• Title/Summary/Keyword: Intermediate phase

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Simulation and randomized measurement of topological phase on a trapped-ion quantum computer

  • Cheong Eung Ahn;Gil Young Cho
    • Journal of the Korean Physical Society
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    • v.81
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    • pp.258-266
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    • 2022
  • Noisy intermediate scale quantum (NISQ) computers are a promising platform for studying many-body quantum states, such as interacting topological states. Here we prepare a one-dimensional bosonic symmetry-protected topological (SPT) phases using variational quantum eigensolver (VQE) algorithms, and demonstrate the randomized measurement of the corresponding many-body topological invariant, on a trapped-ion quantum computer. We show that the randomized measurement protocol is applicable in real machines, with the dominant error arising from the imperfect preparation of the quantum states.

Effect of Difference in Mixing Methods of Zirconia on Mechanical Properties of ZTA (ZrO2의 혼합방법 차이가 ZTA의 기계적 물성에 미치는 영향)

  • Sohn, Jeongho
    • Korean Journal of Materials Research
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    • v.23 no.11
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    • pp.625-630
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    • 2013
  • In this study, intermediate-mixed powders were prepared by loading zirconia powders initially in a ball-mill jar and loading alumina powders afterward; the initial-mixed powders were produced by loading zirconia and alumina powders together in the ball-mill jar. The effect of such differences in mixing method on the mechanical properties was investigated. In intermediate-mixed powders, the volume fraction of large particles slightly increased and, simultaneously, zirconia particles formed agglomerates that, due to early ball-mill loading of the zirconia powders only, were more dispersed than were the initial-mixed powders. For the intermediate-mixed powders, zirconia agglomerates were destroyed more quickly than were initial-mixed powders, so the number of dispersed zirconia particles rose and the inhibitory effect of densification due to the addition of a second phase was more obvious. In the microstructure of intermediate-mixed powders, zirconia grains were homogeneously dispersed and grain growth by coalescence was found to occur with increasing sintering temperature. For the initial-mixed powders, large zirconia grains formed by localized early-densification on the inside contacts of some zirconia agglomerates were observed in the early stages of sintering. The intermediate-mixed powders had slightly lower hardness values as a whole but higher fracture toughness compared to that of the initial-mixed powders.

Implementation and Analysis of Optimizers on Tuple codes (튜플 코드 상에서의 최적화기 구현과 분석)

  • 송진국
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.3 no.4
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    • pp.723-736
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    • 1999
  • Code optimization phase in a compiler are very important because the phase reduces the running time and the storage size of machine codes. I developed flow analyzers and optimizers on intermediate codes. The flow analyzers generate control-flow and data-flow information. The optimizers transform the intermediate codes into the improved codes using this information. This paper describes the development of flow analyzers and optimizers. I also examined the execution performance, the cost and the dependency of each optimization.

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Wake Flow Control by Acoustic Perturbation (음향섭동에 의한 후류유동의 제어)

  • 이종춘
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.4
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    • pp.451-459
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    • 1998
  • THe influence of internal acoustic exitation through a square prism on the turbulent wake flow characteristics was investigated. The intermediate wake region where is about ten times the respective length of the body was experimentally investigated using a conditional phase average technique. At first the static base pressures of square prism and the shedding frequencies have been measured at various internal acoustic exciation frequencies. The experiment were performed under the four cases of internal acoustic excitation frequencies 0Hz 30Hz($St_e$=0.09) 65Hz($St_e$=0.20) 120Hz($St_e$=0.38) And velocity vector fields were presented and discussed. The influence of acoustic exvitation frequencies on the structure of intermediate turbulent wake region is evident. As the internal acoustic frequency increased shedding frequency gradually increased and aerodynamic force decreased. Also it was found that the vortex shedding occurs dratically well and shedding frequency reached nearly the same value as the internal acoustic frequency. but above Strouhal number 0.3 the influence disappeared.

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Theoretical Studies on the Gas-Phase Pyrolysis of Carbonate Esters, Hydroxy-Esters and -Ketones

  • Lee, Ik-Choon;Cha, Ok-Ja;Lee, Bon-Su
    • Bulletin of the Korean Chemical Society
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    • v.12 no.1
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    • pp.97-101
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    • 1991
  • Gas-phase pyrolyses of carbonate esters, ${\alpha}$- and ${\beta}$-hydroxy esters and ${\beta}$-hydroxy ketones have been studied theoretically by the AM1 MO method. Carbonate esters were found to decompose by two types of processes; in the reaction pathway involving an intermediate, the decomposition of the intermediate was rate-limiting, but direct pyrolyses were also possible via a six-membered cyclic transition state in which the methoxy oxygen attacks a hydrogen atom on the ${\beta}$-carbon. The hydroxy esters and ketones were found to decompose in a concerted process involving a six-membered cyclic transition state. Successive methylation on the ${\alpha}$- and ${\gamma}$-carbon led to an increase in the reactivity in agreement with experiments.

Theoretical Studies on Gas-Phase Reactions of Negative Ions with Alkyl Nitrites

  • Park, Hyeong Yeon;Kim, Chan Gyeong;Lee, Bon Su;Lee, Hae Hwang;Lee, Ik Chun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.8
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    • pp.823-827
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    • 2000
  • Gas-Phase reactions of methyl and ethyl nitrites with anionic nucleophiles of SH-, F- and OH- are investigated theoretically at the MP2/6-311+G* level. The SN2 processes are all highly exothermic and proceed with a typ-icaI double-weIl reaction coordinate profile. The elimination reactions of methyl nitrite with SH- and F- are double-well energy surface processes,with stabilizedproduct complexes of NO-...H2S and NO-...HF, pro-ceeding by an E1 cb-like E2 mechanism. The $\beta-elimination$ of ethyl nitrite is an E2 type process. The $\alpha-elimi-nation$ reactions of methyl and ethyl nitrites with OH- have triple-well energy profiles of Elcb pathway with an $\alpha-carbanion$ intermediate which is stabilized bythe vicinal $nc\alpha-{\sigma}*o-N$ charge transfer interactions. CompIex-ation ofmethyl carbanion with HF seems to provide a stable intermediate within a triple-well energy profile of El cb channel in the reaction of F- with methyl nitrite.

Sequential conversion from line defects to atomic clusters in monolayer WS2

  • Gyeong Hee Ryu;Ren-Jie Chan
    • Applied Microscopy
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    • v.50
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    • pp.27.1-27.6
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    • 2020
  • Transition metal dichalcogenides (TMD), which is composed of a transition metal atom and chalcogen ion atoms, usually form vacancies based on the knock-on threshold of each atom. In particular, when electron beam is irradiated on a monolayer TMD such as MoS2 and WS2, S vacancies are formed preferentially, and they are aligned linearly to constitute line defects. And then, a hole is formed at the point where the successively formed line defects collide, and metal clusters are also formed at the edge of the hole. This study reports a process in which the line defects formed in a monolayer WS2 sheet expends into holes. Here, the process in which the W cluster, which always occurs at the edge of the formed hole, goes through a uniform intermediate phase is explained based on the line defects and the formation behavior of the hole. Further investigation confirms the atomic structure of the intermediate phase using annular dark field scanning transition electron microscopy (ADF-STEM) and image simulation.

Reactivity and Suitability of t-Boc-protected Thiophosphotyrosine Intermediate Analogs for the Solid or Solution Phase Peptide Synthesis

  • Kim, Eun-Kyung;Choi, Hee-Sung;Lee, Eung-Seok
    • Archives of Pharmacal Research
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    • v.21 no.3
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    • pp.330-337
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    • 1998
  • N-(tert-Butoxycarbonyl)-O-(dimethythiophosphono)-L-tyrosine (6) and N-(tert-butoxycarbonyl)-O-(dicyanoethylthiophosphono)-L-tyrosine (15) were prepared as intermediates for the synthesis of thiophosphotyrosine-containing peptides. The reactivity and suitability of two compounds for the solid phase or solution phase peptide synthesis utilizing t-Boc chemistry were examined.

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Planar Active Rectrodirective Array With Subharmonic Phase Conjugation Mixers

  • Kim Gi-Rae;Park Ji-Yong
    • Journal of information and communication convergence engineering
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    • v.2 no.3
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    • pp.153-156
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    • 2004
  • A planar active retrodirective four-element array with subharmonic phase conjugation mixers based on anti-parallel diode pairs (APDPs) is proposed. As compared to previous phase conjugation mixers using twice RF frequency for LO frequency, the proposed conjugation mixers need only half RF frequency so that it can be easily applied for millimeter-wave applications. Receiving, transmitting, local oscillator, and intermediate frequencies are 5.79, 5.81, 2.9 GHz, and 10 MHz. Monostatic RCS and Bistatic RCS measurements at source locations of $0^{\circ},\;-20^{\circ},\;and\;28^{\circ}$ show good agreement with the calculated data.

Formation of Icosahedral Phase in Bulk Glass Forming Ti-Zr-Be-Cu-Ni Alloy

  • Park, Jin Man;Lee, Jun Hyeok;Jo, Mi Seon;Lee, Jin Kyu
    • Applied Microscopy
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    • v.45 no.2
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    • pp.58-62
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    • 2015
  • Formation of an icosahedral phase in the bulk glass forming $Ti_{40}Zr_{29}Be_{14}Cu_9Ni_8$ alloy during crystallization from amorphous phase and solidification from melt is investigated. The icosahedral phase with a size of 10 to 15 nm forms as a thermodynamically stable phase at intermediate temperature during the transformation from amorphous to crystalline phases such as Laves and ${\beta}$-(Ti-Zr) phases, indicating that the existence of the icosahedral cluster in the undercooled liquid. On the other hand, the icosahedral phase forms as a primary solidification phase even though the Laves phase is stable at high temperature, which is can be explained based on the high nucleation rate of icosahedral phase relative to that of competing crystalline Laves phase due to lower interfacial energy between icosahedral and liquid phases.