• Title/Summary/Keyword: Iron(Fe)

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Selective Phase Transformation of Arsenopyrite by Microwave Heating and their Enhancement Au Recovery by Thiocyanate Solution (마이크로웨이브 가열에 의한 황비철석의 선택적 상변환과 티오시안산염 용액에 의한 Au 회수율 향상)

  • Han, Oh-Hyung;Kim, Bong-Ju;Cho, Kang-Hee;Choi, Nag-Choul;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.2
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    • pp.73-83
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    • 2014
  • In order to investigate selective phase transformations and to determine the maximum Au leaching factors from microwave treated Au-bearing complex sulfides, a microscope, SEM-EDS analysis, and thiocyanate leaching tests were performed. When the Au-bearing complex sulfides were exposed to microwave heating, increasing the microwave exposure time increased temperature and decreased weight. Arsenopyrite was first selectively transformed to hematite, which formed a concentric rim structure. In this hematite, oxygen and carbon was detected and always showed high iron content and low arsenic content due to arcing and oxidation from microwave heating. The results of the leaching test using microwave treated sample showed that the maximum Au leaching parameters was reached with 0.5 g concentration thiocyanate, 2.0 M hydrochloric acid, 0.3 M copper sulfate and leaching temperature at$60^{\circ}C$. Under the maximum Au leaching conditions, 59% to 96.69% of Au was leached from the microwave treated samples, whereas only 24.53% to 92% of the Au was leached from the untreated samples.

An Analysis of Related Factors and Nutrients Intake Affecting Bone Mineral Density of College Women in Daegu Area (대구지역 여대생의 골밀도에 영향을 미치는 관련인자와 영양소 섭취와의 상관성 분석)

  • Kim, Jeong-Mi
    • Journal of the Korean Dietetic Association
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    • v.11 no.1
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    • pp.86-94
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    • 2005
  • This study was conducted to examine bone mineral density and factors which effect on bone mineral density such as daily nutrients intake, age, menarch age and physical condition among healthy female college students in Daegu area from April 20, to May 20, 2004. 1. Average age was 20.5$\pm$0.96 years old, average height was 160.9$\pm$4.30㎝, and average weight was 55.9$\pm$7.67㎏. Body mass index was 21.6$\pm$2.91㎏/㎡, body fat was 25.6$\pm$5.79%, menarche age was average 12.5$\pm$1.1 years old and WHR(waist/hip circumference ratio) was 0.8$\pm$0.01㎝/㎝. 2. Average level of bone mineral density(T-score -0.56$\pm$0.91) was in normal range. But, 11 persons(24.4%) are over T-score -1.0, 33 persons(73.4%) were within -1.0 - -2.5 and one person(2.2%) was under -2.5. It is very anxious level for Osteopenia-low bone mass, as research result shows 73.4% of the subject of examine on the level of Osteopenia. 3. Daily calorie intake was 2,550㎉ and each nutrient intake, compared to the seventh recommended dietary allowances for korean, was as follows ; Calorie 112%, protein 123%, calcium 78%, phosphorus 137%, iron 68%, vitamin A 101%, vitamin $B_1$ 141%, vitamin $B_2$ 95%, niacin 107%, vitamin C 128% and zinc 120%. The ratio of calcium to phosphorus(Ca/P) is 0.66, low compared to RDA, but phosphorus intake is so high compared to RDA that precautions should be taken. The ratio of calcium to protein(Ca/Protein) is 8.55. 4. Menarche age and bone mineral density of calcaneus showed positive correlation and body mass index(BMI) indicated positive correlation. Age, height, weight. WHR and physical activity coefficient all do not indicate any significant correlation with bone mineral density. 5. Intake of Calorie, Ca, Ca/p ratio, carbohydrate and fat intake were positively correlated and, protein was negatively correlated, and Fe, Na, P and cholesterol were negatively correlated with BMD. These results indicate that average bone mineral density of subjects was in normal range, but subjects in the stage of osteopenia-low bone mass are many and bad effects are expected to have on their bone mineral density after menopause. Therefore, in order reach maximal bone mineral density, they should improve the balance between calcium and phosphorus and reduce salt intake. And it is thought that education and profound studies on relevant factors affecting the genesis of bone mineral density should be made.

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Heavy Metal Contamination and the Roles of Retention Pond and Hydrologic Mixing for Removal of Heavy Metals in Mine Drainage, Kwangyang Au-Ag Mine Area (광양 폐 금-은 광산 지역 광산폐수의 중금속 오염과 중금속의 제거에 있어 소택지와 지류 혼합의 역할 평가)

  • 정헌복;윤성택;김순오;소칠섭;정명채
    • The Journal of Engineering Geology
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    • v.13 no.1
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    • pp.29-50
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    • 2003
  • Physicochemical Properties of acid mine water of the Chonam-ri Creek and the Sagok-ri Creek in the Kwangyang Au-Ag mine area were determined using geochemical approaches. Metal contamination (Cd, Cu, Pb, Zn) is more serious in the Chonam-ri Creek than in the Sagok-ri Creek. However, the contents of Al and Fe is higher in the Sagok-ri Creek. Such differences between the two creeks probably reflect the abundance and composition of ore minerals. The attenuation processes for acid mine water in both creeks were investigated. In the Chonam-ri Creek, a small retention pond which contains limestone plays an important role in the removal of heavy metals by adsorption or coprecipitation due to increase of pH. The capacity of metal scavenging in this pond depends on the seasonal variation of inflow volume. Reddish yellow precipitates sampled in the Chonam-ri Creek were analyzed by XRD, SEM-EDS, EPMA, and chemical decomposition. The precipitates mainly consist of goethite and are also enriched in Al, Mn, Cu and Zn. This inditates that precipitation of goethite is important for scavenging those trace elements, possibly due to adsorption or coprecipitation. In the Sagok-ri Creek, on the other hand, hydrologic mixing of uncontaminated tributaries results in removal of heavy metals with iron hydroxides precipitation due to the pH increase. The mechanisms proposed for metal attenuation at the confluence between contaminated mine water and uncontaminated tributary water are also explained by the property-property plots.

A Comparative Study on the Dietary Attitudes and Nutritional Status of Preschoolers in Different Income Levels in Seoul and Kyunggi-Do: 2. Focusing on Preschoolers' Nutrients and Fatty Acid Intakes (서울과 경기 일부지역의 소득수준별 미취학 아동의 식생활 태도 및 영양상태에 관한 비교 연구: 2. 영양소 및 지방산 섭취실태를 중심으로)

  • Chung, Eun-Jung;Nam, Hae-Won;Um, Young-Sook
    • Journal of the Korean Society of Food Culture
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    • v.13 no.4
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    • pp.293-305
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    • 1998
  • According to economical status, under-nutrition and over-nutrition coexist in preschool children in Korea. Subjects consumed more than RDA in most nutrients, and children in of the upper income class tended to have more nutrients than those of the low income class. Especially in case of energy, protein, fat, vitamin $B_2$, and P there were significant differences among the different classes. The mean calorie compositions of carbohydrates, protein and fat were $57{\sim}59:\;16{\sim}17:\;26{\sim}27$ and fat calorie percentage was higher than quantity recommended for Korean adults. Energy, protein, Fe, vitamin A, $B_1$ and C intakes were taken mostly from plant food sources. In the upper income class group, intakes of protein and vitamin $B_2$ from animal food sources were higher than in any other income classes. Intakes of iron, vitamin A, $B_1$ and C were largely provided by plant food group. Especially 44-45% of vitamin A were taken from vegetable and fruits group, which indicated that about 50% of vitamin A intake was the form of ${\beta}-carotene$. Also compared with other groups, in the upper income class group, the intakes of energy, protein, Ca, p, vitamin $B_1$ and vitamin $B_2$ from cereal and potatoes were significantly lower, and those of Ca and P from milks and meats, fishes & eggs were significantly higher(p<0.05). The mean fat intake in all subjects was $38{\sim}43g/day$. Regardless of income class, oleic acid($6.6{\sim}8.4g$) and linoleic acid($6.7{\sim}8.1g$) were the most abundant fatty acids contained in the diet. The upper class group consumed significantly more total saturated fatty acids and total monounsaturated fatty acids(p<0.05). In polyunsaturated fatty acids, there were no differences between 3 different income classes, but intakes of total ${\omega}6$ fatty acids in the upper class tended to be higher and those of total o3 fatty acids in low class tended to be higher. Therefore, ${\omega}6/{\omega}3$ tended to be higher in the upper class group. Regardless of income classes, P/M/S and ${\omega}6/{\omega}3$ ratios in all subjects were $0.9{\sim}l.3/1.0{\sim}1.1/1.0$ and $5.2{\sim}7.4/1.0$, respectively and were in a desirable range. Cholesterol intake of subject was 184-218 mg/day, which was comparable to the value of Korean adult intake.

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Dyeability and Antibacterial Activity against Food Poisoning Bacteria Dyed with Geranium nepalense Extracts (이질풀 추출물로 염색한 면직물의 염색성과 항식중독균성)

  • Park, Yun-Jum;Kim, Hyun-Ju;Park, Yong-Seo;Cho, Ja-Yong;Jang, Hong-Gi;Heo, Buk-Gu
    • Korean Journal of Medicinal Crop Science
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    • v.14 no.3
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    • pp.139-142
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    • 2006
  • This study was conducted to develop antibacterial hand towel and dishcloth against food poisoning bacteria, and to examine the dyeability and the antibacterial activity of cotton fabrics against food poisoning bacteria, which was dyed with 1 % extracts of Geranium nepalense at $50\;to\;60^{\circ}C$ minutes. Surface colors of cotton fabrics treated nothing, alum $[AIK(SO_4)_2{\cdot}nH_2O]$, and calcium hydroxide $[Ca(OH)_2]$ with mordants showed grayed-yellow group, that treated copper sulfate $(CUSO_4)$ with mordant was grey-brown group, and that treated sulfate of iron $(FeSO_4{\cdot}7H_2O)$ made grayed-green group. Hue value of cotton fabrics dyed with the extracts of Geranium nepalense and dried until twenty times was an order of descent Y, that dried thirty to forty an order of descent YR. Cotton fabrics dyed with the extracts of Geranium nepalense had the antibacterial activity against food poisoning bacteria such as Staphylococcus aureus, Escherichia coil and Salmonella typhimurium by over 99.99%. And that dried over thirty times showed the antibacterial activities against food poisoning bacteria by 52.91%.

Analysis of General Components, Mineral Contents, and Dietary Fiber Contents of Synurus deltoides (수리취(Synurus deltoids)의 일반성분, 무기질 및 식이섬유에 관한 연구)

  • Park, Min-Hee;Choi, Byoung-Gon;Lim, Sang-Hyun;Kim, Kyung-Hee;Heo, Nam-Ki;Yu, Seong-Hee;Kim, Jong-Dai;Lee, Kwang-Jae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.11
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    • pp.1631-1634
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    • 2011
  • This study was conducted to estimate the general components, minerals, and dietary fiber contents of Synurus deltoides. S. deltoides contained 81.1% moisture content, and the proportions of crude fat, crude protein, crude ash, and crude fiber were 0.3%, 4.2%, 2.6%, and 3.5%, respectively. Potassium (3,249.1 mg) was the most abundant component among the minerals in S. deltoides. In addition, S. deltoides contained many other minerals, e.g. calcium (854.8 mg), phosphorus (60.3 mg), magnesium (344.7 mg), sodium (57.3 mg), zinc (1.7 mg), iron (30.9 mg), copper (0.8 mg), and manganese (5.8 mg). Almost all of the mineral contents of S. deltoides were higher than those of Aster scaber and Ligularia fischeri, except for zinc, copper, and manganese. Total dietary fiber (TDF), insoluble dietary fiber (IDF), and soluble dietary fiber (SDF) contents of S. deltoides were 42.6 g, 37.9 g, and 4.7 g, respectively, and these were also higher than those of A. scaber and L. fischeri used in this study. These results suggest that S. deltoides may be a valuable nutrient source.

Effects of High Pressure Treatment on Antioxidant Compounds and Activity of Germinated Rough Rice (Oryza sativa L.) (고압처리가 발아벼의 항산화 성분과 활성에 미치는 영향)

  • Kim, Min Young;Lee, Sang Hoon;Jang, Gwi Young;Park, Hye Jin;Meishan, Li;Kim, Shinje;Lee, Youn Ri;Lee, Junsoo;Jeong, Heon Sang
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.11
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    • pp.1783-1791
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    • 2013
  • This study is investigated to evaluate the enhancement of antioxidant compound and activity of rough rice with different germination periods and high pressure treatment. The subject was germinated at $37^{\circ}C$ for 6 days (HP0), and then the germinated rough rice were subjected to 30 MPa for 24 hr (HP24) and 48 hr (HP48), respectively. HP0, HP24 and HP48 samples were prepared and extracted with 80% ethanol. The highest total polyphenol contents (5.15 mg/g) occurred in treating at HP48 after germination for 5 days. The total phenolic acid contents including gallic acid, chlorogenic acid, catechin, ${\rho}$-coumaric acid, ferulic acid, salicylic acid, naringin, myricetin, trans-cinnamic acid, naringenin and kaempferol increased from $37.26{\sim}204.32{\mu}g/g$ at HP0 to $77.29{\sim}283.05{\mu}g/g$ at HP48. In antioxidant activity analyses, HP48 extracts showed higher values in ABTS and DPPH radical scavenging activity, reducing power, and $Fe^{2+}$ iron chelating effect than those of the HP24 and HP0 extracts. These results suggest that the combined treatment of high pressure treatment and germination process efficiently enhanced antioxidant compound and activity of rough rice.

Inhibitory Effect of Extract from Acanthocoris sordidus on Oxidative Damage (꽈리허리노린재(Acanthocoris sordidus) 추출물이 산화적 손상에 미치는 억제 효과)

  • Park, Young Mi;Lim, Jae Hwan;Lee, Jong Eun;Seo, Eul Won
    • Journal of Life Science
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    • v.24 no.10
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    • pp.1078-1084
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    • 2014
  • Here, we showed that Acanthocoris sordidus extract inhibited both cell and DNA damage caused by oxidative stress. In a radical scavenging assay, the scavenging activity of the A. sordidus extract against 1,1-diphenyl-2-picrylhydrazyl (DPPH) and hydroxyl radicals was 48.9% and 37.8%, respectively, that of ascorbic acid, which was used as a positive control. The ferrous iron chelating activity of the A. sordidus extract was 80.0% compared to that when ethylenediaminetetraacetic acid (EDTA) was used a control. To verify the inhibitory effect of the extract on oxidative cell damage induced by reactive oxygen species (ROS), a lipid peroxidation assay was performed. The results showed that peroxidation was completely inhibited in an extract-treated group compared to a radical-treated group. The level of p21 protein expression was 68.1% that of a control sample. The DNA cleavage-inhibiting property of the A. sordidus extract-treated group was 53.3% that of a control group. Moreover, the phosphorylation of the H2AX protein was reduced to 39.0% of that treated with radical agents, indicating that the extract might inhibit the DNA damage that causes radical oxidation. Taken together, our findings suggest that the A. sordidus extract is effective not only in repressing oxidation by free oxygen radicals and hydroxyl radicals but also in decreasing cell and DNA damage caused by oxidative stress.

Chemical Composition and Biological Feed Value of Autoclaved Poultry By-products for Poultry (가압열처리한 도계부산물의 화학적 조성과 닭에 대한 생물학적 사료가치)

  • 이규호
    • Korean Journal of Poultry Science
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    • v.24 no.4
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    • pp.185-191
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    • 1997
  • In order to obtain the basic information needed to utilize poultry by-products as feed resources, the yielding ratio, chemical composition and nutrient bioavailability of 5 offal components such as autoclaved head, feet, viscera, blood and feathers were investigated. Yielding ratios of head, feet, viscera, blood and feathers were 2.93% 4.78%, 10.98%, 3.91% and 4.83%, respectively. The crude protein contents of feathers (86.71%) and blood (82.99%) were higher than those of viscera (64.67%), feet (58.76%) and head (49.51%) , Inversely, the crude fat contents of blood (6.96%) and feathers (2.96%) were lower than those of head (26.19%), viscera (23.96%) and feet (13.73%). The crude ash contents of feet (21.69%) and head (20.38%) were higher than those of other by-products (0.96∼8.62%). The macro-mineral contents of head and feet were higher than those of other components, and the iron content of blood was higher than the other by-products. The total amino acid contents of poultry by-products showed the same trend as the crude protein contents. In addition, the Iysine content of feathers was very low compared to its high protein content. The essential amino acid contents of feathers were poorer than those of other offal components. Among the 5 offal components, the feathers showed the poorest amino acid availabilities. The ME contents were highest in viscera, and head, blood, feathers and feet. in decreasing order.

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Preparation of Inorganic Coagulants Using Red Mud (적니를 이용한 무기응집제의 제조연구)

  • Kim, Jung-Sik;Lee, Jae-Rok;Han, Sang-Won;Hwang, In-Gook;Bae, Jae-Heum
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2085-2095
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    • 2000
  • Red mud is generated as a by-product during the production of aluminum hydroxide from bauxite ore. In this study inorganic coagulants were prepared by leaching aluminum and iron from red mud with acids under various operating conditions. The optimum leaching efficiency of Al and Fe was obtained by contacting red mud with acids of 5M $H_2SO_4$ and 9M HCI with the ratio of 1/10(g/mL) at $85^{\circ}C$ and $25^{\circ}C$, respectively. In addition. the removal experiments of heavy metal ions($Pb^{2+}$, $Cd^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Cr^{3+}$), turbidity and phosphate phosphorus($PO_4{^{3-}}-P$) in aqueous solutions were also studied in various experimental conditions. As a result, the developed coagulants are found to show a good removal performance of heavy metal ions. turbidity and phosphate phosphorus in aqueous solutions.

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