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Effect of Various Supports on the Catalytic Performance of V-Sb Oxides in the Oxidative Dehydrogenation of sobutane (이소부탄의 산화탈수소반응에 대한 여러 담지체에 따른 V-Sb 산화물 촉매 성능 효과)

  • Shamilov, N.T.;Vislovskiy, V.P.
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.81-85
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    • 2011
  • $V_{0.9}Sb_{0.1}O_x$ systems, bulk and deposited on different supports (five types of $\gamma$-aluminas, $\alpha$-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. Catalytic performance of VSb oxides has shown to be highly dependent on the support and the nature of the support decreasing in a series: $\gamma$-$Al_2O_3$ > $\alpha$-$Al_2O_3$ > Si-Al-O > $SiO_2$ $\approx$ MgO $\gg$ unsupported. Variation of the V-Sb-O-loading in the studied range of coverage (0.5-2 theoretical monolayer) only slightly influences the catalysts' activity and selectivity. The best catalytic performance of $\gamma$-alumina-supported $V_{0.9}Sb_{0.1}O_x$ systems can be explained by the optimal surface interaction between support and supported components resulting in the formation of well-spread amorphous active $VO_x$-component with vanadium in a high oxidation state.

Assessment of the Counter-Flow Thrust Vector Control in a Three-Dimensional Rectangular Nozzle (3차원 직사각형 노즐에서 역유동 추력벡터 제어 평가)

  • Wu, Kexin;Kim, Tae Ho;Kochupulickal, James Jintu;Kim, Heuy Dong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.1
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    • pp.34-46
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    • 2020
  • Computational assessment of gas-dynamic characteristics is explored for a three-dimensional counter-flow thrust vector control system in a rectangular supersonic nozzle. This convergent-divergent nozzle is designed by Method of Characteristics and its design Mach number is specially set as 2.5. Performance variations of the counter-flow vector system are illustrated by varying the gap height of the secondary flow duct. Key parameters are quantitatively analyzed, such as static pressure distribution along the centerline of the upper suction collar, deflection angle, secondary mass flow ratio, and resultant thrust coefficient. Additionally, the streamline on the symmetry plane, three-dimensional iso-Mach number surface contour, and three-dimensional turbulent kinetic energy contour are presented to reveal overall flow-field characteristics in detail.

A Study on Three-Dimensional Image Modeling and Visualization of Three-Dimensional Medical Image (삼차원 영상 모델링 및 삼차원 의료영상의 가시화에 관한 연구)

  • Lee, Kun;Gwun, Oubong
    • Journal of the Korea Computer Graphics Society
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    • v.3 no.2
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    • pp.27-34
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    • 1997
  • 3-D image modeling is in high demand for automated visual inspection and non-destructive testing. It also can be useful in biomedical research, medical therapy, surgery planning, and simulation of critical surgery (i.e. cranio-facial). Image processing and image analysis are used to enhance and classify medical volumetric data. Analyzing medical volumetric data is very difficult In this paper, we propose a new image modeling method based on tetrahedrization to improve the visualization of three-dimensional medical volumetric data. In this method, the trivariate piecewise linear interpolation is applied through the constructed tetrahedral domain. Also, visualization methods including iso-surface, color contouring, and slicing are discussed. This method can be useful to the correct and speedy analysis of medical volumetric data, because it doesn't have the ambiguity problem of Marching Cubes algorithm and achieves the data reduction. We expect to compensate the degradation of an accuracy by using an adaptive sub-division of tetrahedrization based on least squares fitting.

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The effect of thermocycling on the degree of conversion and mechanical properties of a microhybrid dental resin composite

  • Ghavami-Lahiji, Mehrsima;Firouzmanesh, Melika;Bagheri, Hossein;Jafarzadeh Kashi, Tahereh S.;Razazpour, Fateme;Behroozibakhsh, Marjan
    • Restorative Dentistry and Endodontics
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    • v.43 no.2
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    • pp.26.1-26.12
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    • 2018
  • Objective: The purpose of this study was to investigate the degree of conversion (DC) and mechanical properties of a microhybrid Filtek Z250 (3M ESPE) resin composite after aging. Method: The specimens were fabricated using circular molds to investigate Vickers microhardness (Vickers hardness number [VHN]) and DC, and were prepared according to ISO 4049 for flexural strength testing. The initial DC (%) of discs was recorded using attenuated total reflectance-Fourier transforming infrared spectroscopy. The initial VHN of the specimens was measured using a microhardness tester under a load of 300 g for 15 seconds and the flexural strength test was carried out with a universal testing machine (crosshead speed, 0.5 mm/min). The specimens were then subjected to thermocycling in $5^{\circ}C$ and $55^{\circ}C$ water baths. Properties were assessed after 1,000-10,000 cycles of thermocycling. The surfaces were evaluated using scanning electron microscopy (SEM). Data were analyzed using 1-way analysis of variance followed by the Tukey honest significant difference post hoc test. Results: Statistical analysis showed that DC tended to increase up to 4,000 cycles, with no significant changes. VHN and flexural strength values significantly decreased upon thermal cycling when compared to baseline (p < 0.05). However, there was no significant difference between initial and post-thermocycling VHN results at 1,000 cycles. SEM images after aging showed deteriorative changes in the resin composite surfaces. Conclusions: The Z250 microhybrid resin composite showed reduced surface microhardness and flexural strength and increased DC after thermocycling.

The nervous system of Fibricola seoulensis by acetylcholinesterase histochemistry (Acetylcholinesterase 조직화학법으로 관찰한 Fibricola seoulensis 신경계의 분포)

  • 전은우;김창환
    • Parasites, Hosts and Diseases
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    • v.31 no.4
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    • pp.321-330
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    • 1993
  • F. seoulensis were obtained from artificially infected albino rats at 3, 4, 5, 6, 7 days after infection. The worms and metacercariae were washed in physiological saline solution, and fled with 10% neutral formalin. The acetylcholinesterase (AchE) stained by one histochemistry using acetylthiocholine iodide as substrate. Eserine, ism-OMPA and BW284C51 were used as inhibitors of AchE. The nervous system consists of three pairs longitudinal nerve trunks interconnected with excretory plexus in posterior half, and phinmc and oral sucker in anterior half of metacercariae and adults. The longitudinal nerve trunks are interconnected with transverse commissures and numerous circular commissures. Considerable numbers of circular commissures are interconnected with longitudinal nerve trunks tying on the surface of the worms. At each stage of juvenile worms, AchE and nonspecific cholinesterase activites were observed in the oral sucker, ventral sucker, pharynx and nerve system. Isoxymes of AchE in f seoderuts were separated into the two bands, 69 kDa and 132 kDa. The major band was 69 kDa.

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A Study on the Effect of Metallic Fillers and Plastic for Ionic Migration (이온마이그레이션에 대한 플라스틱과 금속첨가제의 영향 연구)

  • Jeon, Sang Soo;Kim, Ji Jung;Lee, Ho Seung
    • Journal of Auto-vehicle Safety Association
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    • v.13 no.2
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    • pp.30-34
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    • 2021
  • Electrical failures and reliability problems of electronic components by ionic migration between adjacent device terminals have become an issue in automotive electronics. Especially unlike galvanic corrosion, ionic migration is occurred at high temperature and high humidity under applied electric field condition. Until now, although extensive studies of the ionic migrations dealing with PCBs, electrodes, and solders were reported, there is no study on the effect of insulation polymers and metallic fillers for ionic migration. In this research, therefore, ionic migration induced by the types and contents of polymers and metallic fillers, and variety conditions of temperature, humidity, and applied voltage was studied in detail. Ester and amide types of liquid crystal polymer (LCP) and poly (phthalamide) (PPA) were used as base polymers, respectively and compounded with the metallic fillers of Copper iodide (CuI), Zinc stearate (Zn-st), or Calcium stearate (Ca-st) in various compositions. The compounding polymers were fabricated in IPC-B-24 of SIR test coupon according to ISO 9455-17 with Cu electrodes for ionic migration test. While there is no change in LCP-based samples, ionic migration in PPA compounding sample with a high water absorption property was accelerated in the presence of 0.25 wt% or above of CuI at the environmental conditions of 85℃, 85% RH and 48V. The dendritic short-circuit growth of Cu caused by ionic migration between the electrodes on the surface of compounded polymers was systematically observed and analyzed by using optical microscopy and SEM (EDX).

Flexural response of steel beams strengthened by fibre-reinforced plastic plate and fire retardant coating at elevated temperatures

  • Ahmed, Alim Al Ayub;Kharnoob, Majid M.;Akhmadeev, Ravil;Sevbitov, Andrei;Jalil, Abduladheem Turki;Kadhim, Mustafa M.;Hansh, Zahra J.;Mustafa, Yasser Fakri;Akhmadullina, Irina
    • Structural Engineering and Mechanics
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    • v.83 no.4
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    • pp.551-561
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    • 2022
  • In this paper, the effect of fire conditions according to ISO 834 standard on the behavior of carbon fibre-reinforced plastic (CFRP) reinforced steel beams coated with gypsum-based mortar has been investigated numerically. To study the efficiency of these beams, 3D coupled temperature-displacement finite element analyzes have been conducted. Mechanical and thermal characteristics of three different parts of composite beams, i.e., steel, CFRP plate, and fireproof coating, were considered as a function of temperature. The interaction between steel and CFRP plate has been simulated employing the adhesion model. The effect of temperature, CFRP plate reinforcement, and the fireproof coating thickness on the deformation of the beams have been analyzed. The results showed that within the first 120 min of fire exposure, increasing the thickness of the fireproof coating from 1 mm to 10 mm reduced the maximum temperature of the outer surface of the steel beam from 380℃ to 270℃. This increase in the thickness of the fireproof layer decreased the rate of growth in the temperature of the steel beam by approximately 30%. Besides excellent thermal resistance and gypsum-based mortar, the studied fireproof coating method could provide better fire resistance for steel structures and thus can be applied to building materials.

A Study on the ACC Safety Evaluation Method Using Dual Cameras (듀얼카메라를 활용한 ACC 안전성 평가 방법에 관한 연구)

  • Kim, Bong-Ju;Lee, Seon-Bong
    • Journal of Auto-vehicle Safety Association
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    • v.14 no.2
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    • pp.57-69
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    • 2022
  • Recently, as interest in self-driving cars has increased worldwide, research and development on the Advanced Driver Assist System is actively underway. Among them, the purpose of Adaptive Cruise Control (ACC) is to minimize the driver's driving fatigue through the control of the vehicle's longitudinal speed and relative distance. In this study, for the research of the ACC test in the real environment, the real-road test was conducted based on domestic-road test scenario proposed in preceding study, considering ISO 15622 test method. In this case, the distance measurement method using the dual camera was verified by comparing and analyzing the result of using the dual camera and the result of using the measurement equipment. As a result of the comparison, two results could be derived. First, the relative distance after stabilizing the ACC was compared. As a result of the comparison, it was found that the minimum error rate was 0.251% in the first test of scenario 8 and the maximum error rate was 4.202% in the third test of scenario 9. Second, the result of the same time was compared. As a result of the comparison, it was found that the minimum error rate was 0.000% in the second test of scenario 10 and the maximum error rate was 9.945% in the second test of scenario 1. However, the average error rate for all scenarios was within 3%. It was determined that the representative cause of the maximum error occurred in the dual camera installed in the test vehicle. There were problems such as shaking caused by road surface vibration and air resistance during driving, changes in ambient brightness, and the process of focusing the video. Accordingly, it was determined that the result of calculating the distance to the preceding vehicle in the image where the problem occurred was incorrect. In the development stage of ADAS such as ACC, it is judged that only dual cameras can reduce the cost burden according to the above derivation of test results.

A Study on the Standard of Number of Verticals in the Discharge Measurements using Electromagnetic Wave Surface Velocimeter (전자파표면유속계를 이용한 유량측정시 측선수 기준에 관한 연구)

  • Song, Jae Hyun;Lee, Ki Sung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.253-253
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    • 2022
  • 수문조사 방법 및 기준은 각 국가별 기후, 유역 및 하천특성에 따라 다르게 제시되고 있으며, 세계기상기구(WMO)나 국제표준화기구(ISO)에서는 국제적으로 통용될 수 있는 기준을 제시하고 있다. 대부분의 국가에서는 국제기구 또는 수문조사 선진국(미국, 일본, 영국 등)에서 제시한 기준 및 방법을 도입하여 적용하고 있으며, 국내의 경우도 국제기준과 더불어 미국의 기준과 우리나라와 기후, 지형 및 하천특성이 비슷한 일본의 기준을 많은 부분에서 도입하였다. 유속계에 의한 유량측정 시 측선수를 늘리면 정확도를 높일 수 있지만 대하천 또는 수위(유속)가 급변하는 경우에는 측선수를 많이 해서 측정시간이 길어지면 오히려 정확도를 떨어뜨릴 수 있다. 특히, 국내에서 홍수시 신속한 측정에 사용되는 부자와 전자파표면유속계는 기존의 회전식유속계 측선수 기준을 적용하는 것은 적합하지 않다. 이에 따라, 우리나라 수문조사 전담기관인 한국수자원조사기술원에서는 전자파표면유속계 측선수 기준을 실무적으로 제시하고 있으나 이에 대한 기술적인 검토가 부족한 실정이다. 본 연구에서는 2016년~2020년까지 한국수자원조사기술원에서 측정된 58개 지점의 총 739개의 전자파표면유속계 측정성과에 대하여 수면폭 및 측선수 현황을 살펴보았다. 한국수자원조사기술원 일반기준 이상 측선수 비율은 646개(87.4%), 긴급기준 이상 측선수 비율은 739개(100.0%) 그리고 전체 평균값 이상 측선수 비율은 404개(54.7%)로 나타났다. 일반기준 이상 측선수가 많은 원인을 파악해보기 위하여 측선수를 최대구간유량비 20% 이상일 때까지 측선수를 10%씩 감소하여 산정된 유량의 변화를 검토하였다. 유량 변화 검토 결과 현장에서 유량측정 시 측선수의 등유량 배치, 최대구간유량비(20%) 및 불확도(±10%) 기준을 준수하기 위해서 기준 이상의 측선수를 확보하는 경향으로 판단되었다. 이러한 문제를 해소하기 위하여 측선수 감소에 따른 유량 편차율 ±10%와 불확도 ±10% 조건을 만족하는 수면폭 구간별 최소 기준을 제시하였으며, 이 기준을 적용할 경우 전자파표면유속계로 현장에서 보다 신속하고 정확한 유량측정을 수행할 수 있을 것으로 기대된다.

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A study of the antifungal properties and flexural strength of 3D printed denture base resin containing titanium dioxide nanoparticles (이산화티타늄 나노입자를 함유한 3D 프린팅 의치상 레진의 항진균성 및 굽힘 강도에 대한 연구)

  • Seok-Won Yoon;Young-Eun Cho
    • The Journal of Korean Academy of Prosthodontics
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    • v.62 no.2
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    • pp.95-103
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    • 2024
  • Purpose. With the advancement of digital technology, 3D printing is being utilized in the fabrication of denture base. Nevertheless, increasing microbial adhesion to the surface of denture base has been reported as the disadvantage of 3D-printed denture base. The purpose of this study is to investigate the antifungal properties and flexural strength of 3D-printed denture base resin according to the different contents of titanium dioxide nanoparticles. Materials and methods. Titanium dioxide nanoparticles were mixed with the 3D printing resin at the ratios of 0.5, 1, 1.5, and 2 wt%. Twenty specimens per each group were printed in the form of cylindrical shape (diameter: 20 mm, height: 3 mm) to evaluate antifungal properties. Ten specimens from each group underwent polishing using autogrinder, while the remaining ten specimens did not. Candida albicans in hyphae form was inoculated onto each specimen, optical density and colony-forming unit were analyzed. The surface of the specimen was observed using scanning electron microscopy. To evaluate the flexural strength, twenty specimens per each group were 3D printed in the form of rectangular prism shape (length: 64 mm, height: 10 mm, width: 3 mm) and three-point bending tests were conducted using universal testing machine according to ISO 20795-1. Results. Colony-forming unit of C.albicans and optical density of culture medium showed no difference between non-polished groups, but decreased in the polished groups at concentration of 1, 1.5, 2 wt% titanium dioxide nanoparticles. Flexural strength increased with titanium dioxide nanoparticle at concentration of 0.5, 1, 1.5 wt%, but decreased at 2 wt% compared to 1.5 wt%. Conclusion. When 1.5 wt% of titanium dioxide nanoparticles were added to the 3D-printed denture base resin with polishing, antifungal properties were increased.