• Title/Summary/Keyword: Ion storage

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Design and Dynamic Performance Analysis of a Stand-alone Microgrid - A Case Study of Gasa Island, South Korea

  • Husein, Munir;Hau, Vu Ba;Chung, Il-Yop;Chae, Woo-Kyu;Lee, Hak-Ju
    • Journal of Electrical Engineering and Technology
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    • v.12 no.5
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    • pp.1777-1788
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    • 2017
  • This paper presents the design and dynamic analysis of a stand-alone microgrid with high penetration of renewable energy. The optimal sizing of various components in the microgrid is obtained considering two objectives: minimization of levelized cost of energy (LCOE) and maximization of renewable energy penetration. Integrating high renewable energy in stand-alone microgrid requires special considerations to assure stable dynamic performance, we therefore develop voltage and frequency control method by coordinating Battery Energy Storage System (BESS) and diesel generators. This approach was applied to the design and development of Gasa Island microgrid in South Korea. The microgrid consists of photovoltaic panels, wind turbines, lithium-ion batteries and diesel generators. The dynamic performance of the microgrid during different load and weather variations is verified by simulation studies. Results from the real microgrid were then presented and discussed. Our approach to the design and control of microgrid will offer some lessons in future microgrid design.

Enhancement of Calcium-Binding Quality of Proglycinin Peptides by Chemical Phosphorylation

  • Yang, Jung-Ik;Lee, Shin-Hee;Hahm, Dae-Hyun;Kim, Il-Hwan;Choi, Sang-Yun
    • Journal of Microbiology and Biotechnology
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    • v.14 no.3
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    • pp.607-611
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    • 2004
  • Glycinin, one of the predominant storage proteins in soybeans, was examined as to whether it could be used as a calcium-binding mediator after chemical phosphorylation and enzymatic hydrolysis. Glycinin is composed of six subunits. One of the proglycinin subunits $(A_{la}B_{lb})$ was overexpressed in E. coli to obtain nonphosphorylated proteins with homogeneity. To investigate the enhanced calcium-binding properties of the phosphopeptides, the proglycinin was purified, phosphorylated, and hydrolyzed with trypsin. The proglycinin expressed in E. coli was purified by ammonium sulfate precipitation, ion-exchange chromatography, and cryoprecipitation. Chemical phosphorylation by sodium trimetaphosphate was performed to obtain phosphorylated proglycinin. After the phosphorylation, one-dimensional isoelectric focusing gel electroanalysis confirmed the phosphorylation of the proglycinin. The phosphorylated peptides were then hydrolyzed with trypsin, followed by a binding reaction with calcium chloride. The calcium-bound phosphopeptides were finally separated using immobilized metal $(Ca^{2+})$ chromatography. Consequently, a limited tryptic hydrolysate of the isolated phosphopeptides exhibited an enhanced calcium-binding ability, suggesting the potential of glycinin phosphopeptides as a calcium-binding mediator with greater availability.

Kernel Pattern Recognition using K-means Clustering Method (K-평균 군집방법을 이요한 가중커널분류기)

  • 백장선;심정욱
    • The Korean Journal of Applied Statistics
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    • v.13 no.2
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    • pp.447-455
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    • 2000
  • We propose a weighted kernel pattern recognition method using the K -means clustering algorithm to reduce computation and storage required for the full kernel classifier. This technique finds a set of reference vectors and weights which are used to approximate the kernel classifier. Since the hierarchical clustering method implemented in the 'Weighted Parzen Window (WP\V) classifier is not able to rearrange the proper clusters, we adopt the K -means algorithm to find reference vectors and weights from the more properly rearranged clusters \Ve find that the proposed method outperforms the \VP\V method for the repre~entativeness of the reference vectors and the data reduction.

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Fully Room Temperature fabricated $TaO_x$ Thin Film for Non-volatile Memory

  • Choi, Sun-Young;Kim, Sang-Sig;Lee, Jeon-Kook
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.28.2-28.2
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    • 2011
  • Resistance random access memory (ReRAM) is a promising candidate for next-generation nonvolatile memory because of its advantageous qualities such as simple structure, superior scalability, fast switching speed, low-power operation, and nondestructive readout. We investigated the resistive switching behavior of tantalum oxide that has been widely used in dynamic random access memories (DRAM) in the present semiconductor industry. As a result, it possesses full compatibility with the entrenched complementary metal-oxide-semiconductor processes. According to previous studies, TiN is a good oxygen reservoir. The TiN top electrode possesses the specific properties to control and modulate oxygen ion reproductively, which results in excellent resistive switching characteristics. This study presents fully room temperature fabricated the TiN/$TaO_x$/Pt devices and their electrical properties for nonvolatile memory application. In addition, we investigated the TiN electrode dependence of the electrical properties in $TaO_x$ memory devices. The devices exhibited a low operation voltage of 0.6 V as well as good endurance up to $10^5$ cycles. Moreover, the benefits of high devise yield multilevel storage possibility make them promising in the next generation nonvolatile memory applications.

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Simulation of Open-Loop Borehole Heat Exchanger System using Sand Tank Experiment and Numerical Model (토조 및 수치모형을 이용한 개방형 지중 열교환 시스템 모의)

  • Lee, Seong-Sun;Bae, Gwang-Ok;Lee, Kang-Kun
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.489-492
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    • 2007
  • Understanding the thermohydraulic processes in the aquifer is necessary for a proper design of the aquifer thermal energy utilization system under given conditions. Experimental and numerical test were accomplished to evaluate the relationship between the geothermal heat exchanger operation and hydrogeological conditions in the open-loop geothermal system. Sand tank experiments were designed to investigate the open-loop geothermal system. Water injection and extract ion system as open-loop borehole heat exchanger was applied to observe the temperature changes in time at injection well, extraction well and ambient groundwater. The thermohydraulic transfer for heat storage was simulated using FEFLOW for two cases of extraction and injection phase operation in sand tank model. As one case, the movement of the thermal plume was simulated with variable locations of injection and extraction well. As another case, the simulation was performed with fixed location of injection and extraction well. The simulation and experimental results showed that the temperature distribution depends highly on the injected water temperature and the length of injection time and the groundwater flow and pumping rate sensitively affect the heat transfer.

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Application of Generalized Transmission Line Models to Mixed Ionic-Electronic Transport Phenomena

  • Ahn, Pyung-An;Shin, Eui-Chol;Kim, Gye-Rok;Lee, Jong-Sook
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.549-558
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    • 2011
  • Application of a generalized equivalent circuit including the electrode condition for the Hebb-Wagner polarization in the frequency domain proposed by Jamnik and Maier can provide a consistent set of material parameters, such as the geometric capacitance, partial conductivities, chemical capacitance or diffusivity, as well as electrode characteristics. Generalization of the shunt capacitors for the chemical capacitance by the constant phase elements (CPEs) was applied to a model mixed conducting system, $Ag_2S$, with electron-blocking AgI electrodes and ion-blocking Pt electrodes. While little difference resulted for the electron-blocking cell with almost ideal Warburg behavior, severely non-ideal behavior in the case of Pt electrodes not only necessitates a generalized transmission line model with shunt CPEs but also requires modelling of the leakage in the cell approximately proportional to the cell conductance, which then leads to partial conductivity values consistent with the electron-blocking case. Chemical capacitance was found to be closer to the true material property in the electron-blocking cell while excessively high chemical capacitance without expected silver activity dependence resulted in the electron-blocking cell. A chemical storage effect at internal boundaries is suggested to explain the anomalies in the respective blocking configurations.

Hydration Characteristics of Coal-Fly Ash Containing High CaO Compound (CaO 화합물이 다량 함유된 비산재의 수화 특성에 관한 연구)

  • Sim, Jun-Soo;Lee, Ki-Gang;Kim, Yu-Taek;Kang, Seung-Ku
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.185-190
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    • 2012
  • The purpose of this study was to examine a possibility that fly ash could be used as raw material for carbonation by conducting the experiment on magnetic separation and hydration of fly ash that contained a large amount of CaO composite. Wet magnetic separation experiment was performed to remove the component of magnetic substance that contained fly ash, which aimed at increasing the content of CaO in the non-magnetic domain. The selected fly ash was used for hydration experiment before the TG-DTA, XRF and XRD analyses were made to confirm the Ca component that could be carbonated. Then, the fly ash was turned to a hydrate that was favorable to dissociation of $Ca^{2+}$ ion. As a result, the magnetic separation enabled detecting the content of CaO component by up to 61 wt% in the non-magnetic domain. Since the hydrate was confirmed, it is believed that the fly ash can be used as raw material for carbonation.

Carbon nanoballs: formation mechanism and electrochemical performance as an electrode material for the air cathode of a Li-air battery

  • Kang, Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.8
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    • pp.838-842
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    • 2015
  • The Li-air battery is a promising candidate for the most energy-dense electrochemical power source because it has 5 to 10 times greater energy storage capacity than that of Li-ion batteries. However, the Li-air cell performance falls short of the theoretical estimate, primarily because the discharge terminates well before the pore volume of the air electrode is completely filled with lithium oxides. Therefore, the structure of carbon used in the air electrode is a critical factor that affects the performance of Li-air batteries. In a previous study, we reported a new class of carbon nanomaterial, named carbon nanoballs (CNBs), consisting of highly mesoporous spheres. Structural characterization revealed that the synthesized CNBs have excellent a meso-macro hierarchical pore structure, with an average diameter greater than 10 nm and a total pore volume more than $1.00cm^3g^{-1}$. In this study, CNBs are applied in an actual Li-air battery to evaluate the electrochemical performance. The formation mechanism and electrochemical performance of the CNBs are discussed in detail.

Magnetic and Electric Properties of Multiferroic Ni-doped BiFeO3

  • Yu, Yeong-Jun;Hwang, Ji-Seop;Park, Jeong-Su;Lee, Ju-Yeol;Gang, Ji-Hun;Kim, Gi-Won;Lee, Gwang-Hun;Lee, Bo-Hwa;Lee, Yeong-Baek
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.182-182
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    • 2014
  • Multiferroic materials have attracted much attention due to their own fascinating fundamental physical properties and potential technological applications to magnetic/ferroelectric data storage systems, quantum electromagnets, spintronics, and sensor devices. Among single-phase multiferroic materials, $BiFeO_3$, in particular, has received considerable attention because the enhanced ferromagnetism was found by the Fe-site ion substitution with magnetic ions. The structural, the magnetic and the ferroelectric properties of polycrystalline $BiFe_{1-x}Ni_xO_3$ (x=0, 0.01, 0.02, 0.03 and 0.05), which were prepared by the solid-state reaction and the rapid-sintering method, have been investigated. The x-ray diffraction patterns reveal that all the samples are in single phase and show rhombohedral structure with R3c space group. The magnetic properties are enhanced according to the doping content. The Ni-doped $BiFeO_3$ samples exhibit lossy P-E loop due to the oxygen vacancy. The leakage current density of Ni-doped samples (x=0.01 and 0.02) is increased by four orders of magnitude. On the other hand, the x=0.03 and 0.05 samples show the relative reduction of the leakage current.

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Milk-clotting Enzyme from Microorganisms, Part 10, Studies on General Properties and storage of Mucor-rennin (Milk-clotting Enzyme) isolated from Mucor pusillus var. Lindt (미생물(微生物)이 생산(生産)하는 응유효소(凝乳酵素) (제10보(第10報)) -Mucor-pusillus의 고체배양(固體培養)으로부터 단리(單離)된 결정(結晶) 응유효소(凝乳酵素) Mucor-rennin의 일반적(一般的) 성질(性質)과 그의 저장성(貯藏性)-)

  • Yu, Ju-Hyun;Tamura, Gakuzo;Hong, Yun-Myung;Arima, Kei
    • Applied Biological Chemistry
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    • v.12
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    • pp.7-11
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    • 1969
  • Mucor-rennin, the crystalline milk-clotting enzyme, isolated from Mucor pusillus var. Lindt, has an acid protease activity. The optimum pH for the digestion of k-casein is 4.5, while that for hemoglobin digestion is 4.0. The skim milk solution was easily clotted acidic solution than alkalin solution, and the milk clotting activated by Ca ion. The enzyme was heat stable against heat from pH 4.0 to 6.0 but was more stable at pH 5.0. The activity of the enzyme at pH 5.0 did not decrease at 30 C for 15 days and the activity was not effected by sodium propionate and salicilic acid. Therefore, the enzyme of liguid type could store for a long time and could be transported from Erzyme production Co. to Manufacture of cheese Co. by adding the antiesptic and by adjusting pH to 5.0.

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