• 상하수도학회지
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• 제32권2호
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• pp.145-152
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• 2018

This study is focused on manganese (Mn(II)) removal by ozonation in surface water. Instant ozone demand for the water was 0.5 mg/L in the study. When 0.5 mg/L of Mn(II) is existed in water, the optimum ozone concentration was 1.25 mg/L with reaction time 10 minutes to meet the drinking water regulation. The ozone concentration to meet the drinking water regulation was much higher than the stoichiometric concentration. The reaction of soluble manganese removal was so fast that the reaction time does not affect the removal dramatically. When Mn(II) is existed with Fe, the removal of Mn(II) was not affected by Fe ion. However As(V) is existed as co-ion the removal of Mn(II) was decreased by 10%. Adding ozone to surface water has limited effect to remove dissolved organic matter. When ozone is used as oxidant to remove Mn(II) in the water, the existing co-ion should be evaluated to determine optimum concentration.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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• pp.23-30
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• 1998

The stabilization characteristics of diffusion flame formed in the wake of a cylindrical flame holder were investigated. Distribution of turbulence intensity, concentration distribution of combustion gas, and ion currents were measured. The turbulence intensity in the wake of cylindrical- game holder is increased with increase of diameter or blockage ratio of grid. If the auxiliary fuel is injected into recirculation zone, the concentration of $C_3H_8$ is high, but the concentration of $CO_2$ is low at the boundary of recirculation zone. The region with highest average value of ion currents in the middle of flame is moved to the upstream side by the turbulent components of main stream. The flame mass with partially active reaction is moved fast for uniform flow and turbulence generator G3, but the flame mass with relatively slow reaction is moved slowly for turbulence generator G1.

• 한국재료학회지
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• 제32권4호
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• pp.230-236
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• 2022

The formation behavior of a passive state film on the surface of STS304 in electrolytic solution was analyzed to determine its metallic ion composition. The properties of passive state films vary depending on the Fe and Cr ions in the electrolytic solution. It was observed that the passive state film surface became flat and glossy as the concentration of Fe and Cr ions in the electrolytic solution increased. The corrosion resistance property of the passive state film was proportional to the amount of Fe and Cr in the electrolytic solution. An initial passive state film with high Fe concentration was formed on the surface of STS304 during early electrolytic polishing. Osmotic pressure of Fe ions occurs between the passive state film and electrolytic solution due to the Fe ion concentration gradient. The Fe in the passive state film is dissolved into the electrolyte, and Cr fills up the Fe ion vacancies. As a result, a good corrosion-resistant floating film was formed. The more Fe ions in the electrolytic solution, the faster the film is formed, and as a result, a flat passive state film containing a large amount of Cr can be formed.

• 한국산학기술학회논문지
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• 제3권2호
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• pp.141-145
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• 2002

이온교환수지탑으로 유입된 이온은 연속적인 이온교환 평형을 이루면서 수지층을 통과한다는 가정하에 질량작용법칙과 몰 균형식을 조합하여 연속이은교환평형 칼럼모델을 개발하였다. 연속이온교환평형 칼럼모델을 이용하여 원자력발전소 복수탈염설비 탈염기의 성능을 평가한 결과, Na/sup +/및 Cl/sup -/누출 농도는 수지의 재생효율에 따라 다르며, 특정이온의 유입수 및 유출수에서 농도 비율은 용액 및 수지의 상태에 따라 달라짐을 확인하였다. 본 모델은 수지농도를 보정하여 국부 불완전 평형을 고려할 수 있고, 다성분 존재하의 경쟁적 이온교환을 묘사할 수 있는 장점을 가지고 있다.

• 한국표면공학회지
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• 제55권3호
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• pp.156-163
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• 2022

An ammonium ion with a size and charge similar to that of potassium can bind to valinomycin, which is used as an ion carrier for potassium, and cause a meaningful interference effect on the detection of potassium ions. Currently, there are few ion sensors that correct the interference effect of ammonium ions, and there are few studies that specifically suggest the mechanism of the interference effect. By fabricating a SPCE-based potassium ion-selective electrode, the electromotive force was measured in the concentration range of potassium in the nutrient solution, and the linear range was measured to be 10^-5 to 10^-2 M, and the detection limit was 10^-5.19 M. And the interference phenomenon of the potassium sensor was investigated in the concentration range of ammonium ions present in the nutrient solution. Therefore, a data-based analysis strategy using deep learning was presented as a method to minimize the interference effect.

• 세라미스트
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• 제22권4호
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• pp.357-367
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• 2019

Secondary Ion Mass Spectrometry(SIMS) is an analytical method that measures the distribution and concentration of elements or compounds by analyzing the mass of secondary ions released by irradiating ion beams with energy of hundreds eV to 20 keV on the sample surface. Unlike other similar analytical instruments, SIMS directly detect the elemental ions that constitute a sample, allowing you to accurately identify components and obtain concentration information in the depth direction. It is also a great feature for measuring isotopes and analyzing light elements, especially hydrogen. In particular, with the development of materials science, there is an increasing demand for trace concentration analysis and isotope measurements in the micro-regions of various materials. SIMS has a short history compared to other similar methods; nevertheless, SIMS is still advancing in hardware and is expected to contribute to the development of materials science through research and development of advanced analytical techniques.

• 대한화학회지
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• 제20권4호
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• pp.316-320
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• 1976

단백질에 대한 비닐 단위체의 그라프트 공중합 실험결과를 기초로하여 유기물과 Ce(IV)이온의 산화환원계에 의하여 개시되는 중합반응에 대하여 중합반응 메카니즘을 추구하였다. Ce(IV) 이온에 의한 산화성 종결반응을 고려하여 반응속도식을 유도 하였으며 Ce(IV) 이온 농도가 클때와 작을 때를 별개로 취급하여 Ce(IV) 이온 농도의 변화에 따라 그라프트 수득률의 최대점이 나타나는 현상을 설명하였다.

• 환경위생공학
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• 제16권2호
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• pp.38-46
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• 2001

In this work, the heterogeneous ion exchange membrane was used in a electrodialysis apparatus to treat a Ni planting rinse water because the heterogeneous ion exchange membrane was excellent efficiency as compared with low manufacturing cost, was easy to make, and had a good mechanical properties. For a regeneration of membrane and to obtain the optimal condition for a scale-up of apparatus after treating Ni plating rinse water, we would find about the limiting current density and the concentration polarization. When the Ni plating rinse water 150mg/L was treated with the electrodialysis apparatus using the heterogeneous ion exchange membrane, the limiting current density was about $1.49{\;}mA/\textrm{cm}^2$. And the limiting current density increased with the flow rate and concentration of Ni plating rinse water. We recognized that the used membrane could be reused by periodic backwashing because efficiency was constant when the membrane was backwashed after treating wastewater.

• 분석과학
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• 제12권2호
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• pp.171-175
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• 1999

Carbon paste electrodes, modified with podands containing more than two sulfur atoms, have been employed for the voltammetric determination of Ag(I) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(I) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(I) ion concentration ranging from $1.0{\times}10^{-6}$ to $9.0{\times}10^{-5}M$, and detection limit was $5.0{\times}10^{-7}M$.

• 분석과학
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• 제15권1호
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• pp.91-95
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• 2002

Carbon paste electrodes, modified with 5,6,14,15-dibenzo-1,4-dioxa-8,12-diazacyclopentadeca-5,14-diene containing different ligating atoms of oxygen and nitrogen, have been employed for the voltammetric determination of Ag(I) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(I) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(I) ion concentration ranging from $3.0{\times}10^{-6}M$ to $8.0{\times}10^{-5}M$, and detection limit was $8.5{\times}10^{-7}M$.