• Title/Summary/Keyword: Ion effect

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A Study on the Chloride Ion Diffusion Coefficient of Concrete by Submergence in Salt Water (침적시험에 의한 콘크리트의 염소이온 확산계수 평가)

  • 김동석;양승규;정연식;유재상;이종열;본간건일
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.297-300
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    • 2003
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon. In this study, It is evaluated the diffusion coefficient of chloride ion in non-steady state by Fick's second law. Submergence method in salt water carried out in this experiment. Two types of cement which is different in mineral composition were used. In addition, the effect of mineral admixtures of blast-furnace slag and meta-kaolin was studied. In conclusion, the diffusion coefficient of chloride ion is much affected according to cement type and mineral admixtures, also, it is proved that meta-kaolin as well as blast-furnace slag is effective in preventing penetration of chloride ion.

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Improvement of reliability of an ISFET pH-meter by employing multiple sensors

  • Chang, Kee-Seok;Cho, Byung-Woog;Kim, Chang-Soo;Choi, Sang-Bok;Sohn, Byung-Ki
    • Journal of Sensor Science and Technology
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    • v.6 no.2
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    • pp.131-136
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    • 1997
  • The ISFET(ion sensitive field effect transistor), a semiconductor ion sensor, has many advantages over conventional ion sensors. Various single-sensor type ISFET pH-meters have been developed. However, they could not be applied in fields because their performances are directly affected by the sensor condition. With only one sensor, the system could be easily damaged from environmental factors, and reliability of it is decreased. Therefore, a 4-channel PH-meter system is proposed to improve the reliability of ISFET pH-meter. It has 4 ISFETS as ion sensor, and a software which contains a new calibration and measurement algorithm appropriate to the system. The reliability of the system was proved by measuring hydrogen ion concentration in the pH standard solutions and buffer solutions.

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Fatigue Strength Characteristics of 1Cr-1Mo-0.25V Steel by Improved TiN Coated Processes (TiN코팅 공정 개선에 의한 1Cr-1Mo-0.25V 강재의 피로강도 특성)

  • 서창민;김경렬
    • Journal of Ocean Engineering and Technology
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    • v.11 no.4
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    • pp.49-60
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    • 1997
  • This paper deals with the effect of coating layer on the fatigue strength of TiN coated 1Cr-1Mo-0.25V steel prepared by using the arc ion plating (AIP) process, in which it was characterized by the presence of extractor grid (ion filter). The rotary bending fatigue tests were carried out under room air conditions, and the fatigue crack initiation and growth bwhavior were observed by using plastic replica method. As experimental results, it was found that the obvious improvement of fatigue life at lower stress region was confirmed in TiN coated specimen processed with ion filter. It was also exlained that the increase of fatigue life in the case of an improved AIP process with ion filter was attributed to the retardation of crack initiation of the substrate surface due to hard coating layer, more densly formed with the reduced size and density of droplets.

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A Study on the Adsorption of Hg(II) Ion by Activated Carbon(1) (活性炭에 依한 Hg(II) 이온의 吸着에 관한 조사연구(1))

  • Lee, Hyun;Lee, Jong-Hang;Yun, O. Sub
    • Journal of Environmental Health Sciences
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    • v.14 no.2
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    • pp.65-71
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    • 1988
  • In this study, the method of adsorption by activated carbon in the removal of Hg(II) ion in waste water was treated. The influence of kinds of activated carbon and effect of temperature and the influence of coexistent salt on adsorption rates, the influence of pH in the adsorption, equilibrium and adsorption of mercury from activated carbon were investigated. From the adsorption on activated carbon of mercury(II) ion in the presence of cyanide or thiocyanate ion was found that mercury(II) was easily adsorved onto the activated carbon in the form of complex artion such as Hg(CN)$_4^{2-}$, Hg(SCN)$_4^{2-}$ respectively. ZnCl$_2$ activation method had a higher adsorptive ability than steam activation method in adsorption of Hg on activated carbon. Activated carbon adsorbed iodide ion is very effective on adsorption of Hg.

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Development of Chloride-ion Penetration Device for Concrete Considering Pressure Condition (압력조건을 고려한 콘크리트의 염화물이온 침투 장치 개발)

  • Kim, Gyeong-Tae;Kim, Gyu-Yong;Lee, Sang-Kyu;Hwang, Eui-Chul;Son, Min Jae;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.25-26
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    • 2018
  • In this study, the device was developed for evaluating the effect of pressure on chloride ion penetration of concrete. And chloride-ion penetration depth and water soluble chloride contents was evaluated concrete using ordinary portland cement and blast-furnace slag cement using developed device. As a result, chloride ion penetration of concrete was promoted according to the action of pressure and the exposure period. and the incorporation of blast-furnace slag was effective for chloride attack resistibility under pressure.

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Improvement of Mechanical Property by Single Ion Exchange Process in Substrate Glass

  • Lee, Hoi-Kwan;Kang, Won-Ho;Green, David J.
    • Journal of Information Display
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    • v.4 no.3
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    • pp.12-16
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    • 2003
  • In connection with the ion exchange strengthening on soda-lime-silicate, substrate glass for display use was investigated. In the processing, the temperature was varied during the ion exchange in order to make stress profile and to determine optimum condition. In the present work, we found that the maximum value of strength was 617.8 MPa after an ion exchange process at 470 $^{\circ}C$ for 1h, and then, at 450 $^{\circ}C$ for 24h. Also, the effect of residual stress placed on the near surface was measured by analyzing the number of crack branches and brittleness. This approach allowed us the residual stress profile to be engineered to improve mechanical reliability.

A calculation on the Metal-Film Mixing by Intense Pulse Ion Beam (IPIB)

  • Le, X.Y.;Yan, S.;Zhao, W.J.;Wang, Y.G.;Xue, J.M.
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.74-78
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    • 2003
  • In this paper, we studied, by numerical calculation, a system, which was composed of metal-film and metal-substrate irradiated by IPIB with beam ion energy 250 keV, current density 10 to 250 A/$\textrm{cm}^2$. While the IPIB irradiation was going on, an induced effect named mixing occurred. In this case, metal-film and part of metal-substrate melted and mixed. The mixing state was kept as it was in melting phase due to the fast cooling rate. Our works were simulating the heating and cooling process via our STEIPIB program and tried to find proper parameters for a specific film-substrate system, 500 nmtitanium film coated on aluminum, to get best mixing results. The parameters calculated for such Ti-Al system were compared with the experimental results and were in good accordance to the experimental results.

Ion Shower Doping Effect in Diamond and Diamond-Like Carbon Films

  • Jin Jang;Chun, Soo-Chul;Park, Kyu-Chang;Kim, Jea-Gak;Moon, Jong-Hyun;Park, Jong-Hyun;Song, Kyo-Jun;Lee, Seung-Min;Oh, Myung-Hwan
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.34-39
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    • 1995
  • we have studied the possibility of n-type doping in diamond and DLC films. After ion doping of either p-type or n-type, the electrical conductivities were remarkably increased and conductivity activation energies were decreased. The Raman intensity at 1330 cm-1 decreases slightly by ion doping of $7.2\times 10^{16}\; \textrm{cm}^{-2}$. The increase in conductivity by ion doping appears to be arised from the combined effects by substitutional doping and graphitization by ion damage.

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The Effect of Temperature on the Stable Region of Magnesium Ion in Aqueous System (수중 마그네슘이온의 안정영역 변화에 대한 온도효과)

  • Kim, Hee-Jin;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.438-444
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    • 2011
  • Magnesium is one of the abundant natural resources in the earth crust and seawater, which is directly related to various organisms activities interconnecting with water-rock system. In aqueous system, magnesium is known to predominantly exist in the form of $Mg^{2+}$ ion which is verified in its $E_h-pH$ diagram. When it is at equilibrium in aqueous system, temperature takes an essential role to complete equilibrium states. This study represents the change of the stable region of magnesium ion according to temperature, and how the consequences would affect aquatic organisms. It was revealed that there is a noticeable tendency shrinking the stable region of magnesium ion in a diagram as temperature increases, and as a result, aquatic bio-species presumably have difficulties to absorb the nutrient. Also, it was considered that the water system would be acidified by decreasing alkalinity.

Effect of Chloride Ion-reducing Bacteria on the Chloride ion Concentration in Cement Mortars (염소이온 저감능 박테리아가 모르타르의 염소이온 농도에 미치는 영향)

  • Hwang, Ji-Won;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.49-50
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    • 2022
  • This study examined the potential of halophilic bacteria in reducing the chloride ion concentration within the cement mortars exposed to chloride attack. As a result of the experiment, the compressive strength of mortar with Halomonas venusta showed an equivalent performance to that of counterpart mortars without bacteria. Also, the chloride ion concentration measured in mortars including Halomonas Venusta was 71% lower than that of the counterpart mortars without bacteria.

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