• 제목/요약/키워드: Ion Irradiation

검색결과 453건 처리시간 0.026초

UV 조사한 신립초 및 케일 녹즙의 항산화 활성 및 아질산염 소거작용의 변화 (Changes in Antioxidant and Nitrite Scavenging Activities of Angelica keiskei and Brassica loeracea var. acephala Vegetable Juices Treated with UV Irradiation during Storage)

  • 최구희;권상철;이경행
    • 한국식품영양과학회지
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    • 제39권8호
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    • pp.1187-1193
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    • 2010
  • 녹즙은 가열살균공정을 거치지 않기 때문에 유통기한이 매우 짧아 비가열 살균기술 중의 하나인 UV 살균처리 방법을 이용하여 신립초 및 케일 녹즙을 제조한 후 저장기간에 따른 항산화 활성의 변화 및 아질산염 소거능의 변화를 측정하였다. 저온살균방법 중 UV 처리 기술을 이용하여 신립초 및 케일 녹즙을 제조한 후 UV 처리에 따른 저장기간 내 항산화 활성의 변화 및 아질산염 소거능 변화를 측정하였다. 신립초 및 케일 녹즙의 polyphenol 화합물의 함량은 UV 처리에 의하여 다소 감소하였으며 저장기간이 증가할수록 대조군 및 UV 처리군 모두 polyphenol 화합물의 함량이 감소하였다. DPPH 전자공여능의 변화는 UV 처리 직후 대조군에 비하여 UV 처리군이 다소 높은 활성을 보였고 저장기간 내내 유의적인 차이를 보이지는 않았다. 또한 UV 처리군 간에는 크게 유의적인 차이는 없는 것으로 나타났다. ABTS 활성을 보면 UV 처리 직후 녹즙의 활성은 대조군에 비하여 UV 처리군이 다소 낮게 나타났으며 케일의 경우 UV 처리군간에는 처리 유속이 느릴수록 낮게 나타났다. 금속이온 제거능에서는 신립초의 경우 UV 처리 직후 대조군이 가장 높았고 UV 처리군이 다소 낮은 활성을 보였으며 UV 처리 유속과는 크게 관계없는 것으로 나타났다. 케일의 경우, 대조군과 UV 처리군 모두 제조 직후 유의적인 차이는 없는 것으로 나타났으며 저장기간에 따른 변화는 신립초와 마찬가지로 증가하는 경향이었다. 지질과산화 억제능은 신립초와 케일 모두 blank에 비하여 낮은 O.D.값을 보여 지질과산화 억제능이 있었으며 대조군보다 UV 처리군이 다소 높은 O.D.값을 보여 UV 처리 시 지질과산화 억제능이 감소함을 나타냈다. 아질산염 소거능의 경우, 대조군과 UV 처리군 모두 큰 차이가 없었으며 pH 1.2에서 가장 높은 소거활성을 나타내었다.

Mass Spectrometric Study of Carbon Cluster Formation in Laser Ablation of Graphite at 355 nm

  • Koo, Young-Mi;Choi, Young-Ku;Lee, Kee-Hag;Jung, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제23권2호
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    • pp.309-314
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    • 2002
  • The ablation dynamics and cluster formation of $C_n^+$ ions ejected from 355 nm laser ablation of a graphite target in vacuum are investigated using a reflectron time-of-flight (RTOF) mass spectrometer. At low laser fluence, odd-numbered cluster ions with $3{\leq}n{\leq}15$ are predominantly produced. Increasing the laser fluence shifts the maximum size distribution towards small cluster ions, implying the fragmentation of larger clusters within the hot plume. The temporal evolution of $C_n^+$ ions was measured by varying the delay time of the ion extraction pulse with respect to the laser irradiation, providing significant information on the characteristics of the ablated plume. Above a laser fluence of $0.2J/cm^2$ , large cluster ions ($n{\geq}30$) are produced at relatively long delay times, indicating that atoms or small carbon clusters aggregate during plume propagation. The dependence of the intensity of ablated $C_n^+$ ions on delay time after laser irradiation shows that the most probable velocity of each cluster ion decreases with cluster size.

Observations on the structural changes of embryos of Paeonia rockii L. by low-energy ion irradiation

  • Zhang, D.M.;Cui, F.Z.;Lin, Y.B.
    • 한국진공학회지
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    • 제7권s1호
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    • pp.37-43
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    • 1998
  • The mechanism of interaction between low energy ions and biological organisms has been paid much attention recently. In order to clarify the microstructural response to low energy ion irradiation embryonic cells of Paeonia rockii L. implanted by $Fe^{1+}$ ions with the energy of 80KeV were investigated by Optical Microscopy (OM), Scanning electron Microscopy(SEM) and Transmission Electron Microscopy(TEM). At the dose of 1$\times$1015 ions/$\textrm{cm}^2$, apparent cellular damage was observed in the outer several layers of the radicle. The shape of the cells was obviously deformed from regular polygon to irregular. The cell walls became obscure. SEM micrographs showed that the surface of the radicle was etched severely. It was observed by TEM that nucleus of the implanted cell was elongated and tended to fracture. Nuclear envelope lost its integrity. The implanted $Fe^{1+}$ ions were detected by Energy Dispersive Spectroscopy (EDS). These observations showed that low energy ions could damage to the plant organisms with the thickness of about 30~50$\mu\textrm{m}$. The possible reasons for radiation damage in the biological organisms were discussed.

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방사선 중합에 의한 ACF/PP-g-AN 복합섬유의 합성 및 우라늄 분리에 관한 연구 (A Study on the Synthesis of ACE/PP-g-AN Hybrid Fibers by Irradiation and Separation of Uranium)

  • 황택성;황대성;노영창
    • 폴리머
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    • 제24권2호
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    • pp.174-181
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    • 2000
  • 방사선 전조사법을 이용하여 아크릴로니트릴을 ACF/PP 복합섬유에 그라프트 반응시켜 섬유형 ACF/PP-g-AN 공중합체를 합성하였다. 합성한 공중합체의 FT-lR 결과 2250$cm^{-1}$ / 부근에서 -C=N에 대한 피크, 3450$cm^{-1}$ / 부근에서 -OH와 -NH$_2$에 의한 피크 확인으로 그라프트 반응 및 아미드옥심화 반응을 확인할 수 있었다. 아미드옥심화된 ACF/PP-g-AN 공중합체의 우라늄 이온에 대한 흡착능의 최적시간은 8일이었으며, 최적 pH는 8이었다. 동일 조건하에서의 흡착능은 아미드옥심기의 함량이 증가할수록, 그라프트율이 116.3%일 때 최대 흡착능을 나타내었다. 또한 ACF/PP-g-AN 공중합체는 10회 이상 흡착능의 변화없이 흡탈착이 가능한 홉착제임을 알 수 있었다.

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Enhanced field emission and luminescent properties of straightened carbon nanotubes for applications in field emission display

  • Kim, Do-Hyung;Jang, Hoon-Sik;Lee, Sung-Youp;Lee, Hyeong-Rag;Kim, Chang-Duk;Cho, Dong-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.207-212
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    • 2003
  • The field emission and luminescent properties of carbon nanotubes (CNTs) that were straightened out by argon ion irradiation were investigated. Argon ion irradiation permanently straightened out both as-grown and screen-printed CNTs in the presence of a strong electric field. The straightening process enhanced the emission properties of CNT films by showing a decrease in turn-on field, an increase in total emission current, and a stable emission. Furthermore, the number of emission sites was confirmed to increase by observing the luminescent properties of CNT films after the straightening. The mechanism involved in the straightening of the CNTs is proposed and the enhancement in field emission is discussed in detail.

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Effect of Hydrogen Radicals for Ion Implanted CVD Diamond Using Remote Hydrogen Plasma Treatment(RHPT)

  • Won, Jaihyung;Hatta, Akimitsu;Yagi, Hiromasa;Wang, Chunlei;Jiang, Nan;Jeon, Hyeongmin;Deguehi, Masahiro;Kitabatake, Makoto;Ito, Toshimichi;Sasaki, Takatomo;Hiraki, Akio
    • The Korean Journal of Ceramics
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    • 제4권1호
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    • pp.15-19
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    • 1998
  • Defects formation of Chemical Vapor Deposition (CVD) diamond on $^4He^{2+}$ irradiation and after remote hydrogen plasma treatment(RHPT) were investigated by cathodoluminescence(CL). As calculated in the TRIM simulation, the light elements of $^4He^{2-}$ can be penetrated into the diamond bulk structure at 3~4 $\mu\textrm{m}$ depth. The effects of the implantation region were observed when 5 keV~20 keV electron energy (insight 0.3~4.0$\mu\textrm{m}$) of CL measurement was irradiated to diamond at temperature 80 K. After the RHPT, rehybridization of irradiation damaged diamond was studied. The intensity of 5RL center(intrinsic defect of C) was diminished. The 2.16 eV center (N-V center) occurring usually by annealing could not be seen after RHPT. The diamond was rehybridized by hydrogen radicals without etching and thermal degradation by the RHPT.

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Monte Carlo Calculation for Production Cross-Sections of Projectile's Isotopes from Therapeutic Carbon and Helium Ion Beams in Different Materials

  • Quazi Muhammad Rashed Nizam;Asif Ahmed;Iftekhar Ahmed
    • Journal of Radiation Protection and Research
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    • 제48권4호
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    • pp.204-212
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    • 2023
  • Background: Isotopes of the projectile may be produced along the beam path during the irradiation of a target by a heavy ion due to inelastic interactions with the media. This study analyzed the production cross-section of carbon (C) and Helium (He) projectile's isotopes resulting from the interactions of these beams with different materials along the beam path. Materials and Methods: In this study, we transport C and He ion beams through different materials. This transportation was made by the Monte Carlo simulation. Particle and Heavy Ion Transport code System (PHITS) has been used for this calculation. Results and Discussion: It has been found that 10C, 11C, and 13C from the 12C ion beam and 3He from the 4He ion beam are significant projectile's isotopes that have higher flux than other isotopes of these projectiles. The 4He ion beam has a higher projectile's isotope production cross-section along the beam path, which adds more impurities to the beam than the 12C ion beam. These projectile's isotopes from both the 12C and 4He ion beams have higher production cross-sections in hydrogenous materials like water or polyethylene. Conclusion: It is important to distinguish these projectile's isotopes from the primary beam particles to obtain a precise and accurate cross-section result by minimizing the error during measurement with a nuclear track detector. This study will show the trend of the production probability of projectile's isotopes for these ion beams.

광촉매를 이용한 Humic Acid 광부해시 공존물질이 광분해에 미치는 영향 (The Influence of Coexisting Material on the Photocatalytic Removal of Humic Acid)

  • 류성필;현경자;오윤근
    • 한국환경과학회지
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    • 제13권3호
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    • pp.279-288
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    • 2004
  • This study aimed at improving the $TiO_2$ photocatalytic degradation of HA. A set of tests was first conducted in the dark to study the adsorption of HA at different coexisting material concentration. Adsorption rate increased with adding cation ion but decreased with adding bicarbonate ion. The photodegradation of HA in the presence of UV irradiation was investigated as a function of different experimental condition: initial concentration of HA, $TiO_2$ weight, pH, air flow rate and coexisting material. It was increased either at low pH or by adding cation ion. The increase of cation strength in aqueous solution could provide a favorable condition for adsorption of HA on the $TiO_2$ surface and therefore enhance the photodegradation rate. It was found that bicarbonate ions slowed down the degradation rate by scavening the hydroxyl radicals.

Behavior of the implanted ions in solid oxide electrolyte

  • Cho, Won-Je;Lee, Il-Seop;Kim, Tae-Hyung;Ryu, Boo-Hyung;Lee, In-Ja
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.445-445
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    • 2008
  • The behavior of ion trapping and migration in the yittria-stabilized zirconia pellets following high dose ion beam irradiation have been studied using SEM, EDX, and TGA. The ion beam was irradiated at room and higher temperatures and the differences in their results were interpreted in terms of dynamic annealing effects. The SRIM calculation was also performed to explain the cross sectional SEM image of the electrolytes.

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아르곤 이온빔을 이용한 CNT 페이스트 에미터의 표면처리에 관한 연구 (A Study on the Surface Treatment of CNT Paste Emitter by Ar Ion Irradiation)

  • 권상직
    • 한국전기전자재료학회논문지
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    • 제20권5호
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    • pp.456-461
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    • 2007
  • In this study, a surface treatment method using accelerated Ar ions was experimented for exposing the carbon nanotubes (CNT) from the screen-printed CNT paste. After making a cathode electrode on the glass substrate, photo sensitive CNT paste was screen-printed, and then back-side was exposed by UV light. Then, the exposed CNT paste was selectively remained by development. After post-baking, the remained CNT paste was bombarded by accelerated Ar ions for removing some binders and exposing only CNTs. As results, the field emission characteristics were strongly depended on the accelerating energy, bombardment time, and the power of RF plasma ion source. When Ar ions accelerated with 100 eV energy from the 100 W RF plasma source are bombarded on the CNT paste surface for 10 min, the emission level and the uniformity were best.