• Title/Summary/Keyword: Iron saturation

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Synthesis of Monodisperse Iron-oxide Nanoparticles from Fe(acac)3 Precursor (Fe(acac)3 전구체를 사용한 균일한 산화철 나노입자 제조)

  • Kim, Dong Young
    • Journal of the Korean Magnetics Society
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    • v.24 no.1
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    • pp.18-21
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    • 2014
  • The microwave absorption ($P_{tot}$), which is the double integration value of ferromagnetic resonance signal, propositional to the saturation magnetization, and the increase of the $P_{tot}$ measured during the thermal reaction time expect the growth process of the nanoparticles. Therefore, in this work, we measured the $P_{tot}$ in order to obtain the growth time of iron oxide nanoparticles after thermal decomposition of $Fe(acac)_3$ precursor at aging temperature $T_a=273$, 300 and $324^{\circ}C$, respectively. The best condition for monodisperse nanoparticles was obtained at $T_a=300^{\circ}C$, which condition showed the most rapid increase of $P_{tot}$ with thermal reaction time. Finally, the rapid growth rate was necessary condition for the synthesis of iron-oxide monodisperse nanoparticles.

A Survey of Nutrition and Blood Contents of Rural Women in Korea (일부 농촌지역 부인의 영양실태 및 혈액성상에 관한 연구)

  • Lim, Hyeon-Sook;Hwang, Geum-Hee
    • Journal of Nutrition and Health
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    • v.15 no.3
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    • pp.171-180
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    • 1982
  • The nutritional survey and blood sampling was conducted from May 23 to 27, 1971, in order to investigate the state of the nutritional intake in relation to blood contents of rural women. This survey covered a total of 47 women residing in Youngam-gun, Cholla-namdo, Korea. The daily diet of these subjects was observed by 24-hour recall method and weighing method for 3 days and hemoglobin (Hb), hematocrit(Hct), mean corpuscular hemoglobin concentration (MCHC), serum protein, serum albumin, A/G ratio, serum iron, total iron binding capacity (TIBC), transferrin saturation (TS), serum cholesterol and blood specific gravity (SG) were measured. The results were summarized as follows ; The rate of intake of vegetable foods was high, especially cereals, and that of animal foods was low, especially eggs and milk and milk products. The daily intake of niacin was sufficient, and the intakes of energy and iron were also tend to be adequate. On the contrary, the intakes of vitamin A, $B_2$ and C, calcium and protein were insufficient. The mean red blood cell number was $410.8{\pm}26.4{\times}10^{4}/mm^{3},$ the mean values of Hb, Hct and MCHC were $12.5{\pm}0.9gm%$, $37.5{\pm}2.4%$ and $33.2{\pm}0.5%$ thus the anemic prevalences were 21.3%, 12.8% and 93.6% comparing with the anemic criteria of WHO. The levels of serum protein and serum albumin were $7.1{\pm}0.4gm\;%$ and $4.3{\pm}0.3gm\;%$so the A/G ratio was indicated $1.6{\pm}0.2.$. The levels of serum iron and TIBC were $91.9{\pm}27.5{\mu}g/100ml and $297.5{\pm}31.4{\mu}g/100ml,$ so TS was calculated $31.2{\pm}9.7\;%$. The mean value of SG was $1.044{\pm}0.002,$ and the level of serum cholesterol was $164.3{\pm}25.4mg/dl$. In the relation between each of bloood content, Hb showed positive correlation not only with Hct but also protein at the level of significance of 1 per cent and 5 per cent, and protein also showed a positive correlation with serum cholesterol at the 1 per cent level of significance. In the relation between the nutrient intake and blood contents, vitamin C intake showed a positive correlation with Hb, serum protein and serum iron at the level of significance of 1 per cent, iron intake also showed a positive correlation with serum iron and serum cholesterol at the same significant level, and protein intake showed a positive correlation with serum iron at the at the level of significance of 5 per cent.

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Bioavailability of Aspartic Acid Chelated Iron on Iron-deficient Rats (아스파르트산 킬레이트 철분의 철분 결핍쥐에서의 생물학적 유용성)

  • Park, Myoung-Gyu;Ha, Tae-Yul;Shin, Kwang-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.12
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    • pp.1720-1725
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    • 2011
  • Aspartic acid chelated iron (Asp-Fe) was synthesized by a new method using calcium carbonate, aspartic acid, and ferrous sulfate. This study was carried out to investigate the bioavailability of Asp-Fe in iron-deficient rats. We divided the rats into four experimental groups. The first was the normal diet control group, or NC. The second was the no treated control group of iron-deficient (ID) rats, or ID+C. The third was the heme-iron (heme-Fe) treated group of ID rats, ID+heme-Fe. And the fourth was the Asp-Fe treated group of ID rats, or ID+Asp-Fe. There were no differences among any of the experimental groups in diet consumption, change of body weight, or the weight of the livers, kidneys, or spleens. After 7 days of feeding, the iron content in the sera of the ID+Asp-Fe group (175.2 ${\mu}g$/dL) and the ID+heme-Fe group (140.8 ${\mu}g$/dL) were significantly higher than that of the ID-C group (96.1 ${\mu}g$/dL). The total iron binding capacity (TIBC) of the ID+Asp-Fe group (735.4 ${\mu}g$/dL) was significantly normalized compared to the ID+C group (841.9 ${\mu}g$/dL) or ID+heme-Fe group (824.6 ${\mu}g$/dL). The hematocrit level of the ID+Asp-Fe group was increased to normal levels, but there was no statistical difference among ID groups. The absorption ratio of heme-Fe was 21.3% and that of Asp-Fe was 50.2%, which indicates a 2.3 times higher ratio in comparison with heme iron. With the above results we found that Asp-Fe seems to be an efficient form of iron to supply iron deficient rats in order to cure them of anemia. Thus, these findings suggest that aspartic acid chelated iron has the potential to serve as a functional food related to iron metabolism.

Reticulocyte hemoglobin content for the diagnosis of iron deficiency in young children with acute infection (급성 감염성 질환을 가진 영유아에서 철결핍 진단 지표로서의 망상적혈구혈색소량)

  • Kim, Jon Soo;Choi, Jun Seok;Choi, Doo Young;You, Chur Woo
    • Clinical and Experimental Pediatrics
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    • v.51 no.8
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    • pp.827-833
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    • 2008
  • Purpose : Early identification of iron deficiency in young children is essential to prevent damaging long-term consequences. It is often difficult for the pediatrician to know which indices should be used when diagnosing these conditions especially in hospitalized young children. This study investigated the clinical significances of reticulocyte hemoglobin content in young children with acute infection. Methods : We studied 69 young children aged from 6 to 24 months admitted with acute infection in a single center. Venous blood was drawn to determine hemoglobin (Hb), mean corpuscular volume (MCV), mean corpuscular hemoglobin (MCH), hemoglobin content (CH), reticulocyte hemoglobin content (CHr), and red blood cell distribution width (RDW) using ADVIA 120 (Bayer Diagnostics, NY, USA). For evaluating iron status, iron, total iron binding capacity, ferritin and transferrin saturation (Tfsat) were determined. Iron deficiency was defined as Tfsat less than 20%, and iron deficiency anemia as Tfsat less than 20% and Hb level less than 11 g/dL. Results : In all, 47 were iron deficient; 17 of these had iron deficiency anemia. CHr was the only significant predictor of iron deficiency (likelihood ratio test=71.25; odds ratio=0.67; P<0.05). Plasma ferritin level had no predictive value (P=0.519). Subjects with CHr less than 27.4 pg had lower Hb level, MCH, CH, Tfsat, and iron levels than those with CHr 27.4 pg or more (P<0.05 for all). Conclusion : CHr level was a sensitive screening tool and the strongest predictor of iron deficiency in hospitalized infants with acute infection; it was cost saving and avoiding additional sampling. However its reference range should be established.

Synthesis and Magnetic Properties of Electrodeposited Cobalt-Iron-Vanadium Thin Films

  • Chae, Kwang-Pyo
    • Journal of Magnetics
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    • v.11 no.2
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    • pp.87-89
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    • 2006
  • CoFeV thin film alloys were fabricated by electrodeposition, and the dependences of their magnetic properties on the current density were investigated using an X-ray diffractometer and a vibrating sample magnetometer. The deposited Co increased from about 45 to 60 wt.% with increasing current density until $25mA/cm^2$ whereas the deposited Fe decreased from about 55 to 40 wt.% with increasing current density until $25mA/cm^2$. The deposited V, about 2 wt.%, was independent of the current density. The current efficiencies of electrodeposition decreased linearly from about 40 to 29% with increasing current density. The X-ray diffraction measurement showed that all peaks of the CoFeV films were consistent with those of a typical Co hcp and Fe bcc mixed phase. An increase in the current density decreased the grain size and increased the lattice constant. The saturation magnetization increased from about 2.2 to 2.5 T with increasing current density. The coercivity measured in the perpendicular direction decreased from 260 to 120 Oe with increasing current density; a drastic drop of 60 Oe occurred at $5mA/cm^2$. The coercivity measured in the in-plane direction remained almost unchanged, at about 20 Oe, with increasing current density.

Properties of Polyalphaolefin-Based Ferrofluids

  • Kim, Jong-Hee;Park, Keun-Bae
    • Journal of Magnetics
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    • v.20 no.4
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    • pp.371-376
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    • 2015
  • Magnetite nanoparticles were synthesized by adding excess ammonium hydroxide to a solution of iron (II) and (III) chlorides. The surfactants of oleic acid and Span 80 were applied in sequence to the magnetic particles as a combined stabilizer, and poly-${\alpha}$-olefin (PAO) 30 or 60 was used as the liquid base with a low or high viscosity, respectively. The ferrofluids were prepared with the concentrations of 200, 300, 400, and 500 mg/mL, and characterized by density, dispersion, magnetization, and viscosity. The density of the fluids increased proportionally to the concentration from 0.98 to 1.27 g/mL and 1.01 to 1.30 g/mL with PAO 30 base and PAO 60 base, and the dispersion stability was 77-95 and 81-74% for the PAO-30 and PAO-60-based fluids, respectively. The observed saturation magnetization values of the PAO-30 and PAO-60-based ferrofluids were 16 to 42 mT and 17 to 41 mT with the concentration increase in the range 200-500 mg/mL, respectively, depending upon the content of magnetic particles in the fluid. The viscosity variation of the PAO-30 and PAO-60-based ferrofluids in the temperature range $20-80^{\circ}C$ was the least with the concentrations of 400 and 300 mg/mL, respectively.

Analysis on Fault Current Limiting Characteristics Dependent on Air-Gap in a Flux-Lock Type SFCL with parallel connection of two coils (병렬연결된 두 코일을 가진 자속구속형 초전도 전류제한기의 공극유무에 따른 전류제한 특성 분석)

  • Lim, Sung-Hun;Kim, Jae-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.2
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    • pp.77-81
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    • 2009
  • Air-gap was introduced to suppress the saturation of the iron core comprising the flux-lock type superconducting fault current limiter (SFCL) with parallel connection of two coils. However, the air-gap makes the impedance of this SFCL decreased and can result in unusefulness of the SFCL. To analyze the current limiting characteristics of the SFCL with the air-gap, the experimental circuit for short-circuit test was constructed. Through the comparison with the current limiting characteristics of the SFCL without air-gap, the merit and the demerit of the flux-lock type SFCL with the air-gap were discussed.

Structural and Magnetic Properties of Co-Mn Ferrite Prepared by a Sol-gel Method

  • Kim, Woo Chul;Yi, Young Suk;Kim, Chul Sung
    • Journal of Magnetics
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    • v.5 no.4
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    • pp.111-115
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    • 2000
  • Ultrafine $Co_{0.9}Mn_{0.1}Fe_2O_4$ powders have been fabricated by a sol-gel method. Structural and magnetic properties of the powders were investigated by x-ray diffractometry, transmission electron microscopy (TEM), Mossbauer spectroscopy, and vibrating sample magnetometry (VSM). Co-Mn ferrite powders that were fired at and above 773 K contained only a single spinel phase and behaved ferrimagnetically. Powders fired at 673 and 723 K had a spinel structure and were mixed paramagnetic and ferrimagnetic in nature. The magnetic behavior of Co-Mn ferrite powders fired at and above 873 K showed that an increase of the firing temperature yielded a decrease in the coercivity and an increase in the saturation magnetization. The maximum saturation magnetization and coercivity of Co-Mn ferrite powders were 66.7 emu/g and 1523 Oe, respectively, Mossbauer spectra of the powder fired at 923 K were taken at various temperatures ranging from 13 to 850 K. The iron ions.at both A (tetrahedral) and B (octahedral) sites were found to be in ferric high-spin states. The Nel temperature $T_N$ was found to be 850 $\pm$ 2 K. Debye temperatures far A and B sites were found to be $\Theta_A = 757 \pm$5K and $Theta_B = 282 \pm$5 K, respectively.

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A Study on the Compensation of the Inductance Parameters of Interior Permanent-Magnet Synchronous Motors Affected by the Magnet Size

  • Jang, Ik-Sang;Lee, Hyung-Woo;Kim, Won-Ho;Cho, Su-Yeon;Kim, Mi-Jung;Lee, Ki-Doek;Lee, Ju
    • Journal of Magnetics
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    • v.16 no.1
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    • pp.74-76
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    • 2011
  • Interior permanent-magnet synchronous motors (IPMSMs) produce both magnetic and reluctance torques. The reluctance torque is due to the difference between the d- and q-axis inductances based on the geometric rotor structure. The steady-state performance analysis and precise control of the IPMSMs greatly depend on the accurate determination of the parameters. The three essential parameters of the IPMSMs are the armature flux linkage of the permanent magnet, the d-axis inductance, and the q-axis inductance. In the basic design step of an IPMSM, the inductance parameters are very important for determining the motor characteristics, such as the input voltage, torque, and efficiency. Thus, it is very important to accurately estimate the values of the motor inductances. The inductance parameters of IPMSMs have nonlinear characteristics along the magnet size because the iron core is saturated by the magnet and armature reaction fluxes. In this study, the inductance parameters were calculated using both the magnetic-equivalent-circuit method and the finite-element method (FEM). Then the calculated parameters were compensated by the saturation coefficient function, which was also calculated via the magnetic-equivalent-circuit method and FEM.

The Influences of Aquifer Thermal Energy Storage (ATES) System on Geochemical Properties of Groundwater (대수층 계간 축열시스템 적용을 위한 지하수의 화학적 특성 변화)

  • Choi, Hanna;Lee, Hong-Jin;Shim, Byoung Ohan
    • Journal of Soil and Groundwater Environment
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    • v.26 no.3
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    • pp.14-24
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    • 2021
  • Aquifer thermal energy storage (ATES) system uses groundwater thermal energy for cooling and heating of buildings, and it is also often utilized to provide warm water to crops and plants for the purpose of enhancing agricultural yields. This study investigated the potential influences of a ATES system on the geochemical properties of groundwater by simulating the variation of hydrochemistry and saturation index of groundwater during ATES operation. The test bed was installed at an agricultural field, which is mainly composed of an groundwater-rich alluvial plain. The simulation results showed no significant precipitation of mineral phases such as manganese-iron oxide, carbonate and sulfate around the ATES test bed, as well as no debasement of other important water quality parameters. The implementation of ATES system in the study area was appropriate and effective for utilizing the thermal energy of groundwater for agricultural use.