• Title/Summary/Keyword: Intermediate flow

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Analysis of the statistical properties for the background fractures in the LILW disposal site of Korea (중.저준위 방사성폐기물 처분 부지 내 배경 단열의 통계적 특성 분석)

  • Ji, Sung-Hoon;Park, Kyung-Woo;Kim, Kyoung-Su;Kim, Chun-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.4
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    • pp.257-263
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    • 2008
  • We analyzed the statistical properties for the conductive background fractures in the Low and Intermediate Level Waste(LILW) disposal site to conceptualize of its groundwater flow system. The background fractures were classified to fracture sets based on their trends and plunges that were obtained from the borehole logging data, and then the fracture transmissivity distribution was inferred from the fixed interval hydraulic test results. The fracture size distribution of each fracture set was estimated using the fracture density and fracture mapping data. To verify the analyzed results, we compared observed field data to simulated one from the DFN model that was constructed with the analyzed statistical properties of the background fractures, and they showed a good agreement.

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Tetramethyl orthosilicate(TMOS) Synthesis by the Copper-Catalyzed Reaction of the Metallic Silicon with Methanol (II) - The Kinetics of the Copper-Catalyzed Reaction of Silicon with Methanol - (구리 촉매하에서 규소와 메탄올의 반응에 의한 Tetramethyl orthosilicate(TMOS) 합성(제2보) - 구리촉매하에서 규소와 메탄올과의 반응의 반응속도론 -)

  • Soh, Soon-Young;Won, Ho-Youn;Chun, Yong-Jin;Lee, Bum-Jae;Yang, Hyun-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.259-262
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    • 1999
  • The copper-catalyzed reaction of silicon with methanol was carried out in a mixed bed reactor to obtain tetramethyl orthosilicate (TMOS). In order to determine the kinetics of the reaction per active site on the silicon surface, a flow rate transition technique was employed. A kinetic study showed the reaction was in Linear relationship with the amount of contact mass and independent on the concentration of methanol. This result indicated that the rate-determining step was not the chemical process involving methanol, but the formation of silicon intermediate on the contact mass. On the basis of optimum experimental conditions, the maximum TMOS formation rate per g-silicon is 0.030 (g/min) at $210^{\circ}C$, in which activation energy was 8.5 kcal/mol and reaction rate equation was $k=4.09{\times}10^4\;exp$ ($-4.73{\times}10^3/T$).

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Effect of B2O3 Additives on GaN Powder Synthesis from GaOOH (GaOOH로부터 GaN 분말의 합성에 미치는 B2O3의 첨가효과)

  • Song, Changho;Shin, Dongwhee;Byun, Changsob;Kim, Seontai
    • Korean Journal of Materials Research
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    • v.23 no.2
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    • pp.104-111
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    • 2013
  • In this study, GaN powders were synthesized from gallium oxide-hydroxide (GaOOH) through an ammonification process in an $NH_3$ flow with the variation of $B_2O_3$ additives within a temperature range of $300-1050^{\circ}C$. The additive effect of $B_2O_3$ on the hexagonal phase GaN powder synthesis route was examined by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Fourier transformation infrared transmission (FTIR) spectroscopy. With increasing the mol% of $B_2O_3$ additive in the GaOOH precursor powder, the transition temperature and the activation energy for GaN powder formation increased while the GaN synthesis limit-time ($t_c$) shortened. The XPS results showed that Boron compounds of $B_2O_3$ and BN coexisted in the synthesized GaN powders. From the FTIR spectra, we were able to confirm that the GaN powder consisted of an amorphous or cubic phase $B_2O_3$ due to bond formation between B and O and the amorphous phase BN due to B-N bonds. The GaN powder synthesized from GaOOH and $B_2O_3$ mixed powder by an ammonification route through ${\beta}-Ga_2O_3$ intermediate state. During the ammonification process, boron compounds of $B_2O_3$ and BN coated ${\beta}-Ga_2O_3$ and GaN particles limited further nitridation processes.

The Role of Cognitive Absorption as a Mediating Variable in Virtual Community (가상공동체에서 매개 변수로서의 몰입의 역할)

  • Kim, Jin-Hwa;Byun, Hyun-Soo
    • Information Systems Review
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    • v.6 no.2
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    • pp.47-63
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    • 2004
  • As Internet usages proliferate, the interests on cyber space and virtual community increase. The purpose of this study is to find the role of cognitive absorption as an intermediate variable. It is a variable that links factors that affect on members' usage of virtual community and cognitive absorption. The result of this study shows that challenges, skills, perceived reality, and needs affect the usage of virtual community through cognitive absorption, while only interactivity affects the usage of virtual community directly. This shows that cognitive absorption plays an important role in the usage of virtual community. The major contribution in this study is that cognitive absorption influences on the usage of virtual community greatly. If there is a way to increase the intensity of cognitive absorption, it will strongly help increase the performance of virtual community.

POLYCHLORINATED NAPHTHALENE (PCN) AND DIBENZOFURAN (PCDF) CONGENER PATTERNS FROM PHENOL PRECURSORS IN THERMAL PROCESS: [I] A PRIORI HYPOTHESIS OF PCN AND PCDF FORMATION PATHWAYS FROM MONOCHLOROPHENOLS

  • Ryu, Jae-Yong;Kim, Do-Hyong;Choi, Kum-Chan;Suh, Jeong-Min
    • Environmental Engineering Research
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    • v.11 no.4
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    • pp.217-231
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    • 2006
  • The gas-phase formation of polychlorinated naphthalenes (PCNs) and dibenzofurans (PCDFs) was experimentally investigated by slow combustion of the three chlorophenols (CPs): 2-chlorophenol (2-CP), 3-chlorophenol (3-CP) and 4-chlorophenol (4-CP), in a laminar flow reactor over the range of 550 to $750^{\circ}C$ under oxidative condition. Contrary to the a priori hypothesis, different distributions of PCN isomers were produced from each CP. To explain the distributions of polychlorinated dibenzofuran (PCDF) and PCN congeners, a pathway is proposed that builds on published mechanisms of PCDF formation from chlorinated phenols and naphthalene formation from dihydrofulvalene. This pathway involves phenoxy radical coupling at unsubstituted ortho-carbon sites followed by CO elimination to produce dichloro-9, 10-dihydrofulvalene intermediates. Naphthalene products are formed by loss of H and/or Cl atoms and rearrangement. The degree of chlorination of naphthalene and dibenzofuran products decreased as temperature increased, and, on average, the naphthalene congeners were less chlorinated than the dibenzofuran congeners. PCDF isomers were found to be weakly dependent to temperature, suggesting that phenoxy radical coupling is a low activation energy process. Different PCN isomers, on the other hand, are formed by alternative fusion routes from the same phenoxy radical coupling intermediate. PCN isomer distributions were found to be more temperature sensitive, with selectivity to particular isomers decreasing with increasing temperature.

THE EFFECT OF ADHESIVE CURING TIMING ON THE DIRECTION OF POLYMERIZATION SHRINKAGE OF COMPOSITE RESIN (상아질 접착제의 중합 시간 조절에 따른 복합레진의 중합 수축 방향의 변화)

  • 배지현;오명환;김창근;손호현;엄정문;조병훈;권혁춘
    • Restorative Dentistry and Endodontics
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    • v.26 no.4
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    • pp.316-325
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    • 2001
  • The purpose of this study was to evaluate the effect of adhesive curing timing on the direction of polymerization shrinkage of light-curing composite resin. In this study, the curing times of adhesive and composite resin were measured by differential scanning calorimeter(DSC). 28 extracted human molars were embedded in clear resin and box-type cavities were prepared. Based on DSC data, the experimental teeth were divided into 4 groups. Group 1: no bond; Group 2: late curing; Group 3: Intermediate curing; Group 4: Early curing. After treating with adhesive, the buccal cavities were filled with Z-100 hybrid composite resin and the lingual ones were filled with AEliteflo flowable composite resin. The depressions at the surface were measured by surface profilometer, then the specimens were embedded in clear resin and sectioned. Impressions were obtained and used to get epoxy resin replicas. The epoxy replicas were gold-coated and observed under SEM. Average Maximum Gap(AMG), Gap Proportion(GP), Average Marginal Index(AMI) were used to compare the shrinkage gap of each group. The results were statistically analyzed using the Kruskal-Wallis One Way ANOVA, Student-Newman-Keuls method. The results of this study were as follows. 1. Average Maximum Gap, Gap Proportion, Average Marginal Index and depression at the surface or Z-100 hybride composite resin were smaller than those of AEliteflo flowable composite resin(P<0.05). 2. When the bonding between composite resin and tooth structure was strong, the shrinkage gap was small, and depression at the surface was deep(P<0.05). 3. In the well-bonded group, light-curing composite resin shrank toward bonded cavity wall, not toward light source. The result suggested that the direction of polymerization shrinkage was affected by the quality of bonding in the dentin-resin interface. The strong was the bonding between composite resin and tooth structure, the smaller was the gap and the deeper was the depression at the surface. Then the flow to compensate the polymerization shrinkage proceeded from surface to bonded cavity wall.

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Fundamental Properties of Recycled Cold Asphalt Mixtures with Recycled Sludge and Recycled Glass Aggregate (순환 슬러지 및 순환 유리골재를 사용한 순환 상온아스팔트 혼합물의 기초특성)

  • Lee, Hoo-Seok;Kang, Suk-Pyo;Kang, Hye-Ju;Lee, Min-Hi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.302-309
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    • 2020
  • This paper is a basic study for applying the dried recycled sludge of waste sludge generated in construction waste intermediate treatment facility and the crushed recycled glass aggregate of waste glass bottles that cannot be recycled to the recycled cold asphalt mixtures. This paper reviewed the characteristics of recycled cold asphalt mixtures using recycled sludge and recycled glass aggregate. As a result, as contents of recycled sludge and recycled glass aggregate increased, the Marshall stability, indirect tensile strength, and tensile strength ratio of the recycled cold asphalt mixtures decreased, but flow and void ratio of that increased.

Structure Hierarchic of the Intra-East Asia Direct Investment Flows (동아시아 역내 직접투자 흐름의 계층성)

  • 문남철
    • Journal of the Economic Geographical Society of Korea
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    • v.6 no.2
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    • pp.355-375
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    • 2003
  • Since the mid 1980s, the emergence of the Newly Industrialized Countries has been the most remarkable mutation in the foreign direct investment. This emergence is creating the new international spacial flows constituted by the developed country, the newly industrialized country and the developing country. According to the active foreign direct investment of the Asia Newly Industrialized Countries (ANICs) into East Asia from the middle of the 1980s, the intra-East Asia direct investment flow has a observable structure hierarchic composed of Japan, ANICs, ASEAN and China. In the inflow of intra-East Asia direct investment, Japan and ANICs flows from the extra-developed country and Japan, AESAN from ANICs, Japan, and China from the ANICs. In the outflow, Japan flows relatively into the ANICs and ASEAN, ANICs into ASEAN and China, ASEAN and China into the ANICs. In conclusion, the emergence of ANICs and theirs role intermediate in the East Asian economy causes the intra-East Asia direct investment flows to make a hierarchical structure.

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A Study on Deep Geothermal Energy and Potential of Geothermal Power Generation in Mongolia (몽골의 심부 지열에너지 자원과 지열발전에 관한 연구)

  • Hahn, Jeong-Sang;Yoon, Yun-Sang;Kiem, Young-Seek;Hahn, Chan;Park, Yu-Chul;Mok, Jong-Gu
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.8 no.3
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    • pp.1-11
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    • 2012
  • Mongolia has three(3) geothermal zones and eight(8) hydrogeothermal systems/regions that are, fold-fault platform/uplift zone, concave-largest subsidence zone, and mixed intermediate-transitional zone. Average temperature, heat flow, and geothermal gradient of hot springs in Arhangai located to fold-fault platform/uplift zone are $55.8^{\circ}C$, 60~110 mW/m2 and $35{\sim}50^{\circ}C/km$ respectively and those of Khentii situated in same zone are $80.5^{\circ}C$, 40~50 mW/m2, and $35{\sim}50^{\circ}C/km$ separately. Temperature of hydrothermal water at depth of 3,000 m is expected to be about $173{\sim}213^{\circ}C$ based on average geothermal gradient of $35{\sim}50^{\circ}C/km$. Among eight systems, Arhangai and Khentii located in A type hydrothermal system, Khovsgol in B type, Mongol Altai plateau in C type, and Over Arhangai in D type are the most feasible areas to develop geothermal power generation by Enhanced Geothermal System (EGS). Potential electric power generation by EGS is estimated about 2,760 kW at Tsenher, 1,752 kW at Tsagaan Sum, 2,928 kW at Khujir, 2,190 kW at Baga Shargaljuut, and 7,125 kW at Shargaljuut.

ACCRETION-JET MODEL FOR THE HARD X-ray Γ - LX CORRELATION IN BLACK HOLE X-ray BINARIES

  • YANG, QI-XIANG;XIE, FU-GUO;YUAN, FENG;ZDZIARSKI, ANDRZEJ A.;GIERLINSKI, MAREK;HO, LUIS C.;YU, ZHAOLONG
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.565-568
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    • 2015
  • In this work, we study the correlation between the photon index (${\Gamma}$) of the X-ray spectrum and the 2-10 keV X-ray luminosity ($L_X$) for black hole X-ray binaries (BHBs). The BHB sample is mainly from the quiescent, hard and intermediate states, with values of $L_X$ ranging from ${\sim}10^{30.5}$ to $10^{37.5}$ erg $s^{-1}$. We find that the photon index ${\Gamma}$ is positively or negatively correlated with the X-ray luminosity $L_X$, for $L_X$ above or below a critical value, ${\sim}10^{36.5}$ erg $s^{-1}$. This result is consistent with previous works. Moreover, when $L_X{\leq}{\sim}10^{33}$ erg $s^{-1}$, we found that the photon index is roughly independent of the X-ray luminosity. We interpret the above correlations in the framework of a coupled hot accretion flow - jet model. Besides, we also find that in the moderate-luminosity region, different sources may have different anti-correlation slopes, and we argue this diversity is caused by the different value of ${\delta}$, which describes the fraction of turbulent dissipation that directly heats electrons.