• 제목/요약/키워드: Iodine transport

검색결과 31건 처리시간 0.023초

$CdAl_2S_4 : Co_{2+}$ 단결정의 광학적 특성 (Optical Properties of $CdAl_2S_4 : Co_{2+}$ Single Crystal)

  • 김형곤;김남오;손경춘
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제49권7호
    • /
    • pp.382-387
    • /
    • 2000
  • The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals were grown by the chemical transport reaction method using iodine as a transport agent. The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$single crystals were crystallized into a defect chalcopyrite structure. The optical energy gap of the $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals was found to be 3.377 eV and 2.924 eV, respectively, at 300 K. Blue emission with peaks in 456nm~466nm at 280K was observed in the $CdAl_2S_4$ single crystal. Optical absorption and emission peaks due to impurities in the $CdAl_2S_4 Co^{2+}$ single crystal were observed and described as originating from the electron transition between energy levels of the $Co^{2+} ion sited at the Td symmetry point.

  • PDF

용해도가 큰 핵종의 충전물질에서 주변 암반으로의 이동 현상 (Mass Transport of Soluble Species Through Backfill into Surrounding Rock)

  • Kang, Chul-Hyung;Park, Hun-Hwee
    • Nuclear Engineering and Technology
    • /
    • 제24권3호
    • /
    • pp.228-235
    • /
    • 1992
  • 처분된 폐기물에서 용해도가 큰 핵종이 침출될 때, 그 핵종의 용해도에 의해 조절되거나 조화 용해하지 않는 경우가 있다. 예를 들면 원자로 운영시 핵분열 생성물의 일부는 그레인 경계나 핵연료와 피복재 사이의 틈새에 축적될 수가 있다. 사용후 핵연료 처분장에서 이와 같이 축적된 핵분열 생성물중 세슘이나 요오드와 같이 용해도가 큰 핵종은 용기가 부식되면 지하수내에 급격하게 녹게된다. 이와 같이 틈새에 녹아있는 용해도가 큰 핵종의 이동현상을 시간 및 공간의 함수로 모사하고 그 수치 결과를 제시하였다. 전구간에서 유효한 근사해를 제시하고 이를 초기 및 후기 접근해와 Laplace 변환을 수치 재변환으로 얻은 해들과 비교함으로 검증하였다.

  • PDF

FeSi$_2$박막 흘 효과의 자계의존성 (Hall Effect of FeSi$_2$ Thin Film by Magnetic Field)

  • 이우선;김형곤;김남오;서용진
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
    • /
    • pp.234-237
    • /
    • 2001
  • FeSi$_2$/Si Layer were grown using FeSi$_2$, Si wafer by the chemical transport reaction method. The directoptical energy gap was found to be 0.871ev at 300 K. The Hall effect is a physical effect arising in matter carrying electric current in the presence of a magnetic field. The effect is named after the American physicist E. H. Hall, who discovered it in 1879. In this paper, we study electrical properties of FeSi$_2$/Si layer And then we measured Hall coefficient Hall mobility, carrier density and Hall voltage according to variation magnetic field and temperature, Because of important Part for it application Various phase of silicide is formed at the metal-Si interface when transition metal contacts to Si. Silicides belong to metallic or semiconducting according to their electrical and optical properties. Metallic silicides are used as gate electrodes or interconnections in VLSI devices. Semiconducting silicides can be used as a new material for IR detectors because of their narrow energy band gap.

  • PDF

$FeSi_2$박막 홀 효과의 온도의존성 (Hall Effect of $FeSi_2$ Thin Film by Temperature)

  • 이우선;김형곤;김남오;정헌상
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
    • /
    • pp.230-233
    • /
    • 2001
  • FeSi$_2$ Layer were grown using FeSi$_2$, Si wafer by the chemical transport reaction method. The directoptical energy gap was found to be 0.87leV at 300 K. The Hall effect is a Physical effect arising in matter carrying electric current in the presence of a magnetic field. The effect is named after the American physicist E.H. Hall, who discovered it in 1879. In this paper, we study electrical properties of FeSi$_2$/Si layer. And then we measured Hall coefficient Hall mobility, carrier density and Hall voltage according to variation magnetic field and temperature, Because of important part for it application various phase of silicide is formed at the metal-Si interface when transition metal contacts to Si. Silicides belong to metallic or semiconducting according to their electrical and optical properties. Metallic silicides are used as gate electrodes or interconnections in VLSI devices. Semiconducting silicides can be used as a new material for IR detectors because of their narrow energy band gap.

  • PDF

$Cd_4GeSe_6$$Cd_4GeSe_6:Co^{2+}$ 단결정의 광전도도 특성 (Photoconductivity spectra of undoped and co-doped $Cd_4GeSe_6$ single crystals)

  • 김덕태
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제9권2호
    • /
    • pp.152-158
    • /
    • 1996
  • Optical absorption and photoconductivity spectra of undoped and Co-doped Cd$_{4}$GeSe$_{6}$ single crystals, grown by the chemical transport reaction using iodine as a transporting agent, were investigated. At 20K, the optical energy gaps of the single crystals are 1.934eV for Cd$_{4}$GeSe$_{6}$ and 1.815eV for Cd$_{4}$GeSe$_{6}$ :Co$^{2+}$. The photoconductivity spectra of these single crystals were closely investigated over the temperature range 20-290K. At 20K, the photoconductivity peaks were located at 1.797eV, 1.347eV for Cd$_{4}$GeSe$_{6}$ and 1.815eV, I,.57eV, 1.46eV and 1.38eV for Cd$_{4}$GeSe$_{6}$ :Co$^{2+}$, respectively.ely.

  • PDF

CdS 및 CdS:Co2+ 단결정의 성장과 광학적 특성 (Growth and optical properties of undoped and Co-doped CdS single crystals)

  • 오금곤;김남오;김형곤;현승철;박현;오석균
    • 전기학회논문지P
    • /
    • 제51권3호
    • /
    • pp.137-141
    • /
    • 2002
  • CdS and $CdS:Co^{2+}$ single crystals were grown by CTR method using iodine as transport material. The grown single crystals have defect chalcopyrite structure with direct band gap. The optical energy band gap was decreased according to add of Co-impurity. We can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

STUDY ON THE ELECTRON GENERATION BY A MICRO-CHANNEL PLATE BASED ON EGS4 CALCULATIONS AND THE UNIVERSAL YIELD CURVE

  • Moon, B.S.;Han, S.H.;Kim, Y.K.;Chung, C.E.
    • Journal of Radiation Protection and Research
    • /
    • 제26권3호
    • /
    • pp.177-181
    • /
    • 2001
  • The conversion efficiency of a cesium iodine coated micro-channel plate is studied. We use the EGS4 code to transport photons and generated electrons until their energies become less than 1keV and 10keV respectively. Among the generated electrons, the emission from the secondary electrons located within the escape depth of 56nm from the photo-converter boundary is estimated by integrating the product of the secondary electrons with a probability depending only on their geometric locations. The secondary electron emission from the generated electrons of energy higher than 100eV is estimated by the 'universal yield curve'. The sum of these provides an estimate for the secondary electron yield and we show that results of applying this algorithm agree with known experimental results. Using this algorithm, we computed secondary electron emissions from a micro-channel plate used in a gas electron multiplier detector that is currently being developed at Korea Atomic Energy Research Institute.

  • PDF

CdS 및 $CdS:Co^{2+}$ 단결정의 성장과 광학적 특성 (Growth and optical properties of undoped and Co-doped CdS single crystals)

  • 김남오;방태환;현승철;박광호;박현;오석균
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
    • /
    • pp.94-97
    • /
    • 2002
  • CdS and $CdS:Co^{2+}$ single crystals were grown by CTR method using iodine as transport material. The grown single crystals have defect chalcopyrite structure with direct band gap. The optical energy band gap was decreased according to add of Co-impurity. We can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

  • PDF

$I^B-AI-VI^B_2$$I^B-AI-VI^B_2 :Co^{2+}$결정의 광학적 특성연구 (Optical Properties of $I^B-AI-VI^B_2$$I^B-AI-VI^B_2 :Co^{2+}$ Crystals)

  • 김화택;김창대;윤창선;진문석;최성휴
    • 한국진공학회지
    • /
    • 제4권3호
    • /
    • pp.334-341
    • /
    • 1995
  • IB-AI-VIB2 및 IB-AI-VIB2 :Co2+ 결정을 고순도 원소를 출발 물질로 하고 iodine을 수송 매체로 사용하여 chemical transport reaction method로 성장시켰다. 성장된 결정의 결정구조는 chalcopyrite 구조였으며, energy gap은 direct band gap으로 3.514~1.814 eV 정도로 주어졌으며, cobalt를 불순물로 첨가할 때 energy gap은 감소하였다. IB-AI-VIB2 :Co2+ 결정에서 첨가된 cobalt가 모체결정의 Td symmetry site에 Co2+ ion으로 위치하여, Co2+ ion의 energy 준위 사이의 전자전이에 기인하는 불순물 광흡수 peaks가 나타났다. 이 불순물 광흡수 peaks에 결정장 이론을 적용하여 구산 1st-order spin-orbit coupling parameter(λ)는 -183~ -189cm-1정도였고, 2nd-order spin-orbit coupling parameter(P)는 225~239 cm-1정도였으며, crystal field parameter(Dq)는 328~395cm-1, Racah parameter(B)는 531~552cm-1정도였다.

  • PDF

열화학적 수소제조 IS 프로세스의 효율향상을 위한 전해-전기투석의 실험적 평가 (Evaluation on the Electro-electrodialysis for hydrogen production by thermochemical water-splitting IS process)

  • 홍성대;김정근;이상호;최상일;배기광;황갑진
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2006년도 춘계학술대회
    • /
    • pp.13-16
    • /
    • 2006
  • Electro-electrodialysis (EED) experiments were carried out for the HI concentration from HIx $(HI-H_2O-I_2)$ solution to improve the Hl decomposition reaction in the thermochemical water-splitting is (iodine-Sulfur) process. EED cell is composed of the collector electrode and electrolyte. Nafion 117 which was cation exchange membrane used as an electrolyte, and the activated carbon cloth used as an electrode. The HI concentration experiment was carried out using the HIx solution and molar ratio of the $I_2$ were varied from 1 to 3 mole. The cell voltages were decreased as temperature increase. And, membrane properties such as transport number of proton and electro-osmosis coefficient were decreased as temperature increase

  • PDF