• Title/Summary/Keyword: Iron by-product

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Correlation between Characteristics of SOD in Coastal Sewage and Predictive Factor (연안 저질 SOD의 특성과 유발 영향인자에 대한 상관관계)

  • Kim, Beom-Geun;Khirul, Md Akhte;Kwon, Sung-Hyun;Cho, Dae-Chul
    • Korean Journal of Environment and Ecology
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    • v.33 no.5
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    • pp.596-604
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    • 2019
  • This study conducted a sediment culture experiment to investigate the effects of sediment oxygen demand (SOD) and environmental factors on sediment and water quality. We installed a leaching tank in the laboratory, cultured it for 20 days, and analyzed the relationship between P and Fe in the sediment. As a result, the dissolved oxygen of the water layer decreased with time, while the oxidation-reduction potential of the sediment progressed in the negative direction to form an anaerobic reducing environment. The SOD was measured to be 0.05 mg/g at the initial stage of cultivation and increased to 0.09 mg/g on the 20th day, indicating the tendency of increasing consumption of oxygen by the sediment. The change is likely to have caused by oxygen consumption from biological-SOD, which is the decomposition of organic matter accumulated on the sediment surface due to the increase of chl-a, and chemical-SOD consumed when the metal-reducing product produced by the reduction reaction is reoxidized. The correlation between SOD and causality for sediment-extracted sediments was positive for Ex-P and Org-P and negative for Fe-P. The analysis of the microbial community in the sediment on the 20th day showed that anaerobic iron-reducing bacteria (FeRB) were the dominant species. Therefore, when the phosphate bonded to the iron oxide is separated by the reduction reaction, the phosphate is eluted into the water to increase the primary productivity. The reduced substance is reoxidized and contributes to the oxygen consumption of the sediment. The results of this study would be useful as the reference information to improve oxygen resin.

Crystal growth of gypsum by neutralization reaction of waste sulphuric acid using sludge and dust in Pohang Iron & Steel plant (포항제철(주) 슬러지와 Dust를 이용한 폐황산 중화반응에서 얻어진 석고의 결정성장연구)

  • Ji whan Ahn;Ka yeon Kim;Hwan Kim;Sang bop Lee;Eu dug Hwang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.673-680
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    • 1997
  • NaOH, $Na_2CO_3, CaO, Ca(OH)_2$ and $CaCO_3$ are widely used counteractives for neoutralizing the waste sulphuric acid produced during the metal surface treatment process and/or the metal refining process. To reduce the tremendous expenses for the neutralization treatment of the waste sulphuric acid, the sludge from calcination plant and the stainless refining dust in POSCO (Pohang Iron & Steel co. Ltd.) was utilized. For the sludge, it will be effective to use calcined and then hydrated sludge in strong acid region (pH<2) and to use the sludge itself in weak acid region (pH>2), The gypsum, the by-product of this treatment, was tested to fit the industrial standard of gypsum, so it is expected that it will solve the lack of gypsum supply. For the stainless refining dust, the phase and the morphology of produced gypsum from waste suiphuric acid neutralization was compared with those from pure sulphuric acid. Because of high reactivity and reaction temperature, $CaSO_4$ non-hydrate was obtained in pure sulphuric acid. But $CaSO_4$ dihydrate was obtained in waste sulphuric acid. It is also judged to be a good material for a counteractive of the waste sulphuric acid.

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Metallurgical Analysis for Non-ferrous Smelting Slag Collected from Seosan Area (서산 지역 수습 비철제련 슬래그의 금속학적 특성 분석)

  • Lee, Hye Jin;Lee, Hye Youn;Lee, So Dam;Cho, Nam Chul
    • Journal of Conservation Science
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    • v.32 no.2
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    • pp.189-202
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    • 2016
  • To figure out the material characteristics about slag and raw materials which are founded in iron product sites in Seosan area, we used XRF, EDS to analysis chemical compositions. Also we observe the microstructure by microscope and SEM. To identify the mineral component, XRD analysis was used and to assume the provenance of the raw material, lead isotope ratio analysis was used. From the results, we figure out that slags are non-ferrous created when metal was refined. Also, main tissue of slags were Fayalite, Galena, Magnetite, and raw materials were identified as mineral of Galena, Anglesite, Pyrite etc. From the result about lead isotope ratio analysis, we found out most samples are classified as the Western Gyeonggi massif in South Korea. Especially three of raw materials and slag samples which collected in the Seosan Doseongri was presumed to be the provenance. We figure out that slags we analyzed were made in non-ferrous metal smelting process and especially that were more likely to smelt from Seosan Doseongri. If various slags in this area are analysed by someone, It will contribute understanding non-ferrous metal refining process as well as metal refining which are composed.

Effect of Zine Oxide Size and Oxygen Pressure on the Magnetic Properties of (Ni, Zn) Ferrite Powders Prepared by Self-propagating High Temperature Synthesis (ZnO의 입도와 산소압이 고온연소합성법으로 제조된 Ni-Zn Ferrite 분말의 자기적 특성에 미치는 영향)

  • Choi, Yong;Cho, Nam-Ihn;Hahn, Y.D.
    • Journal of the Korean Magnetics Society
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    • v.9 no.2
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    • pp.78-84
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    • 1999
  • $(Ni, Zn)Fe_2O_4$ powders were prepared through self-propagating high temperature synthesis reaction and the effects of initial zinc oxide powder size and oxygen pressure on the magnetic properties of the final combustion products were studied. The ferrite powders were combustion synthesized with iron, iron oxide, nickel oxide, and zinc oxide powders under various oxygen pressures of 0.5~10 atmosphere after blended in n-hexane solution for 5 minutes with a spex mill, followed by dried at 120 $^{\circ}C$ in vacuum for 24 hours. The maximum combustion temperature and propagating rate were about 1250 $^{\circ}C$ and 9.8 mm/sec under the tap density, which were decreased with decreasing ZnO size and oxygen pressure. The final product had porous microstructure with spinel peaks in X-ray spectra. As the ZnO particle size in the reactant powders and oxygen pressure during the combustion reaction increase, coercive force, maximum magnetization, residual magnetization, squareness ratio were changed from 1324 Oe, 43.88 emu/g, 1.27 emu/g, 0.00034 emu/gOe, 37.8$^{\circ}C$ to 11.83 Oe, 68.87 emu/g, 1.23 emu/g, 0.00280 emu/gOe, 43.9 $^{\circ}C$ and 7.99 Oe, 75.84 emu/g, 0.791 emu/g, 0.001937 emu/gOe, 53.8 $^{\circ}C$ respectively. Considering the apparent activation energy changes with oxygen pressure, the combustion reaction significantly depended on initial oxygen pressure and ZnO particle size.

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Changes in nutritional status of Korean older adults during COVID-19 Pandemic by household income and demographic factors -using the Korea National Health and Nutrition Examination Survey(2019-2020): a cross-sectional study (가구소득 및 인구학적 특성에 따른 코로나19 유행 전·후 한국 노인의 영양소 섭취변화에 대한 단면연구: 국민건강영양조사 제8기(2019-2020) 자료를 활용하여)

  • You-Sin Lee;Yoonna Lee
    • Korean Journal of Community Nutrition
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    • v.28 no.4
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    • pp.302-316
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    • 2023
  • Objectives: The study aim was to identify changes in the nutritional status of older adults during the COVID-19 pandemic according to household income and demographic characteristics. Methods: Study participants were 2,408 adults aged 65 and over who participated in the 2019-2020 Korea National Health and Nutrition Examination Survey (KNHANES). To examine changes in nutrient intake levels resulting from COVID-19, data of 2019 and of 2020 were compared. Study participants were divided into three groups based on household income level to compare these changes. The changes were compared according to household income level, age group, and household type. Results: Percentages of recommended intakes for energy, protein, and most micronutrients were the lowest for the low-income group of both males and females in 2020. The Mean Adequacy Ratio (MAR) score was the lowest for the low-income group in both years. When comparing nutrient density for 2019 and 2020 by income group, the male low-income group experienced a decrease in nutrient densities of vitamin A, thiamine, calcium, and iron. For the same group, a decreased percentage for energy intake from protein was noted. Fruit intake was lowest in the low-income group for both males and females. Low-income males had the lowest intake levels for meat, fish, eggs, and legumes in both 2019 and 2020 and the lowest milk and milk product intake levels in 2020. Older adults living alone or single older adults with children had lower MAR scores than those living with a spouse. Older adults living alone experienced decreases in energy and thiamine and iron intake levels in 2020 compared to their intake levels in 2019. Conclusions: Because of the COVID-19 pandemic, nutrition intake levels worsened for older adult males in the low-income group and older adults living alone. This finding shows the need for a more systematic nutritional support strategy for the vulnerable older adults population in national disaster situations.

Hydration properties of OPC with Synthesized Calcium Alumino Ferrite(CAF) (합성 Calcium Alumino Ferrite(CAF) 치환량에 따른 시멘트 수화 특성)

  • Woong-Geol Lee;Myong-Shin Song
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.9-15
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    • 2023
  • The cement is a typical CO2 emission industry. Manufacturing process improvements and increased use of alternative materials are needed to reduce energy consumption and CO2 emissions. This study confirmed the basic characteristics of cement hydration by sintering CAF at low temperature as a CO2 adsorbent material. For the hydration product of the synthetic CAF, crystal phase analysis, porosity, and structural images were confirmed, and the compressive strength was measured. The replacement rate of SCAF was 10, 20, and 100 %, and the compressive strength tended to decrease as the replacement rate increased. In addition, when the SCAF substitution rate is 100 %, the hydration products of the early age are calcium aluminum oxide hydrate (Ca3Al2O6 x H2O) and calcium iron hydroxide (Ca3Fe(OH)12), and at substitution rates of 10 and 20 %, CAF compounds other than general cement hydrates brownmillerite was observed. As for the porosity, the pore size increased and the porosity increased with the increase of the replacement ratio. As a result of this study, CAF manufactured by low-temperature sintering seems to be difficult to use alone and general curing for utilization as a CO2 adsorbing material.

An Analysis of Hair Renderings in Reference to Entertainers' Hair Styles - Focused on Byeon Jeong-su's Hair Styles- (연예인 헤어스타일에 근거한 헤어연출 분석 -변정수 헤어스타일을 중심으로-)

  • Kang, Pyeong-Mi
    • Journal of the Korean Society of Fashion and Beauty
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    • v.1 no.1 s.1
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    • pp.105-118
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    • 2003
  • The purpose of this study was to analyze entertainer Byeon Jeong-su's hair styles and thereby, apply the results to models. For the applications, models' hair styles were bisected into two sections, and thereby, the edges of the outsides were cut into solid points, and thereupon, into diverse bases by using vertical section, Perpendicular direction and square angles. On the other hand, the insides were cut in the same way of the outside bases by using radial section, varied combing and $45{\sim}90$ degree head angles. In addition, tops and sides were arranged in their corners, while a graduation technique was used to express a natural difference of levels. The fringes were cut by using free-hand and slicing techniques. furthermore, the quantity and mass of the hairs were treated with such techniques as thinning, swing, effect, rolling, slide and slicing, while a bridge product was used for coloring together with a highlight technique. The hair styles were rendered for straight and wave by using an magic iron machine. It was confirmed through this study that the same cutting techniques would result in different images depending on individuals' physical shapes, facial shapes, head skeletons and types of hairs. Thus, it is required of the hair designers to suggest their own custom hair designs adequate to individuals' images through continued image-wise hair design practices.

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Suppression of Methane Emission from Rice Paddy Soils with Fly ash Amendment

  • Ali, Muhammad Aslam;Oh, Ju-Hwan;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.26 no.2
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    • pp.141-148
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    • 2007
  • Fly ash, a by-product of the coal-burning industry, and a potential source of ferro-alumino-silicate minerals, which contains high amount of ferric oxide and manganese oxide (electron acceptors), was selected as soil amendment for reducing methane $(CH_4)$ emission during rice cultivation. The fly ash was applied into potted soils at the rate of 0, 2, 10, and 20 Mg $ha^{-1}$ before rice transplanting. $CH_4$ flux from the potted soil with rice plants was measured along with soil Eh and floodwater pH during the cropping season. $CH_4$ emission rates measured by closed chamber method decreased gradually with the increasing levels of fly ash applied but rice yield significantly increased up to 10 Mg $ha^{-1}$ application level of the amendment. At this amendment level, total seasonal $CH_4$ emission was decreased by 20% along with 17% rice grain yield increment over the control. The decrease in total $CH_4$ emission may be attributed due to suppression of $CH_4$ production by the high content of active and free iron, and manganese oxides, which acted as oxidizing agents as well as electron acceptors. In conclusion fly ash could be considered as a feasible soil amendment for reducing total seasonal $CH_4$ emissions as well as maintaining higher grain yield potential under optimum soil nutrients balance condition.

Preparation of β-FeSi2 Thermoelectric Materials by MA/SPS Process -Formation ofβ-FeSi2Phase- (MA/SPS 공정에 의한 β-FeSi2 열전재료의 제조(I) -β-FeSi2상의 형성-)

  • Kim, Hwan-Tae;Gwon, Yeong-Sun;Lee, Chung-Hyo
    • Korean Journal of Materials Research
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    • v.12 no.3
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    • pp.176-181
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    • 2002
  • Fabrication of ${\beta}-FeSi_2$ was attempted by making use of the combined process of mechanical alloying (MA) and spark plasma sintering (SPS). MA was performed under the Ar gas atmosphere using mixed powders of pure iron and silicon having the mole fraction of 1:2. SPS process was performed at 800-85$0^{\circ}C$ with the applied pressure of 50MPa and the holding time was ranging from 0 to 30min. The mechanically alloyed powder by cyclic operation of rotor for 15hrs consisted of $\varepsilon$-FeSi and Si phases. When this mechanically alloyed powder was sintered by SPS process above 85$0^{\circ}C$, $\varepsilon$-FeSi and ${\alpha}-Fe_2Si_5$ phase were formed. Bulk product sintered at 82$0^{\circ}C$ for 30min consisted of ${beta}-FeSi_2$ phase with a small fraction of $\varepsilon$-FeSi and the density of sintered specimen was 75.3% theoretical density. It was considered that the MA/SPS combined process was effective for the preparation of ${\beta}-FeSi_2$ without heat treatment process after sintering.

Upgrade of $TiO_2$ by Carbon Reduction of Ilmenite (Ilmenite의 炭素還元에 의한 $TiO_2$ 品位 向上 硏究)

  • Kim, Joon-Soo;Kim, Sung-Don;Park, Hyung-Kyu;Sohn, Hong-Yong
    • Resources Recycling
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    • v.13 no.5
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    • pp.17-22
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    • 2004
  • It has been carried our for establishing the methodology to upgrade $TiO_2$ by carbothermal reduction of iron oxide in ilmenite. Based on present experimental results, the possibility for substitution with rutile has been investigated. It could by proposed that the 2 wt.% $FeCl_3$ of sample and carbon of 2 equivalents are optimum conditions as a feeding materials. And also appropriate reducing temperature and reduction time were about $1100^{\circ}C$ and 30 minutes. The product obtained by the processes of carbon reduction and magnetic separation may be used the substitute mineral of rutile.