• 제목/요약/키워드: Ion-Exchangers

검색결과 45건 처리시간 0.029초

Evaluation of the Nitrate Anion in Recon Extract by Adsorbents

  • Han, Young-Rim;Sung, Yang-Joo;Park, Jin-Won;Kim, Yang-Ok;Rhee, Moan-Soo
    • 한국연초학회지
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    • 제29권2호
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    • pp.104-109
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    • 2007
  • The amount of nitrate in the tobacco leaf has been shown to be correlated with the levels of alkaloids and nitrosamines. Also the nitrate content of the tobacco correlated closely with the smoke delivery of nitric oxide and tobacco-specific nitrosamines (TSNAs). These are related with the effect of the reconstituted tobacco leaf(Recon) using the tobacco stems. Adsorption process is gaining interest as one of the effective processes of advanced liquid treatment for liquid containing unnecessary materials. This study is focused on the evaluation of four anion exchangers, a cation exchanger and an activated carbon, as adsorbents for reduction of nitrate anion from Recon extract. In order to analyze the nitrate anion, the IC method used in this work was carried out with a Dionex ICS-2000 system. The effects of dosages of adsorbents and concentration of extract on the removal of nitrate anion were examined. Experimental results showed that for nitrate-anion exchanger, nitrate-cation exchanger and nitrate-activated carbon adsorption system, approximately 70 %, 10 %, and 4 % removal efficiencies were achieved at the Brix 10 and the 20 % addition. Although the activated carbon was little efficient for removal of nitrate ion, the removal of nicotine was very efficient at given conditions.

순수물질 냉매에 대한 증발엔탈피의 새로운 상관식 (A new correlation of the enthalpy of vaporization for pure refrigerants)

  • 박경근
    • 설비공학논문집
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    • 제10권4호
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    • pp.449-455
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    • 1998
  • A header' is the device that makes uniform flow distribution in all branches from header of heat exchangers, pipe burner or chemical equipments. In this study, experimental tests have been performed in order to investigate the flow distribution characteristics in a straight header and tapered header which have 6 and 11 glass pipe branches. The experimental equipment consists of a water circulation system where the fluid velocity in each glass pipe is measured by Ar-ion LDV system. From the experiments and the theoretical equation, it could be recommended that tapered header should be determined so that its internal velocities inside the header become uniform according to taper of the header and number of attached branches for uniform flow distribution in energy systems.

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INORGANIC AND BIO-MATERIALS IN THE REMOVAL/SPECIATION OF RADIOCESIUM AND RADIOSTRONTIUM : AN OVERVIEW

  • Tiwari, Diwakar;Prasad, S.K.;Yang, Jae-Kyu;Choi, Bong-Jong;Lee, Seung-Mok
    • Environmental Engineering Research
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    • 제11권2호
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    • pp.106-125
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    • 2006
  • Cesium and strontium are two important fission products and the removal/speciation of these two cations with several inorganic/bio-materials is an interesting topic to discuss. It is to be noted that inorganic materials are found to be fairly effective and efficient in the removal/speciation of these cations. Moreover, these solids are to be found promising as they show fairly good radiation and temperature stability. Hence, they play an important role in the radioactive waste management studies. However, various studies reveal that in addition to inorganic materials various biosorbents can also be employed in the removal/speciation of these ions. But the radiation and temperature stability of these bio-sorbents and dead biomasses are still the topic lying among the researchers to be investigated.

경사 분배관에 의한 다지관내의 유속분포에 대한 실험적 연구 (Experimental study on flow distribution in manifolds by a tapered header)

  • 윤영환;이상헌
    • 설비공학논문집
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    • 제10권1호
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    • pp.1-10
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    • 1998
  • A header is the device that makes uniform flow distribution in all branches from header of heat exchangers, pipe burner or chemical equipments. In this study, experimental tests have been performed in order to investigate the flow distribution characteristics in a straight header and tapered header which have 6 and 11 glass pipe branches. The experimental equipment consists of a water circulation system where the fluid velocity in each glass pipe is measured by Ar-ion LDV system. From the experiments and the theoretical equation, it could be recommended that tapered header should be determined so that its internal velocities inside the header become uniform according to taper of the header and number of attached branches for uniform flow distribution in energy systems.

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아민화 GMA-DVB 공중합체의 합성과 질소 성분에 대한 흡착 특성 (Synthesis of Aminated GMA-DVB Copolymer and Their Adsorption Properties for Nitrate)

  • 황택성;이선아;이면주
    • 폴리머
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    • 제25권3호
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    • pp.311-317
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    • 2001
  • 본 연구에서는 반응성이 큰 친수성 단량체인 glycidylmethacrylate (GMA)를 이용하여 현탁중합법으로 bead type의 GMA-DVB 공중합체를 제조하고, 이들 공중합체를 trimethyl-ammonium chloride로 아민화하여 trimethylammonium기를 갖는 거대망상형 음이온 교환수지를 합성하였다. 여기서 지하수에 공존하는 음이온 중 $NO_3^-$ 제거에 가장 방해가 되는 $SO_4^{2-}$ 이 입체적으로 크다는 것에 착안하여 가교제인 divinylbenzene (DVB)의 양을 변화시켜 가교도에 따른 음이온에 대한 선택능을 확인하였고, 각각의 수지에 대한 물성과 $NO_3^-$ 에 대한 흡착능을 고찰하였다. 또한 FT-IR을 통하여 공중합체의 합성여부를 확인하였고, 또한 아민화 수율, 이온교환 용량 및 팽윤율을 평가하여 가교도에 따른 영향을 조사하였다. 여기서 DVB의 함량이 4wt%일 때 아민화 수율은 384.3%, 이온교환용량은 3.25 meq/g, 팽윤율은 77.1%로 가장 최적으로 나타났다.

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液狀이온交換體에 依한 蒼鉛中 不純物의 分離定量 (The Separation of the Impurities in Bismuth Metal by Liquid Ion Exchangers and Colorimetric Determination)

  • 박면용;노성린
    • 대한화학회지
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    • 제12권4호
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    • pp.139-141
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    • 1968
  • 液狀이온交換體 Amberite LAI을 chloroform에 10%로 묽혀서 鹽酸算性에서 Bi(III), As(III), Sb(III), Zn(II) 및 Fe(III)의 推出率을 試驗한 結果, Zn(II)는 2M에서 98%. As(III)는 7~14M에서 Sb(III)는 2~4M에서 , Fe(III)는 6~10M에서 蒼鉛과 定量的으로 分離되었다. 그리고 chloroform을 溶媒로 썼을 때는 xylene이나 hexane을 溶媒로 썼을때보다 더 急傾斜를 이루는 推出率曲線을 나타냈다. 各各의 不純物을 分離後 Zn(II)는 dithizone. As(III)는 Gutzeit method, Sb(III)는 brilliant green, Fe(III)는 thiocyanate에 依한 比色方法으로 定量하였다.

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Prediction of the Volume of Solid Radioactive Wastes to be Generated from Korean Next Generation Reactor

  • Cheong, Jae-Hak;Lee, Kun-Jai;Maeng, Sung-Jun;Song, Myung-Jae;Park, Kyu-Wan
    • Nuclear Engineering and Technology
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    • 제29권3호
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    • pp.218-228
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    • 1997
  • Correlations between the amount of DAW (Dry Active Waste) generated from present Korean PWRs and their operating parameters were analyzed. As the result of multi-variable linear regressions, a model predicting the volume of DAW using the number of shutdowns ( $f_{FS}$ ) and total personnel exposure ( $P_{\varepsilon}$) was derived. Considering one standard error bound, the model could successfully simulate about 8575 of the real data. In order to predict the amount of DAW to be generated from a KNGR another model was derived by taking into account the additional volume reduction by supercompaction system. In addition, the volume of WAW (Wet Active Waste) to be generated from KNGR (Korean Next Generation Reactor) was calculated by considering conceptual design data and replacement effect of radwaste evaporator with selective ion exchangers. Finally, total volume of SRW (Solid Radioactive Waste) to be generated from KNGR was predicted by inserting design goal values of $f_{FS}$ and $P_{\varepsilon}$ into the model. The result showed that the expected amount of SRW to be generated from KNGR would be in the range of 33~44㎥. $y^{-1}$ . It was proved that the value would meet the operational target of KNGR proposed by KEPCO, that is, 50㎥. $y^{-1}$ .

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이온교환체로서 리그닌의 이용과 평가 (Use and Evaluation of Lignin as Ion Exchangers)

  • Ads, Essam.N.;Nada, A.M.A.;El-Masry, A.M.
    • 대한화학회지
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    • 제55권1호
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    • pp.86-91
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    • 2011
  • 수산화나트륨과 과산화 무기산을 사용하여 흑색 액체로부터 수산화 리그닌과 과산화 리그닌을 얻었다. 과산화 리그닌을 10% HCl을 사용하여 가수분해하여 가수분해 리그닌을 얻었다. 카르복실화와 인산화과정을 거쳐 카르복시 리그닌과 인산화 리그닌을 얻었다. 에피클로르히드린을 사용하여 가교 리그닌도 얻었다. 이들 얻어진 리그닌들을 적외선분광법, 열김량분석, 시차열분석법으로 분석 하였다. 이들 얻어진 리그닌의 금속이온 흡착효과를 조사하였다. 과산화 리그닌이 수산화된 리그닌 보다 흡착 능력이 우수하였다.

고자기장용 자석을 위한 밀폐순환형 냉각장치 (Closed-Loop Cooling System for High Field Mangets)

  • 최연석;김동락;이병섭;양형석
    • 한국초전도ㆍ저온공학회논문지
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    • 제8권1호
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    • pp.59-64
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    • 2006
  • A closed-loop cryogenic cooling system for high field magnets is presented. This design is motivated by our recent development of cooling system for 21 tesla Fourier Transform ion Cyclotron Resonance (FT-ICR) superconducting magnets without any replenishment of cryogen. The low temperature superconducting magnets are immersed in a subcooled 1.8 K bath, which is connected hydraulically to the 4.2 K reservoir through a narrow channel. Saturated liquid helium is cooled by Joule-Thomson heat exchanger and flows through the JT valve, isenthalpically dropping its pressure to approximately 1 6 kPa, corresponding saturation temperature of 1.8 K. Helium gas exhausted from pump is now recondensed by two-stage cryocooler located after vapor purify system. The amount of cryogenic Heat loads and required mass flow rate through closed-loop are estimated by a relevant heat transfer analysis, from which dimensions of JT heat exchanger and He II heat exchanger are determined. The detailed design of cryocooler heat exchanger for helium recondensing is performed. The effect of cryogenic loads, especially superfluid heat leak through the gap of weight load relief valve, on the dimensions of cryogenic system is also investigated.

설비공학 분야의 최근 연구 동향: 2014년 학회지 논문에 대한 종합적 고찰 (Recent Progress in Air-Conditioning and Refrigeration Research: A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2014)

  • 이대영;김사량;김현정;김동선;박준석;임병찬
    • 설비공학논문집
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    • 제27권7호
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    • pp.380-394
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    • 2015
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2014. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering have been reviewed as groups of heat and mass transfer, cooling and heating, and air-conditioning, the flow inside building rooms, and smoke control on fire. Research issues dealing with duct and pipe were reduced, but flows inside building rooms, and smoke controls were newly added in thermal and fluid engineering research area. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the results for thermal contact resistance measurement of metal interface, a fan coil with an oval-type heat exchanger, fouling characteristics of plate heat exchangers, effect of rib pitch in a two wall divergent channel, semi-empirical analysis in vertical mesoscale tubes, an integrated drying machine, microscale surface wrinkles, brazed plate heat exchangers, numerical analysis in printed circuit heat exchanger. In the area of pool boiling and condensing, non-uniform air flow, PCM applied thermal storage wall system, a new wavy cylindrical shape capsule, and HFC32/HFC152a mixtures on enhanced tubes, were actively studied. In the area of industrial heat exchangers, researches on solar water storage tank, effective design on the inserting part of refrigerator door gasket, impact of different boundary conditions in generating g-function, various construction of SCW type ground heat exchanger and a heat pump for closed cooling water heat recovery were performed. (3) In the field of refrigeration, various studies were carried out in the categories of refrigeration cycle, alternative refrigeration and modelling and controls including energy recoveries from industrial boilers and vehicles, improvement of dehumidification systems, novel defrost systems, fault diagnosis and optimum controls for heat pump systems. It is particularly notable that a substantial number of studies were dedicated for the development of air-conditioning and power recovery systems for electric vehicles in this year. (4) In building mechanical system research fields, seventeen studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, and renewable energies, piping in the buildings. Proposed designs, performance performance tests using numerical methods and experiments provide useful information and key data which can improve the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the evaluation of work noise in tunnel construction and the simulation and development of a light-shelf system. The subjects of building energy were worked on the energy saving of office building applied with window blind and phase change material(PCM), a method of existing building energy simulation using energy audit data, the estimation of thermal consumption unit of apartment building and its case studies, dynamic window performance, a writing method of energy consumption report and energy estimation of apartment building using district heating system. The remained studies were related to the improvement of architectural engineering education system for plant engineering industry, estimating cooling and heating degree days for variable base temperature, a prediction method of underground temperature, the comfort control algorithm of car air conditioner, the smoke control performance evaluation of high-rise building, evaluation of thermal energy systems of bio safety laboratory and a development of measuring device of solar heat gain coefficient of fenestration system.