• Title/Summary/Keyword: Ion components

Search Result 583, Processing Time 0.027 seconds

Effect of M2O3 on the Sinterbility and Electrical Conductivity of ZrO2(Y2O3) System(III) : Ceramics of the ZrO2-Y2O3-Ln2O3 System (ZrO2(Y2O3)계 세라믹스의 소결성과 전기전도도에 대한 M2O3의 영향(III) : ZrO2-Y2O3-Ln2O3계 세라믹스)

  • 오영제;정형진;이희수
    • Journal of the Korean Ceramic Society
    • /
    • v.24 no.2
    • /
    • pp.123-132
    • /
    • 1987
  • Yttria-stabilized zirconia with erbia-lanthana were investigated with respect to the amount of Ln2O3 (Ln; Er, La) addition in the range of 0.5∼5 mol% to the base composition of 8 mol% yttriazirconia. Following analysis and measurement were adopted for the characterization of synthesizes of solid electrolyte; phase transformation, lattice parameter, crystallite size, relative density, chemical composition and SEM/EDS. Electrical conductivity by two-probe method versus temperature from 350$^{\circ}C$ to 800$^{\circ}C$ and frequency in the range of 5Hz∼13MHz by complex impedance method was also conducted together with the determination of oxygen ion transference number by EMF method for the evaluation of their electrical properties. The results were as followsing; Electrical conductivity were decreased with increase in Ln2O3 content, but their activation energies increased. In the case of La2O3 addition, espicially, its electrical conductivity was decreased owing to the segregation of second phases at the grain-boundary. Grain-boundary conductivity of the specimen contained 0.5 mol% Er2O3 exhibited a maximum conductivity among thecompositions experimented. However, their bulk conductivities decreased in both case. Oxygen ion transference number was also reduced with decrease in oxygen partial pressure. For example, in the case of Er2O3 addition it retained value in the range of 0.97∼0.94 abvove 4.74${\times}$10-2in oxygen partial pressure. With the increase in the quantities of the evaporation of additive components, the crystallite size of stabilized zirconia decreased, and their relative density also reduced owing to the formation of porosity in their matrices. In the case of La2O3 the sinterbility was improved in the limited amount of addition up to 0.5 mol%, in the same range of addition the strength of sintered bodies were improved perhaps owing to the precipitation of metastable tetragonal phase in the fully stabilized zirconia.

  • PDF

Biochemical Properties and Antibacterial Activity of Lactoferrin from Korean Native Cow (한우 Lactoferrin의 생화학적 특성 및 항균 활성)

  • Yang, Hui-Jin;Lee, Su-Won
    • Journal of Dairy Science and Biotechnology
    • /
    • v.23 no.1
    • /
    • pp.1-8
    • /
    • 2005
  • The purpose of this study was to demonstrate biochemical properties and antibacterial activity of lactoferrin(Lf) obtained from the colostrum of Korean native cow. Lactoferrin was isolated from the colostrum of Korean native cow by purification steps using batch extraction, ion exchange chromatography, gel filtration chromatography, affinity chromatography. Other whey protein components that is similar molecular weight and affinity to lactoferrin were gradually removed from crude Korean Native cow's lactoferrin during the purification steps. The molecular weight of the purified Korean native cow's Lf(K-Lf) was 81 kDa, the isoelectric point was 9, and the content of iron was 0.56mg/g, which is indicated that iron saturation of the K-Lf was 40.6%. Amino acid composition and a-helix content were different K-Lf from bovine Lf(B-Lf). Antibacterial activity of E. coli O111 by K-Lf was lower than that of B-Lf. A minimal inhibitory concentration(MIC) of K-Lf and B-Lf was 2.75mg/ml and 1.5mg/ml respectively.

  • PDF

A Study on Turbulent Boundary Layer around a Two-Dimensional Hydrofoil using LDV System (레이저 유속계를 이용한 2차원날개 단면 주위의 난류경계층 연구)

  • J.W. Ahn;J.T. Lee;K.S. Kim;C.Y. Lee
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.28 no.2
    • /
    • pp.146-158
    • /
    • 1991
  • The flow around a two-dimensional foil section Is measured by a LDV(Laser Doppler Velocimetry) system which is capable of measuring the datailed flow field without interfering the original flow field. A 2-color 3-beam LDV system, which is capable of mea,;tiring 2 velocity components simultaneously and uses 2W Ar-Ion laser source, is used to measure the flow field around an NACA0012 foil section. The measured flow velocities are analysed iii order to study the boundary layer characteristics, flow separation and the detail structure of the flow near the trailing edge of the foil. The boundary layer characteristics are compared with the results by the head's momentum integral method. For the case of small angle of attack at relatively higher Reynolds number, both results show good agreements. The measured data of the velocity field around an NACA0012 foil section would be valuable data to validate the CFD(Computational Fluid Dynamic) calculation results. The developed experimental technique to evaluate the characteristics of two-dimensional foil sections is essential tool to develope new blade sections which have good lift characteristics and better cavitation performances.

  • PDF

Effect of Aluminum Potassium Sulfate Addition on the Color Change in Caesalpinia Sappan Dyeing by Rice Straw Ash Solution (볏짚 잿물 매염에 의한 소목 염색에서 명반 첨가가 색상변화에 미치는 영향)

  • Seo Hee-Sung;Jeon Dong-Won;Kim Jeon-Jun
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.29 no.11
    • /
    • pp.1465-1474
    • /
    • 2005
  • The primary purpose of this study is to investigate the differences in the characteristics of the mordants, synthetic aluminum mordants and ash solutions as natural mordants, used in Caesalpinia sappan dyeing. By introducing aluminum potassium sulfate in the ash solutions, the behavior of the aluminum in the ash solutions were observed. In the rice straw ash solutions, adjusted to the levels of pH6 and pH10, the aluminum potassium sulfate was introduced to achieve various concentration levels. From the analysis of the ash solution of pull, $K^+$ and $Na^+$ ion concentrations were found to be extremely high, while $Al^+$ ion concentration was 0. The color development in the Caesalpinia sappan dyeing by ash solution mordanting was found to be mainly governed not by the mordanting actions of the metallic ions but by those of alkali components. In the case of cotton, the application of pH10 ash solution promoted reddish color development compared to the case of non-mordanting, regardless of the aluminum potassium sulfate addition. In the case of silk, the application of pH10 ash solution increased a* value and decreased b* value compared to the case of non-mordanting.

Modulation of Sarcodon Aspratus on lon Currents-induced by Excitatory Neurotransmitters in Rat Periaqueductal Gray Neurons

  • Kim, Sung-Tae;Sung, Yun-Hee;Kim, Chang-Ju;Joo, Kwan-Joong;Han, Seung-Ho;Lee, Choong-Yeol;Kim, Youn-Sub
    • Journal of Physiology & Pathology in Korean Medicine
    • /
    • v.20 no.6
    • /
    • pp.1672-1677
    • /
    • 2006
  • Sarcodon aspratus is the mushroom of Telephoracea which was been classified into Alphllophorales. The aqueous extract of Sarcodon aspratus in known to have anti-tumor activity, immune modulatory effect, and anti-oxidative action. The descending pain control system consists of three major components: the periaqueductal gray (PAG) of the midbrain, the rostroventral medulla including the nucleus raphe magnus, and the spinal dorsal horn. Glutamate is the primary excitatory neurotransmitter in the brain. Glutamate ionotropic receptors are classified as N-methyl-D-aspartate (NMDA) receptor, ${\alpha}$-amino-3-hydroxy-5-methyl-4-isoxazolepropionate (AMPA) receptor, and kainate receptor. In the present study, the modulation of Sarcodon aspratus on the ion currents activated by glutamate, NMDA, AMPA, and kainate in the acutely dissociated PAG neurons was investigated by nystatin-perforated patch-clamp technique under boltage-clamp condition. Sarcodon aspratus increased glutamate- and NMDA-induced ion currents were not increased by Sarcodon aspratus. The present results show that Sarcodon aspratus may activate the descending pain control system in rat PAG neurons through NMDA receptor.

Advanced Analytical Techniques for Dissolved Organic Matter and Their Applications in Natural and Engineered Water Treatment Systems (최근 용존 유기물 분석 기법 및 자연환경과 수 처리 시스템 내 활용방안)

  • Lee, Yun Kyung;Hur, Jin
    • Journal of Korean Society on Water Environment
    • /
    • v.38 no.1
    • /
    • pp.31-42
    • /
    • 2022
  • Dissolved organic matter (DOM), which changes according to various factors, is ubiquitously present from natural environments to engineered treatment systems. Only limited information is available regarding the environmental functions of DOM after bulk analyses are only applied for characterization. In this paper, latest DOM analytical techniques are briefly introduced, which include fluorescence excitation-emission matrix with parallel factor analysis (EEM-PARAFAC), size-exclusion chromatography with an organic carbon detector (SEC-OCD), carbon/nitrogen stable-isotope ratio, and Fourier transform-ion cyclotron resonance-mass spectroscopy (FT-ICR-MS). Recent examples of using advanced analyses to interpret the phenomena associated with DOM occurring in natural and engineered systems are presented here. Through EEM-PARAFAC, different components like protein-like, fulvic-like, and humic-like can be identified and tracked individually through the investigated systems. SEC-OCD allows researchers to quantify different size fractions. FT-ICR-MS provides thousands of molecular formulas present in bulk DOM samples. Lastly, carbon/nitrogen stable-isotope ratio offers reasonable tools for tracking the sources in environments. We also discuss the advantages and weakness of the above-mentioned characterizing tools. Specifically, they focus on single environmental factors (different sourced-DOM and interaction of sediment-pore water) or simple changes after individual treatment processes. Through collaboration with the advanced techniques later, they help the researchers to better understand environmental behaviors in aquatic systems and serve as essential tools for addressing various pending problems associated with DOM.

Two-dimensional measurements of the ELM filament using a multi-channel electrical probe array with high time resolution at the far SOL region in the KSTAR

  • Hong, Young-Hun;Kim, Kwan-Yong;Kim, Ju-Ho;Son, Soo-Hyun;Lee, Hyung-Ho;Eo, Hyun-Dong;Kim, Min-Seok;Hong, Suk-Ho;Chung, Chin-Wook
    • Nuclear Engineering and Technology
    • /
    • v.54 no.10
    • /
    • pp.3717-3723
    • /
    • 2022
  • For the first time, two-dimensional temporal behavior of the edge localized mode (ELM) filament is measured in the edge tokamak plasma with a multi-channel electrical probe array (MCEP). MCEP, which has 16 floating probes (4 × 4), is mounted at the far scrape-off layer (SOL) region in the KSTAR. An electron temperature and an ion flux are measured by sideband method (SBM), which can achieve two-dimensional measurements with high time resolution. Furthermore, temporal evolutions of the electron temperature and the ion flux are obtained during the ELM occurrence. In the H-mode period, short spikes from ELM bursts are observed in measured plasma parameters, and the trend is similar to that of typical Hα signal. Interestingly, when blob-like ELM filaments crash the probe, the heat flux is significantly higher in a local region of the probe array. The results show that our probe array using the SBM can measure the ELM behavior and the plasma parameters without the effect of the stray current caused by the huge device. This study can provide valuable data needed to understand the interaction between the SOL plasma and the plasma facing components (PFCs).

Meteorological Parameters and Fine Particle Concentration during Two Successive Cold Fronts in Busan on 1~2 February 2021 (부산지역 2021년 2월 1일~2일 연속적인 2개의 한랭전선 통과 시 기상요소와 미세먼지 농도의 특성 )

  • Byung-Il Jeon
    • Journal of Environmental Science International
    • /
    • v.31 no.12
    • /
    • pp.1069-1078
    • /
    • 2022
  • This study investigated the weather conditions, fine particle concentration, and ion components in PM2.5 when two cold fronts passed through Busan in succession on February 1 and 2, 2021. A analysis of the surface weather chart, AWS, and backward trajectory revealed that the first cold front passed through the Busan at 0900 LST on February 1, 2021, with the second cold front arriving at 0100 LST on February 2, 2021. According to the PM10 concentration of the KMA, the timing of the cold front passage had a close relationship with the occurrence of the highest concentration of fine particles. The transport time of the cold front from Baengnyeongdo to Mt. Gudeok was approximately 11 hours . The PM10 and PM2.5 concentrations in Busan started to increase after the first cold front had passed, and the maximum concentration occurred two hours after the second cold front passed. The SO42-, NO3-, and NH4+ concentration in PM2.5 started to increase from 1100 to 1200 LST on February 1, after the first cold front passed, and peaked at 0100 LST to 0300 LST on February 2. However, the highest Ca2+ concentration was recorded 2-3 hours after the second cold front had passed.

The Hardness Water Production By RO/NF/ED Linking Process From Deep Seawater (RO/NF/ED 연계 공정에 의한 고경도 담수 제조)

  • Moon, Deok-Soo;Kim, Kwang Soo;Gi, Ho;Choi, Mi Yeon;Jung, Hyun Ji;Kim, Hyun Ju
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.16 no.4
    • /
    • pp.227-238
    • /
    • 2013
  • The purpose of this study is to develop a process technology to produce high hardness drinking water which meet drinking water standard, remaining useful minerals like magnesium and calcium in the seawater desalination process while removing the sulfate ions and chloride ions. Seawater have been separated the concentrated seawater and desalted seawater by passing on Reverse Osmosis membrane (RO). Using Nano-filtration membrane (NF), We were prepared primary mineral concentrated water that sodium chloride were not removed. By the operation of electro-dialysis (ED) having ion exchange membrane, we were prepared concentrated mineral water (Mineral enriched desalted water) which the sodium chloride is removed. We have produced the high hardness water to meet the drinking water quality standards by diluting the mineral enriched desalted water with deionized water by RO. Reverse osmosis membranes (RO) can separate dissolved material and freshwater from seawater (deep seawater). The desalination water throughout the second reverse osmosis membrane was completely removed dissolved substances, which dissolved components was removed more than 99.9%, its the hardness concentration was 1 mg/L or less and its chloride concentration was 2.3 mg/L. Since the nano-filtration membrane pore size is $10^{-9}$ m, 50% of magnesium ions and calcium ions can not pass through the nano-filtration membrane, while more than 95% of sodium ions and chloride ions can pass through NF membrane. Nano-filtration membrane could be separated salt components like sodium ion and chloride ions and hardness ingredients like magnesium ions and calcium ions, but their separation was not perfect. Electric dialysis membrane system can be separated single charged ions (like sodium and chloride ions) and double charged ions (like magnesium and calcium ions) depending on its electrical conductivity. Above electrical conductivity 20mS/cm, hardness components (like magnesium and calcium ions) did not removed, on the other hand salt ingredients like sodium and chloride ions was removed continuously. Thus, we were able to concentrate hardness components (like magnesium and calcium ions) using nano-filtration membrane, also could be separated salts ingredients from the hardness concentration water using electrical dialysis membrane system. Finally, we were able to produce a highly concentrated mineral water removed chloride ions, which hardness concentration was 12,600 mg/L and chloride concentration was 2,446 mg/L. By diluting 10 times these high mineral water with secondary RO (Reverse Osmosis) desalination water, we could produce high mineral water suitable for drinking water standards, which chloride concentration was 244 mg/L at the same time hardness concentration 1,260 mg/L. Using the linked process with reverse osmosis (RO)/nano filteration (NF)/electric dialysis (ED), it could be concentrated hardness components like magnesium ions and calcium ions while at the same time removing salt ingredients like chloride ions and sodium ion without heating seawater. Thus, using only membrane as RO, NF and ED without heating seawater, it was possible to produce drinking water containing high hardness suitable for drinking water standard while reducing the energy required to evaporation.

Study on the Re-corrosion Characteristics of Corrosion Products by Weeping of Iron Artifacts (철제유물 Weeping에 따른 부식화합물의 재부식 특성 연구)

  • Park, Hyung-Ho;Lee, Hye-Youn;Lee, Jae-Sung;Yu, Jae-Eun
    • Journal of Conservation Science
    • /
    • v.29 no.3
    • /
    • pp.287-296
    • /
    • 2013
  • Excavated iron objects are preserved in stable condition through processes of conservation treatment because they are found in the form of various corrosion products. However, the conservation treatment leads to re-corrosion over time and accordingly, iron objects can be severely damaged, and therefore fundamental measures need to be prepared to control it. In this study, the types and characteristics of corrosion products were scientifically analyzed according to the re-corrosion of iron artifacts. In addition, the stability of the corrosion products was evaluated by exposing the standard samples under the re-corrosion environment. Re-corrosion proceeded with weeping in reddish brown on the cracks of iron artifacts. Weeping was detected akagan$\acute{e}$ite had a low hydrogen ion concentration and high chloride ion. The selection of standard sample goethite, lepidocrocite, hematite, and magnetite, were evaluated corrosive by weeping. After the samples were immersed in HCl(pH 1), $H_2SO_4$(pH 1), $H_2O$(pH 6) solution, they had been maintained for 180 days in relative humidity of 20%, 50%, 80% to investiage the changes of chemical components. As a result of analysis, the changes of chemical components were not showed in goethite, lepidocrocite, and hematite. But magnetite was changed to lepidocrocite in solution including chloride ion($Cl^-$) and to goethite and lepidocrocite solution including sulfuric acid($SO{_4}^{2-}$). Results of the study, in the case of magnetite known as s stable corrosion compound, it was identified the corrosion of magnetite occurs by corrosive ions, which means weeping generated in the iron artifacts can corrode magnetite as well as base metal.