results obtained from sediments to investigate the relationship between synthetic pyrethroids and sediments containing different amounts of organic carbon. Results demonstrated that the sorption capabilities of bifenthrin and cis- and trans-permethrin was in the order of bifenthrin, cis-permethrin and trans-permethrin, respectively, indicating that adsorbed bifenthrin was the most stable followed by cis- and trans-permethrin in all sediments. Their sorption capability was closely related to organic carbon contents in sediments. Higher sorption was observed in sediments containing higher organic carbon contents. Sorption study extended into the fractions, clay and humic acids, extracted from a sediment, indicated that higher sorption capacity in humic acids occurred than in the clay of both examined bifenthrin and permethrin. This study demonstrates the sorption of synthetic pyrethroids with sediments, and will help in the understanding of the transport and fate of synthetic pyrethroids existing in field sediments.

Urban Climate Mapping - The Case of Sanggye 4-Dong - (도시기후지도의 작성 -상계 4동을 중심으로-)

  • 송영배
    • Journal of the Korean Institute of Landscape Architecture
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    • v.29 no.6
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    • pp.27-36
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    • 2002
  • The objective of this study is to improve the quality of the atmospheric environment by incorporating the factors of meteorology and urban climate into the field of urban and environmental planning. To this end, we have conducted a study on CLIMATOP and the mapping of urban climate, which are basic data used to analyze changes in climatic factors and the stagnation and accumulation of air pollutants. In particular, we focused on understanding the formation and movement of cold fresh air and its influx into urban areas by measuring and analyzing climatic factors. As a study result, classification criteria far CLIMATOP and a urban climatic map were made. In addition, we analyzed a digital elevation model, climatic data, and isothermal curves. As a result, we identified the corridor through which cold fresh air moves. We also observed that the temperature of the fluxed cold fresh air increased as land use changed. When the results of this study are applied to urban re-development and re-building projects, which require preliminary environmental assessment and environmental impact assessment, the practice proposed by this study is expected to contribute to the natural purification of air pollution activating the movement of cold fresh air and its influx into urban areas.

Thermal Analysis and Equivalent Lifetime Prediction of Insulation Material for Nuclear Power Cable (원전 케이블용 절연재료의 열분석과 등가수명)

  • Kim, Ji-Yeon;Yang, Jong-Suk;Park, Kyeung-Heum;Seong, Baek-Yong;Bang, Jeong-Hwan;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.1
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    • pp.17-22
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    • 2016
  • The activation energy of a material is an important factor that significantly affects the lifetime and can be used to develop a degradation model. In this study, a thermal analysis was carried out to evaluate and collect quantitative data on the degradation of insulation materials like EPR and CSP used for nuclear power plant cables. The activation energy was determined from the relationship between log ${\beta}$ and 1/T based on the Flynn.Wall.Ozawa method, by a TGA test. The activation energy was also derived from the relationship between ln(t) and 1/T based on isothermal analysis, by an OIT test. The activation energy of EPR derived from thermal analysis was used to calculate the accelerated aging time corresponding to the number of years of use, employing the Arrhenius equation, and determine the elongation corresponding to the accelerated aging time.

A Finite Element Analysis of Thixoforging Process by using Arbitrarily Shaped Dies (임의 형상의 다이를 이용한 반용융 단조 공정의 유한요소해석)

  • Kang, Chung-Gil;Kim, Nam-Seok
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.9
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    • pp.123-134
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    • 1999
  • A new forming technology has been developed to fabricate near-net shape components by using aluminum alloys with globular microstructure. The estimations of filling characteristic in the forging simulation with arbitrarily shaped dies of SSM are calculated by finite element method with proposed algorithm. The proposed model and various boundary conditions for arbitrarily shaped die are investigated with the coupling calculation between the liquid phase flow and the solid phase deformation. The simulation processes with arbitrarily shaped dies are performed on the isothermal conditions and axisymmetric problems. To analyze the forging process simulation with SSM, new stress-strain relationship for semi-solid behaviour is described, and forging the liquid flow. Furthermore, For the purpose of getting net shape of SSM, it is important to be obtain a solid fraction in forging process with arbitrarily shaped dies. To produce a automotive part which have good mechanical properties, the filling pattern in accordance with die velocity and solid fraction distribution has to be estimated for arbitrarily shaped die.

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Effects of Additive and Preheat on the Partially Premixed $CH_4-Air$ Counter Flow Flames Considering Non-gray Gas Radiation

  • Park Won-Hee;Chang Hee-Chul;Kim Tae-Kuk
    • Journal of Mechanical Science and Technology
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    • v.20 no.2
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    • pp.242-250
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    • 2006
  • Detailed structures of the counterflow flames formed for different inlet fluid temperatures and different amount of additives are studied numerically. The detailed chemical reactions are modeled by using the CHEMKIN-II code. The discrete ordinates method and the narrow band based WSGGM with a gray gas regrouping technique (WSGGM-RG) are applied for modeling the radiative transfer through non-homogeneous and non-isothermal combustion gas mixtures generated by the counterflow flames. The results compared with those obtained by using the SNB model show that the WSGGM-RG is very successful in modeling the counterflow flames with non-gray gas mixture. The numerical results also show that the addition of $CO_2\;or\;H_2O$ to the oxidant lowers the peak temperature and the NO concentration in flame. But preheat of fuel or oxidant raises the flame temperature and the NO production rates. $O_2$ enrichment also causes to raise the temperature distribution and the NO production in flame. And it is found that the $O_2$ enrichment and the fuel preheat were the major parameters in affecting the flame width.

Modeling of combined thermal and mechanical action in roller compacted concrete dam by three-dimensional finite element method

  • Abdulrazeg, A.A.;Noorzaei, J.;Mohammed, T.A.;Jaafar, M.S.
    • Structural Engineering and Mechanics
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    • v.47 no.1
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    • pp.1-25
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    • 2013
  • A combined thermal and mechanical action in roller compacted concrete (RCC) dam analysis is carried out using a three-dimensional finite element method. In this work a numerical procedure for the simulation of construction process and service life of RCC dams is presented. It takes into account the more relevant features of the behavior of concrete such as hydration, ageing and creep. A viscoelastic model, including ageing effects and thermal dependent properties is adopted for the concrete. The different isothermal temperature influence on creep and elastic modulus is taken into account by the maturity concept, and the influence of the change of temperature on creep is considered by introducing a transient thermal creep term. Crack index is used to assess the risk of occurrence of crack either at short or long term. This study demonstrates that, the increase of the elastic modulus has been accelerated due to the high temperature of hydration at the initial stage, and consequently stresses are increased.

Effect of Radiation on Laminar Film Boiling of Binary Mixtures (2성분 혼합물질의 층류 막비등에서 복사열전달의 효과)

  • Seong Hyeon-Chan;Kim Kyoung-Hoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.10
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    • pp.942-951
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    • 2004
  • This paper presents the results of a theoretical study of the effect of radiation during free convective laminar film boiling for methanol/water binary mixtures on an isothermal vertical wall at atmospheric pressure. With the well-known boundary layer theory as a basis, a theoretical model has been formulated into consideration for mass diffusion at liquid phase. The equations are numerically solved by a similarity method to investigate the effects of radiation emissivity on the surface with various parameters such as wall superheat and composition of more volatile component at liquid phase far from the wall. From the results, the distributions of the physical quantifies are investigated in both phases. New correlations are proposed to predict the heat transfer coefficient of binary mixtures. It is shown that the proposed correlations are in good agreement with numerical results and with Bromley's correlation within maximum $11\%$ errors. It is also found that as the wall superheat is increased, radiation effect becomes more important.

Circumferential steady-state creep test and analysis of Zircaloy-4 fuel cladding

  • Choi, Gyeong-Ha;Shin, Chang-Hwan;Kim, Jae Yong;Kim, Byoung Jae
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2312-2322
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    • 2021
  • In recent studies, the creep rate of Zircaloy-4, one of the basic property parameters of the nuclear fuel code, has been commonly used with the axial creep model proposed by Rosinger et al. However, in order to calculate the circumferential deformation of the fuel cladding, there is a limitation that a difference occurs depending on the anisotropic coefficients used in deriving the circumferential creep equation by using the axial creep equation. Therefore, in this study, the existing axial creep law and the derived circumferential creep results were analyzed through a circumferential creep test by the internal pressurization method in the isothermal conditions. The circumferential creep deformation was measured through the optical image analysis method, and the results of the experiment were investigated through constructed IDECA (In-situ DEformation Calculation Algorithm based on creep) code. First, preliminary tests were performed in the isotropic β-phase. Subsequently in the anisotropic α-phase, the correlations obtained from a series of circumferential creep tests were compared with the axial creep equation, and optimized anisotropic coefficients were proposed based on the performed circumferential creep results. Finally, the IDECA prediction results using optimized anisotropic coefficients based on creep tests were validated through tube burst tests in transient conditions.

Analysis of cure behavior of low temperature curing liquid silicone rubber (LSR) for multi-material injection molding (이중사출 성형을 위한 저온 경화 액상실리콘고무 (LSR)의 경화 거동 분석)

  • Hyeong-min Yoo
    • Design & Manufacturing
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    • v.17 no.1
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    • pp.1-5
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    • 2023
  • In multi-material injection molding, since two or more materials with different process conditions are used, it is essential to maximize process efficiency by operating the cooling or heating system to a minimum. In this study, Liquid silicone rubber (LSR) that can be cured at a low temperature suitable for the multi-material injection molding was selected and the cure behavior according to the process conditions was analyzed through differential scanning calorimetry (DSC). Dynamic measurement results of DSC with different heating rate were obtained, and through this, the total heat of reaction when the LSR was completely cured was calculated. Isothermal measurement results of DSC were derived for 60 minutes at each temperature from 80 ℃ to 110 ℃ at 10 ℃ intervals, and the final degree of cure at each temperature was calculated based on the total heat of reaction identified from the Dynamic DSC measurement results. As the result, it was found that when the temperature is lowered, the curing start time and the time required for the curing reaction increase, but at a temperature of 90 ℃ or higher, LSR can secure a degree of cure of 80% or more. However, at 80 ℃., it was found that not only had a relatively low degree of curing of about 60%, but also significantly increased the curing start time. In addition, in the case of 110 ℃, the parameters were derived from experimental result using the Kamal kinetic model.

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