• Title/Summary/Keyword: Iron-oxide

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Effect of Iron Oxide on the Dielectric and Piezoelectric Properties of (K0.5Na0.5)(Nb0.96Sb0.04)O3Ceramics (Iron Oxide가 (K0.5Na0.5)(Nb0.96Sb0.04)O3 세라믹스의 유전 및 압전특성에 미치는 영향)

  • Seo, Byeong-Ho;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.8
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    • pp.617-621
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    • 2010
  • ($K_{0.5}Na_{0.5}$)($Nb_{0.96}Sb_{0.04}$)$O_3$+1.2 mol% $K_4CuNb_8O_{23}$ ceramics doped with iron oxide ($Fe_2O_3$) were prepared by a conventional mixed oxide method. And then, their piezoelectric and dielectric properties were investigated as a function of $Fe_2O_3$ addition. X-ray diffraction studies reveal that $Fe^{3+}$ diffuses into the NKN lattices to form a solid solution with a pure perovskite structure at room temperature. At the sintering temperature of $1,060^{\circ}C$, when 0.2 mol% $Fe_2O_3$ was doped, the piezoelectric constant ($d_{33}$), electromechanical coupling factor (Kp), and mechanical quality factor ($Q_m$) showed the excellent values of 131.67 pC/N, 0.436, and 696.36, respectively. Results show that $Fe_2O_3$ deped ($K_{0.5}Na_{0.5}$)($Nb_{0.96}Sb_{0.04}$)$O_3$+1.2 mol% $K_4CuNb_8O_{23}$ lead-free piezoelectric ceramics are a promising lead free material for piezoelectric transformer applications.

Comparison of Sulfate Reduction Rates Associated with Geochemical Characteristics at the Continental Slope and Basin Sediments in the Ulleung Basin, East Sea (동해 울릉분지에서 대륙사면과 분지 퇴적물의 지화학적 특성에 따른 황산염 환원 비교)

  • You, Ok-Rye;Mok, Jin-Sook;Kim, Sung-Han;Choi, Dong-Lim;Hyun, Jung-Ho
    • Ocean and Polar Research
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    • v.32 no.3
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    • pp.299-307
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    • 2010
  • In conjunction with geochemical characteristics, rate of sulfate reduction was investigated at two sediment sites in the continental slope and rise (basin) of the Ulleung Basin in the East Sea. Geochemical sediment analysis revealed that the surface sediments of the basin site (D2) were enriched with manganese oxides (348 ${\mu}mol$ $cm^{-3}$) and iron oxides (133 ${\mu}mol$ $cm^{-3}$), whereas total reduced sulfur (TRS) in the solid phase was nearly depleted. Sulfate reduction rates (SRRs) ranged from 20.96 to 92.87 nmol $cm^{-3}$ $d^{-1}$ at the slope site (M1) and from 0.65 to 22.32 nmol $cm^{-3}$ $d^{-1}$ at the basin site (D2). Depth integrated SRR within the top 10 cm depth of the slope site (M1; 5.25 mmol $m^{-2}$ $d^{-1}$) was approximately 6 times higher than that at the basin site (D2; 0.94 mmol $m^{-2}$ $d^{-1}$) despite high organic content (>2.0% dry wt.) in the sediment of both sites. The results indicate that the spatial variations of sulfate reduction are affected by the distribution of manganese oxide and iron oxide-enriched surface sediment of the Ulleung Basin.

The Effect of Different Iron Oxides Produced from Steel Plants in the Magnetic Properties of Cabined Sr-ferrite Powders. (염산폐액 정제방법에 따른 산화철이 Sr-ferrite의 히소특성에 미치는 영향)

  • 김효준;조태식;양충진;남효덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.124-127
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    • 1997
  • The magnetic properties of calcined Sr-ferrites, related to the iron oxides, produced from three different process in steel plants, have been investigated. The powder f.characteristics of iron oxides are much affected on the magnetic properties of calcined Sr-ferrite Powders. It was possible to improve the magnetic property of calcined Sr-ferrites with the iron oxide powders of small size and narrow size distribution. The maximum magnetic properties of calcined Sr-ferrites, showing 69 emu/g of saturation magnetization and 4020 Oe of intrinsic coercivity, are achieved at the following conditions; the iron oxides from the chemirite process(EP), mole ratio of 5.8, and calcination condition of 120$0^{\circ}C$/1hr.

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Adsorption of $\alpha$-Fe2O3 on the Surface of Mica Particles (운모표면에 대한 $\alpha$산화철 흡착)

  • 김대웅;조동희;김명숙;박면용
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.215-222
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    • 1987
  • ${\alpha}$-Ferric Hydrous Oxide and ${\alpha}$-Ferric Oxide were obtained as following processes that Ferric Nitrate solution was adjusted to pH 6-8 with Ammonium Hydroxide, refluxed the Iron precipitate for 1 hr. at 80$^{\circ}C$, washed it with water and Methanol (95%), dried it to obtain ${\alpha}$-Ferric Hydrous Oxide at 60$^{\circ}C$, and then heated in atmosphere to prepare ${\alpha}$-Ferric Oxide for 1 hr. at 450$^{\circ}C$. Mica particles cleaned with ultrasonicator (45KHz) in water were mixed with Ferric Nitrate solution and treated it to adsorb ${\alpha}$-Ferric Oxide on the surface of mica particles by using the abovementioned processes, but the heated temperature was at 500$^{\circ}C$. The maximum wavelength of reflected light on the surface of mica-${\alpha}$-Ferric Oxide (50%) was appeared at 546nm but -Ferric Oxide free mica only was at 436 nm. The maximum wavelength was shifted to longer when the weight ratios of ${\alpha}$-Ferric Oxide to mica was changed from 1% to 50%.

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Atmospheric Effects on Corrosion of Iron in Borate Buffer Solution (Borate 완충용액에서 철의 부식에 대한 대기의 영향)

  • Kim, Hyun-Chul;Kim, Younkyoo
    • Journal of the Korean Chemical Society
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    • v.56 no.6
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    • pp.673-678
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    • 2012
  • Using potentiodynamic and linear polarization method, the atmospheric effect on the corrosion of iron in borate buffer solution was investigated. The corrosion of iron was heavily influenced by the degree of oxygen concentration. The supply of reduction current was increased by the reduction of dissolved oxygen, and the corrosion potential of iron was shifted to the positive side. The $OH^-$ ion, which was produced through the reduction of either water or oxygen, significantly increased the $OH^-$ ion concentration inside of the electrical double layers of iron electrode, and facilitated the adsorption of $OH^-$ ion on the surface of the iron electrode. The adsorption of $OH^-$ ion on the iron electrode can be explained either by Langmuir isotherm or by Temkin logarithmic isotherm.

The Effect of Iron Oxides $(Fe_2O_3,\;Fe_3O_4)$ on Tribological Characteristics of Automotive Friction Materials (자동차용 마찰재에서 철산화물이 마찰특성에 미치는 영향에 관한 연구)

  • Cho KeunHyung;Jang Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.289-295
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    • 2004
  • The relationship between friction characteristics and iron oxides at the sliding interface was investigated. Three friction materials containing iron, magnetite $(Fe_3O_4)$ or hematite $(Fe_2O_3)$ were manufactured and friction tests were performed on gray cast iron disks to evaluate the friction coefficient as a function of sliding speed $\mu-\nu$. In-situ noise spectrum analyzer was employed to compare noise propensity during friction tests. Results show that the specimens with magnetite are more sensitive to velocity than those with iron or hematite. The specimens containing magnetite and hematite generated noise with different peaks in the spectrum. The difference in the peak frequency seems attributed to the different surface aggressiveness of iron oxides and intermittent changes of real contact area at the sliding interface during sliding. Surface morphology and roughness of the counter disc after the tests are also consistent with the aggressiveness of iron oxides.

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