• Title/Summary/Keyword: Intermediate complex

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Solid Lubrication Characteristics of DLC Coated Alumina Seals in High Temperature

  • Ok, Chul-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.356-356
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    • 2007
  • Plasma immersion ion beam deposition (PIIBD) technique is a cost-effective process for the deposition of diamond like carbon thin film, the possible solid lubricant on large surface and a complex shape. We used PIIB process for the preparation of DLC thin film on $Al_2O_3$ with deposition conditions of deposition temperature range $200^{\circ}C$, working gas pressure of 1.310-1Pa. DLC thin films were coated by $C_2H_2$ ion beam deposition on $Al_2O_3$ after the ion bombardment of SiH4 as the bonding layer. Energetic bombardment of $C_2H_2$ ions during the DLC deposition to ceramic materials generated mixed layers at the DLC-Si interface which enhanced the interface to be highly bonded. Wear test showed that the low coefficient of friction of around 0.05 with normal load 2.9N and proved the advantage of the low energy ion bombardment in PIIBD process which improved the tribological properties of DLC thin film coated alumina ceramic. Furthermore, PIIBD was recognized as a useful surface modification technique for the deposition of DLC thin film on the irregular shape components, such as molds, and for the improvement of wear and adhesion problems of the DLC thin film, high temperature solid lubricant.

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Maple Syrup Urine Disease : Longterm Diet Therapy and Treatment of Acute Metabolic Decompensation (단풍당뇨증의 식이요법과 급성대상부전의 치료)

  • Lee, Hong-Jin;Bae, Eun-Joo;Park, Won-Il;Lee, Kyung-Ja
    • Journal of The Korean Society of Inherited Metabolic disease
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    • v.3 no.1
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    • pp.4-14
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    • 2003
  • Maple syrup urine disease or branched chain ketoacidurias caused by a deficiency in activity of the branched-chain ${\alpha}$-keto acid dehydrogenase(BCKD) complex. This metabolic block results in the accumulation of the branched-chain amino acids(BCAAs) leucine, isoleucine and valine, and the corresponding branched chain ${\alpha}$-keto acids (BCKAs). Based on the clinical presentation and biochemical responses to thiamine administration, MSUD patients can be divided into five phenotypes : classic, intermediate, intermittent, thiamine responsive and dihydrolipoyl dehydrogenase(E3)-deficient. Classic MSUD has a neonatal onset of encephalopathy, and is the most severe ad most common form. Variant forms of MSUD generally have the initial symptoms by 2 years of age. The majority of untreated classic patients die within the early months of life from recurrent metabolic crisis and neurologic deterioration. Treatment involves both longterm dietary management and aggressive intervention during acute metabolic decompensation. We report here our experience of longterm diet therapy and treatment of acute metabolic decompensation of a case of classic MSUD.

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Main factors determining the shear behavior of interior RC beam-column joints

  • Costa, Ricardo;Providencia, Paulo
    • Structural Engineering and Mechanics
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    • v.76 no.3
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    • pp.337-354
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    • 2020
  • Reinforced concrete beam-column (RCBC) joints of laterally loaded unbraced frames are sometimes controlled by their shear behavior. This behavior relies on multiple and interdependent complex mechanisms. There are already several studies on the influence of some parameters on the shear strength of reinforced concrete joints. However, there are no studies methodically tackling all the most relevant parameters and quantifying their influence on the overall joint behavior, not just on its shear strength. Hence, considering the prohibitive cost of a comprehensive parametric experimental investigation, a nonlinear finite element analysis (NLFEA) was undertaken to identify the key factors affecting the shear behavior of such joints and quantify their influence. The paper presents and discusses the models employed in this NLFEA and the procedure used to deduce the joint behavior from the NLFEA results. Three alternative, or complementary, quantities related to shear are considered when comparing results, namely, the maximum shear stress supported by the joint, the secant shear stiffness at maximum shear stress and the secant shear stiffness in service conditions. Depending on which of these is considered, the lower or higher the relevance of each of the six parameters investigated: transverse reinforcement in the joint, intermediate longitudinal bars and diagonal bars in the column, concrete strength, column axial load and confining elements in transverse direction.

Realization of optical logic gates using photocycle properties of bacteriorhodopsin (박테리아로돕신의 광순환 특성을 이용한 광학적 논리회로 구현)

  • 오세권;유연석
    • Korean Journal of Optics and Photonics
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    • v.13 no.5
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    • pp.414-420
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    • 2002
  • We realized optical logic gates using a bacteriorhodopsin (bR) doped polymer film. The bR undergoes a complex photocycle characterized by several spectroscopically distinct intermediate states. We realized optical logic gates using a He-Ne laser (632.8 nm) and a He-Cd laser (413 nm) that consider B-state and absorption change of M-state in the photocycle of bR. Also, we realized high speed AND logic gate using He-Ne laser (632.8 nm) and the second harmonics at 532 nm from a pulsed Nd-YAG laser that considering absorption spectrum between B-state and K-state.

Factors Affecting Consumer Purchasing Behavior: A Green Marketing Perspective in Vietnam

  • LE, Quang Hung
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.5
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    • pp.433-444
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    • 2021
  • The study seeks to identify the factors affecting the green marketing element of students' food purchasing decision at Co-opMart supermarket chain in Ho Chi Minh City through the application of a mix of qualitative and quantitative research methods that include probability sampling and convenient sampling of 400 students from Ho Chi Minh City University of Technology (HUTECH). The data are analyzed with SPSS software using Cronbach's Alpha, Exploratory Factor Analysis, Multiple Linear Regression and PATH model to test the model through the intermediate variable 'student's perception' and the hypotheses, identifying the green marketing effects on HUTECH students' food purchasing decisions at Ho Chi Minh City Co-opMart supermarket chain. The results of the study identify four factors of the green marketing mix (4Cs), namely, green commodity, green cost, green convenience, and green communication. All these factors have an influence on the student's food purchasing decision at Co-opMart supermarket. Cost is the strongest factor eliciting student's interest in purchasing green products, followed by convenience, then communication. Commodity has the least impact on green purchasing decision. This study proposes some feasible solutions for Co-opMart managers to attract more students using green food in the complex situation of contaminated food, which is extremely harmful to consumers' health.

A Comparative Study on Korean Reading Comprehension by Adjusting Vocabulary Levels (수준별 어휘 조정에 따른 한국어 읽기 텍스트 이해도 비교 연구)

  • Ju, Jae-hwan
    • Journal of Korean language education
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    • v.29 no.4
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    • pp.201-223
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    • 2018
  • The purpose of this study is to observe the effects of text modification by comparing differences in Korean reading comprehension levels that arise from differences in vocabulary levels in texts. This study intends to use simplified texts with the vocabulary difficulty adjusted differently from the original text to measure reading comprehension levels of Korean learners and analyze the result. To measure reading comprehension, the researcher divided 55 Korean learners of intermediate to advanced level of fluency into two groups; the control group read the original text and the treatment group read a simplified text in which complex vocabulary were substituted with easier words of medium difficulty. Then the two groups were tested with the same questionnaire to measure comprehension levels of each group. The result showed that the groups that read simplified texts scored higher than the control group; this suggests that the reading comprehension level was increased in the treatment group. The experiment confirmed that unknown vocabulary density has direct impact on Korean reading comprehension. The result shows that the proportion of unknown vocabulary should be reduced for meaning-focused reading. It also demonstrates that comprehension of the learner was enhanced with lexical simplification rather than structural simplification i.e. simplification of grammar or sentences. Thus, diverse reading materials adjusted to the learners' level of fluency should be developed to enable reading for learning Korean. By reducing the burden of understanding the meaning of each vocabulary, learners will be able to achieve the initial goal of reading.

A Comparative Study on Speech Rate Variation between Japanese/Chinese Learners of Korean and Native Korean (학습자의 발화 속도 변이 연구: 일본인과 중국인 한국어 학습자와 한국어 모어 화자 비교)

  • Kim, Miran;Gang, Hyeon-Ju;Ro, Juhyoun
    • Korean Linguistics
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    • v.63
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    • pp.103-132
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    • 2014
  • This study compares various speech rates of Korean learners with those of native Korean. Speech data were collected from 34 native Koreans and 33 Korean learners (19 Chinese and 14 Japanese). Each participant recorded a 9 syllabled Korean sentence at three different speech rate types. A total of 603 speech samples were analyzed by speech rate types (normal, slow, and fast), native languages (Korean, Chinese, Japanese), and learners' proficiency levels (beginner, intermediate, and advanced). We found that learners' L1 background plays a role in categorizing different speech rates in the L2 (Korean), and also that the leaners' proficiency correlates with the increase of speaking rate regardless of speech rate categories. More importantly, faster speech rate values found in the advanced level of learners do not necessarily match to the native speakers' speech rate categories. This means that learning speech rate categories can be more complex than we think of proficiency or fluency. That is, speech rate categories may not be acquired automatically during the course of second language learning, and implicit or explicit exposures to various rate types are necessary for second language learners to acquire a high level of communicative skills including speech rate variation. This paper discusses several pedagogical implications in terms of teaching pronunciation to second language learners.

Spatial Multilevel Optical Flow Architecture-based Dynamic Motion Estimation in Vehicular Traffic Scenarios

  • Fuentes, Alvaro;Yoon, Sook;Park, Dong Sun
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.12 no.12
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    • pp.5978-5999
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    • 2018
  • Pedestrian detection is a challenging area in the intelligent vehicles domain. During the last years, many works have been proposed to efficiently detect motion in images. However, the problem becomes more complex when it comes to detecting moving areas while the vehicle is also moving. This paper presents a variational optical flow-based method for motion estimation in vehicular traffic scenarios. We introduce a framework for detecting motion areas with small and large displacements by computing optical flow using a multilevel architecture. The flow field is estimated at the shortest level and then successively computed until the largest level. We include a filtering parameter and a warping process using bicubic interpolation to combine the intermediate flow fields computed at each level during optimization to gain better performance. Furthermore, we find that by including a penalization function, our system is able to effectively reduce the presence of outliers and deal with all expected circumstances in real scenes. Experimental results are performed on various image sequences from Daimler Pedestrian Dataset that includes urban traffic scenarios. Our evaluation demonstrates that despite the complexity of the evaluated scenes, the motion areas with both moving and static camera can be effectively identified.

Alkylhydridorhodium(Ⅲ) Route for Isomerization and Hydrogenation of Unsaturated Alcohols with Rh(ClO$_4)(CO)(PPh_3)_2$ and [Rh(CO)(PPh$_3)_3]ClO_4$ under Hydrogen

  • Chin, Chong-Shik;Park, Jeong-Han;Kim, Choon-Gil
    • Bulletin of the Korean Chemical Society
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    • v.10 no.4
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    • pp.360-362
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    • 1989
  • Catalytic isomerization of unsaturated alcohols to the corresponding carbonyl compounds with$Rh(ClO_4)(CO)(PPh_3)_2\;(1)\;and\;[Rh(CO)(PPh_3)_3]ClO_4$ (2) is faster under hydrogen (where hydrogenation also occurs to give saturated alcohols) than under nitrogen. The isomerization under hydrogen seems to occur through an alkylhydridorhodium(III) complex which also undergoes reductive elimination to give hydrogenation products, saturated alcohols. The isomerization under hydrogen is faster with 2 than with 1, which is understood by acceleration of the last step, enol formation by $PPh_3$ dissociated from 2 and present in the reaction mixture when 2 is used as catalyst. Relative rates of the isomerization observed for different unsaturated alcohols are interpreted by steric effects of substituted groups and numbers of hydrogens to be abstracted by the rhodium of the intermediate, alkylhydridorhodium(III) to undergo the reductive elimination to give enol which is then rapidly converted into a carbonyl compound. It has been observed that the hydrogenation is relatively significant when reactions occur slowly whereas the isomerization is predominant when reactions proceed rapidly.

CFD Numerical Calcultion for a Cavity Matrix Combustor Applying Biogas (바이오가스 적용 캐비티 매트릭스 연소기 CFD 수치연산)

  • CHUN, YOUNG NAM;AN, JUNE
    • Journal of Hydrogen and New Energy
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    • v.33 no.5
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    • pp.598-606
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    • 2022
  • With the advancement of industry, the use of various sustainable energy sources and solutions to problems affecting the environment are being actively requested. From this point of view, it is intended to directly burn unused biogas to use it as energy and to solve environmental problems such as greenhouse gases. In this study, a new type of cavity matrix combustor capable of low-emission complete combustion without complex facilities such as separation or purification of biogas produced in small and medium-sized facilities was proposed, and CFD numerical calculation was performed to understand the performance characteristics of this combustor. The cavity matrix combustor consists of a burner with a rectangular porous microwave receptor at the center inside a 3D cavity that maintains a rectangular parallelepiped shape composed of a porous plate that can store heat in the combustor chamber. As a result of numerical calculation, the biogas supplied to the inlet of the combustor is converted to CO and H2, which are intermediate products, on the surface of the 3D matrix porous burner. And then the optimal combustion process was achieved through complete combustion into CO2 and H2O due to increased combustibility by receiving heat energy from the microwave heating receptor.