• 제목/요약/키워드: Intermediate phase

검색결과 492건 처리시간 0.033초

BSCCO 초전도 전구체의 합성 (Fabrication of BSCCO High Tc Superconducting Precursor)

  • 이상헌;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.1964-1965
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_Y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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BSCCO 초전도 전구체의 합성 (Fabrication of BSCCO High Tc Superconducting Precursor)

  • 이상헌
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.290-291
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_Y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h. the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factor in determining whether it is easy to form the high Tc phase or not. because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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열분해법에 의한 고온 초전도 합성 (Fabrication of High Tc Superconductor Using Thermal Pyrolysis)

  • 이상헌
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.85-86
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    • 2006
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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열분해법에 의한 초전도체의 전기적 특성 (Electric Perperties of Superconductor Using Pyrolysis Methods)

  • 이상헌;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.79-80
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    • 2005
  • The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important fact in determining whether it is easy to form the superconducting phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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유기금속염을 이용한 전력 전송용 YBCO 초전도 전구체 합성 (Synthesis of YBCO Superconducting Precursor using Organic metal salts method for Electric power transmission)

  • 이상헌
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.1966-1967
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    • 2005
  • The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important fact in determining whether it is easy to form the superconducting phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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Optical Phase Properties of Small Numbers of Nanoslits and an Application for Higher-efficiency Fresnel Zone Plates

  • Kim, Hyuntai;Lee, Seung-Yeol
    • Current Optics and Photonics
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    • 제3권4호
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    • pp.285-291
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    • 2019
  • We have studied the behavior of light in the intermediate regime between a single nanoslit and an infinite nanoslit array. We first calculated the optical characteristics of a small number of nanoslits using finite element numerical analysis. The phase variance of the proposed nanoslit model shows a gradual phase shift between a single nanoslit and ideal nanoslit array, which stabilizes before the total array length becomes ${\sim}0.5{\lambda}$. Next, we designed a transmission-enhanced Fresnel zone plate by applying the phase characteristics from the small-number nanoslit model. The virtual-point-source method suggests that the proposed Fresnel zone plate with phase-invariant nanoslits achieves 2.34x higher transmission efficiency than a conventional Fresnel zone plate. Our report describes the intermediate behaviors of a nanoslit array, which could also benefit subwavelength metallic structure research of metasurfaces.

입자 응집이 중기/말기 미구조에 미치는 영향 (Particle Agglomerate Effect on Intermediate/Final Microstructure)

  • 손영돈;전병세
    • 한국세라믹학회지
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    • 제29권11호
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    • pp.843-850
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    • 1992
  • The purpose of this study was to describe the heterogeneity effects on Intermediate/Final microstructure in isothermal liquid phase sintering. Several kinds of pore shapes were made by the different in the heterogeneity stress level during Intermediate/Final stage. Specimen with 48% green density especially showed that the local regions of a sintered compact were subject to more rapid shrinkage than the surroundings. This densification limiting factors generally inhibited sintering and made the large isolated crack-like pore in heterogeneous microstructures.

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열분해법에 의한 전력기기용 초전도 합성 기술에 관한 연구 (A Study on the Fabrication of Superconductor Using Pyrolysis Methods for Electric power Machinery)

  • 이상헌;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.153-154
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_Y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at 120$^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at 400$^{\circ}C$ and calcination at 840$^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

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유기금속염을 이용한 고효율 전력 전송용 초전도 전구체 합성 (Synthesis of high functional Superconducting Precursor using Organic metal salts method for Electric power transmission)

  • 이상헌
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.270-271
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    • 2005
  • A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_Y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not. because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

  • PDF