• Title/Summary/Keyword: Iron(III)

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Comparison of Iron(Fe) Data of ENDF/B-IV and VI in Yonggwang Nuclear Unit-3/4 Vessel Fluence Calculation (영광 3/4호기 압력용기의 중성자 조사량계산을 통한 ENDF / B-IV와 VI 철(Fe) 자료의 비교)

  • Kim, Tae-Hyeong;Cho, Nam-Zin
    • Nuclear Engineering and Technology
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    • v.27 no.1
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    • pp.74-83
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    • 1995
  • The accurate determination of the fast neutron flux/fluence onto the pressure vessel is an essential part of the reactor pressure vessel surveillance program. It has been reported recently that the iron cross section data in ENDF/B versions III through V might underestimate the flux/fluence of fast neutrons in steel structures such as reactor pressure vessel. In this study, for the comparison of iron data of ENDF/B-IV and VI we produced two 47-group cross section sets, CXFe-IV and CXFe-Ⅵ, which are based on Yonggwang nuclear unit-3/4 model and the iron data of ENDF/B-IV and VI, respectively. A comparison was made of the results obtained from DOT4.3 calculation using CXFe-IV and CXFe-VI. From the results, it was found that the fast flux(E 〉 1.0 MeV), which is important for the pressure vessel embrittlement analysis, increases by about 7.6% at the inner wall and 20% at the outer wall of the vessel, if the iron data are used from ENDF/B-VI instead of ENDF/B-IV.

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Removal of Heavy Metal and Phenol from Aqueous Solution Using Fe(III) loaded Adsorbent (3가철 함유 흡착제를 이용한 수용액상의 중금속 및 페놀제거연구)

  • Kim, Seok-Jun;Kim, Won-Gee;Lee, Seung-Mok;Yang, Jae-Kyu;Lee, Nam-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.541-548
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    • 2009
  • Iron coated media (activated carbon, sand and starfish) were prepared at pH 4 and applied for the treatment of landfill leachate containing organic compounds and soluble metal ions such as $Zn^{2+},\;Cu^{2+},\;Mn^{2+}$ in batch and column experiment. The amount of iron coated in media was analyzed with EPA 3050B method. The removal efficiency of metal ions and phenol was compared with iron coated media. The amount of iron coated in Fe-AC and ICS(iron coated sand) were 1,612 mg/kg and 1,609 mg/kg, respectively, while it was higher with 1,768 mg/kg in ICSF(iron coated starfish). The result of batch study represent the highest removal efficiency in the treatment of wastewater using iron coated starfish. In column study, the removal efficiency of phenol and metal ions was higher in multi-layered system of ICS, Fe-AC and ICSF compared to single layered system. Breakthrough time in the effluent was relatively enhanced for $Cu^{2+}$ and $Zn^{2+}$ in multi-layered system while the removal efficiency of $Mn^{2+}$ were not varied much. Therefore, multi-layered system was identified as the better system for the treatment of wastewater containing of metal ions and organic compound.

Fenton Degradation of Highly Concentrated Fe(III)-EDTA in the Liquid Waste Produced by Chemical Cleaning of Nuclear Power Plant Steam Generators (펜톤 반응을 이용한 원전 증기발생기 화학세정 폐액의 고농도 Fe(III)-EDTA 분해)

  • Jo, Jin-Oh;Mok, Young Sun;Kim, Seok Tae;Jeong, Woo Tae;Kang, Duk-Won;Rhee, Byong-Ho;Kim, Jin Kil
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.552-556
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    • 2006
  • An advanced oxidation process catalyzed by iron ions in the presence of hydrogen peroxide, the so-called Fenton's reaction, has been applied to the treatment of steam generator chemical cleaning waste containing highly concentrated iron(III)- ethyl-enediaminetetraaceticacid (Fe(III)-EDTA) of 70000 mg/L. The experiments for the degradation of Fe(III)-EDTA were carried out not only with a simulated waste, but also with the real one. The effect of pH and the amount of hydrogen peroxide added to the waste on the degradation was examined, and the results were discussed in several aspects. The optimal pH to maximize the degradation efficiency was dependent on the amount of hydrogen peroxide added to the waste. i.e., when the amount of hydrogen peroxide was different, maximum degradation efficiency was obtained at different pH's. The optimal amount of hydrogen peroxide relative to that of Fe(III)-EDTA was found to be 24.7 mol ($H_{2}O_{2}$)/mol (Fe(III)-EDTA) at pH around 9.

$\alpha$-$Fe_2O_3$ 미분말 합성 및 제조 특성에 관한 연구

  • 김병수;정용선;오근호
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.75-80
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    • 1997
  • Ethanol을 용매로 사용한 iron(III) Nitrate(Fe(NO$_3$)$_3$.9$H_2O$) 용액의 가수분해 반응에 의해 $\alpha$-Fe$_2$O$_3$미분말을 합성하였다. 가수분해 정도를 알아보기 위해 pH 변화를 측정하였으며, 반응온도와 iron(III) nitrate의 농도를 변화시켜 각각이 입자크기에 미치는 영향을 관찰하였다. 하소 후의 XRD pattern을 관찰하여 $\alpha$-Fe$_2$O$_3$결정상의 생성을 확인하였으며, 미세구조 관찰 결과 얻어진 $\alpha$-Fe$_2$O$_3$분말은 50nm이하의 미세한 입자임이 확인되었다.

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Water carrying iron (iii) oxide (Fe3O4) ferrofluid flow and heat transfer due to deceleration of a rotating plate

  • Bhandari, Anupam
    • Structural Engineering and Mechanics
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    • v.82 no.5
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    • pp.679-690
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    • 2022
  • This research effort examines the flow behavior and heat transfer assessment of water carrying iron (iii) oxide magnetic fluid due to a rotating and moving plane lamina under the influence of magnetic dipole. The effect of rotational viscosity and magnetic body force is taken into consideration in the present study. The involvement of the moving disk makes a significant contribution to the velocity distribution and heat transfer in rotational flow. Vertical movement of the disk keeps the flow unsteady and the similarity transformation converts the governing equation of unsteady flow into nonlinear coupled differential equations. The non-dimensional equation in the present system is solved through the finite element procedure. Optimizing the use of physical parameters described in this flow, such results can be useful in the rotating machinery industries for heat transfer enhancement.