• Bulletin of the Korean Chemical Society
• /
• 제35권3호
• /
• pp.881-885
• /
• 2014

Photophysics of 10-hydroxybenzo[h]quinoline (HBQ) has been in controversy, in particular, on the nature of the electronic states before and after the excited state intramolecular proton transfer (ESIPT), even though the dynamics and mechanism of the ESIPT have been well established. We report highly time resolved fluorescence spectra over the full emission frequency regions of the enol and keto isomers and the anisotropy in time domain to determine the accurate rates of the population decay, spectral relaxation and anisotropy decay of the keto isomer. We have shown that the ~300 fs component observed frequently in ESIPT dynamics arises from the $S_2{\rightarrow}S_1$ internal conversion in the reaction product keto isomer and that the ESIPT occurs from the enol isomer in $S_1$ state to the keto isomer in $S_2$ state.

• 한국소음진동공학회논문집
• /
• 제16권4호
• /
• pp.387-393
• /
• 2006

이 논문에서는 내부에 비정상 유동이 흐르는 균일한 직선 파이프에 대한 스펙트럴요소모델을 개발하였다. 개발된 스펙트럴요소모델에 대한 스펙트럴요소행렬은 주파수 영역에서 구한 파이프 역학 방정식의 엄밀해를 이용하여 유도되었다. 이 스펙트럴요소모델의 정확성을 평가하고 한 예제 파이프 계의 진동특성과 파이프 내부 유동특성을 고찰하기 위하여 스펙트럴 동역학 해석을 수행하였다.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2005년도 추계학술대회논문집
• /
• pp.925-928
• /
• 2005

In this paper, a spectral element model is developed for the uniform straight pipelines conveying internal unsteady fluid. The spectral element matrix is formulated by using the exact frequency-domain solutions of the pipe-dynamics equations. The spectral element dynamic analyses are then conducted to evaluate the accuracy of the present spectral element model and to investigate the vibration characteristics and internal fluid transients of an example pipeline system.

• 대한기계학회논문집B
• /
• 제37권9호
• /
• pp.855-862
• /
• 2013

개방 노심 열적여유도 해석 코드에 입력으로 제공되는 APR+ (Advanced Power Reactor Plus)의 수력학적 특징을 결정하기 위해 일련의 1/5 축소 원자로 유동분포 시험이 수행되었다. 본 연구에서는 원자로 내부 유동 계산시 다공성 모델을 사용한 전산유체역학의 적용성을 평가하기 위해 상용 전산유체역학 소프트웨어인 ANSYS CFX V.14를 사용하여 계산을 수행하였다. 결론적으로 본 연구에서 사용한 일부 원자로 내부 구조물에 대한 다공성 영역 처리방식을 통해 원자로 내부의 유동 특성을 정성적으로 적절히 파악할 수 있을 것으로 판단된다. 만일 충분한 계산 자원이 확보된 조건인 경우라면 노심 입구 상류에 위치한 원자로 내부 구조물의 실제 기하 형상을 고려함으로써 노심 입구 유량분포를 보다 정확하게 예측할 수 있을 것으로 예상된다.

• International Journal of Naval Architecture and Ocean Engineering
• /
• 제10권6호
• /
• pp.692-710
• /
• 2018

The Three-dimensional (3-D) dynamical behaviors of a fluid-conveying pipe subjected to vortex-induced vibration are investigated with different internal flow velocity ${\nu}$. The values of the internal flow velocity are considered in both subcritical and supercritical regimes. During the study, the 3-D nonlinear equations are discretized by the Galerkin method and solved by a fourth-order Runge-Kutta method. The results indicate that for a constant internal flow velocity ${\nu}$ in the subcritical regime, the peak Cross-flow (CF) amplitude increases firstly and then decrease accompanied by amplitude jumps with the increase of the external reduced velocity. While two response bands are observed in the In-line (IL) direction. For the dynamics in the lock-in condition, 3-D periodic, quasi-periodic and chaotic vibrations are observed. A variety of CF and IL responses can be detected for different modes with the increase of ${\nu}$. For the cases studied in the supercritical regime, the dynamics shows a great diversity with that in the subcritical regime. Various dynamical responses, which include 3-D periodic, quasi-periodic as well as chaotic motions, are found while both CF and IL responses are coupled while ${\nu}$ is beyond the critical value. Besides, the responses corresponding to different couples of ${\mu}_1$ and ${\mu}_2$ are obviously distinct from each other.

• 설비공학논문집
• /
• 제25권5호
• /
• pp.269-278
• /
• 2013

In this study, in order to examine the applicability of computational fluid dynamics with the porous model to the analysis of APR+ (Advanced Power Reactor Plus) internal flow, simulation was conducted with the commercial multi-purpose computational fluid dynamics software, ANSYS CFX V.14. In addition, among the various reactor internals, the effect of flow skirt geometry on reactor internal flow was investigated. It was concluded that the porous model for some reactor internal structures could adequately predict the hydraulic characteristics inside the reactor in a qualitative manner. If sufficient computation resource is available, the predicted core inlet flow distribution is expected to be more accurate, by considering the real geometry of the internal structures, especially located in the upstream of the core inlet. Finally, depending on the shape of the flow skirt, the flow distribution was somewhat different locally. The standard deviation of the mass flow rate (${\sigma}$) for the original shape of flow skirt was smaller, than that for the modified shape of flow skirt. This means that the original shape of the flow skirt may give a more uniform distribution of mass flow rate at the core inlet plane, which may be more desirable for the core cooling.

• Bulletin of the Korean Chemical Society
• /
• 제33권3호
• /
• pp.897-900
• /
• 2012

We examined theory for force-induced unbinding on a two-dimensional free energy surface where the internal dynamics of biomolecules is coupled with the rupture process under constant tension f. We show that only if the transition state ensemble is narrow and activation barrier is high, the f-dependent rupture rate in the 2D potential surface can faithfully be described using an effective 1D energy profile.

• 한국지능시스템학회:학술대회논문집
• /
• 한국퍼지및지능시스템학회 1997년도 추계학술대회 학술발표 논문집
• /
• pp.296-300
• /
• 1997

Recently, the genetic algorithm has been applied to the various types of optimization problems and these attempts have very successfully. However, in most cases on these approaches, there is not given by investigator about to the theoritical analysis. The reason that the analysis of the dynamics for genetic algorithm is not clear, is the probablitic aspect of genetic algorithm. In this paper, we investigate the analysis of the internal dynamics for genetic algorithm using stochastic differential method. In addition, we provide a new genetic algorithm, based on the study of the convergence property for the genetic algorithm.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2017년도 전력전자학술대회
• /
• pp.100-101
• /
• 2017

This paper presents the dynamics of the current-mode controlled buck and boost converters, which are both connected to an ill-conditioned source. This paper investigates the origin of potential instability and demonstrates internal/external dynamics of the converters under adverse interactions with the source.

• 한국시스템다이내믹스연구
• /
• 제8권1호
• /
• pp.211-227
• /
• 2007

Like the saying "You can't manage what you can't measure," performance measurement is considered as one of the most important management activities for the organizations in either private or public sector. Performance measurement, however, has thus far relied too much on financial statements. Realizing the importance of a more scientific and comprehensive performance measurement, many organizations have adopted several different systems in order to objectively estimate their balanced performance results. The Balanced Scorecard (BSC) has become a popular means to measure performance. But the BSC has also received some criticisms. In this paper four limitations in the use of the BSC are discussed : BSCs focus on unidirectional causality, are unable to distinguish delays between actions and their impacts on performance, integrate insufficiently strategy with operational measures, and lead to internal biases. We propose a system dynamics approach with causal loop diagram(CLD) to develop a Dynamic BSC in order to overcome these limitations. The results suggest that developing a BSC with system dynamics is a promising approach to supplement existing BSC frameworks.