• Title/Summary/Keyword: Interlayer length

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Deintercalation and Thermal Stability of Na-graphite Intercalation Compounds

  • Oh, Won-Chun
    • Carbon letters
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    • v.2 no.1
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    • pp.22-26
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    • 2001
  • Na alloyed graphite intercalation compounds with stage 1 and 2 were synthesized using the high temperature and pressure technique. Thermal stability and staging transitions of the compounds were investigated depending on heating rates. The thermal stability and temperature dependence of the deintercalation compounds were characterized using differential scanning calorimeter (DSC) analyzer. Enthalpy of formations were confirmed at temperatures between 25 and $500^{\circ}C$, depending on the various heating rates. The structure ions and interlayer spaces of the graphite were identified by X-ray diffraction (XRD). Diffractograms of stages with non-integral (00l) values were obtained in the thermal decomposition process, and stacking disorder defects and random stage modes were observed. The average value of the interlayer C-C bond lengths were found approximately $2.12{\AA}$ and $1.23{\AA}$ from the diffractions. Based on the stage transition, the degree of the deintercalaton has a inverse-linear relationship against the heating rate.

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Hump Characteristics of 64M DRAM STI(Shallow Trench Isolated) NMOSFETs Due to Defect (64M DRAM의 Defect 관련 STI(Shallow Trench Isolated) NMOSFET Hump 특성)

  • Lee, Hyung-J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.291-293
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    • 2000
  • In 64M DRAM, sub-1/4m NMOSFETs with STI(Shallow Trench Isolation), anomalous hump phenomenon of subthreshold region, due to capped p-TEOS/SiN interlayer induced defect, is reported. The hump effect was significantly observed as channel length is reduced, which is completely different from previous reports. Channel Boron dopant redistribution due to the defect should be considered to improve hump characteristics besides consideration of STI comer shape and recess.

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Size and Aspect Ratio Effects on the Magnetic Properties of a Spin-Valve Multilayer by Computer Simulation

  • Lim, S.H.;Han, S.H.;Shin, K.H.;Kim, H.J.
    • Journal of Magnetics
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    • v.5 no.3
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    • pp.90-98
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    • 2000
  • The change in the magnetic properties of a spin-valve multilayer with the structure IrMn (9 m)/CoFe (4 nm)/Cu (2.6 nm)/CoFe (2 nm)/NiEe (6 nm) is investigated as a function of the size and the aspect ratio. At a fixed aspect ratio (the length/width ratio) of 2, the magnetostatic interactions begin to affect the magnetic properties substantially at a spin-valve length of 5 $\mum$, and, at a length of 1 $\mum$, they become even more dominant. In the case of a fixed multilayer size (2.4 $\mum$) which is indicated by the sum of the length and the width, magnetization change occurs by continuous spin-reversal and M-H loops are characterized by no or very small hysteresis at aspect ratios smaller than unity, At aspect ratios greater than unity, magnetization change occurs by spin-flip resulting in squared hysteresis loops. A very large changes in the coercivity and the bias field is observed, and these results are explained by two separate contributions to the total magnetostatic interactions: the coercivity by the self-demagnetizing field and the bias field by the interlayer magnetostatic interaction field.

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A Study on the Brazing Bondinf Conditions of A1050 Using Al-Si Alloy Filler Metal (Al-Si계 필러메탈을 이용한 A1050알루미늄의 브레이징 접합조건에 관한 연구)

  • 김정일;김영식
    • Journal of Advanced Marine Engineering and Technology
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    • v.17 no.1
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    • pp.66-72
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    • 1993
  • The brazing of Al to Al using Al-Si alloy filler metal was performed under different bonding conditions such as ratio of lap length to plate thickness, surface roughness and joint clearance of the lap joint. The adopted thickness of the base metal in this experiments were two kinds of 4mm and 7mm which were most commonly used in various field. Influence of several bonding conditions of Al/Al joint was quantitavely evaluated by bonding strength test, and microstructural analysis at the interlayer were performed by optical microscope. From above experiments, the optimum bonding conditions of the brazing bonding of Al/Al using Al-Si alloy filler metal was determined. The major results obtained are as follows. 1) The fracture occurs at brazed joint in the conditions of that the ratio of lap length to plate thickness is less than 2 in case of 7mm plate thickness. 2) The ratio of lap length to plate thickness which the fracture occurs at base metal is decreased with the decreasing of the plate thickness. 3) The joint strength is not affected by the surface roughness and joint clearance of the brazed part. 4) The heat-treatment of the brazed joint contribute to eliminate the boundary between the base metal and filler metal. However, the joint strength is not affected by the heat-treatment.

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The Effect of Crystalline Type of Carbonaceous Materials on Performance of the Carbon Anode for Lithium Ion Secondary Battery (리튬이온이차전지에서 결정성 탄소재료가 탄소부극 특성에 미치는 영향)

  • Kim, Hyun-Joong;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1059-1064
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    • 1998
  • We have investigated various kind of graphite and MCMB6-28 to develop carbon negative electrode for lithium ion secondary battery. The interlayer length of them was $3.358{\sim}3.363{\AA}$ and the BET specific surface area was $2.95{\sim}26.15m^2/g$. From this study, When the interlayer of them was large and the BET specific surface area was high, the electrochemical characteristics of them was very excellent. Adding 0, 3, 5, wt% of KJ-Black as conducting agent to various graphitic carbon active materials, interface resistance of electrode and electrolyte was less, but rechargeability was better at 3 wt%. At constant current charge and discharge test, discharge capacity was small according to large current.

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A Strong Dependence of the P-P Bond Length on the Transition Metal Component in ThCr2Si2-Type Phosphides CaM2P2 (M = Fe, Ni): The Influence of d Band Position and σp* Mixing

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1215-1218
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    • 2003
  • An analysis of the bonding situation in CaM₂P₂ (M=Fe, Ni) with ThCr₂Si₂ structure is made in terms of DOS and COOP plots. The main contributions to covalent bonding are due to M-P and P-P interactions in both compounds. Particularly, the interlayer P-P bonding by variation in the transition metal is examined in more detail. It turns out that the shorter P-P bonds in CaNi₂P₂ form as a result of the decreasing electron delocalization into ${{\sigma}_p}^*$ of P₂ due to the weaker bonding interaction between the metal d and ${{\sigma}_p}^*$ as the metal d band is falling from Fe to Ni.

Electrochemical Characteristics of Expanded Graphite by Microwave Irradiation in Lithium Ion Battery (리튬 이온 커패시터에서 마이크로파 조사에 의한 팽창 흑연의 전기화학적 특성)

  • Seol, Sun-hwa;Park, Soo-gil;KIM, Han-Ju;Kim, Hong-il
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.167-167
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    • 2014
  • Graphite is used as a negative electrode active material of Lithium ion capacitor (LIC). At the cathod, electrostatic reaction of EDLC is a very high reaction rate compared to a oxidaion reduction reaction. When the graphite was expanded that the length between the sheet, the intercalation of lithium ions is smoothed. And thus, the power density increases. By measuring the XRD, it was confirmed that the increase in interlayer spacing of graphite. And by measuring an electrochemical reactionin Lithium Ion Battery (LIB), it was confirmed the tendency of power density is improved.

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Analytical wave dispersion modeling in advanced piezoelectric double-layered nanobeam systems

  • Ebrahimi, F.;Haghi, P.;Dabbagh, A.
    • Structural Engineering and Mechanics
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    • v.67 no.2
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    • pp.175-183
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    • 2018
  • This research deals with the wave dispersion analysis of functionally graded double-layered nanobeam systems (FG-DNBSs) considering the piezoelectric effect based on nonlocal strain gradient theory. The nanobeam is modeled via Euler-Bernoulli beam theory. Material properties are considered to change gradually along the nanobeams' thickness on the basis of the rule of mixture. By implementing a Hamiltonian approach, the Euler-Lagrange equations of piezoelectric FG-DNBSs are obtained. Furthermore, applying an analytical solution, the dispersion relations of smart FG-DNBSs are derived by solving an eigenvalue problem. The effects of various parameters such as nonlocality, length scale parameter, interlayer stiffness, applied electric voltage, relative motions and gradient index on the wave dispersion characteristics of nanoscale beam have been investigated. Also, validity of reported results is proven in the framework of a diagram showing the convergence of this model's curve with that of a previous published attempt.

Computer Simulation of Sensing Current Effects on the Magnetic and Magnetoresistance Properties of a Crossed Spin-Valve Read

  • Lim, S.H;Han, S.H;Shin, K.H;Kim, H.J
    • Journal of Magnetics
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    • v.5 no.2
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    • pp.44-49
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    • 2000
  • Computer simulation of sensing current effects on the magnetic and magnetoresistance properties of a crossed spin-valve head is carried out. The spin-valve head has the following layer structure: Ta (8.0 nm)/NiMn (25 nm)/NiFe (2.5 nm)/Cu (3.0 nm)/NiFe (5.5 nm)/Ta (3.0 nm), and it is 1500 nm long and 600 nm wide. Even with a high pinning field of 300 Oe and a high hard-biased field of 50 Oe, the ideal crossed spin-valve structure, which is essential to the symmetry of the output signal and hence high density recording, is not realized mainly due to large interlayer magnetostatic interactions. This problem is solved by applying a suitable magnitude of sensing currents along the length direction generating magnetic fields in the width direction. The ideal spin-valve head is expected to show good symmetry of the output signal. This has not been shown explicitly in the present simulation, however, The reason for this is possibly related to the simple assumption used in this calculation that each magnetic layer consists of a single domain.

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A Study on Frictional Characteristics and Polishing Result of SiO2 Slurry in CMP (CMP시 SiO2 슬러리의 마찰 특성과 연마결과에 관한 연구)

  • Lee Hyunseop;Park Boumyoung;Seo Heondeok;Jung Jaewoo;Jeong Sukhoon;Jeong Haedo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.7 s.238
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    • pp.983-989
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    • 2005
  • The effects of mechanical parameters on the characteristics of chemical mechanical polishing(CMP) can be directly evaluated by friction force. The piezoelectric quartz sensor for friction force measurement was installed, and friction force could be detected during CMP process. Furthermore, friction energy can be calculated by multiplying relative velocity by integration of the friction force throughout the polishing time. $SiO_2$ slurry for interlayer dielectric(ILD) CMP was used in this experiment to consider the relation of frictional characteristics and polishing results. From this experiment, it is proven that the friction energy is an essential factor of removal rate. Also, the friction force is related to removal amount per unit length(dH/ds) and friction energy has corelation to the removal rate(dH/dt) and process temporature. Moreover, within wafer non-unifornity(WIWNU) is related to coefficient of friction because of the mechanical moment equilibrium. Therefore, the prediction of polishing result would be possible by measuring friction force.