• Title/Summary/Keyword: Ion concentration

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Preparation of Cation-exchange Resin from Lignin

  • Kamelt S.
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.5 s.108
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    • pp.78-84
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    • 2004
  • Lignin precipitated from black liquor of soda pulping of bagasse was used to prepare cation-exchange resin. The effect of sulfuric acid treatment, concentration of phenol and formaldehyde on the properties of the prepared cation-exchange resin was investigated. It was found that sulfonated resinified phenolated lignin gave a resin with an ion-exchange capacity higher than that of resin, which resulted from sulfonation of resinified lignin at zero phenol concentration. Infrared spectroscopy of the prepared ion-exchange resin shows anew bands at 1060, 1160, 1280 and $1330\;cm^{-1}$ which indicated to the presence of $SO_{3}$.

The Effect of N2 Molecules on Kinetics of Pulsed $CO_2$ Laser (펄스 $CO_2$ 레이저의 Kinetics에서 질소분자의 영향)

  • Cho, Soon-Cheon;Lee, Choo-Hee
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.412-414
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    • 1987
  • Theoretical studies of concentration for negative ion and neutral species in electrical excitation discharge have been conducted at $CO_2-N_2-He=1-7-12$, total pressure 20torr. With a computer model of neutral and negative ion processes we have calculated that the concentration of co was less than 20% when expected molecular.

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An analysis of the ion penetration phenomena in amorphous $Se_{75}Ge_{25}$ thin film (비정질 $Se_{75}Ge_{25}$박막으로의 이온침투 현상 해석)

  • 이현용;정홍배
    • Electrical & Electronic Materials
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    • v.7 no.5
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    • pp.389-396
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    • 1994
  • The bilayer film of Ag/a-S $e_{75.G}$ $e_{25}$ and the monolayer film of a-S $e_{75.G}$ $e_{25}$ act as a negative-type and a positive-type resist in focused ion beam lithography, respectively. Using a model which takes into account the ion stopping power, the ion projected range, the ion concentration implanted into resists and the ion transmission coefficient, etc., the ion resist parameters are calculated for a broad range of ion energies and implanted doses. Ion sources of A $r^{+}$, S $i^{++}$ and G $a^{+}$ are used to expose resists. As the calculated results, the energy loss per unit distance by Ga'$^{+}$ ion is about 10$^{3}$[keV/.mu.M] and nearly constant for all energy range. Especially, the projected range and struggling for 80[keV] G $a^{+}$ ion energy are 0.0425[.mu.m] and 0.020[.mu.m], , respectively and the resist thickness of a-S $e_{75}$ G $e_{25}$ to minimize the ion penetration rate into a substrate is 0.118[.mu.m].u.m]..u.m].

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Analysis of Chloride Ion Penetration for Harbor Concrete Structure with In-situation Environment (항만 콘크리트 구조물의 현장환경변화에 따른 염소이온 침투해석)

  • Han, Sang-Hun;Jang, In-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.225-228
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    • 2004
  • In order to estimate the chloride ion penetration, the model, which considers diffusion and sorption, is proposed on the basis of Finite Element Method (FEM). The FEM program provides the estimation of chloride concentration according to cyclic humidity and sorption. After the humidity diffusion analysis is carried out, the chloride ion diffusion and sorption analysis are conducted on the basis of the preestimated humidity data in each element. Each element has different analysis variables at different ages and locations. At early ages and constant outer humidity, the difference between inner and outer relative humidity causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference with age, the effect of sorption on the chloride ion penetration decreases. By the way, the cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and the quantity of chloride ion around steel at later ages. Therefore, the in-situ analysis of chloride ion penetration for marine concrete structures must be performed considering the cyclic humidity condition and the long term sorption.

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The Adsorption of Phosphate Son Using Hydroxyapatite synthesized by Wastewater Sludge of Semiconductor Fabrication Process (반도체 제조공정의 폐수슬러지로 합성된 Hydroxyapatite를 이용한 인산이온의 흡착)

  • 강전택;정기호;신학기
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.257-262
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    • 2002
  • The hydroxyapatite(HAp) for the present study was prepared with the wastewater sludge from semiconductor fabrication process and it was crystallized in an electric furnace for 30 min at 90$0^{\circ}C$. The adsorption characteristics of HAp for phosphate ion in aqueous solution has been investigated. The adsorbed ratio of phosphate ion for HAp were investigated according to the reaction time, amount of HAp, concentration of standard solution, pH of solution, and influence of concomitant ions. The amount of adsorbed phosphate ion decreased with the increase of pH due to the mutual electrostatic repulsion between adsorbed phosphate ions and competitive adsorption between phosphate ion and OH- ion in aqueous solution. The maxium amount of the adsorption equilibrium for phosphate ion was about 24 mg/g of HAp. The HAp would likely to be a possible adsorbent for the removal of phosphate ion in the waste water.

The Effects of Ferrous Ion on Properties of Bright Nickel Electordeposit (광택 니켈 도금속에 미치는 이가식 이온의 영향)

  • 육기진;여운관;박룡진
    • Journal of the Korean institute of surface engineering
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    • v.15 no.4
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    • pp.218-225
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    • 1982
  • The effects of ferrous ion on the properties of bright nickel electrodeposit were exa-mined. Iron exists as ferrous ion (Fe+2) and ferric ion (Fe+3) in the bath, a portion of the former tend to be oxidized to the somewhat harmful ferric ion. Iron was added to bath as the ferrous sulfate, ferrous ion prevented from the oxidation with citric acid. It was found that the hardness was increased as the concentration of ferrous ion, the ductility was slightly increased too. The appearance can obtain the wide bright deposits within 4g/$\ell$. The corrosion resistance drastically dropped from 5g/$\ell$ In the case of considering the effect of ferrous ion on the corrosion resistance and the appearance, the allowable limits is 4g/$\ell$, if the reductant is used.

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Removal of Cadmium Ion (Cd2+) by Pseudomonas aeruginosa Immobilized in Ca-Alginate Gel Beads in Packed-Bed Column Reactor (충전층 반응기내에서 고정된 Pseudomonas aeruginosa에 의한 Cd2+의 제거)

  • Choi, Kwang Soo;Kim, Chul Kyung
    • Clean Technology
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    • v.8 no.4
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    • pp.217-222
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    • 2002
  • The effects of initial cadmium ion concentrations (50, 100, 200, 300ppm), and feeding velocities (30, 45, 60mL/hr) on the removal ratio of cadmium ion by Pseudomonas aeruginosa ATCC 27853 immobilized in Ca-alginate gel beads in a packed-bed column reactor were investigated at operating temperature $37^{\circ}C$. The removal ratio of cadmium ion with variable initial concentration was decreased in the following order : 50ppm > 100ppm > 200ppm > 300ppm. The optimum removal conditions of cadmium ion by Pseudomonas aeruginosa ATCC 27853 were initial concentration 50ppm, feeding velocity 30mL/hr.

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A New Cone Shaped Asymmetrically Substituted Calix[4]arene as an ExcellentIonophore in Construction of Ag(I) ion-Selective Membrane Electrode

  • Ganjali, Mohammad Reza;Babaei, Leila Hajiagha;Taghvaei-Ganjali, Saeed;Modjallal, Atoosa;Sahmsipur, Mojtaba;Hosseini, Morteza;Javanbakht, Mehran
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.177-181
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    • 2004
  • A PVC membrane electrode for silver ion based on a new cone shaped calix[4]arene (CASCA) as membrane carrier was prepared. The electrode exhibits a Nernstian response for $Ag^+$ over a wide concentration range ($1.0{\times}10^{-1}-8.0{\times}10^{-6}$M) with a slope of 58.2 {\pm}$ 0.5 mV per decade. The limit of detection of the sensor is $5.0{\times}10^{-6}$M. The sensor has a very fast response time (~5 s) in the concentration range of ${\leq}=1.0{\times}10^{-3}$ M, and a useful working pH range of 4.0-9.5. The proposed sensor displays excellent discriminating ability toward $Ag^+$ ion with respect to common alkali, alkaline earth, transition and heavy metal ions. It was used as an indicator electrode in potentiometric titration of $Ag^+$ with EDTA and in direct determination of silver ion in wastewater of silver electroplating.

Effect of Na, K, Ca and Mg ions on the Action Potential of the Sinoatrial Node in the Rabbit (토끼 동방결절 활동전압에 대한 Na, K, Ca 및 Mg 이온의 영향)

  • Lee, Jeong-Ryeol;Eom, Yung-Ui
    • Journal of Chest Surgery
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    • v.18 no.1
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    • pp.1-6
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    • 1985
  • Isolated sinus node cells of the rabbit were used to assess the effects of extracellular Na, K, Ca and Mg concentrations on cardiac pacemaker activity. With intracellular glass micro-electrodes spontaneous action potentials of SA node were recorded and the effects of various ions and their blockers were analyzed in terms of the cycle length, the amplitude and the duration of action potentials, the results obtained were as follows. 1. Sodium reduction [up to 30%] decreased the amplitude of action potential and lengthened the cycle length. TTX, specific blocker of Na channel slightly lengthened the cycle length. 2. Increasing potassium ion concentration, the duration of action potential decreased and the frequency increased in 6mM, however, spontaneous action potential was stopped in 24 mM. Barium ion known to be decreasing K conductance increased the duration of action potential but no significant change in the cycle length was noticed. 3. Calcium ion has shortening effect on the duration and the cycle length of action potential but not with dose-dependent manner. Cadmium ion .[0.02mM] lengthened cycle length and the duration of action potential. 4. Increasing the concentration of magnesium ion the cycle length was lengthened, significantly.

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Removal Characteristics of Sr Ion by Na-A Zeolite Synthesized using Coal Fly Ash Generated from a Thermal Power Plant (화력발전소에서 발생하는 석탄비산재로부터 합성한 Na-A 제올라이트의 Sr 이온 제거 특성)

  • Lee, Chang-Han;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.26 no.3
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    • pp.363-371
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    • 2017
  • This study evaluates the adsorption properties of Sr ions in an aqueous solution of the synthetic zeolite (Z-Y1) prepared using coal fly ash generated from a thermal power plant. In order to investigate the adsorption characteristics, the effects of various parameters such as the initial concentrations of Sr ion, contact time, and solution pH were investigated in a batch mode. The Langmuir and Redlich-Peterson model fitted the adsorption isotherm data better than the Freundlich model. The maximum adsorption capacity of Sr ions, as determined the Langmuir model, was 181.68 mg/g. It was found that by varying the Sr ion concentration, pH, and temperature, the pseudo-second-order kinetic model describes the adsorption kinetics of the Sr ion better than the pseudo-first-order kinetic model. The calculated thermodynamic parameters of ${\Delta}H^0$ and ${\Delta}G^0$ showed that the adsorption of Sr ions on Z-Y1 was occurred through a spontaneous and an endothermic reaction. We found that the adsorption of Sr ions by Z-Y1 was more affected by pH than by temperature and Sr ion concentration.