• Title/Summary/Keyword: Intermediate temperature

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Physical Oceanographic Characteristics between Hawaii and Chuuk Observed in Summer of 2006 and 2007 (2006년과 2007년 여름에 관측한 Hawaii-Chuuk 사이의 물리특성)

  • Shin, Chang-Woong;Kim, Dong-Guk;Jeon, Dong-Chull;Kim, Eung
    • Ocean and Polar Research
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    • v.33 no.spc3
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    • pp.371-383
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    • 2011
  • To investigate the physical characteristics and variations of oceanic parameters in the tropical central North Pacific, oceanographic surveys were carried out in summer of 2006 and 2007. The survey periods were classified by Oceanic Ni$\tilde{n}$o Index as a weak El Ni$\tilde{n}$o in 2006 and a medium La Ni$\tilde{n}$a in 2007. The survey instruments were used to acquire data on CTD (Conductivity Temperature and Depth), XBT (Expendable Bathythermograph), and TSG (Thermosalinograph). The dominant temporal variation of surface temperature was diurnal. The diurnal variation in 2007, when the La Ni$\tilde{n}$a weather pattern was in place, was stronger than that in 2006. Surface salinity in 2006 was affected by a northwestward branch of North Equatorial Current, which implies that the El Ni$\tilde{n}$o affects surface properties in the North Equatorial Current region. Two salinity minimum layers existed at stations east of Chuuk in both year's observations. The climatological vertical salinity section along $180^{\circ}E$ shows that the two salinity minimum layers exist in $2^{\circ}N{\sim}12^{\circ}N$ region, consistent with our observations. Analysis of isopycnal lines over the salinity section implies that the upper salinity minimum layer is from intrusion of the upper part of North Pacific Intermediate Water into the lower part of South Pacific Subtropical Surface Water and the lower salinity minimum layer is from Antarctic Intermediate Water.

A Study on the Thermal-Hydraulic Characteristics of Molten Salt in Minichannels of an Intermediate Heat Exchanger for a Very High Temperature Reactor (VHTR) (초고온원자로 중간열교환기 미니챈널에서의 Molten Salt 열수력 특성 연구)

  • Jeong, Hui-Seong;Hwang, In-Seon;Bang, Kwang-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.12
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    • pp.1093-1099
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    • 2010
  • For Very High Temperature Reactors (VHTR), the designs of the Intermediate Heat Transport Loop (IHTL) and the Intermediate Heat Exchanger (IHX) are particularly difficult because of the high-temperature operation (up to $950^{\circ}C$). In this study, Flinak molten salt, a eutectic mixture of LiF, NaF, and KF (46.5:11.5:42.0 mole %) is considered as the heat transporting fluid in the IHTL. To evaluate the flow and heat transfer performance of the Flinak molten salt in small channels with hydraulic diameters in the millimeter range, a double-pipe heat exchanger was constructed using small-diameter tubes for the heat exchange between the Flinak and the gas flow. The experimental data showed that, for laminar Flinak flow, the measured friction factors were close to the 64/Re curve and the Nusselt numbers were generally between 3.66 and 4.36.

Effect of External and Intramolecular Nucleophiles on Nature of Products of Carboxypeptidase A-Catalyzed Hydrolysis of Esters. Attempted Trapping of Acyl-Enzyme Intermediate (카르복시펩티다제A의 에스테르 가수분해 반응생성물의 종류에 대한 외부 및 분자내 친핵체의 영향. 아실-효소중간체의 포획시도)

  • Junghun Suh;Emil Thomas Kaiser
    • Journal of the Korean Chemical Society
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    • v.22 no.3
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    • pp.164-172
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    • 1978
  • Carboxypeptidase A-catalyzed hydrolysis of ester substrates was carried out at room temperature in the presence of a number of external reagents. If the acyl-enzyme intermediate, an anhydride, is attacked by the external reagents, products formed by trapping at the acyl portion or at the enzyme portion of the anhydride group can be obtained. Examination of the uv/vis spectral properties of the reaction products and of changes in enzyme activity indicated that such trapping reactions did not occur. Also performed was evaluation of enzymatic rate parameters for the the hydrolysis of O-(o-hydroxyphenylacetyl)-L-${\beta}$-phenyllactate. Detection of 2-coumaranone possibly formed by attack of the o-hydroxy group as an intramolecular trapping group at the acyl-enzyme intermediate was tried, but no evidences for the intramolecular trapping reaction were obtained. Failure to trap the intermediate was discussed in terms of steric hindrance imposed on the approach of the trapping reagents to the anhydride group of the acyl-enzyme intermediate and of the fast enzymatic breakdown of the intermediate.

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Joining and properties of electrode for CoSb3 thermoelectric materials prepared by a spark plasma sintering method (방전 플라즈마 소결법을 이용한 CoSb3계 열전재료의 전극 접합 및 특성)

  • Kim, K.H.;Park, J.S.;Ahn, J.P.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.30-34
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    • 2010
  • $CoSb_3$-based skutterudite compounds are promising candidates as thermoelectric (TE) materials used in intermediate temperature region. In this study, sintering of $CoSb_3$ powder and joining of $CoSb_3$ to copper-molybdenum electrode have been simultaneously performed by spark plasma sintering technique. The Ti foil was used for preventing the diffusion of copper into $CoSb_3$ and the Cu : Mo = 3 : 7 Vol. ratio composition was selected by the consideration of thermal expansion coefficients. The insertion of Ti interlayer between Cu-Mo and $CoSb_3$ was effective to join $CoSb_3$ to Cu-Mo by forming an intermediate layer of $TiSb_2$ at the Ti-$CoSb_3$ boundary. However, the formation of TiSb and TiCoSb intermediate layers deteriorated the joining properties by the generation of cracks in the interface of intermediate layer/$CoSb_3$ and intermediate/intermediate layers.

A Study on Spontaneous Ignition of Painting Waste (도장 폐기물의 자연발화에 관한 연구)

  • 최재욱;목연수;옥곤;사공성호
    • Journal of the Korean Society of Safety
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    • v.14 no.2
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    • pp.90-96
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    • 1999
  • The characteristics of spontaneous ignition of painting waste was investigated at constant ambient temperature in oven. As the results of experiments, the spontaneous ignition temperature decreased as the sample vessel became large, and the spontaneous ignition temperature of the sample in small, intermediate and large vessels was $165.5^{\circ}C$, $144.5^{\circ}C$ and $134.5^{\circ}C$ respectively. The apparent activation energy calculated by the Frank-Kamentskii's thermal ignition theory was 34.73 kcal/mol.

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Intermediate Culture of the Scallop, Patinopecten yessoensis in the East Coast of Korea (동해안 참가리비, Patinopecten yessoensis의 중간육성)

  • Park, Young-Je;Rho, Sum;Lee, Jeong-Yong
    • Journal of Aquaculture
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    • v.13 no.4
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    • pp.339-351
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    • 2000
  • Optimal environmental conditions, that sustained fastest growth, lowest mortality and abnormality of the scallop Patinopecten yessoensis, were identified from field experiments undertaken at Chumunjin during 1991-1998. Temperature within the water column 10~30 m depth ranged between 5 and 23$^{\circ}C$; high temperature and daily fluctuation resulted in growth retardation and heavy mortality of the scallop. Optimal salinity range was between 31.5 and 34.5%0 and water transparency 6.0 and 18.1 m, which was significantly affected by phytoplankton density. Chlorophyll concentration ranged between 0.04 and 3.51 f.lgfL. Low temperature and high chlorophyll concentration appear to support faster growth of the scallop. Optimal periods of transplantation for intermediate culture were between mid July and early November: cultured under high density during July-August as a first step and under low density during mid September through early November as a second step. Optimal stocking density in square net cage (<35${\times}$35 em) for intermediate culture was 30-40 individuals per cage for main culture using lantern net and 80 -100 individuals of the size of 1.5 ~ 3.0 em shell height per cage for sowing culture. During the intermediate culture, the highest growth was realized, when the cage was held at water depth between 10 and 15 m. Water depth below 25 m, however, was best to avoid mass mortality during the periods of abnormally high water temperature and high variation of water temperature. The daily growth rate during the intermediate culture was between 0.019~0.381 mm; low in January and February but high in March and April. It is suggested that the main culture is commenced before June under low stocking density to avoid the possibility of mass mortality during summer by high water temperature.

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A Study on Intermediate Layer for Palladium-Based Alloy Composite Membrane Fabrication (팔라듐 합금 복합막 제조를 위한 Intermediate Layer 연구)

  • Hwang, Yong-Mook;Kim, Kwang-Je;So, Won-Wook;Moon, Sang-Jin;Lee, Kwan-Young
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.458-464
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    • 2006
  • The Pd-Ni-Ag alloy composite membrane using modified porous stainless steel (PSS) as a substrate was prepared by a electroless plating technique. In this work, we have introduced the intermediate layer between Pd-based alloy and a metal substrate. As an intermediate layer, the mixtures of nickel powder and inorganic sol such as $SiO_{2}$ sol, $Al_{2}O_{3}$ sol, and $TiO_{2}$ sol were used. The intermediate layers were coated onto a PSS substrate according to various membrane preparation conditions and then $N_{2}$ fluxes through the membranes with different intermediate layers were measured. The surface morphology of the intermediate layer in the mixture of nickel powder and inorganic sol was analyzed using scanning electron microscope (SEM). Finally, the Pd-Ni-Ag alloy composite membrane using the support coated with the mixture of nickel powder and silica as an intermediate layer was fabricated and then the gas permeances for $H_{2}$ and $N_{2}$ through the Pd-based membrane were investigated. The selectivity of $H_2/N_2$ was infinite and the $H_{2}$ flux was $1.39{\times}10^{-2}mol/m^2{\cdot}s$ at the temperature of $500^{\circ}C$ and trans-membrane pressure difference of 1 bar.

Electrical Properties in GDC (Gd2O3-Doped CeO2)/LSCF (La0.6Sr0.4Co0.2Fe0.8O3) Cathode Composites for Intermediate Temperature Solid Oxide Fuel Cells

  • Lee, Hong-Kyeong;Hwang, Jin-Ha
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.110-115
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    • 2011
  • $Gd_2O_3$-doped $CeO_2$ (GDC) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ (LSCF) composite cathode materials were prepared in order to be applied to intermediate-temperature solid oxide fuel cells. The electrochemical polarization was evaluated using ac impedance spectroscopy involving geometric restriction at the interface between an ionic electrolyte and a mixed-conducting cathode. In order to optimize the cathode composites applicable to a GDC electrolyte, the cathode composites were evaluated in terms of polarization losses with regard to a given electrolyte, i.e., GDC electrolyte. The polarization increased significantly with decreasing temperature and was critically dependent on the compositions of the composite cathodes. The optimized cathode composite was found to consist of GDC 50 wt% and LSCF 50 wt%; the corresponding normalized polarization loss was calculated to be 0.64 at $650^{\circ}C$.

The Hot Deformation Behaviors of Intermediate Thermo-Mechanical Treated Al-Li Based Alloy (중간가공열처리한 AI-Li계 합금의 고온변형거동)

  • Yoo, C.Y.;Jin, Y.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.3
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    • pp.1-6
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    • 1991
  • In this study, intermediate thermo-mechanical treated Al-2.0 wt%Li, and Al-2.0 wt%Li-1.2 wt%Cu-1.0 wt%Mg-0.12 wt%Zr alloys were tested in tension at $10^{\circ}C$ and elevated temperature(100, 200 and $300^{\circ}C$). The results are follows : The tensile strength of Al-Li-Cu-Mg-Zr alloy is the highest but the elongation of Al-Li alloy is the highest(106%) among the all alloys in tension at $300^{\circ}C$. The Portervin-LeChartlier effect is showed in AI-Li-Cu-Mg-Zr alloy at 10 and $100^{\circ}C$, because of tangled dislocation by Mg and Cu. In the true stress-strain curves of all alloy, the peaks of stress at $300^{\circ}C$ are showed at the strain less than 0.1. In the binary alloy, the dynamic restoration process at 200 and $300^{\circ}C$ is nearly similar to dynamic recovery type. The hot deformation stress is decreased with increase of dynamic recovery degree, but the elongation is increased. When the strain the strain rate are constant, the temperature dependence of hot deformation stress is increased with increase of deformation temperature. The elongation and degree of dynamic recovery are decreased with increase of hot deformation activation energy, but the deformation stresses slightly increased.

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