• Journal of Information Display
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• 제12권1호
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• pp.51-55
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• 2011

Efficient two-color-mixed white organic light-emitting diodes are presented herein by employing a sky-blue phosphorescent dopant of iridium(III)bis[4,6-(difluorophenyl)-pyridinato-N,$C^{2'}$]picolinate (FIrpic) and an orange phosphorescent dopant of bis(2-phenylquinoline)(acetylacetonate)iridium(III) ($Ir(phq)_2$acac) on the emissive layer. Very stable color variation under ${\Delta}$0.02 until a 5000 cd/$m^2$ brightness value was realized by efficient carrier control in a multi-stacked emitting layer of blue/red/blue colors. Maximum current and power efficiencies of 23.8 cd/A and 22.9 lm/W in the forward direction were obtained. With balanced emission from the two emitters, the white-light emission of high correlated color temperature of 7308K and the Commission Internationale de I'Eclairage coordinates of (0.30, 0.33) were achieved.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.64-65
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• 2007

High-efficiency white organic light-emitting diodes (WOLEDs) were fabricated with two emissive layers and exciton blocking layer was sandwiched between two phosphorescent dyes which were, bis(3,5-Difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium III (Flrpic) as blue emission and a newly synthesized red phosphorescent material guest, Bis(5-benzoyl-2-phenylpyridinato-C,N)iridium(III) (acetylacetonate) ((Bzppy)2Ir(III)acac). This exciton blocking layer prevents a triple-triple energy transfer between the two phosphorescent emissive layers with balanced emission of blue and red. The white device showed the Commission Internationale d'Eclairage (CIEx,y) coordinates of (0.34, 0.40) at the maximum luminance of $24100\;cd/m^2$ and maximum luminous efficiency of 22.4 cd/A, respectively.

• Bulletin of the Korean Chemical Society
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• 제20권5호
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• pp.535-538
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• 1999

Five coordinated water-soluble iridium(l) complex, IrH(CO)(TPPTS)3 (1) (TPPTS = P(m-C6H4SO3Na)3-xH2O) has been prepared from the reaction of IrCl3·3H2O with TPPTS and HCHO in H2O/EtOH solution. Complex 1 catalyzes the hydration of nitrites (RC ≡ N, R = CH3, CICH2, CH3(CH2)4, Ph) in aqueous solution to give the corresponding amides (RCONH2) at 100℃. The hydration of unsaturated nitrites (R'C ≡ N, R'=CH3CH=CH, CH3OCH=CH, trans-PhCH=CH, CH2=C(CH3)) takes place regioselectively on-C ≡ N group to give unsaturated amides (R'CONH2) leaving the olefinic group intact. The yields of the amides seem to be depending on the electrophilicity of the carbon of nitrile: The more the electron withdrawing ability of the substituents on nitrites, the more amides are obtained. The hydration of dinitriles (NC-R-CN, R=(CH2)4, (CH2)6) with complex 1 initially gives mono-hydration products (NC-R-CONH2) which are slowly hydrated further to give dihydration products (H2NCO-R-CONH2). The hydration of 1,4-dicyanobutane has been found to be somewhat faster than that of 1,6-dicyanohexane.

• 대한금속재료학회지
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• 제48권5호
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• pp.430-435
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• 2010

Solvent extraction experiments of Rh(III) and Ir(IV) were performed on the HCl solution by using Alamine336 and TBP. The extraction percentage of Rh and Ir by Alamine336 was much higher than that by TBP. For the solvent extraction with Alamine336, the extraction percentage of Rh and Ir decreased with a HCl concentration. However, the extraction percentage of both metals by TBP was below 12% in our experimental range and increased with an increasing HCl concentration of up to 8 M. From the mixed solution of Ir with an excess SnCl$_{2}$, most of the tin was extracted by Alamine336 and TBP. However, the extraction percentage of Ir by Alamine336 was reduced and no iridium was extracted by TBP. The extraction behavior of Ir and Sn was investigated by scrubbing experiments on the loaded Ir with a SnCl$_{2}$ solution.

• 천문학회보
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• 제45권1호
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• pp.39.3-40
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• 2020

For the space weather research, KASI (Korea Astronomy and Space Science Institute) is developing the SNIPE (Small-scale magNetospheric and Ionospheric Plasma Experiment) mission, which consists of four 6U CubeSats of ~10 kg. Besides of space weather research, the SNIPE mission has another astrophysical objective, detecting Gamma-Ray Bursts(GRB). By cross-correlating the light curves of the detected GRBs, the fleet shall be able to determine the time difference of the arriving signal between the satellites and thus determine the position of bright short bursts with an accuracy ~100'. To demonstrate the technology of the GRB observation, CSI gamma-ray detectors combined with GPS and IRIDIUM communication modules are placed on each SNIPE CubeSat. The time of each spacecraft is synchronized and when the GRB is detected, the light curve will be transferred to the Mission Operation Center (MOC) by IRIDIUM communication module. By measuring time difference of each GRB signals, the technology for localization of GRB will be proved. If the results show some possibilities, we can challenge the new astrophysical mission for investigating the origin of GRB.

• 한국재료학회지
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• 제26권3호
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• pp.117-122
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• 2016

White organic light-emitting diodes with a structure of indium-tin-oxide [ITO]/N,N-diphenyl-N,N-bis-[4-(phenylm-tolvlamino)-phenyl]-biphenyl-4,4-diamine [DNTPD]/[2,3-f:2, 2-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile [HATCN]/1,1-bis(di-4-poly-aminophenyl) cyclo -hexane [TAPC]/emission layers doped with three color dopants/4,7-diphenyl-1,10-phenanthroline [Bphen]/$Cs_2CO_3$/Al were fabricated and evaluated. In the emission layer [EML], N,N-dicarbazolyl-3,5-benzene [mCP] was used as a single host and bis(2-phenyl quinolinato)-acetylacetonate iridium(III) [Ir(pq)2acac]/fac-tris(2-phenylpyridinato) iridium(III) $[Ir(ppy)_3]$/iridium(III) bis[(4,6-di-fluoropheny)-pyridinato-N,C2] picolinate [FIrpic] were used as red/green/blue dopants, respectively. The fabricated devices were divided into five types (D1, D2, D3, D4, D5) according to the structure of the emission layer. The electroluminescence spectra showed three peak emissions at the wavelengths of blue (472~473 nm), green (495~500 nm), and red (589~595 nm). Among the fabricated devices, the device of D1 doped in a mixed fashion with a single emission layer showed the highest values of luminance and quantum efficiency at the given voltage. However, the emission color of D1 was not pure white but orange, with Commission Internationale de L'Eclairage [CIE] coordinates of (x = 0.41~0.45, y = 0.41) depending on the applied voltages. On the other hand, device D5, with a double emission layer of $mCP:[Ir(pq)_2acac(3%)+Ir(ppy)_3(0.5%)]$/mCP:[FIrpic(10%)], showed a nearly pure white color with CIE coordinates of (x = 0.34~0.35, y = 0.35~0.37) under applied voltage in the range of 6~10 V. The luminance and quantum efficiency of D5 were $17,160cd/m^2$ and 3.8% at 10 V, respectively.

• 마이크로전자및패키징학회지
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• 제30권1호
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• pp.79-89
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• 2023

산성 조건에서의 산소 발생 반응(OER)의 효율 향상 및 안정적인 전기 촉매 개발은 양이온 교환 막 (PEM) 수전해 장치의 상용화를 위한 바람직한 목표다. 여기서 우리는 산성 OER에 대해 Ir 함량이 낮은 유망한 촉매로서 Ir이 도핑된 수소화 티타네이트 (Ir-HTO) 나노벨트를 보고한다. 크게 확인할 수 있는 {100}면이 있는 단결정 HTO 나노벨트에 낮은 함량의 Ir(~3.36 at %)을 추가하면 산성 조건에서 OER에 대한 촉매 활성과 안정성이 크게 향상된다. Ir-HTO는 상용적인 대조군 IrO2 촉매보다 성능이 뛰어나다. 10mA cm^-2의 전류밀도에서 과전압은 Ir-HTO가 25% 감소했다. Ir-HTO 촉매 성능은 산성 OER에 대한 가장 효율적인 전기 촉매로서 자리 잡고 있다. 심층적인 전기화학적 특성화를 통해 Ir-HTO에 대해 개선된 고유한 촉매 활성 및 안정성도 확인되었다. 따라서, 우리의 실험결과는 낮은 함량의 Ir이 도핑된 단결정 HTO 나노벨트가 산성조건에서 효율적이고 내구성 있는 OER 촉매로 유망 될 수 있음을 보여준다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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• pp.1474-1477
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• 2007

We demonstrate relaxation of roll-off characteristics by controlling the dopant concentrations and the thickness of an emitter layer in electrophosphorescence diodes composed of 2,6-dicarbazolo-1,5-pyridine (PYD2)-host doped with 25 wt%-Iridium(III)bis[(4,6-di-fluorophenyl)-pyridinato-$N,C^2$] picolinate (FIrpic).

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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• pp.1133-1137
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• 2005

In this paper, a renovated approach in the fabrication of red organic light-emitting diodes (OLEDs) is described. The hard-to-control doping process required for dopant-based red OLEDs can be avoided due to the novel red fluorophores that are not concentration quenching in solid state. Doping is in general a must for phosphorescence OLEDs because of the triplet-triplet annihilation, a common problem for phosphorophore dopants. However, we have recently found that extraordinary red iridium complex showing relatively short emission lifetime render the non-doped phosphorescence red OLED possible.

• 한국표면공학회지
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• 제35권6호
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• pp.401-407
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• 2002

Most of organic compounds discharged from industrial wastewater are treated by chemical oxidation, adsorption and biodegradable process. This process has been demanded a new advanced environmental wastewater treatment process. From this point of view, an electrochemical oxidation process using electrocatalysts has been developed for the destruction of organic compounds. Through this study, a ruthenium oxide/iridium oxide supported on titanium expanded metal was fabricated by thermal decomposition method and its performance was excellent during this experiment.