• Journal of Magnetics
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• 제21권3호
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• pp.303-307
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• 2016

$Y_{3-x}R_xFe_5O_{12}$ (R = La, Nd, and Gd) powder were fabricated using a sol-gel pyrolysis method. Their magnetic properties and crystalline structures were investigated using x-ray diffraction (XRD), a vibrating sample magnetometer (VSM), and $M{\ddot{o}}ssbauer$ Spectrometer. The $M{\ddot{o}}ssbauer$ spectra for the powders were taken at various temperatures ranging from 12 K to Curie temperature (Tc). The isomer shifts indicated that the valence states of Fe ions for the 16(a) and 24(d) sites have a ferric character. The saturation magnetization (Ms) increases from 32 to 34 (emu/g) for the YIG, and Nd-YIG, respectively. However, Ms decreases to 27 (emu/g) at Gd-YIG.

• 천문학회보
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• 제38권2호
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• pp.67.1-67.1
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• 2013

It has been known that HCN is one of ubiquitous high-density gas tracer, and the abundance ratio between HCN and its Isomer, HNC sensitively depends on kinetic temperature in star-forming regions. Here we investigate the molecular abundance ratio toward three different evolutionary phases of massive star formation: Infrared Dark Clouds, High-mass Protostellar Objects and Ultracompact HII Regions. We obtained the abundances of HCN and HNC using optically thin H13CN and HN13C lines observed with the KVN single-dish telescopes and MAMBO 1.2mm and SCUBA $850{\mu}m$ continuum data. According to our results, the ratio of [HCN]/[HNC] increases statistically with the evolutionary stage, indicative of the effect of temperature. We also found a strong anti-correlation between the column density of molecular hydrogen and the HNC abundance.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2003년도 생물공학의 동향(XII)
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• pp.382-385
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• 2003

Organic solvent tolerant bacterium, designated as strain BCNU 106 is a gram negative, rod-shaped aerobe and grows on benzene, toluene, ethylbenzene, and xylenes (BTEX) as a sole carbon source. According to 16S rDNA analysis and fatty acid analysis, strain BCNU 106 showed highest similarity to Pseudomonas syringae var. savastanoi (Pseudomonas savastanoi). Strain BCNU 106 was able to utilize toluene, ethylbenzene, both o-, m-, p-xylene , m-cresol and o-cresol. The degradation of o-, m-, p-xylene by strain BCNU 106 is particularly important, since o-xylene is a compound of considerable environmental interest, owing to its recalcitrance; and very few microorganism have been reported to utilize both o-, m-, p-xylene as a sole carbon source.

• Mass Spectrometry Letters
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• 제8권4호
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• pp.79-89
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• 2017

Ion mobility mass spectrometry (IM-MS) combines the advantages of ion mobility spectrometry (IMS) and MS for effective gas-phase ion analysis. Separation of ions based on their mobilities prior to MS can be performed without a great loss in other analytical figures of merit, and the extra dimension of analysis offered by IM can be beneficial for isomer and complex sample analyses. In this review, basic principles of IMS and IM-MS are described in addition to an introduction to various IMS techniques and commercial IM-MS instruments. The nature of collision cross-section (${\Omega}_D$), an important parameter determining the transport properties of ions in IMS, is also explained in detail.

• Journal of the Korean Wood Science and Technology
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• 제35권2호
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• pp.96-101
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• 2007

Seeds of Paulownia coreana were collected, extracted with acetone-$H_2O$ (7 : 3, v/v), concentrated under reduced pressure and successively fractionated with n-hexane, methylene chloride, ethyl acetate and water on a separatory funnel. The $H_2O$ soluble fraction was chromatographed on a Sephadex LH-20 column using aqueous methanol and ethanol-hexane as washing solvents. Two isomeric phenylethanoid glycosides, verbascoside (1) and isoverbascoside (2), and one epimeric phenylethanoid glycoside, campneoside II (3), were isolated and their structures were elucidated on the basis of chemical and spectroscopical data.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2011년도 제44차 학술발표회
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• pp.67-67
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• 2011

Recently, Phthalocyanine dye has attentions due to their excellent photochemical properties and used to optical applications such as chemical sensors. And azo groups can change photochemical properties in the UV irradiation because their molecualr structure reverse cis-trans isomer and changes cooperative motion, aggregation and so on. In this study, we synthesized the azo compound between amino pyridine and phenol. this azo derivative used the combination with 3-nitro phthalonitrile and makes phthalocyanine structure through the synthesis with 1,8-diazabicyclo[5.4.0]undec-7-ene(DBU), zinc acetate. Finally, we synthesized a new photoswiching dye zinc-phthalocyanine azo compound. This compound was studied by phothoswichiing phenomenon by UV irradiation and analyzed molecular aggregation through the SEM images.

• Natural Product Sciences
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• 제10권6호
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• pp.262-267
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• 2004

A reversed-phase liquid chromatographic method for decursin and decursinol angelate of Angelicae gigantis Radix, an important crude drug in Korean traditional medicine, was developed and validated. Decursin and decursinol angelate, the structure isomer (pyranocoumarin) each other, are the main organic constituents in Angelicae gigantis Radix. This method was developed using a RP-18 column, UV detector at 280 nm and 50% acetonitrile solution containing 0.01 M sodium dodecyl sulfate and 25 mM sodium dihydrogen phosphate (pH 5.0) as the mobile phase. Various validation parameters were included and evaluated satisfactorily. Linearity was established in range 2-75 mg/ml of decursin and decursinol angelate (correlation coefficient = 0.9997 and 0.9995, respectively). This analytical method showed good accuracy (98.1% and 99.5%, respectively). Precision (repeatability) revealed a relative standard deviation value of 1.71% (decursin) and 3.19% (decursinol angelate). For intermediate precision measure the considered variables were equipment and days. A robustness test showing the influence of deferent counter-ion concentration in mobile phase was also performed.

• 한국미생물·생명공학회지
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• 제19권6호
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• pp.561-567
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• 1991

Identification of the Actinomycetes isolate strain No. 497 producing an actinomycin antibiotic MT-497 was performed by ISP and chemotaxonomic methods. The strain Nu. 497 formed various shapes of sclerotia and smooth surface spore. Menaquinone MK-9 ($H_6, H_8$) and iso-, anteiso-branched $C_{15}C_{17}$ fatty acids were detected from whole cell extract. The wall chemotype of stram No. 497 was decided as wall chemotype I from the analysis of DAP isomer, peptidoglycan type and sugar pattern. From these morphological, chemotaxonomic characteristics and analysis of various physiological characteristics. the strain No. 497 was identified as Streptomyces nigrifaciens.

• 한국응용과학기술학회지
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• 제17권2호
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• pp.113-119
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• 2000

Alkylation of phenol with tert-butanol in the liquid phase on mordenite was studied. The influence of many reaction parameters such as calcination temperature, reaction temperature, t-butanol/phenol molar ratio on catalytic properties was discussed. The main products were 2,4-di-t-butylphenol, o-t-butylphenol, p-t-butylphenol, the last of these was wanted product. In order to enhance the selectivity of p-t-butylphenol, optimum conditions were recommended at $500^{\circ}C$ calcination temperature, $140^{\circ}C$ reaction temperature, 1.0 molar ratio of reactants over mordenite. P-t-butylphenol was formed with 90% isomer selectivity at optimum conditions after 4hr reaction. On the basis of the behavior obtained in the cases mentioned, optimum conditions and catalytic properties for t-butylation of phenol were provided.

• Bulletin of the Korean Chemical Society
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• 제26권4호
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• pp.619-628
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• 2005

We attempted to replace a benzopyran ring of 4-[(N-imidazol-2-ylmethyl)-4-chloroanilino]benzopyran, previously discovered as anti-angiogenic agent with antitumor activity, with pyranopyridines. The [3,2-c]-, [3,2-b]-, [2,3-c]-, and [2,3-b]-pyranopyridines with -(imidazol-2-ylmethyl)aniline moiety at the 4-position, were synthesized respectively, and evaluated for primary anti-angiogenic properties through primary cultured HUVEC tube formation assay. From this study, we found that the pyranopyridine ring, especially [3,2-b]- and [2,3-c]-isomer, can replace the benzopyran ring of the compound 1 and can be optimized through the introduction of substituents both on the pyranopyridine ring and the aniline moiety for the identification of a novel anti-angiogenic agent.