• Title/Summary/Keyword: Ion component

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Structural and component characterization of the B4C neutron conversion layer deposited by magnetron sputtering

  • Jingtao Zhu;Yang Liu;Jianrong Zhou;Zehua Yang;Hangyu Zhu;Xiaojuan Zhou;Jinhao Tan;Mingqi Cui;Zhijia Sun
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3121-3125
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    • 2023
  • Neutron conversion detectors that use 10B-enriched boron carbide are feasible alternatives to 3He-based detectors. We prepared boron carbide films at micron-scale thickness using direct-current magnetron sputtering. The structural characteristics of natural B4C films, including density, roughness, crystallization, and purity, were analyzed using grazing incidence X-ray reflectivity, X-ray diffraction, X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, and scanning electron microscopy. A beam profile test was conducted to verify the practicality of the 10B-enriched B4C neutron conversion layer. A clear profile indicated the high quality of the neutron conversion of the boron carbide layer.

Influence of Cu Composition on the Mechanical Properties and Microstructure of Ti-Al-Si-Cu-N thick films (Ti-Al-Si-Cu-N 후막의 Cu 조성에 따른 기계적 특성과 미세구조 변화에 관한 연구)

  • Yeon-Hak Lee;Sung-Bo Heo;In-Wook Park;Daeil Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.5
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    • pp.335-340
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    • 2023
  • Quinary component of 3㎛ thick Ti-Al-Si-Cu-N films were deposited onto WC-Co and Si wafer substrates by using an arc ion plating(AIP) system. In this study, the influence of copper(Cu) contents on the mechanical properties and microstructure of the films were investigated. The hardness of the films with 3.1 at.% Cu addition exhibited the hardness value of above 42 GPa due to the microstructural change as well as the solid-solution hardening. The instrumental analyses revealed that the deposited film with Cu content of 3.1 at.% was a nano-composites with nano-sized crystallites (5-7 nm in dia.) and a thin layer of amorphous Si3N4 phase.

Effect of Abnormal Grain Growth on Ionic Conductivity in LATP (LATP 내 비정상 입자성장이 이온 전도도에 미치는 영향)

  • Hyungik Choi;Yoonsoo Han
    • Journal of Powder Materials
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    • v.31 no.1
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    • pp.23-29
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    • 2024
  • This study investigates the effect of the microstructure of Li1.3Al0.3Ti1.7(PO4)3 (LATP), a solid electrolyte, on its ionic conductivity. Solid electrolytes, a key component in electrochemical energy storage devices such as batteries, differ from traditional liquid electrolytes by utilizing solid-state ionic conductors. LATP, characterized by its NASICON structure, facilitates rapid lithium-ion movement and exhibits relatively high ionic conductivity, chemical stability, and good electrochemical compatibility. In this study, the microstructure and ionic conductivity of LATP specimens sintered at 850, 900, and 950℃ for various sintering times are analyzed. The results indicate that the changes in the microstructure due to sintering temperature and time significantly affect ionic conductivity. Notably, the specimens sintered at 900℃ for 30 min exhibit high ionic conductivity. This study presents a method to optimize the ionic conductivity of LATP. Additionally, it underscores the need for a deeper understanding of the Li-ion diffusion mechanism and quantitative microstructure analysis.

Diffusion Behaviors of B and P at the Interfaces of Si/$SiO_2$ Multilayer System After the Annealing Process

  • Jang, Jong-Shik;Kang, Hee-Jae;Hwang, Hyun-Hye;Kim, Kyung-Joong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.232-232
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    • 2012
  • The doping of semiconducting elements is essential for the development of silicon quantum dot (QD) solar cells. Especially the doping elements should be activated by substitution at the crystalline sites in the crystalline silicon QDs. However, no analysis technique has been developed for the analysis of the activated dopants in silicon QDs in $SiO_2$ matrix. Secondary ion mass spectrometry (SIMS) is a powerful technique for the in-depth analysis of solid materials and the impurities analysis of boron and phosphorus in semiconductor materials. For the study of diffusion behaviour of B and P by SIMS, Si/$SiO_2$ multilayer films doped by B or P were fabricated and annealed at high temperatures for the activated doping of B and P. The distributions of doping elements were analyzed by SIMS. Boron found to be preferentially distributed in Si layer rather than the $SiO_2$ layer. Especially the B in the Si layers was separated to two components of an interfacial component and a central one. The central component was understood as the activated elements. On the other hand, phosphorus did not show any preferred diffusion.

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A Study on the Three-Dimensional Turbulent Flour Characteristics of a Small-sized Axial Fan at the Maximum Flowrate Region (최대유량역에서 소형 축류 홴의 3차원 난류유동 특성에 관한 연구)

  • Kim, J.K.
    • Journal of Power System Engineering
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    • v.4 no.3
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    • pp.25-33
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    • 2000
  • This study represents three-dimensional turbulent flow characteristics around an axial fan measured at the operating point ${\varphi}=0.32$, which is equivalent to the maximum flowrate region, by using three-dimensional fiber-optic type LDA system. This LDA system is composed of a 5 W Argon-ion laser, two optics in back-scatter mode, three BSA's, a PC, and a three-dimensional automatic traversing system. A kind of paraffin fog is used for laser particles in this study. Mean velocity profiles around an axial fan along the downstream radial distance show that the streamwise and the tangential components exist as a predominant velocity and have the maximum value at the radial distance ratio 0.8, while the radial component has a small scale distribution and its flow direction is inward except a part of blade tip. The turbulent intensity profiles show that the radial component exists the most greatly. And also the turbulent kinetic energy shows about 60% as a maximum value at the radial distance ratio 0.9. Moreover, the Reynolds shear stresses do not exist at upstream flow, but the streamwise and the radial components of them show about 20% as a maximum value at the radial distance ratio 0.9 at downstream flow.

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Chemical Composition and Seasonal Variation of Acid Deposition in Chiang Mai, Thailand

  • Sillapapiromsuk, S.;Chantara, S.
    • Environmental Engineering Research
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    • v.15 no.2
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    • pp.93-98
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    • 2010
  • This study aims to determine the chemical composition and seasonal variation of atmospheric acid deposition in order to identify possible sources contributing to precipitation. Sampling and analysis of 132 wet deposition samples were carried out from January to December 2008 at Mae Hia Research Center, Chiang Mai University, Chiang Mai Province. Total precipitation was 1,286.7 mm. Mean electro-conductivity and pH values were 0.94 mS/m and 6.27, respectively. Major cations ($Na^+$, ${NH_4}^+$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$) and major anions ($HCOO^-$, $CH_3COO^-$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were determined by Ion Chromatography. The relative volume weight mean concentrations of anions, in descending order, were ${SO_4}^{2-}$ > ${NO_3}^-$ > $Cl^-$ > $CH_3COO^-$ > $HCOO^-$ and those of cations were $NH_4^+$ > $Ca^{2+}$ > $Mg^{2+}$ > $K^{+}$ > $Na^+$. Results of a principle component analysis highlighted the influence of various possible sources of ions such as agricultural activity, fuel combustion, marine sources, soil resuspension, and biomass burning.

Visual and Quantitative Analysis of Different Tastes in liquids with Fuzzy C-means and Principal Component Analysis Using Electronic Tongue System

  • Kim, Joeng-Do;Kim, Dong-Jin;Byun, Hyung-Gi;Ham, Yu-Kyung;Jung, Woo-Suk;Choo, Dae-Won
    • Proceedings of the KIEE Conference
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    • 2005.10b
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    • pp.133-137
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    • 2005
  • In this paper, we investigate visual and quantitative analysis of different tastes in the liquids using multi-array chemical sensor (MACS) based on the ion-selective electrodes (ISEs), which is so called the electronic tongue (E-Tongue) system. We apply the Fuzzy C-means (FCM) algorithm combined with Principal Component Analysis (PCA), which can be used to reduce multi-dimensional data to two- or three-dimensional data, to classify visually data patterns detected by E-Tongue system. The proposed technique can be determined the cluster centers and membership grade of patterns through the unsupervised way. The membership grade of an unknown pattern, which does not shown previously, can be visually and analytically determined. Throughout the experimental trails, the E-tongue system combined with the proposed algorithms is demonstrated robust performance for visual and quantitative analysis for different tastes in the liquids.

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A Study on the Three Dimensional Statistical Turbulent Flow Characteristics Around a Small-Sized Axial Fan for Refrigerator (냉장고용 소형 축류홴의 통계학적 3차원 난류유동 특성에 관한 연구)

  • Kim, Jang-Gwon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.6
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    • pp.819-828
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    • 2001
  • The operating point of a small-sized axial fan is strongly dependent upon the system resistance. Therefore, the turbulent flow characteristics around a small-sized axial fan may change significantly according to the operating point. This study represents three-dimensional turbulent flow characteristics around a small-sized axial fan measured at the ideal design point $\phi$=0.25, which is equivalent to the maximum total efficiency point, by using three dimensional fiber-optic type LDA system. This LDA system is composed of a 5 W Argon-ion laser, two optics in back-scatter mode, three BSAs, a PC, and a three-dimensional automatic traversing system. A kind of paraffin fluid is used to supply particles by means of fog generator. Mean velocity profiles downstream of a small-sized axial fan along the radial distance show that the streamwise and the tangential components exist in a predominant manner, while the radial component has a small scale distribution and shows the inflection which its flow direction is inward or outward. Moreover, the turbulent intensity profiles show that the radial component exists the most greatly among turbulent energies.

Effects of the Antitumor Component, F-D-P, Isolated from Elfvingia applanata on the Immune Response

  • Kim, Young-So;Ryu, Ku-Hyun;Mo, Young-Keun;Lee, Chong-Kil;Han, Seong-Sun
    • Korean Journal of Pharmacognosy
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    • v.25 no.4 s.99
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    • pp.348-355
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    • 1994
  • An antitumor component, F-D-P, was purified from the hot water extract of the carpophores of Elfvingia applanata by precipitation with ethanol, dialysis, and passage through a column of DEAE-cellulose ion exchange. F-D-P inhibited the growth of Sarcoma 180 in mice showing the tumor inhibition ratio of 88.3% in doses of 20 mg/kg for ten days. Chemical analysis of F-D-P showed that it was composed of polysaccharide(65.3%) and protein(6.5%0, and that the monosaccharides consisting of the polysaccharide was glucose(89.1%) and mannose(10.9%). The immunomodulatory activities of F-D-P were explored by determining its effect on the proliferation of the whole and subpopulations of lymphocytes, and on the generation of natural killer(NK) cell activity in vitro. F-D-P was mitogenic to total lymphocytes and B cells, but not to purified T cells, even in the presence of accessory cells. F-D-P did not increase NK cell activity when added to cultures of resting lymphocytes. From these results, it is clear that F-D-P modulates primarily the humoral immune responeses.

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A Study on the Radioactive Products of Components in Proton Accelerator on Short Term Usage Using Computed Simulation (몬테칼로 시뮬레이션을 활용한 양성자가속기 단기사용 시 구성품의 방사화 평가)

  • Bae, Sang-Il;Kim, Jung-Hoon
    • Journal of radiological science and technology
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    • v.43 no.5
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    • pp.389-395
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    • 2020
  • The evaluation of radioactivated components of heavy-ion accelerator facilities affects the safety of radiation management and the exposure dose for workers. and this is an important issue when predicting the disposal cost of waste during maintenance and dismantling of accelerator facilities. In this study, the FLUKA code was used to simulate the proton treatment device nozzle and classify the radio-nuclides and total radioactivity generated by each component over a short period of time. The source term was evaluated using NIST reference beam data, and the neutron flux generated for each component was calculated using the evaluated beam data. Radioactive isotopes caused by generated neutrons were compared and evaluated using nuclide information from the International Radiation Protection Association and the Korea Radioisotope association. Most of the nuclides produced form of beta rays and electron capture, and short-lived nuclides dominated. However, In the case of 54Mn, which is a radioactive product of iron, the effect of gamma rays should be considered. In the case of tritium generated from a material with a low atomic number, it is considered that handling care should be taken due to its long half-life.