• 연구논문집
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• s.34
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• pp.139-146
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• 2004

In this study, effect of temperature and time on melt-out of 25wt% Al-alloyed ductile iron has been investigated. The oxidation tests were carried out in a tube furnace at $800^\circC$, $930^\circC$, and $1000^\circC$ for lh, 5h, 10h, 50h. The microstructure, microhardness, and $Al_2O_3$ layer of oxidation-treated 25wt% Al-alloyed ductile iron samples (10 x 10 x 10 mm) were investigated. Phase identification was performed by X-ray diffraction(XRD) and EDS. The oxidation-treated 25wt% Al-alloyed ductile iron samples at $930^\circC$ for lh, 5h, 10h and KS GCD 500 were used for melt-out test in an Al alloy melt. The melt-out test results showed that oxidation tested sample at $930^\circC$ for 5h which on the whole forms $2-3\mum$ $Al_2O_3$ layer showed lowest melt-out depth. It was observed showed that appropriate Al203 layer can affect melt-out behaviors.

• Geomechanics and Engineering
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• v.35 no.4
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• pp.437-447
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• 2023

The failures of tailing dams have caused irreparable damage to human lives, assets and environment and this has ultimately resulted in great economic, social and environmental challenges worldwide. Due to this, investigation into mechanical behaviour of tailings has received some attention. However, the knowledge and understanding of mechanics of behaviour in iron tailings is still limited. This study investigates the mechanics of iron tailings from Nigeria considering grading, effects of fabric resulting from different sample preparations and the possibility of non-convergent behaviour. This was achieved by conducting series of one-dimensional compression tests in conjunction with index, microstructural, chemical and mineralogical tests. The materials are predominantly poorly graded, non-clayey and non-plastic. The tailings are characterised by angular particles with no obvious particle aggregations and dominated by silicon, iron, aluminium, haematite and quartz. The compression paths do not converge and unique normal compression lines are not found and this is an important feature of the transitional mode of behaviour. The behaviour of these iron tailings therefore depends on initial specific volume. The preparation methods also have effect on the compression paths of the samples. The gradings of the samples have an influence on the degree of transitional behaviour but the preparation methods do affect the degree of convergence. The transitional mode of behaviour in these iron tailings investigated is very strong.

• Journal of the Mineralogical Society of Korea
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• v.17 no.1
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• pp.75-83
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• 2004

Blackening on stone monuments is serious problem, because it is not only aesthetically unattractive, but also an important process in stone deterioration. Black surface layers contain often a large amounts of iron compound. Therefore it is assumed that besides another elements the iron have influence on blackening of surface. After the samples of black surface layers were collected from the stone monuments (Museumsinsel) in Berlin, Germany, especially in this study has been used Mossbauer spectroscopy in order to determine the valence and chemical composition of iron. Mineralogical and chemical analyses were carried out X-ray diffractormetry and X-ray fluorescence method on the black surface layer's samples and original stone samples. The origin of Iron compound in the black surface provides the important clue for the conservation work of stone monuments, like removing of black surface. To find it, black surface layer on white sandstone -it contains very small amount of iron compound- was compared with that on the red sandstone (Fe contains very small amount of iron compound- was compared with that on the red sandstone (Fe abundant). As a results, it is assumed that the iron in black layer on white sandstone is originated mainly from a surrounding environmental material and for the iron in black layer on the red sandstone is responsible the original stone. Even if black surface layer was removed from the red sandstone, some other conservation method should be studied beyond removing of black surface layer, because the iron can move continuously from the inner zone of original stone to surface area.

• Journal of Conservation Science
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• v.35 no.4
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• pp.317-329
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• 2019

Slag was collected from the iron-producing furnace site in Saengsoegol, Baegun mountain, where iron was manufactured by a righteous army against Japan in the Gwangyang region; then, the iron-manufacturing technique of the early modern period was investigated through scientific analysis. In the microstructure analysis results of the selected samples, iron bloom was mainly observed together with magnetite and fayalite. In the component analysis results of the compounds, it was confirmed that the furnace was built by using gangue of alkali feldspar or plagioclase series, and the ironmaking work was performed at a high temperature of at least 1050℃, because mullite was identified together with cristobalite and hercynite. Based on the chemical composition, it was speculated that low-grade iron ores were used as raw materials, and it seemed that the yield was low, because the total Fe content of the smelting slag samples was 37.72-49.93%. It was difficult to confirm whether a slag former was used, and it seemed that materials easily obtained nearby were used when the furnace was built, without considering the corrosion resistance. It appeared that the ironmaking work was performed at the Gwangyang Saengsoegol iron-producing furnace based on the direct ironmaking method in an environment that could escape the vigilance of the Japanese Empire to produce weapons that would be used for the resistance against Japan. It seemed that there was neither an advanced ironware production system nor a mass production system, and small-scale works were performed in short periods of time.

• Journal of the Korean Society for Heat Treatment
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• v.25 no.1
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• pp.22-26
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• 2012

An influence of the addition of copper (0.5, 1.0 and 1.5 mass% Cu) on the microstructure and mechanical properties of high purity iron (99.998 mass%) was characterized. The microstructure and microhardness of high-purity iron based samples, which were rolled at room temperature and subsequently annealed, were investigated in this work. The microstructure of the samples has been observed by electron back scattering diffraction (EBSD) and the mechanical properties have been studied by using micro-Vickers hardness test. The results of microstructural observation showed that deformation band was formed in high purity iron by rolling at room temperature, and it was recovered by annealing up to about 900 K. The microhardness results showed that the softening of high-purity iron occurred by annealing up to about 900 K, while the hardness of iron added with about 0.5-1.5 mass% copper was kept over 100 Hv and at the early time of annealing reached a maximum. The hardness of iron added with a small amount of copper may be attributed to precipitation hardening as well as solution hardening. The orientation of crystal in recrystallized grain was almost same as that of deformed grain.

• Journal of the Korean Society for Precision Engineering
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• v.12 no.10
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• pp.78-88
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• 1995

For producing iron or steel products with good quality, the concentration of the material components should be analyzed quickly with high relability using XRF(Fluorescent X-Ray Spectrometer). Since the analysis results are much dependent upon the surface con- dition, the samples have to be prepared to have good test condition. This study presents an image processing system for inspecting the surface condition of the iron test sample. In order to use thd computer vision system, we need to develop a lighting device and image processing algorithm. For the adequate lighting device of inspection system, the indirect lighting device is contrived to cut the external light and provide uniform, stable and cold light. The image processing algorithm is aimed to reduce inspection time and to get similar analyzing results to those of the experienced operators. At first, the image processing algorithm checks whether the surface of the iron sample is ground well or not. Then, the defects; hole or dig are conted and surface condition is evaluated. In addition, the algorithm gives the reliability of the analyzing results in order to help operator's decision.

• Journal of the Korean Magnetics Society
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• v.5 no.6
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• pp.921-927
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• 1995

The micro particle,s shapes of the magnetic films obtained by electrode position of Iron ions and Cobalt-Iron mixed ions in aluminum anodic oxidized films are dependent on the size of particle diameter. When the diameter of deposited particles is larger than $300\AA$, the film plane anisotropy caused by bottom extremity increases, and the crystalization orientation of FeC deposited unusually in the part of the bottom extremities affects on the coercive force Hc and the magnetic anisotropy energy Ku. It was confirmed that the shape anisotropy of particle affects on the both Hc and Ku because the FeC did not deposit in the Iron deposited samples entirely, but in the Cobalt-Iron alloy deposited samples, the effects by the very strong crystalization orientation of the FeC is larger than that of the shape anisotropy. From these results, the Cobalt-Iron alloyed films could switchover the film plane magnetic anisotropy to the perpendicular magnetic anisotropy energy by using the constrainting method of FeC deposition with Cu deposition instead of Cobalt-Iron alloy in the bottom extremities.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.1288-1289
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• 2006

Innovative SMC with low iron loss was made from iron powders with evaporated MgO insulation coating. The coating had greater heat-resistance than conventional phosphatic insulation coating, which enabled stress relieving annealing at higher temperature. Magnetic properties of toroidal samples (OD35mm,ID25mm, t5) were examined. The iron loss at 50Hz for Bm = 1.5T was lower 50% of conventional SMC and was almost the same with silicon iron laminations(t0.35). It became clear that MgO insulation coating has enough heat resistance and adhesiveness to powdersurface to obtain innovative SMC with low iron loss.

• Corrosion Science and Technology
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• v.17 no.2
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• pp.60-67
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• 2018

The compounds associated with corrosion, in metallic archaeological samples of carbon steel of insular origin were evaluated to establish their degree of deterioration and structural damage against air pollution. The iron phases present in samples of archaeological artifacts were detected by Raman spectroscopy and confocal Raman microcopy. These samples mainly exhibited ing mainly ${\beta}$-FeO(OH) type goethite oxyhydroxides and small amounts of akaganeite ${\alpha}$-FeO(OH) lepidocrocite ${\gamma}$-FeO(OH) due to dominant chloride in a marine environment and non-stoichiometric oxyhydroxides Fe (II + / III +) as indicators of early corrosion. Some parts showed the presence of magnetic maghemite indicating high corrosion. ${\gamma}$-FeO(OH) is a precursor of phases associated with advanced marine corrosion. By studying its decomposition by Raman spectroscopy, it was synthesized with the following sequence: ${\gamma}-FeO(OH){\rightarrow}{\alpha}-FeO(OH)+{\gamma}-FeO(OH)$, ${\rightarrow}{\gamma}-Fe_2O_3+Fe_3O_4$. Ferric compounds provided evidence for the effect of intensity of laser on them, constituting a very useful input for the characterization of oxidation of iron in this type of artifacts. Thus, destructive analysis techniques should be avoided in addition to the use of small amounts of specimen.

• Journal of the Korean Magnetics Society
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• v.17 no.5
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• pp.205-209
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• 2007

It have been investigated the measured results of the XRF, the X-ray diffractometry and $^{57}Fe\;M{\ddot{o}}ssbauer$ spectrum for scoria samples which are distributed throughout different areas in Mid-mountain Area of Jeju island. We consider that the scoria samples are chiefly made of silicate minerals, like $SiO_2$, others silicate minerals and iron oxides minerals. We study that it's materiel is consisted of olivine, pyroxene, ilmenite, hematite and magnetite. Iron compounds in that are $Fe^{2+}$ of olivine, pyroxene, ilmenite and $Fe^{3+}$ of hematite, magnetite et al. The major Fe fractions of the scoria samples are 51.77 wt%, so Fe fractions of the scoria samples are almost 3+ charge state with a little of the 2+ charge state.