• 제목/요약/키워드: Ion Concentration

검색결과 2,962건 처리시간 0.031초

산업폐수중 유화액막에 의한 크롬(VI)의 분리 (Separation of Chromium(VI) Ion in Industrial Waste Water throunh Liquid Surfactant Membrane)

  • 초민승;강안수;우인성;이영순
    • 한국안전학회지
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    • 제4권1호
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    • pp.15-24
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    • 1989
  • The transport of Chromium(Vl) ion from waste water throughl the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid parafnn oil were analyzed. Extraction euperiments were carried out to observe the effect of system variables, such as stirring speed, concentration of carrier, and NaOH in internal aqueous phase, and concentrations of H$_2$SO$_4$and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt. % and liquid parafnn oil concentration is 50 vol. %. The transport of chromium(VI) ion in bacth extractor increased with increasing carrier concentration, the volume ratio of emulsion to external aqueous phases, and initial concentration of chromium(VI) ion under the optimum stirring speed of chromium(VI) ion below 2 ppm. The theoretical equation on the transport of chromium(Vl) ion agreed well with the experimental results.

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Reuse of Oyster Shell Waste as Antimicrobial Water Treatment Agent by Silver Ion Exchange

  • Jo, Myung-Chan;Byeong-II Noh;Shin, Choon-Hwan
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제4권3호
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    • pp.185-193
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    • 2000
  • A water treatment agent with antimicrobial activity(Ag-Os) was created by exchanging silver ion($Ag^{+}$) on calcined oyster shell powder. The desorption of the exchanged silver ion was negligible, thereby indicating a stable antimicrobial water treatment agent. The sterilization effect of Ag-Os on underwater microorganisms was then investigated. An MIC (Minimum Inhibitory Concentration) test result indicated that Ag-Os had an excellent sterilization effect on G-germs, such as Escherichia coli and Pseudomonas aeruginosa. Most germs were annihilated with an Ag-Os concentration of 200 ppm and contact time of 60 minutes. The sterilization effect was mainly dependent on the contact time. The zeta potential of the Ag-Os powder adsorbed on sand was measured relative to the concentration of exchanged silver ion. As the concentration of the exchanged silver ion increased, the surface charge density of the anions on the surface of the Ag-Os powder adsorbed on sand also increased. Accordingly, this result indicated that a higher silver ion than ion exchange capacity was present on the particle surface due to adsorption. Consequently, this increased concentration of exchanged silver ion would appear to significantly enhance the sterilization power.

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초저이온농도에서 이온교환수지에 의한 실리카제거 평형특성 (Equilibrium Property of Ion Exchange Resin for Silica Removal at Ultralow Concentration)

  • 윤태경;이강춘;노병일
    • 한국환경과학회지
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    • 제16권8호
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    • pp.907-912
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    • 2007
  • Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.

배양액 내의 황산이온 농도가 참쑥의 생육과 품질에 미치는 영향 (Effects of Sulfate Ion Concentration in Nutrient Solution on the Growth and Quality of Artemisia mongolicar var. tenuifolia)

  • Lee, Yun-Jeong;Park, Kuen-Woo;Suh, Eun-Joo;Cheong. Jin-Cheol
    • 생물환경조절학회지
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    • 제7권1호
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    • pp.55-61
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    • 1998
  • 본 실험은 배양액 내의 황산이온이 참쑥(Artemisia mongolica var. tenuifolia)의 생육에 미치는 영향을 알아보고자 수행되었다. 황산이온은 0, 0.5, 1, 2, 3mM의 농도로 처리되었는데 양액은 벨기에의 채소연구소에서 허브용양액으로 개발된 양액조성을 변형하여 이용하였다. 참쑥의 생육은 일반적으로 3mM 처리에서 좋았으며 건물률 또한 3mM 처리에서 가장 좋았다. 배양액내의 황산이온 농도가 증가할수록 참쑥의 엽록소 함량은 증가하였는데 특히 엽록소 a의 함량이 b함량에 비해 증가의 폭이 컸다. 참쑥의 무기물 함량은 배양액내의 황산이온 농도와 유의성을 보이지 않았으나 조직내 Ca의 함량은 3mM 처리에서 급격히 감소하였다. 식물에 의한 황산이온의 흡수는 배양액내의 농도가 증가할수록 증가하였는데 2mM까지는 서서히 증가 하다가 3mM에서 현저하게 증가하였다. 1mM 황산이온 처리에서 정유의 함량은 가장 높았으나 그 이상으로 농도가 증가할 경우 정유의 함량은 오히려 감소하였다.

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염분 농도에 따른 콘크리트 구조물의 염분침투 해석 (Chloride Penetration Analysis of Concrete Structures with Chloride Concentration)

  • 양주경
    • 한국컴퓨터산업학회논문지
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    • 제9권3호
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    • pp.137-142
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    • 2008
  • 염소이온 침투로 인해 철근 부식에 가장 큰 영향을 끼치는 인자는 염소이온 표면농도이다. 본 연구에서는 염소이온 표면농도에 따른 염해 진행 정도를 개발한 프로그램을 통하여 해석적으로 접근하였다. 또한 해석 프로그램을 통하여 염소이온 표면농도에 따른 내구수명을 산정하였다. 염소이온 표면농도가 600ppm인 경우도 염소이온 침투 깊이가 32.3mm 정도로 나타났다. 콘크리트의 피복두께를 40mm를 유지한다면 염소이온 표면농도가 600ppm일 때 콘크리트의 내구수명은 167년으로 검토되었다.

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Suppressed 이온 크로마토그래피에서 과량의 양이온이 낮은 농도의 음이온 분석에 미치는 영향 (The Effect of High Concentration Cation Matrix on the Analysis of the Low Anion Concentration in Suppressed Ion Chromatography)

  • 강미정;이석근
    • 분석과학
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    • 제11권6호
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    • pp.495-498
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    • 1998
  • The effect of high concentration ion matrix on the analysis of low anion concentration in the suppressed ion chromatography was studied. The anions studied were $Br^-$, $NO_3{^-}$, $HPO_4^{2-}$, $SO_4^{2-}$, and $C_2O_4^{2-}$ in the presence of excess NaCl and $CaCl_2$. In this study we suggested that the erroneous results in the suppressed ion chromatographic determination of small concentration of anions were not caused by the interaction of large amount of cation in the suppressor, but by the interaction of cation with concerned anion in the original solution. The error in the analysis of such anion can not be eliminated just by dilution. Therefore, we suggested that standard addition method might be adequate for analyses of those samples.

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배양액 내의 Selenate 이온농도가 웜우드(Artemisia absinthium L.)의 생육 및 정유함량에 미치는 영향 (Effects of Selenate Ion Concentration in Nutrient Solution on the Growth and Essential Oil Content of Wormwood( Artemisia absinthium L.))

  • Park, Kuen-Woo;Lee, Yun-Jeong;Jeong, Jin-Cheol
    • 생물환경조절학회지
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    • 제6권4호
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    • pp.264-269
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    • 1997
  • 본 실험은 고기능성 채소 생산을 위한 배양액내의 적정 셀레니움 농도를 구명하고자 수행되었다. 벨기에의 채소연구소에서 허브재배를 위해 개발된 양액을 이용하여 각각 $Na_2$SeO$_4$를 0, 2, 4, 6, 8mg/$\ell$농도로 처리하였다. 배양액내 셀레니움의 농도가 국화과 식물인 향쑥의 생육에 미치는 영향을 알아본 결과 저농도의 처리는 생육을 향상시켰으나 6mg/$\ell$이상의 고농도 처리는 생육을 감소시켰다. 엽록소의 함량은 셀레니움 처리에 의해 증가되었는데 배양액 내의 selenate ion 농도가 높을수록 전체 엽록소함량도 증가되었다. 비타민 C의 함량은 좋은 생장을 보였던 4mg/$\ell$처리까지는 증가하였으나 그 이상으로 농도가 증가했을 때 비타민C의 함량은 감소하였다. 저농도의 selenate 이온 농도는 정유의 함량을 증가시켰으나 고농도에서는 정유의 함량이 감소되었다. 식물에 의한 셀레니움의 흡수는 배양액내의 selenate 이온 농도가 증가할수록 촉진되었다.

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Continuous ion-exchange membrane electrodialysis of mother liquid discharged from a salt-manufacturing plant and transport of Cl- ions and SO42- ions

  • Tanaka, Yoshinobu;Uchino, Hazime;Murakami, Masayoshi
    • Membrane and Water Treatment
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    • 제3권1호
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    • pp.63-76
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    • 2012
  • Mother liquid discharged from a salt-manufacturing plant was electrodialyzed at 25 and $40^{\circ}C$ in a continuous process integrated with $SO_4{^{2-}}$ ion low-permeable anion-exchange membranes to remove $Na_2SO_4$ and recover NaCl in the mother liquid. Performance of electrodialysis was evaluated by measuring ion concentration in a concentrated solution, permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions, current efficiency, cell voltage, energy consumption to obtain one ton of NaCl and membrane pair characteristics. The permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions was low enough particularly at $40^{\circ}C$ and $SO_4{^{2-}}$ transport across anion-exchange membranes was prevented successfully. Applying the overall mass transport equation, $Cl^-$ ion and $SO_4{^{2-}}$ ion transport across anion-exchange membranes is evaluated. $SO_4{^{2-}}$ ion transport number is decreased due to the decrease of electro-migration of $SO_4{^{2-}}$ ions across the anion-exchange membranes. $SO_4{^{2-}}$ ion concentration in desalting cells becomes higher than that in concentration cells and $SO_4{^{2-}}$ ion diffusion is accelerated across the anion-exchange membranes from desalting cells toward concentrating cells.

농도 분극 현상에서의 이온의 흐름과 pH 변화의 가시화 (Visualization of Ion Transport and pH Change in Ion Concentration Polarization)

  • 고성희;강관형
    • 한국가시화정보학회지
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    • 제8권4호
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    • pp.38-42
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    • 2010
  • Ion concentration polarization is an electrokinetic phenomenon which occurs in membrane systems, such as in an electrodialysis and fuel-cell system. But the phenomenon is not fully understood because hydrodynamics, electrokinetics and electrochemistry are coupled with each other. Here, we report that there occurs a change of pH value of buffer solution in concentration polarization phenomenon. To visualize the change of pH, the litmus solution which is one of the pH indicators was used. It is conjectured that the pH of solution changes because hydrogen ions were concentrated in cathodic side and hydroxide ions were concentrated in anodic side. We anticipate that this work may contribute to the fundamental understanding on the ion concentration polarization phenomenon.

Xanthine oxidase 활성 및 형전환에 미치는 구리이온의 영향 (Effect of Copper ion on Xanthine Oxidase Activity and Type Conversion)

  • 허근;이상일;박진우
    • 약학회지
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    • 제38권2호
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    • pp.211-217
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    • 1994
  • Copper intoxication and disturbance of copper metabolism induced various oxygen-derived free radicals related damages. The effect of copper ion on xanthine oxidase activity and type conversion of the enzyme which is concerned to generation of reactive oxygen species, was investigated, It was observed that xanthine oxidase activity was increased by addition of copper ion in the reaction mixture in proportional to the concentration of the metal ion until $60\;{\mu}M$, while the enzyme activity was inhibited in higher concentration of copper treatment. On the other hand, xanthine dehydrogenase activity was inhibited by copper ion addition with concentration dependently. Preincubation of enzyme source with $30\;{\mu}M$ of copper ion, which concentration marked increased the xanthine oxidase activity, unchanged the enzyme activity and type conversion compare to control in vitro system. It was also observed that copper induced xanthine oxidase activity and the enzyme type conversion was protected by dithiothreitol and penicillamine. These results indicate that the increment of the type conversion of xanthine oxidase necessarilly need the presence of copper ion in enzyme assay system.

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