• Title/Summary/Keyword: Ion-Exchange

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Applicability Evaluation of the Wastewater Treatment System Using Magnetic Ion Exchange Resin in the Existing Wastewater Treatment Plant (기존하수처리장에서 자성체 이온교환수지를 이용한 하수처리공정 적용가능성 평가)

  • Park, Chan G.;Kim, Hee S.;Lee, Jung M.
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.2
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    • pp.35-40
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    • 2014
  • The optimal removal efficiency to develop wastewater treatment system using the magnetic ion exchange resin. The secondary sedimentation effluent of wastewater in W wastewater treatment plant located in Gyeong-gi Province was used as the influent. To compare the sedimentation effluent reacted with the magnetic ion exchange resin to the influent, the concentrations of CODmm, TN, $NO{_3}^-$-N and TP were measured. The flux of the influent and HRT were set to 250 mL/min, 10 min, respectively, and BVTR has adjusted to 200, 150, 100. The removal efficiency of CODmn, TN, $NO{_3}^-$-N and TP in the 200 BVTR from 71%, 40.37%, 46.34%, 42.03%, 150 BVTR from 55.22%, 37.83%, 50.38% 41.6% and 100 BVTR from 74%, 59.15%, 79.94%, 79.16%, respectively. The results on 200 BVTR, 150 BVTR, 100 BVTR tests show that 100 BVTR is the optimal factor capable of the highest rate of rejection of the organic material.

Ion Exchange of Gold(III) from Ammonium Chloride Solution by Anionic Resins (염화암모늄용액에서 음이온 교환수지에 의한 금(III)의 이온교환)

  • Ahn, Hyeong Hun;Lee, Man Seung
    • Resources Recycling
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    • v.27 no.2
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    • pp.48-54
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    • 2018
  • Batch ion exchange experiments of Au(III) were performed from ammonium chloride solution by employing strong anionic exchange resins (Amberlite IRA 402 and AG 1-X8). Au(III) was well loaded into the two resins and the loading behavior of Au(III) into AG 1-X8 was superior to that into Amberlite IRA 402. The loading of Au(III) into AG 1-X8 followed Langmuir adsorption isotherm and the experimentally determined loading capacity was 355 mg/g. Au(III) was successfully eluted by $HClO_4$ from the loaded AG 1-X8 and the elution percentage of Au(III) increased with the concentration of $HClO_4$.

Study on Commercially Available Anion Exchange Membrane for Alkaline Water Eectrolysis (알칼리 수전해를 위한 상용 음이온교환막에 관한 연구)

  • Park, Joo-Wang;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.31 no.4
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    • pp.275-281
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    • 2021
  • To evaluate the possibility as a separator in alkaline water electrolysis, the thermal stability, ion conductivity and durability of 5 commercially available anion exchange membranes were tested. The thermal stability of FAAM-PK-75 and FAAM-40 membrane analyzed by thermo-gravimetric analysis (TGA) showed good performance compared to the other three types of AEM, AHO, and AHA membrane. The ion conductivity of AEM membrane measured in 7 M KOH solution at 25℃ and 80℃ had a higher value of about 4~17 times compared to the other membranes. The durability of FAAM-PK-75 tested in 7 M KOH solution at 25℃ was high compared to the other membranes.

Effects of Extraction Method on Anserine, Protein, and Iron Contents of Salmon (Oncorhynchus keta) Extracts (연어(Oncorhynchus keta) 추출물 중의 Anserine, 단백질 및 철분 함량에 미치는 추출방법의 영향)

  • Min, Hye-Ok;Park, In-Myoung;Song, Ho-Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.2
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    • pp.220-228
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    • 2017
  • Effects of extraction methods on reducing concentrations of pro-oxidants (total iron and protein) of salmon was determined. For development of the extraction process, the effectiveness of several extraction methods was determined and compared, including heat treatment (60, 80, and $100^{\circ}C$), ion exchange and carboxymethyl (CM)-cellulose column chromatography, and ultrafiltration (UF). Protein, total iron, and anserine contents of salmon extracts were 23.64 mg/mL, $16.20{\mu}g/mL$, and 5.47 mg/mL in non-heated extracts, 7.40 mg/mL, $2.32{\mu}g/mL$, and 5.20 mg/mL in heated extracts at $60^{\circ}C$, 7.64 mg/mL, $1.20{\mu}g/mL$, and 5.21 mg/mL at $80^{\circ}C$, and 7.04 mg/mL, $0.68{\mu}g/mL$, and 4.04 mg/mL at $100^{\circ}C$, respectively. Heating and UF decreased contents of protein and total iron, whereas only UF slightly decreased anserine content. Application of the primary ion exchange method increased the content of anserine up to 16%. Protein and total iron contents by the primary ion exchange method decreased by 70 and 98%, respectively. Secondary ion exchange (CM-cellulose) treatment after primary ion exchange and UF resulted in lower anserine content than the primary ion exchange method. However, the content of impurities (protein, total iron) was lower than in all other salmon extracts. Therefore, primary ion exchange, UF, and secondary ion exchange method were the best extraction processes in this study.

Identification of Proteins in Egg White Using Ion Exchange Cartridge and RP-HPLC (이온교환 카트리지와 RP-HPLC를 이용한 난백 단백질의 확인)

  • Kim, Hyun Moon;Kim, Ah Reum;Lee, Chang Soo;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.713-717
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    • 2012
  • Approximately forty proteins in egg white have been widely studied for their functional properties. To develop a procedure of separation for pure and non-altered proteins from egg white, purification study was conducted to isolate lysozyme, ovotransferrin, and ovalbumin. Ion exchange cartridge can selectively separate proteins from egg white, and reversed-phase HPLC (RP-HPLC) could identify separated proteins. Proteins in egg white were purified by HI trap ion exchange cartridge SP and Q with buffers pH 8.0 and 5.2. C18 column (Phenomenex, USA) was used for RP-HPLC analysis and isocratic mobile phase was used with acetonitrile (ACN)/distilled water (DW)/trifluoroacetic acid (TFA) in the ratio of 50/50/0.1. Comparing the retention times of standards in RP-HPLC experiments showed that ovotransferrin, ovalbumin, and lysozyme in egg white were eluted successively in the RP-HPLC column after the pretreatment in SP and Q ion exchange cartridges.

A study on the separation and determination of the rare earth Elements by the AG® 50W-X8 cation exchange resin (AG® 50W-X8 양이온교환수지를 이용한 희토류원소의 분리와 분석에 관한 연구)

  • Lee, Jung Sook;Choi, Beom Suk
    • Analytical Science and Technology
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    • v.21 no.4
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    • pp.272-278
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    • 2008
  • Methods to separate 14 rare earth elements (REEs) and yttrium by the $AG^{(R)}$ 50W-X8 cation exchange resin, and to determine REEs by inductively coupled plasma atomic emission spectrophotometry (ICP-AES) were described. Ion exchange capacities of REEs on the resin were so high that the REEs were quantitatively ion exchanged under the flow rate of 0.3~1.0 mL/min at pH 1~6. The breakthrough capacity curve of the REEs showed that ion exchange capacities of light REEs (Cerium group) were greater than that of the heavy REEs (Yttrium group). When $200{\mu}g$ of each REEs was ion exchanged on 100 mg of resin, most of the heavy REEs were quantitatively desorbed with 10 mL of 2.0 M of $HNO_3$, while most of the light REEs with 30 mL. The method was applied to the monazite sample. The REEs could be separated from matrix, since ion exchange capacities of matrix ions of Ca, Ti, Mg, Mn were much lower than that of the REEs. However the relative standard deviations of the analytical results by the present method were not improved, as high as 1~5%.

The Phosphorus Removal from Water by Zirconium Mesoporous Structure (지르코늄 메조기공 구조체를 이용한 수중의 인 제거)

  • Lee, Byoung-cheun;Lee, Kwan-yong;Lee, Sang-hyup;Choi, Yong-su;Park, Ki-young
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.4
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    • pp.455-461
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    • 2005
  • This study was designed to investigate the fundamental aspects of a possible recovery of phosphorus strategy from wastewater by using the zirconium mesoporous structured materials as a new type of ion exchangers. Zirconium mesoporous structure material was synthesized by hydro-thermal synthesis. The synthesized zirconium mesoporous structure was examined by X-ray diffraction (XRD) and Transmission electron micrograph (TEM). From the results of XRD and TEM, it was found out that hexagonal mesoporous structure, pore size was about $47{\AA}$, was synthesized. Experimental results showed that the complex of zirconium sulfate tetrahydrate and surfactant micelles had very high ability for capture of phosphorus. The amount of phosphate ions exchanged into the solid was as great as 3.4mmol/g-ZS. And the ion exchange reaction was occurred between $PO_4{^{3-}}$ and $SO_4{^{2-}}$ and also between $PO_4{^{3-}}$ and $OH^-$. Therefore, it is possible to get the higher removal efficiency than other ion exchange media and adsorbent.

A Study on Electric Potential Change by Pulse Voltage Polarity in Liquid (펄스전압의 극성에 따른 액중 전위변화에 관한 연구)

  • Kim Jin-Gyu;Kim Hyung-Pyo;Park Young-Ho
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.4
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    • pp.79-84
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    • 2005
  • This paper proposes the new type of an ion exchange water generator system. The system has an +/- ion exchange membrane located in center and a diagonal-interdigit type electrode applied to a pulsed power. This system is studied in the liquid for the oxidation/reduction potential and the dissolved oxygen concentration by the polarity effects. Consequently, as a diagonal-interdigit type electrode is installed in each side of device, the oxidation/reduction potential and dissolved oxygen concentration by polarity changes and electrical resistivity differences be observed. An ion concentration in the ion exchange water generator system is increased by dissolved oxygen generated from oxidation/reduction potential changes.

An Approach for Reducing Carbon-14 Stack Emissions via Optimal Use of Ion Exchang Resins at CANDU Plant

  • Sohn, Wook;Chi, Jun-Ha;Kang, Duk-Won
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2003.05a
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    • pp.445-455
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    • 2003
  • Relatively high carbon-14 emissions, which occurred at PHWR Plant during 1998 and 1999, made the site staff to implement several operational improvements: 1) the frequency and volume of the moderator cover gas purging were reduced through increased $O_2$ additions to the cover gas, 2) the 'old' resin columns were not used during re-start of the reactor from outage, 3) efforts were made to minimize air ingress, 4) the maximum service time of moderator ion-exchange columns were restricted to about 80 days. Through the improvements, the carbon-14 emission from each PHWR reactor returned to the normal levels during the remainder of 1999 and during 2000. We carried out a special surveillance at W-1 and W-3 from September 2001 to August 2002 to properly evaluate ways to optimize the use of moderator ion exchange resins from a C-14 perspective. The surveillance showed that only data that provided an operational marker for deciding when to remove the IX-resin column is an observed increase in the C-14 stack emissions themselves. Also, it is shown that any increase over the rate of 0.4 Ci $month^{-1}$ for two consecutive weeks may be the indication for an ion-exchange resin column change, especially if the IX-resin column has been in service for more than 80 days.

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Characteristics of Cation Selectivity for Equilibrium and Column Cation Exchanges (평형 및 칼럼교환에서 양이온 선택도 특성)

  • 이석중;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.2
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    • pp.156-159
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    • 2002
  • Ion exchange is the most reliable process to remove the ionic impurities and the economic operation. ion exchange is widely used in water and wastewater treatment, especially softening and demineralization. ion selectivity depends on the hydrated radius, charge of ions and concentration. The objective of this study was to determine the selectivity order of cations with equilibrium and column ion exchanges and to investigate the effect of the background anion on selectivity. Cation selectivity increases with decreasing concentration and increasing charge ( $H^+$ < $K^+$ << $Cu^{2+}$ < $Co^{2+}$ < TEX>$Ca^{2+}$ << $Ce^{3+}$)in equilibrium and column cation adsorptions.

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