• Title/Summary/Keyword: Ion Optics

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MAS-NMR Studies in Mixed Alkali Silicate Glasses with low Fe2O3 Content (미소량의 Fe2O3를 첨가시킨 혼합 알칼리 Silicate 유리들의 MAS-NMR 연구)

  • Kang, Myoung-Jin;Shim, Moon-Sik
    • Journal of Korean Ophthalmic Optics Society
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    • v.1 no.1
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    • pp.1-14
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    • 1996
  • The mixed alkali silicate glasses doped 0.1 mol% $Fe_2O_3$ are fabricated for studying the effect of transition metal oxides, which is related to the $Li^-$ ion movement in Magic-Angle-Spinning NMR. We have investigated the spin-lattice relaxation times in the room temperature and measured the $^7Li$ MAS-NMR spectrum with temperature. When the $Fe_2O_3$ oxides are added in alkali silicate glasses, the width of spectrum is changed a little but the line shape is hardly varied. For this reason, we can think that the mixed alkali effects are shown sufficiently in the spin-spin relaxation processes. However, it is not mixed alkali effects in this case. The activation energy of $Li^-$ ions are diminished in mixed alkali glasses. From the analysis of $Li^-$ diffusion environment, spin-lattice relaxation time and the nuclear magnetization, it is confirmed that the alkali mixed effects are not shown in $^7Li$ spin-lattice relaxation processes.

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Wide-line NMR and DSC studies on intrinsically disordered p53 transactivation domain and its helically pre-structured segment

  • Tompa, Peter;Han, Kyou-Hoon;Bokor, Monika;Kamasa, Pawel;Tantos, Agnes;Fritz, Beata;Kim, Do-Hyoung;Lee, Chewook;Verebelyi, Tamas;Tompa, Kalman
    • BMB Reports
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    • v.49 no.9
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    • pp.497-501
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    • 2016
  • Wide-line 1H NMR intensity and differential scanning calorimetry measurements were carried out on the intrinsically disordered 73-residue full transactivation domain (TAD) of the p53 tumor suppressor protein and two peptides: one a wild type p53 TAD peptide with a helix pre-structuring property, and a mutant peptide with a disabled helix-forming propensity. Measurements were carried out in order to characterize their water and ion binding characteristics. By quantifying the number of hydrate water molecules, we provide a microscopic description for the interactions of water with a wild-type p53 TAD and two p53 TAD peptides. The results provide direct evidence that intrinsically disordered proteins (IDPs) and a less structured peptide not only have a higher hydration capacity than globular proteins, but are also able to bind a larger amount of charged solute ions.

Optical memory in photopolymers and rare-earth ion-doped glasses using two-photon absorption (포토폴리머와 희토류이온이 첨가된 유리에서의 이광자흡수를 이용한 광정보저장)

  • Lee, Myeong-Kyu;Kim, Eun-Kyoung;Trinh Minh-Tuan;Lim, Ki-Soo
    • Korean Journal of Optics and Photonics
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    • v.17 no.1
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    • pp.75-80
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    • 2006
  • We studied feasibility of three-dimensional optical memory by utilizing femtosecond laser-induced changes of transmission in photopolymers and photoluminescence in Eu and Sm ion doped sodium borate glasses. We produced transmission change by two photon absorption and obtained sub-Um size spots in photopolymers using 780 nm modelocked Ti-sapphire laser pulses. We also changed valence state of Eu and Sm ions by multi-photon absorption and achieved $\~{\mu}m$ sized spot formation in Sm-doped glasses.

Fabrication of Er/Yb co-doped phosphate glass waveguides by potassium ion exchange (Er과 Yb이 첨가된 인산염 유리의 K 이온교환 공정을 통한 증폭용 광도파로 제조)

  • 김덕준;신장욱;박상호;김태흥;심재기;성희경
    • Korean Journal of Optics and Photonics
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    • v.11 no.3
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    • pp.202-205
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    • 2000
  • One step thermal potassium ion exchange process was carried out to form optical channel waveguides in an ErNb co-doped phosphate glass. Flowing oxygen gas into KN03 melt during ion exchange was effective to prevent glass surface damage that causes an increase of waveguide propagation loss. Amplification characteristics of the waveguides were evaluated at $1.5{\mu}m$ signal wavelength with 980 om laser diode pump. A 45 mm long waveguide whose processing parameters had been optimized exhibited a small signal net gain of 7.5 dB at the launched pump power of 160 mW.160 mW.

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A study on the improvement of optical, structural properties and environmental stability of ZnS optical thin films prepared by ion-assisted deposition (이온 보조 증착에 의한 ZnS 광학 박막의 광학적, 구조적 특성과 환경적 안정성 개선에 관한 연구)

  • 김형근;반승일;김석원;한성홍
    • Korean Journal of Optics and Photonics
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    • v.8 no.1
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    • pp.37-41
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    • 1997
  • The optical property, the environmental stability and the crystallization of ZnS thin films prepared by ion-assisted deposition (IAD) were investigated and compared with those of conventional electron-beam deposited thin films. The humidity(R.H. 85%) test and the thermal(15$0^{\circ}C$) show that the IAD films have relatively higher refractive index, smaller extinction coefficient and environmentally more stable than the conventional films. It is believed to originate from the reduced adsorption of moisture which reflect the increased packing density and the improved microstructure by ion bombardment. XRD experiments also confirm that conventionally grown films have an amorphous in comparison with the crystalline structured IAD films.

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A design and fabrication of asymmetric Y-branch optical power splitters by $Ag^+-Na^+$ ion exchange ($Ag^+-Na^+$ 이온교환법을 이용한 비대칭형 Y-분리기의 설계 및 제작)

  • 전금수;강동성;김희주;반재경
    • Korean Journal of Optics and Photonics
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    • v.12 no.4
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    • pp.320-326
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    • 2001
  • In this paper, we have fabricated asymmetric Y-branch optical power splitters with various optical power splitting ratios by changing the width of one of the output waveguides using $Ag^+-Na^+$ ion change method in BK7 glass. The transmission characteristics of asymmetric Y-branch optical power splitters with different output waveguide width have been investigated using the finitedifference beam propagation method (FD-BPM). We have found the index of the channel waveguide formed by Ag+-Na+ ion change method in BK7 glass and have fabricated channel waveguides to examine the transmission characteristics of channel waveguide. And we have fabricated asymmetric Y-branch optical power splitters with output waveguide width from TEX>$4{\mu}m$ to $6{\mu}m$. /TEX>.

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Characteristics of a CW Ti:sapphire Laser in a Folded Geometry (접힌 공진기 형태의 연속 발진 티타늄 사파이어 레이저의 발진 특성)

  • 강영일;차용호;남창희
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.282-287
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    • 1995
  • We have studied the characteristics of a cw Ti:sapphire laser pumped by an Ar-ion laser. Ti:sapphire is one of the most attractive materials for the generation of ultra-short pulses because of its very broad gain bandwidth. We used a 4.1 mm thick, 0.15 wt. % $Ti^{3+}$ -doped, Brewster-angled Ti:sapphire crystal and made a folded cavity to create a strong focusing mode. The folding angle of the cavity was adjusted to $15.4^{\circ}$ to compensate for the astigmatism from the Brewster-angled Ti:sapphire crystal. 5 WAr-ion laser was used as a pumping source. We observed that the Ti:sapphire cw output power was sensitively changed with respect to the condition of the folded cavity. The threshold pumping power was 2 Wand the slope efficiency was 16% when an output coupler of 10% transmission was used. The maximum output power was more than 450 mW at 5 W pumping. mping.

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Properties of indium tin oxide thin films prepared by ion assisted deposition at room temperature (상온 이온 보조 증착된 ITO 박막의 특성)

  • 이임영;최상대;이기암
    • Korean Journal of Optics and Photonics
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    • v.13 no.3
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    • pp.204-208
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    • 2002
  • We investigate the dependence of indium tin oxide (ITO) thin films on the mixing ratio of Ar:O$_2$ produced by an ion-gun and $O_2$ injected inside the divergence angle of the ion-beam to optimize their sheet resistance and transmittance. The substrate is placed outside the divergence angle, and the films are grown by ion mixing with ITO evaporated at room temperature. From the XRD measurement ITO films are found to be amorphous. ITO thin films show the highest transmittance of 85% at 3$\times$10$^{-5}$ Torr of 0$_2$ and Ae:O$_2$ ratio of 40:60, and the smallest sheet resistance of 132 $\Omega$/$\square$at 1$\times$10$^{-5}$ Torr of $O_2$ and As:O$_2$ ratio of 40:60.

Dielectric Properties in Bi2O3-PbO-SiO2 Glass containing B2O3 (B2O3를 함유한 Bi2O3-PbO-SiO2계 유리의 유전적 특성)

  • Joung, Maeng-Sig;Lee, Su-Dae
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.23-29
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    • 2001
  • In the SP series of glasses, the formation of droplet is well done with increasing PbO. But in the case SP-1, droplet could not be observed in low concentration PbO. These results are considered that PbO does the role of a network modifier, so the crosslinking break down by $SiO_2$. But, in the glasses contained PbO above 50 mol%, glasses are formeddue to $Pb^{4+}$ ion does the role of a network former. As a result of electrical conductivity analysis for SP series of glasses, the electrical conduction is due to bipolaron at high temperature, and it is due to single polaron hopping at low temperature. In the SP series of glasses, electrical conduction mechanism coincide with the correlated-barrier hopping(CBH) model.

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Optical and mechnical properties of ${Ta_2}{O_5}$ optical thin films by ion assisted deposition (이온 보조 증착한 ${Ta_2}{O_5}$ 광학 박막의 광학적 및 기계적 특성 분석)

  • 류태욱;김동진
    • Korean Journal of Optics and Photonics
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    • v.11 no.3
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    • pp.147-151
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    • 2000
  • We deposited the ion assisted ${Ta_2}{O_5}$ films and conventional thermal evaporated ${Ta_2}{O_5}$ films by using electron beam gun, and measured the optical properties and mechanical properties of the fabricated films according to the evaporation conditions. In the case of the TazOs films by oxygen ion assisted deposition with the anode voltage of 120 V, and current density of $50~500\muA/cm^2$, the refractive index exhibited 2.15 which was higher than the conventionally deposited film index 1.94 and the tensile stress exhibited $5.0\times10^8 dyne/cm^2$ which was lower than $7.0\times10^8 dyne/cm^2$. This properties coincided with the optical and mechanical properties of the films deposited at the elevated substrate temperature of $230^{\circ}C$. In the case of the argon ion assisted films the tensile stress was decreased but the absorption existed at the short wavelength in the visible spectral region. And all the fabricated films were found to be amorphous by the X-ray diffraction analysis. lysis.

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