• Title/Summary/Keyword: Internal impedance

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PEMFC Characterization Study by in-situ Analysis Method (In-Situ 분석법에 의한 연료전지 특성 연구)

  • Kim, Young-Min;Lee, Jong-Hyun;Im, Se-Joon;Ahn, Byung-Ki;Lim, Tae-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.3
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    • pp.208-215
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    • 2009
  • PEMFC stack power output is needed to be around 100 kW to meet the requirements of automotive application and scaling-up the active area of the stack cells will allow a higher power. In the case of scaling-up the active area of cells, it is difficult to obtain uniform in-plane internal conditions such as temperature, relative humidity and stoichiometry of the feed gas. These ununiformity with the location in the cell would affect both the performance and durability of the stack, so it is important to understand phenomena in the cell for improving them. In this study, the current density, electrochemical resistance and performance distribution measurement was performed to understand the ununiformity in a single cell using in-situ method; (1) Current Density Distribution (CDD) Device and (2) Segmented Cell Fixture. The influence of location of feed gas on the performance of a single cell was experimentally measured and discussed by using a segmented single cell which was composed of 8 compartments. The correlation between the location and performance in a single cell was discussed by these two tools and it was extended between the local characterization and the durability in a MEA by comparing the used cell with a fresh one. It was also studied in terms of electrochemistry by Electrochemical Impedance Spectroscopy.

Electrochemical Performance of Activated Carbon Electrode Materials with Various Post Treatments for EDLC (활성탄의 후 처리에 의한 EDLC 전극재의 전기화학 성능 개선)

  • Lee, Eunji;Kwon, Soon Hyung;Choi, Pooreum;Jung, Ji Chul;Kim, Myung-Soo
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.285-292
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    • 2014
  • Commercial activated-carbon used as the electrode material of an electric double-layer capacitor (EDLC) was posttreated with various acids and alkalis to increase its capacitance. The carbon samples prepared were then heat-treated in order to control the amount of acidic functional groups formed by the acid treatments. Coin-type EDLC cells with two symmetric carbon electrodes were assembled using the prepared carbon materials and an organic electrolyte. The electrochemical performance of the EDLC was measured by galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the various activated carbons, the carbon electrodes (CSsb800) prepared by the treatments of coconutshell-based carbon activated with NaOH and $H_3BO_5$, and then heat treated at $800^{\circ}C$ under a flow of nitrogen gas, showed relatively good electrochemical performance. Although the specific-surface-area of the carbon-electrode material ($1,096m^2/g$) was less than that of pristine activated-carbon ($1,122m^2/g$), the meso-pore volume increased after the combined chemical and heat treatments. The specific capacitance of the EDLC increased from 59.6 to 74.8 F/g (26%) after those post treatments. The equivalent series resistance of EDLC using CSsb800 as electrode was much lower than that of EDLC using pristine activated carbon. Therefore, CSsb800 exhibited superior electrochemical performance at high scan rates due to its low internal resistance.

A Study on the Improvement of the Dye-sensitized Solar Cell by the Fiber Laser Transparent Conductive Electrode Scribing Technology (파이버 레이저 투명 전극 식각을 통한 염료감응형 태양전지 효율 상승 연구)

  • Son, Min-Kyu;Seo, Hyun-Woong;Shin, In-Young;Kim, Jin-Kyoung;Choi, Jin-Ho;Choi, Seok-Won;Kim, Hee-Je
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.12
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    • pp.2218-2224
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    • 2010
  • Dye-sensitized solar cell (DSC) is a promising alternative solar cell to the conventional silicon solar cell due to several advantages. Development of large scale module is necessary to commercialize the DSC in the near future. A scribing technology of the transparent conductive oxide (TCO) is one of the important technologies on the fabrication of DSC module. A quality of the scribed line on the TCO has a decisive effect on the efficiency of DSC module. Among several scribing technologies, the fiber laser is a suitable for scribing the TCO more precisely and accurately because of their own characteristics. In this study, we try to improve the quality of the TCO scribed line by using the fiber laser. Consequently, the operating parameter of fiber laser is optimized to get the TCO scribed line with good quality. And the fiber laser scribing technology of the TCO is applied to the fabrication of the DSC with optimal operating parameter, operating current 3900mA. As a result, the current density and fill factor are improved and the total efficiency is increased because the internal resistances of DSC such as TCO sheet resistance and the resistance concerned to the electron movement in the $TiO_2$ are reduced. This is analyzed by the electrochemistry impedance spectroscopy (EIS) and the equivalent circuit model of the DSC.

Neural Network Model for Partial Discharge Pattern Analysis of XLPE/EPR Interface (XLPE/EPR 계면의 부분방전 패턴 분석을 위한 신경망 모형)

  • Cho Kyung-Soon
    • Journal of the Korea Computer Industry Society
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    • v.6 no.2
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    • pp.279-286
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    • 2005
  • The prefabricated type used generally in Korea to join cable runs on new installations or to repair broken Cable runs on existing installations, because installation is very simple and save time. This type is a permanent, shielded and submersible cable joint for direct burial or vault application. It confirms to the requirements of IEEE std. 404-1993 by factory testing, but many problems of insulated cable systems are caused by internal defects of the joint part which have to be mounted ensile. Faults arise from impurities or voids. A suitable solution for a monitoring of cable joints during the after-laying test and service is partial discharge detection. <중략> $\Phi-q-n$ properties were measured using detection impedance, high pass filter and computerized data acquisition system. Statistic Value like maximum charge, repetition rate, average charge, etc. are calculated. It is possible to quantitative analysis of $\Phi-q-n$ properties from this statistic value and pattern analysis.

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A Study on Dual Circular Polarized Patch Antenna with Compact Size (소형 이중 원형편파 패치안테나에 관한 연구)

  • Yun, Gi-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.7
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    • pp.1537-1543
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    • 2010
  • This paper describes a compact microstrip antenna with dual polarization characteristics. The antenna, receiving both a left-hand circularly polarized(LHCP) wave and a right-hand circularly polarized(RHCP) wave, can be used for a polarization diversity. A diamond-shaped patch with internal empty room is designed for impedance matching as well as size reduction. And slots are added around feeding point to improve input matching. The proposed antenna has been applied to GPS(global positioning system), operating at 1.57GHz. And, the proposed idea has been verified and estimated by simulation. The measurement results show that it has VSWR 2:1 bandwidth of 83MHz, 3dB axial bandwidth of about 58MHz, 3dB beamwidth of 90degree, and gain of 0dBi, respectively, for RHCP. Also, it has similar performances for LHCP.

Application of SFCL on Bus Tie for Parallel Operation of Power Main Transformers in a Fuel Cell Power Systems

  • Chai, Hui-Seok;Kang, Byoung-Wook;Kim, Jin-Seok;Kim, Jae-Chul
    • Journal of Electrical Engineering and Technology
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    • v.10 no.6
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    • pp.2256-2261
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    • 2015
  • In the power plant using high temperature fuel cells such as Molten Carbonate Fuel Cell(MCFC), and Solid Oxide Fuel Cell(SOFC), the generated electric power per area of power generation facilities is much higher than any other renewable energy sources. - High temperature fuel cell systems are capable of operating at MW rated power output. - It also has a feature that is short for length of the line for connecting the interior of the generation facilities. In normal condition, these points are advantages for voltage drops or power losses. However, in abnormal condition such as fault occurrence in electrical system, the fault currents are increased, because of the small impedance of the short length of power cable. Commonly, to minimize the thermal-mechanical stresses on the stack and increase the systems reliability, we divided the power plant configuration to several banks for parallel operation. However, when a fault occurs in the parallel operation system of power main transformer, the fault currents might exceed the interruption capacity of protective devices. In fact, although the internal voltage level of the fuel cell power plant is the voltage level of distribution systems, we should install the circuit breakers for transmission systems due to fault current. To resolve these problems, the SFCL has been studied as one of the noticeable devices. Therefore, we analyzed the effect of application of the SFCL on bus tie in a fuel cell power plants system using PSCAD/EMTDC.

Design of Circular Patch Antenna for 1.6G Hz band Satellite Navigation System (1.6 GHz대역 위성항법 시스템용 원형 패치 안테나 설계)

  • Kang, NyoungHak;Rhee, Seung-Yeop;Yeo, Junho;Lee, Jong-Ig;Kim, GunKyun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2018.05a
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    • pp.63-64
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    • 2018
  • In this study, a design method for a circular polarization patch antenna operating at a frequency 1.5 GHz~1.7 GHz was studied. To obtain the wide bandwidth and high gain, air substrate between patch and ground plane was applied. The impedance bandwidth is improved by adjusting the sizes of patch, the distance between main patch and ground plate, the length of internal slots, the position of feeding point, the length of external stub, etc. The antenna is designed and simulated for an operation in the frequency range of 1.5GHz~1.7GHz band. The results show that antenna characteristics such as return loss, gain, axial ratio, radiation patterns are appropriate for the satellite navigation system.

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Preparation of Co3O4/NF Anode for Lithium-ion Batteries

  • Tian, Shiyi;Li, Botao;Zhang, Bochao;Wang, Yang;Yang, Xu;Ye, Han;Xia, Zhijie;Zheng, Guoxu
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.384-391
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    • 2020
  • Due to its characteristics of light weight, high energy density, good safety, long service life, no memory effect, and environmental friendliness, lithium-ion batteries (LIBs) are widely used in various portable electronic products. The capacity and performance of LIBs largely depend on the performance of electrode materials. Therefore, the development of better positive and negative materials is the focus of current research. The application of metal organic framework materials (MOFs) derivatives in energy storage has attracted much attention and research. Using MOFs as precursors, porous metal oxides and porous carbon materials with controllable structure can be obtained. In this paper, rod-shaped Co-MOF-74 was grown on Ni Foam (NF) by hydrothermal method, and then Co-MOF-74/NF precursor was heat-treated to obtain rodshaped Co3O4/NF. Ni Foam was skeleton structured, which effectively relieved. The change of internal stress changes and destroys the structural volume of the electrode material and reduces the capacity attenuation. Co3O4/NF composite material has a specific discharge capacity of up to 1858 mA h/g for the first time, and a reversible capacity of up to 902.4 mA h/g at a current density of 200 mA/g, and has excellent rate and impedance performance. The synthesis strategy reported in this article opens the way to design high-performance electrodes for energy storage and electrochemical catalysis.

An Analysis and Design of Wideband Microstrip Rotman Lens by Contour Integral and Segmentation Method (경계적분법과 세그멘테이션 기법에 의한 광대역 마이크로스트립 로트만 렌즈의 해석 및 설계)

  • 이광일;오승엽
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.14 no.7
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    • pp.769-776
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    • 2003
  • This paper presents analysis and design of microstrip Rotman lens operating over wide band and wide steering angle by the contour integral method along with the segmentation method. All mutual coupling, internal reflections between ports and the discontinuity at every junction are taken into account. Equally spaced ports are designed and realized, which make suppress output ripple through the array ports. Impedance matching and mutual coupling between ports are analyzed and optimized using 12 input and 12 output exponential tapers. The measured results of fabricated lens show ${\pm}$ 1.8 dB insertion loss deviation over 6∼18 GHz wide frequency range and beam steering accuracy less than 1$^{\circ}$over ${\pm}$53$^{\circ}$angle and agrees well with the analysis results.

FDTD Analysis of Lossy Multiconductor Transmission Lines Terminated in Linear Loads (선형소자로 종단된 손실이 있는 다중 전송선의 FDTD 해석)

  • 박범준;주재철;이형영;박동철
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.11 no.3
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    • pp.419-428
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    • 2000
  • Multiconductor transmission line(MTL) equations are solved by FDTD(Finite-Difference Time-Domain) method to predict crosstalk and fields to transmission line coupling on lossy multiconductor transmission lines terminated in arbitrary linear loads. Skin effect losses as well as dc losses are included in the analysis. In order to increase computational efficiency, the convolution integral of internal impedance of conductors and the line currents is computed by using Prony method. For boundary conditions of MTLs terminated in linear loads, state-variable formulation is adopted. The simulated results by FDTD method are compared with the measured ones obtained by using TEM cell. The predictions are in good agreement with the measurements. In addition, it has been found that skin effect losses as well as dc losses of the conductors should be included for accurate predictions on relatively high loss transmission lines such as PCB. It has also been found that dc losses and skin-effect losses affect late-time responses and early-time responses, respectively.

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