• Transactions of the Korean hydrogen and new energy society
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• v.16 no.4
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• pp.324-333
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• 2005

The kinetics of external hydrogen embrittlememt is considered. The equation of the crack growth rate (CGR) is derived from modification of the model developed by Wilkinson and Vitek. After calculation of hydrogen pressure build-up in the void, the effect of the internal hydrogen pressure on the void growth is added. The CGR is expressed by two terms. One is the term dependent on the critical stress, which is exactly same as Wilkinson and Vitek. The other is term dependent on the pressure of the hydrogen in void.

• Journal of Aerospace System Engineering
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• v.18 no.3
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• pp.8-16
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• 2024

Because hydrogen has very low density, a different storage method is required to store the same amount of energy as fossil fuel. One way to increase the density of hydrogen is through liquefaction. However, since the liquefied temperature of hydrogen is extremely low at -252 ℃, it is easily vaporized by external heat input. When liquid hydrogen is vaporized, a self-pressurizing phenomenon occurs in which the pressure inside the hydrogen tank increases, so when designing the tank, this rising pressure must be carefully predicted. Therefore, in this paper, the internal pressure of a cryogenic liquid fuel tank was predicted according to the liquid hydrogen filling ratio. A one-dimensional thermodynamic model was applied to predict the pressure rise inside the tank. The thermodynamic model considered heat transfer, vaporization of liquid hydrogen, and fuel discharging. Finally, it was confirmed that there was a significant difference in pressure behavior and maximum rise pressure depending on the filling ratio of liquid hydrogen in the fuel tank.

• Nuclear Engineering and Technology
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• v.53 no.2
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• pp.474-483
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• 2021

To establish the exclusive role of hydrogen on burst behaviour of Zircaloy-4 during loss-of-coolant accident transients, an extensive single-rod burst tests were conducted on both unirradiated as-received and hydrogenated Zircaloy-4 cladding tubes at different heating rates and internal overpressures. The visual observations of cladding tubes during bursting as well as post-burst are presented in detail to understand the effect of hydrogen concentration, heating rate, and internal pressure. Impact of hydrogen on burst parameters-burst stress, burst strain, burst temperature-during loss-of-coolant accident transients are compared and discussed. Rupture at multiple locations for hydrogenated cladding at lower internal pressure and higher heating rate is reported for the very first time. A novel burst criterion accounting hydrogen concentration in nuclear fuel cladding is proposed.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.5
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• pp.411-418
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• 2020

A reformer is a device for producing hydrogen used in fuel cells. Among them, methanol steam reformer uses methanol as fuel, which is present as a liquid at room temperature. It has the advantage of low operating temperature, high energy density, and high hydrogen production. The purpose of this study is to improve the internal flow of the pressure vessel when a bundle of methanol steam reformer in the pressure vessel goes out to a single outlet. An analysis of equilibrium reaction to methanol steam reforming reaction was conducted using Aspen HYSYS^® (Aspen Technology Inc., Bedford, USA), and based on the results, computational analysis was conducted using ANSYS Fluent^® (ANSYS, Inc., Canonsburg, USA). For comparison of the results, the height of the pressure vessel, outlet diameter, and fillet was set as variables, and the optimum geometry was selected by comparing the effects of gravity and the amount of negative pressure.

• Journal of Auto-vehicle Safety Association
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• v.14 no.4
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• pp.43-52
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• 2022

Recently, the government has been expanding the supply of hydrogen vehicles according to the roadmap for vitalizing the hydrogen economy, but is developing safety assessment and inspection technology for the relevant vehicles. This study analyzed the prevention of hydrogen bus accidents' economic effect that arises from the application and development of large-capacity CHSS oil pressure repetition-test assessment technology, hydrogen bus internal chamber pressure transmission and emission volume inspection technology, among various technologies capable of assessing the safety of a hydrogen bus fuel system. To this end, the contingent valuation method (CVM), one of the value evaluation methods of non-market goods, was applied to investigate users' willingness to pay for each inspection technology. The survey for users' willingness to pay was conducted by attaching posters to promote surveys on the internet and within buses to the entire public. As a result of the analysis, the average WTP of the hydrogen bus internal chamber pressure transmission volume inspection technology was 25.3 KRW, the average WTP of the hydrogen bus internal chamber pressure emission volume inspection technology was 18.6 KRW, and the average WTP of the large-capacity CHSS oil pressure repetition-test assessment technology was measured at 16.7 KRW. In addition, the costs and benefits of the introduction of the relevant inspection technology were defined through the interviewing of experts at related research institutions and businesses. As a result of conducting an economic analysis (4.5% discount rate) according to the development of each inspection technology, economic feasibility was seen in all assessment and inspection technologies. As much as the technology is indispensable for the safe use of hydrogen buses, it shows that investment in related technology is very necessary in the future. However, because it was decided that the relevant analysis will differ according to the distribution rate of hydrogen buses, further analysis following this future distribution rate of hydrogen buses is needed, and future users should be made clearly aware of the safety and environmental nature of the technology.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.5
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• pp.497-504
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• 2023

This study analyzes pressure distribution and pressure drop in the receptacle used in charging system of hydrogen fuel cell vehicles. The objective is to minimize receptacle-induced pressure drop by redesigning internal flow channels. Through numerical simulations, three receptacle variants are compared with a baseline case. Results show reduced pressure drop in the filter section. However, the check valve section exhibits higher pressure drop, requiring further improvement. By increasing throat diameter, pressure drop is decreased by 28% between inlet and outlet of the receptacle. This study shows the relationship between dynamic pressure and pressure drop, providing a guideline for receptacle performance optimization. The redesigned receptacle offers potential for enhancing hydrogen charging efficiency.

• Transactions of the Korean hydrogen and new energy society
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• v.35 no.3
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• pp.280-289
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• 2024

In this study, a cryogenic vessel was constructed to maintain and control the safe pressure of liquid hydrogen boil-off gas (BOG), and the numerical analysis was conducted on the development of computational fluid dynamics model inside the high-pressure vessel. An evaluation system was constructed using cryogenic inner and outer containers, pre-cooler, upper flange, and internal high-pressure container. We attempted to analyze the performance of the safety valve by injecting relatively high temperature hydrogen gas to generate BOG gas and quickly control the pressure of the high-pressure vessel up to 10 bar. As a results, the liquid volume fraction decreased with a rapid evaporation, and the pressure distribution increased monotonically inside a high pressure vessel. Additionally, it was found that the time to reach 10 bar was greatly affected by the filling rate of liquid hydrogen.

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.627-631
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• 1992

A simple one dimensional model was proposed to describe a hydrogen bonding in crystals, which was based on the Lippincott's empirical potential. The model was used to calculate internal stretching vibrational frequencies of $NH_4I$ crystal at high pressures. The calculated results were in agreement with Raman experimental results qualitatively. At relatively lower high pressures, as pressure increases internal stretching vibrational frequencies shift lower due to increase of the hydrogen bonding effect. At higher pressures, the frequencies shift higher due to the repulsive contribution of interatomic potential induced by the reduction of interatomic distance as pressure increases.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.7
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• pp.28-33
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• 2022

In this study, we analyze the flow characteristics according to the internal shape of a 700bar hydrogen charging gun for hydrogen electric vehicles. When charging hydrogen, it receives a high-pressure charging pressure. At this time, we analyze the flow characteristics according to the shape of the nozzle and find the shape of the nozzle that minimizes energy loss. Ultimately, the optimal design of the nozzle was obtained by comparing the pressure difference between the inlet pressure and outlet pressure under a fixed mass flow condition.

• Journal of ILASS-Korea
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• v.27 no.2
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• pp.84-93
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• 2022

To implement carbon-neutrality in transportation sectors until 2050, hydrogen is considered a promising fuel for internal combustion engines because hydrogen does not contain carbon itself. Although hydrogen does not emit CO₂ emission from its combustion process, the low energy density in a volume unit hinders the adoption of hydrogen. Therefore, the understanding of hydrogen jet behavior and measurement of equivalence ratio must be conducted to completely implement the high-pressure hydrogen direct injection. The main objective of this research is feasibility test of hydrogen local equivalence ratio measurement by laser-induced breakdown spectroscopy (LIBs). To visualize the macroscopic structure of hydrogen jet, high-speed schlieren imaging was conducted. Moreover, LIBs has been adopted to validate the feasibility of hydrogen local equivalence ratio measurement. The hydrogen injection pressure was varied from 4 MPa to 8 MPa and injected in a constant volume chamber where the ambient pressure was 0.5 MPa. The increased injection pressure extends the vertical penetration of hydrogen jet. Due to the higher momentum supply when the injection pressure is high, the hydrogen has easily diffused in all directions. As the laser trigger timing has delayed, the low hydrogen atomic emission was detected due to the longer mixture formation time. Based on equivalence ratio measurement results, LIBs could be applied as a methodology for hydrogen local equivalence ratio measurement.