• Title/Summary/Keyword: Ionization potential

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A Study on the Electrochemical and Spectroscopic Property Analysis of Organic Eeletroluminescence Materials(BCP, PEDOT, TAZ, TPD) (유기전기발광물질들(BCP, PEDOT, TAZ, TPD)의 전기화학적.분광학적 특성분석)

  • Choi, Don-Soo;Bae, Jeong-Hyo;Kim, Dae-Kyeong;Lee, Jae-Duck;Kim, Mu-Young
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1564-1566
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    • 2004
  • BCP의 이온화에너지 (Ionization Potential; IP)는 5.72ev와 전자친화도 (Electron Affinity; EA)는 2.85ev이며, PEDOT의 IP=5.74ev와 EA=3.3sev이고, TAZ의 IP=6.45ev와 EA=2.77ev, TPD는 IP=5.75ev와 EA=2.S8eV를 나타내었다. 그리고 BCP와 TAZ는 산화전위의 시작점과 증가곡선의 전위 변곡점과의 차이(정공층 갭)와 환원전위의 시작점과 변곡점의 차이(전자층 갭)가 서로 비슷하였으며, PEDOT과 TPD의 경우 정공층의 갭이 전자층의 갭보다 크게 나타났다.

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Effects of shielding Gas Types on $CO_2$ Laser Weldability (보호가스에 따른 Tailored Blank 레이저 용접성 평가에 관한 연구)

  • 정봉근;유순영;박인수;이창희
    • Laser Solutions
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    • v.1 no.1
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    • pp.30-38
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    • 1998
  • This study includes the efface of shielding gas types on $CO_2$ laser weldability of low carbon automotive galvanized steel. The types of shielding gas evaluated are He, $CO_2$, Ar, $N_2$, 50%Ar+50%$N_2$. The weld penetration, strength, formability(Erichsen test) of Laser weld are found to be strongly dependent upon the types of shielding gas used. Further, the maximum travel speed and flow rate to form a keyhole weld is also dependent upon types of shielding gas. The ability of shielding gas in removing plasma plume and thus increasing weld penetration is believed to be closely related with ionization/dissociation potential, which determine the period of plasma formation and disappearance. Further, thermal conductivity and reactivity of gas with molten pool also give strong effect on penetration and porosity formation which in turn affect on the formability and strength.

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Research Trends of Ecotoxicity of Nanoparticles in Water Environment (수환경에서 나노입자의 생태독성 연구동향)

  • Lee, Woo-Mi;An, Youn-Joo
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.566-573
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    • 2010
  • Nanotechnology has been applied to various fields in our life. Although there is a limitation of nanoparticle monitoring so far, it is expected that nanoparticles are widely distributed in environmental multimedia. Nanoparticle is known to be more toxic than its corresponding bulk material. For this reason, developed countries and international organizations are preparing for future regulation. To evaluate the safety of nanoparticles, nanotoxicity studies are internationally underway. In this study, we evaluated the research trends of ecotoxicity of nanoparticles in water environment. Test species include fish, water flea, and algae. Nanoecotoxicological studies are rapidly increasing and the experimental designs become more sophisticated. Physicochemical properties of nanoparticles should be measured and the ionization potential is important for metal-based nanoparticles. We analyzed the research trends based on the type of nanoparticles and test species. Also experimental aspects of nanoecotoxicology are considered.

Improvement of Luminance Properties of Blue OLEO using $SnDP(HPB)_2$ (Sn-complexes를 이용한 OLED의 발광 특성 향상에 관한 연구)

  • Kim, Dong-Eun;Choi, Gyu-Chae;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.121-122
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    • 2008
  • Blue emitting materials have been explored by various researchers. However, blue-emitting materials with high luminous efficiency, good color purity, and thermal stability are still much desired. In this study, we synthesized a new blue luminescent material, $SnDP(HPB)_2$ which is low molecular compound and thermal stability. The PL spectrum of $SnDP(HPB)_2$ was observed blue at the wavelength of 447nm. The ionization potential(IP) and the electron affinity(EA) of $SnDP(HPB)_2$ was measured to be 6.7 eV and 3.0 eV, respectively. The fundamental structure of the OLED was ITO/NPB/$SnDP(HPB)_2/Alq_3$/LiF/Al. As a Result, we obtained to enhance the performance of blue OLED.

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Printability of an Aqueous Gravure Ink for Polyolefin (Polyolefin용 수성 Gravure Ink의 인쇄작성)

  • 김종원
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.1.1-11
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    • 1994
  • The photosensitive properties and carrier transport in the organic photoconductor with the carrier transport layers(CTL) of polymer matrix doped with two carrier transport materials above carrier generation layer(CGL) containing oxotitanium phthalocyanine (TiOPc) were investigated. The CGL of TiOPc dispersed in poly(vinylbutyral) was formed as thickness of 0.1${\mu}{\textrm}{m}$and the carrier transport layer was prepared by coating polycarbonate and polyester doped with oxadiazoly(OXD), polyvinylcarbazole (PVK), trinitro fluorenone(TNF) as thickness of 10~15${\mu}{\textrm}{m}$, respectively. We have measured half decay exposure,sensitivity and xerographic gain from the photo-induced discharge curve(PIDC). In this work, it was found that the characteristics of carrier transport were mainly caused by the ionization potential difference of constitutive materials in molecularly doped polymer.

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Effect of Polymer on the Photosensitive properties of organic Photoconductor (유기감광체의 감광특성에 미치는 고분자의 영향에 관한 연구)

  • 문명준;김명숙;이상남;민성기;김은경
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.43-60
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    • 1998
  • The photosensitive properties and spectroscopic characteristics in the organic photoconductor(OPC) with carrier generation layer(CGL) of poly(vinylbutyral)(PVB) and polycarbonate(PC) doped with titanyl phthalocyanine(TiOPc) were investigated. The change of crystal structure of TiOPc dispersed with PVB and PC was shown by UV-visible reflective spectrum and FT-IR spectrum and mainly caused by the difference of solubility of solvent and the interaction between TiOPc and binder. The particle size of TiOPc dispersed with PVB measured by SEM was smaller than in PC. The crystal structure of TiOPc dispersed with PVB was amorphous type and in PC was $\alpha$type. It was found that the photosensitive properties of OPC were dependent on the change of absorbance and ionization potential of TiOPc occurred from the difference of crystal structure. In this work, the photosensitivity of OPC of TiOPc dispersed with PVB was better than PC due to the crystal type and the smaller particle size.

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Emitting characteristics of poly(3-octylthiophene) electroluminescent devices (Poly(3-octylthiophene) 전계발광소자의 발광특성)

  • Seo, Bu-Wan;Kim, Ju-Seung;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.131-134
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    • 2000
  • Electroluminescent[EL] from conjugated polymers has recently received great attention because polymer light-emitting diodes[LEDs] clearly have potential for applications such as large-area displays. The operation of polymer LEDs is based on double injection of electrons and holes from the electrodes, followed by formation of excitons whose radiative decay results in light emission at wavelength characteristic to the material In this paper, we fabricated the single layer EL device using poly(3-octylthiophene)[P3OT] as emitting material. The orange-red light was clearly visible in a dark room Maximum peak wavelength of EL spectrum saw at 640nm in accordance with photon energy 1.9eV. And we know that ionization energy of P3OT is 4.7eV from the cyclic voltammetry.

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WATER VAPOR MASERS: A SIGNPOST FOR LOW MASS STAR FORMATION

  • Migenes, V.;Trinidad, M.A.;Valdettaro, R.;Brand, J.;Palla, F.
    • Journal of The Korean Astronomical Society
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    • v.40 no.4
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    • pp.127-129
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    • 2007
  • It is well known that water vapor maser emission at 22.2 GHz is associated with the earliest stages of both low- and high-mass star formation and it can be considered a reliable diagnostic of their evolutionary state. Bright Rimmed Clouds (BRCs) are clouds that have been compressed by an external ionization-shock front which focuses the neutral gas into compact globules. The boundary layer between the neutral gas and the gas ionized by the incident photons is often called "bright rim" but the clumps are sometimes classified also as speck globules or cometary globules depending on their appearance. Small globules with bright rims have been considered to be potential sites of star formation and have been studied in several individual regions. We present results from high resolution VLA observations searching for new candidates of recent star formation in bright-rimmed clouds/globules associated with IRAS point sources.

Characterization of an Unconventional MALDI-MS Peak from DHB/pyridine Ionic Liquid Matrices

  • Hong, Jangmi;Kim, Jeongkwon
    • Mass Spectrometry Letters
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    • v.11 no.1
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    • pp.6-9
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    • 2020
  • Matrix-assisted laser desorption/ionization-mass spectrometry (MALDI-MS) analysis of ionic liquid matrices (ILMs) prepared using pyridine and dihydroxybenzoic acid (DHB), such as 2,3-DHB and 2,5-DHB, displayed an unconventional peak at m/z 232.0, which was regarded as [DHB+pyridine-H]+. The peak at m/z 232.0 was not observed from other ILMs prepared using other DHB isomers, such as 2,4-DHB, 2,6-DHB, 3,4-DHB, and 3,5-DHB. Two requirements to observe the peak at m/z 232.0 in a DHB/pyridine ILM are suggested. First, carboxyl and hydroxyl groups must be located ortho to each other. Second, the secondary hydroxyl group must be located at a carbon with a high electron density. Based on these two requirements, a potential mechanism for the generation of the peak at m/z 232.0 is suggested.

Analysis of Arginine, Glucose, Sucrose, and Polyethylene Glycols using a Wood Charcoal Matrix for MALDI-MS

  • Lee, Sun-Young;Kim, Jin-Hee;Yang, Hyo-Jik;Shin, Seong-Jae;Hong, Jang-Mi;Kim, Jeong-Kwon
    • Mass Spectrometry Letters
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    • v.1 no.1
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    • pp.33-36
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    • 2010
  • Wood charcoal was investigated to determine its potential as an alternative matrix for matrix-assisted laser desorption/ionization of various samples. Wood charcoal was an effective matrix for analyzing glucose, sucrose, arginine, and polyethylene glycols (PEGs), with detection levels of 100 pmol for glucose, 1 nmol for sucrose, 100 pmol for arginine, 100 pmol for PEG 400, 1 pmol for PEG 1540, and 10 pmol for PEG 3350. No analyte signal was observed for peptides or proteins.