• Title/Summary/Keyword: Iron Production

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A Study on Chemical Neutralization and Production of Planting Porous Concrete Using Low-Grade Iron Ore (저 품위 철광석을 사용한 식생용 투수 콘크리트의 중성화 및 제작에 관한 연구)

  • Eun, Hee-Chang;Lee, Min-Su;Bae, Choong-Yeol
    • Journal of Industrial Technology
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    • v.27 no.A
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    • pp.31-38
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    • 2007
  • Recently produced concrete has a tendency to overcome environmental defects. Porous and planting Eco-concrete requires the neutralization process and enough void in concrete to contain water, to pass air freely, and provides necessary nutrients to vegetation roots. The biological environment in concrete is not suitable for planting because the concrete possesses strong alkali constituent of pH 11-13. This study evaluated the strength and serviceability of concrete as well as the chemical characteristics of concrete mixed by low-grade iron ore left in the abandoned mine and treated by Ammonium monohydrogen phosphate, $(NH_4)_2HPO_4$. Test variables include two kinds of coarse aggregates such as crushed stones and low-grade iron ore, the duration time and the period for neutralization treatment by Ammonium monohydrogen phosphate, $(NH_4)_2HPO_4$, and the proportion ratio of cement, blast furnace slag and silica fume.

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A Study on the Iron Loss and Demagnetization Characteristics of an Inset-type Flux-Reversal Machine

  • Kim, Tae Heoung
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.297-301
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    • 2013
  • Flux-reversal machine (FRM) is cost effective and suitable for mass production due to its simple structure. However, there is a notable permanent magnet flux leakage which deteriorates the performance. To compensate this drawback with a design method, an Inset-Permanent-Magnet-Type FRM (ITFRM) has been proposed. The ITFRM has permanent magnets perpendicular to the stator teeth surface, and thus, is much more difficult to demagnetize. In this paper, we deal with the iron losses and irreversible permanent magnet demagnetization characteristics of the ITFRM according to various design variables and driving conditions. To analyze the characteristics, a two-dimensional finite-element method (2D-FEM) considering nonlinear analysis of permanent magnets is used. As a result, we propose the design variables that have the largest effects on the iron losses and irreversible magnet demagnetization.

Proteomic Analysis of Recombinant Saccharomyces cerevisiae upon Iron Deficiency Induced via Human H-Ferritin Production

  • Seo, Hyang-Yim;Chang, Yu-Jung;Chung, Yun-Jo;Kim, Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • v.18 no.8
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    • pp.1368-1376
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    • 2008
  • In our previous study, the expression of active H-ferritins in Saccharomyces cerevisiae was found to reduce cell growth and reactive oxygen species (ROS) generation upon exposure to oxidative stress; such expression enhanced that of high-affinity iron transport genes (FET3 and FTR1). The results suggested that the recombinant cells expressing H-ferritins induced cytosolic iron depletion. The present study analyzes metabolic changes under these circumstances via proteomic methods. The YGH2 yeast strain expressing A-ferritin, the YGH2-KG (E62K and H65G) mutant strain, and the YGT control strain were used. Comparative proteomic analysis showed that the synthesis of 34 proteins was at least stimulated in YGH2, whereas the other 37 proteins were repressed. Among these, the 31 major protein spots were analyzed via nano-LC/MS/MS. The increased proteins included major heat-shock proteins and proteins related to endoplasmic reticulum-associated degradation (ERAD). On the other hand, the proteins involved with folate metabolism, purine and methionine biosynthesis, and translation were reduced. In addition, we analyzed the insoluble protein fractions and identified the fragments of Idh1p and Pgk1p, as well as several ribosomal assembly-related proteins. This suggests that intracellular iron depletion induces imperfect translation of proteins. Although the proteins identified above result from changes in iron metabolism (i.e., iron deficiency), definitive evidence for iron-related proteins remains insufficient. Nevertheless, this study is the first to present a molecular model for iron deficiency, and the results may provide valuable information on the regulatory network of iron metabolism.

A Study on th Quality Stabilization of Iron Oxide (산화철의 품질 안정화)

  • 변태봉;한기현;김형석;배우현
    • Resources Recycling
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    • v.7 no.4
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    • pp.55-63
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    • 1998
  • The main purpose of the present study is to reduce quality variation of iron oxide for soft ferrite produced at hydrochloric acid facility )HAF) in a cold rolled mill factory. We investigated the factor of iron oxide quality variation, the operating condition of hydrochloric acid facility and the iron oxide quality with the production lot. Based on this information, we liad developed proper working plan for the diminution of iron oxide quality variation. To reduce iron oxide quality variation, the first priority is to control the picking steels, which seriously affect iron oxide quality variation, and then to separate generated waste acid. theretore, it was possible to reduce iron oxide quality variation with the proper operation of various kinds of waste acid tanks. We could produce iron oxide below 20 ppm SiO$_{2}$ content variation by operation after separation waste acid generated at TCM line.

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Inhibitory Actions of Quercetin and Rutin on $Fe^{2+}-induced$ Lipid Peroxidation ($Fe^{2+}$에 의한 지질 과산화에 있어서 Quercetin과 Rutin의 억제 작용)

  • Chung, Jin-Hee;Lee, Chung-Soo;Shin, Yong-Kyoo;Lee, Kwang-Soo
    • The Korean Journal of Pharmacology
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    • v.27 no.1
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    • pp.69-80
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    • 1991
  • Inhibitory effects of quercetin and rutin on lipid peroxidation of microsomes caused by iron(II) were investigated with respect to the scavenging action for oxygen radicals produced during oxidation of iron and the chelating action for iron. Lipid peroxidation by $Fe^{2+}$ alone was markedly inhibited by quercetin or rutin in a dose dependent fashion. Lipid peroxidation by ascorbate or NADPH in the presence of $Fe^{2+}$ was almost completely inhibited by both quercetin and rutin. The peroxidative action of $Fe^{2+}$ was inhibited by SOD and DABCO and slightly inhibited by catalase, DMSO and mannitol. Quercetin and rutin inhibited oxidation of $Fe^{2+}$ which is responsible for DETAPAC and they showed a significant initial chelating effect. Quercetin and rutin effectively inhibited lipid peroxidation by $H_{2}O_{2}$ and decomposed $H_{2}O_{2}$. Both $OH{\cdot}$ production in the presence of $Fe^{2+}$ and $^1O_2$ production by U.V. irradiation were inhibited by quercetin and rutin. Lipid peroxidations by $Cd^{2+},\;Cu^{2+},\;Ni^{2+},\;Pb^{2+}$ and $Zn^{2+}$ were almost completely inhibited by quercetin. Quercetin and rutin significantly prevented the loss of sulfhydryl groups by $Fe^{2+}$. These results suggest that inhibitory effects of quercetin and rutin on the peroxidative action of $Fe^{2+}$ in the presence or absence of ascorbate and NADPH may be attributable to their scavenging action on reactive oxygen species and chelating action on iron.

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Separation of Heme-iron by Dialysis (투석법에 의한 Heme-iron의 분리)

  • Kang, In-Kyu;In, Man-Jin;Oh, Nam-Soon
    • Applied Biological Chemistry
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    • v.46 no.2
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    • pp.130-133
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    • 2003
  • A method for separating heme-iron from hemoglobin (Hgb) hydrolysate by dialysis was developed. Recovery of heme-iron increased with increasing Hgb concentration, whereas rejection of peptide and separation effciency expressed by HP ratio (heme-iron/peptide) did not show significant differences. HP ratio increased with increases in the degree of hydrolysis of Hgb and $KH_2PO_4$ concentrations of dialysis solution. Recovery of heme-iron decreased with increase in the pH of dialysis solution due to wash-out of heme-iron across the dialysis membrane caused by increase in solubility of heme-iron. Rejections of peptide were 74.5 and 87.5% (2 and 5 kDa of cut off size, respectively), whereas recovery of heme-iron decreased from 86.5 (2 kDa) to 63.1% (25 kDa). Amounts of heme-iron and peptide of dried heme-iron product were 21.7 and 77.0%, and HP ratio and production yield were 28.2 and 6.5%, respectively.

A Provenance Study of Iron Archaeological Sites in the Gyeongsang Province: Petrographic and Geochemical Approaches (경상지역 제철유적의 산지추정 연구: 암석기재학 및 지화학적 접근)

  • Jaeguk Jo;Seojin Kim;Jiseon Han;Su Kyoung Kim;Dongbok Shin;Byeongmoon Kwak;Juhyun Hong;Byeongyong Yu;Jinah Lim
    • Economic and Environmental Geology
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    • v.56 no.4
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    • pp.475-499
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    • 2023
  • To infer the provenance of raw iron materials utilized in iron production at the archaeological sites in Gyeongsang province, petrographic and geochemical analyses were conducted for smelting samples and major iron ores sourced from ore deposits. The smelting samples excavated from various iron archaeological sites were classified into different types according to their refining processes, such as iron bloom, iron bloom slag, pig iron, pig iron slag, forging iron flake, smithery iron, iron flake, and arrowhead. These samples exhibited discernable differences in their mineralogical components and texture. The enrichments of major elements such as aluminum and calcium in silicate minerals of the residual slags and the high contents of trace elements such as nickel and copper in some iron-making relics reflect the characteristics of raw iron ores, and thus can be regarded as potential indicators for inferring the provenance of source materials. In particular, the compositional ranges of Pb-Sr isotope ratios for the iron smelting samples were classified into three categories: 1) those exhibiting similar ratios to those of the raw iron ores, 2) those enriched in strontium isotope ratio, and 3) those enriched in both lead and strontium isotope ratios. The observed distinct Pb-Sr isotope characteristics in the iron smelting samples suggest the potential contribution of specific additives being introduced during the high-temperature refining process. These results provide a new perspective on the interpretation of the provenance study of the iron archaeological samples in Gyeongsang province, particularly in terms of the potential contribution of additives on the refining process.

Temperature dependent 2,3-dihydroxybenzoic acid production in Acinetobacter sp. B-W (Acinetobacter sp. B-W의 온도 의존적 2,3-dihydroxybenzoic acid 생산)

  • Kim, Kyoung-Ja;Lee, Jae-Hun;Yang, Yong-Joon
    • Korean Journal of Microbiology
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    • v.51 no.3
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    • pp.249-255
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    • 2015
  • A soil microorganism producing iron chelator (siderophore) under low iron stress (up to $2{\mu}M$ of iron) was identified as Acinetobacter sp. B-W by 16S rDNA sequence analysis, biochemical-, physiological tests and morphological analysis using electron microscope. Catechol nature of siderophore was detected by Arnow test. Although optimal cell growth was identified at $36^{\circ}C$ in iron-limited media, significant quantities of siderophore were produced only at $28^{\circ}C$. Biosynthesis of siderophore was strongly inhibited by growth at $36^{\circ}C$. Production of siderophore was completely inhibited by $10{\mu}M\;FeCl_3$. Iron chelator produced from Acinetobacter sp. B-W was purified from supernatant using butanol extraction, Sephadex LH-20 column chromatography and HPLC. Purified sideropore was identified as 2,3-dihydroxybenzoic acid by HPLC, TLC and IR analysis.

Nonribosomal Peptide Synthase is Responsible for the Biosynthesis of Siderophore in Vibrio vulnificus MO6-24/O

  • Kim, In-Hwang;Shim, Jung-Im;Lee, Ko-Eun;Hwang, Won;Kim, Ik-Jung;Choi, Sang-Ho;Kim, Kun-Soo
    • Journal of Microbiology and Biotechnology
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    • v.18 no.1
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    • pp.35-42
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    • 2008
  • Vibrio vulnificus produces siderophores, low-molecular-weight iron-chelating compounds, to obtain iron under conditions of iron deprivation. To identify genes associated with the biosynthesis of siderophore in V. vulnificus MO6-24/O, we screened clones with mini-Tn5 random insertions for those showing decreased production of siderophore. Among 6,000 clones screened, nine such clones were selected. These clones contain the transposon inserted in VV2_0830 (GenBank accession number) that is a homolog of a nonribosomal peptide synthase (NRPS). There is an another NRPS module, VV2_0831, 49-bp upstream to VV2_0830. We named these two genes vvs (Vibrio vulnificus siderophore synthase) A and B, respectively. Mutation of either vvsA or vvsB showed a decreased production of siderophore. The expression of an NRPS-lux fusion was negatively modulated by the presence of iron, and the regulation was dependent on Fur (ferric uptake regulator). However, the expression of the NRPS genes was still not fully derepressed in the iron-rich condition, even in furnull mutant cells, suggesting that some other unknown factors are involved in the regulation of the genes. We also demonstrated that the NRPS genes are important for virulence of the pathogen in a mice model.

Current Status of Ilmenite Beneficiation Technology for Production of TiO2 (TiO2 제조를 위한 일메나이트 처리기술 현황)

  • Sohn, Ho-Sang;Jung, Jae-Young
    • Resources Recycling
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    • v.25 no.5
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    • pp.64-74
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    • 2016
  • Titanium and iron are closely related in nature, although titanium is the ninth most abundant element in the Earth's crust. Iron in titanium ores must be removed for use as feedstocks in the manufacture of titanium dioxide pigments and pure $TiCl_4$ for metal titanium. In this study, various beneficiation processes of ilmenite for production of $TiO_2$ have been reviewed and compared. Most of these processes involve a combination of pyrometallurgy and hydrometallurgy. These beneficiation processes of ilmenite generate considerable quantities of wastes primarily in the form of iron salt, iron oxide and acidic effluents. Therefore, it is important that recovery of acid value from waste and conversion of iron bearing waste to useful materials for development of new beneficiation processes of ilmenite.