• Title/Summary/Keyword: Intermediate Layer

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Characterization of Oxide Scales Formed on TiAl-W-Zr Alloys (TiAl-W-Zr 합금에 생성된 고온산화막 분석)

  • Woo Sung-Wook;Lee Dong-Bok
    • Korean Journal of Materials Research
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    • v.14 no.6
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    • pp.394-398
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    • 2004
  • A Ti47Al1.7W-3.7Zr alloy was oxidized between $900^{\circ}C$ and $1050^{\circ}C$, and the oxide scales formed were studied. The oxide scales consisted primarily of an outer$TiO_2$ layer, an intermediate $Al_2$$O_3$-rich layer, and an inner mixed ($TiO _2$ + $Al_2$$O_3$) layer. Besides $TiO_2$ and $Al_2$$O_3$, oxidation led to the formation of some $Ti_2$AlN and TiN. Both W and Zr were preferentially segregated below the intermediate $Al_2$$O_3$-rich layer. Tungsten in the oxide scale was present as $WO_3$ and ${Ti}_{x}$$W_{1-x}$, whereas zirconium as monoclic-$ZrO_2$ and tetragonal-$ZrO_2$.

Phosphate vs. Silicate Discontinuity Layer Developed at Mid-Depth in the East Sea (동해 중층에 발달하는 인산염 대 규산염 비의 불연속층)

  • Kim, Bong-Guk;Lee, Tong-Sup;Kim, Il-Nam
    • Ocean and Polar Research
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    • v.32 no.3
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    • pp.331-336
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    • 2010
  • The CREAMS (Circulation Research of the East Asian Marginal Sea) survey in 1999 revealed a sharp mid-depth discontinuity of the phosphate:silicate ratio in all basins of the East/Japan Sea. Incidentally, this discontinuity layer corresponds to the oxygen minimum layer. Directly below the discontinuity layer, oxygen concentration is increased. This increase in oxygen concentration is interpreted as a proof of intermediate water formation. Oxygen minimum indicates that the water parcel is old and stable against mixing. So it seems be an efficient barrier to vertical exchange of materials. This means that, once materials enter the lower domain, they rarely return to the upper domain. Therefore, the biogeochemistry of the East/Japan Sea depends heavily on material input through the Korea Strait, and flux is expected to be sensitive to the climate change. As a result, the East/Japan Sea ecosystem seems vulnerable to tipping (regime shift), which occurred on a decadal time scale.

General Characteristics of the East Sea Intermediate Water (동해중층수의 일반적인 분포 특성)

  • Shin, Chang-Woong;Byun, Sang-Kyung;Kim, Cheol-Soo;Lee, Jae-Hak;Kim, Bong-Chae;Hwang, Sang-Chull;Seung, Young-Ho;Shin, Hong-Ryeol
    • Ocean and Polar Research
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    • v.29 no.1
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    • pp.33-42
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    • 2007
  • To obtain the overall distribution patterns and characteristics of the East Sea Intermediate Water (ESIW), the historical data obtained by the Japan Maizuru Marine Observatory (MMO) and the Korea Ocean Research and Development Institute (KORDI) were analyzed. To obtain water characteristics of the ESIW on isopycnal surfaces, temperature, salinity and dissolved oxygen were interpolated at every 0.01 interval of potential density. And then the interpolated values were averaged at the same potential density. This potential density average method preserved the salinity minimum layer more clearly compared to the depth average method. The potential density(${\sigma}_{\theta}$) range of the ESIW was $26.9{\sim}27.3$. The representative potential density of the ESIW was found to be 27.2, because the characteristics of the ESIW was clear at this density. From the horizontal distributions of physical properties on the isopycnal surface of $27.2{\sigma}_{\theta}$ it is suggested that the low salinity ESIW circulates anticlockwise over the whole basin with the high salinity intermediate water. The low salinity intermediate water extended from the northwestern part to the east along the sub-polar front and to the Ulleung Basin along the east coast of Korea.

Wind pressure provisions for gable roofs of intermediate roof slope

  • Stathopoulos, Theodore;Wang, Kai;Wu, Hanqing
    • Wind and Structures
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    • v.4 no.2
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    • pp.119-130
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    • 2001
  • The paper addresses the suitability of wind pressure coefficients specified in contemporary design standards and codes of practice for gable roofs of intermediate slope (roof angle $10^{\circ}-30^{\circ}$). In a recent research study, a series of low building models with different roof slopes in this intermediate range were tested in a boundary layer wind tunnel under simulated open country terrain conditions. This was different from the original study in the 70's, which produced the current provisions on the basis of a model tested only for a single roof slope (4:12) in this range. The results of the study suggest that a modification to the American wind provisions would be warranted to make them more representative of the true local and area-averaged wind loads imposed on gable roofs of intermediate slope.

Improved Carrier Tunneling and Recombination in Tandem Solar Cell with p-type Nanocrystalline Si Intermediate Layer

  • Park, Jinjoo;Kim, Sangho;Phong, Pham duy;Lee, Sunwha;Yi, Junsin
    • Current Photovoltaic Research
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    • v.8 no.1
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    • pp.6-11
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    • 2020
  • The power conversion efficiency (PCE) of a two-terminal tandem solar cell depends upon the tunnel-recombination junction (TRJ) between the top and bottom sub-cells. An optimized TRJ in a tandem cell helps improve its open-circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF), and efficiency (PCE). One of the parameters that affect the TRJ is the buffer layer thickness. Therefore, we investigated various TRJs by varying the thickness of the buffer or intermediate layer (TRJ-buffer) in between the highly doped p-type and n-type layers of the TRJ. The TRJ-buffer layer was p-type nc-Si:H, with a doping of 0.06%, an activation energy (Ea) of 43 meV, an optical gap (Eg) of 2.04 eV, and its thickness was varied from 0 nm to 125 nm. The tandem solar cells we investigated were a combination of a heterojunction with intrinsic thin layer (HIT) bottom sub-cell and an a-Si:H (amorphous silicon) top sub-cell. The initial cell efficiency without the TRJ buffer was 7.65% while with an optimized buffer layer, its efficiency improved to 11.74%, i.e., an improvement in efficiency by a factor of 1.53.

The Effect of Initial DC Bias Voltage on Highly Oriented Diamond Film Growth on Silicon

  • Dae Hwan Kang;Seok Hong Min;Ki Bum Kim
    • The Korean Journal of Ceramics
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    • v.3 no.1
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    • pp.13-17
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    • 1997
  • It is identified that the diamond films grown o bias-treated (100) silicon showed different surface morphologies and film textures according to the initial applied dc bias voltage at the same growth condition. The highly oriented diamond film (HODF) was successfully grown on -200 V bias-treated silicon substrate in which the heteroepitaxial relation of $(100)_{dimond}//(100)_{si}\; and\; [110]_{diamond}//[110]_{si}$ was identified. On the contrary, the heteroepitaxial relation was considerably disturbed in the samples bias-voltage was a key factor in growing the highly oriented diamond film on (100) silicon substrate. Considering the experimental results, we proposed a new model about heteroepitaxial diamond growth on silicon, in which 9 diamond unit cell are matched with 4 silicon cells and the bond covalency of both atoms is satisfied via the intermediate layer at the interface as well.

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An Ocean - Atmosphere Coupled Model for the Study of ENSO (해양-대기 결합수치모형을 이용한 ENSO 연구)

  • 안중배
    • Journal of Environmental Science International
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    • v.3 no.2
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    • pp.129-140
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    • 1994
  • An intermediate atmosphere-ocean coupled model appropnate for the study of El Nino has been developed. The model is not only economic to use but also contains several most important physical processes. The geometrical effects which were not confided in the previous intermediate model study of Ahn (1990), are included in the model for more realistic simulation of the event. The results show that the individual models respond appropriately to the given boundary conditions. At the same time, in the coupled model experiment, ENSO-like oceanic and atmospheric anomalies are also well simulated under an external triggering similar to the initiation forcing of ENSO. It is expected that this type of model can be effectively used for the. study and simulation of El Nido. More improvement of modeling may be Possible after inclusion of subsequent processes such as inclusion of ocean mixed layer dynamics.

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Effect of the additional application of a resin layer on dentin bonding using single-step adhesives (중간층 레진 적용이 단일 접착과정 상아질 접착제의 접착에 미치는 영향)

  • Choi, Seung-Mo;Park, Sang-Hyuk;Choi, Kyung-Kyu;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.32 no.4
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    • pp.313-326
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    • 2007
  • The purpose of this study was to prove that an intermediate resin layer (IRL) oan increase the bond strength to dentin by reducing the permeability of single-step adhesives. Flat dentin surfaces were created on buccal and lingual side of freshly extracted third molar using a low-speed diamond saw under copious water flow. Approximately 2.0 mm thick axially sectioned dentin slice was abraded with wet #600 SiC paper. Three single-step self-etch adhesives; Adper Prompt L-Pop (3M ESPE, St Paul, MN, USA), One-Up Bond F (Tokuyama Corp, Tokyo, Japan) and Xeno III (Dentsply, Konstanz, Germany) were used in this study. Each adhesive groups were again subdivided into ten groups by; whether IRL was used or not; whether adhesives were cured with light before application or IRL or not; the mode of composite application. The results of this study were as follows; 1. Bond strength of single-step adhesives increased by an additional coating of intermediate resin layer, and this increasement was statistically signigicant when self-cured composite was used (p < 0.001). 2. When using IRL, there were no difference on bond strengths regardless the curing procedure of single-step adhesives. 3. There were no significant difference on bond strengths between usage of AB2 or SM as an IRL. 4. The thickness of Hybrid layer was correlated with the acidity of adhesive used, and the nanoleakage represented by silver deposits and grains was examined within hybrid and adhesive layer in most of single-step adhesives. 5. Neither thickness of hybrid layer nor nanoleakage were related to bond strength.

Effects of Stoichiometry on Properties of NiAl Intermetallics coated on Carbon Steel through Combustion Synthesis (연소합성 코팅된 NiAl 금속간화합물의 화학양론이 미끄럼 마모특성에 미치는 영향)

  • Lee, Han-Young;Lee, Jae-Sung
    • Tribology and Lubricants
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    • v.36 no.3
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    • pp.124-132
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    • 2020
  • The effect of the stoichiometry on the sliding wear properties of NiAl coatings has been investigated. Three different powder mixtures with the compositions of Ni-50at%Al, Ni-54at%Al and Ni-42at%Al were diepressed respectively, and which were subsequently coated on mild steel through combustion synthesis in an induction heating system. Sliding wear behavior of the coatings was examined against an alloyed tool steel using a pin-on-disc type sliding wear test machine. As results, it could be seen that powder mixture(Ni-54at%Al) with displaying Al-rich deviations from the stoichiometry of NiAl(Ni-50at%Al) was promoted the most the synthetic reactivity. The microstructure of the coating layer with the compositions of Ni-54at%Al exhibits the porous NiAl single phase structure. However, the microstructure of the coating layer of the compositions of Ni-42at%Al exhibits the denser multi-phase structure containing several intermediate phases in addition to NiAl. Densification of the coating layer was enhanced by increasing the reacting temperature. On the other hand, the wear properties of the coating layers showed that the wear mode at speeds of around 1 m/s was severe wear, regardless of the stoichiometry and reacting temperature. However, wear properties of coating layer with the compositions of Ni-42at%Al were superior to those of coating layer with the compositions of Ni-54at%Al. This would be attributed by the fact that coating layer with the compositions of Ni-42at%Al develops little void and much intermediate phases with high strength.