• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2003년도 ICCAS
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• pp.1749-1753
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• 2003

We proposed several systems for 1Giga bit Modem. The first, Binary ASK(Amplitude Shift Keying) system has a high speed shutter transmitter and no IF(Intermediate Frequency) receiver only by symbol synchronization. The advantage of proposed system is that circuitry is very simple without IF process. The disadvantage of proposed system are that line spectrum occurs interference to other channels, and enhancement to 4-level system is impossible due to its large SNR degradation. The second, Binary phase modulation system has a high speed shutter transmitter and IF-VCO(IF-Voltage Controlled Oscillator) control by base-band phase rotation. Polarity of shutter window is changed by the binary data. The window should be narrow same as above ASK. The advantage of proposed system is which error rate performance is superior. The disadvantage of proposed system are that Circuitry is more complex, narrow pull-in range of receiver caused by VCO and spectrum divergence by the non-linear amplifier. The third, 4-QAM(Quadrature Amplitude Modulation)system has a nyquist pulse transmitter and IF-VCO control by symbol clock. The advantage of proposed system are that signal frequency band is a half of 1GHz, reliable pull-in of VCO and possibility of double speed transmission(2Gbps) by keeping 1GHz frequency-band. The disadvantage of proposed system are that circuit complexity of pulse shaping and spectrum divergence by the non-linear amplifier.

• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.3055-3060
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• 2012

A simple, rapid and sensitive spectrofluorometric method was developed for the determination of folic acid (FA), based on its quenching effect on the fluorescence intensity of enoxacin (ENX)-europium ($Eu^{3+}$) complex as a fluorescent probe. Fluorometric interaction between ENX-$Eu^{3+}$ complex and FA was studied using UV-visible and fluorescence spectroscopy. The quenched fluorescence intensity at an emission wavelength of 614 nm was proportional to the concentration of FA. Optimum conditions for the determination of FA were investigated. Under optimal conditions, the reduced fluorescence intensity at 614 nm was responded linearly with the concentration of FA. The linearity was maintained in the range of $1.25{\times}10^{-9}$ to $1.50{\times}10^{-7}$ M (R = 0.9986) with the limit of detection ($3S_b/m$) (where $S_b$ is the standard deviation of blank and m is the slop of linear calibration curve) of $6.94{\times}10^{-10}$ M. The relative standard deviation (RSD) for 9 repeated measurements of $1.0{\times}10^{-9}$ M FA was 1.42%. This method was simple, cost effective, and relatively free of interference from coexisting substances. Successful determinations of FA in pharmaceutical formulation and biological samples with the developed method were demonstrated.

• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.1907-1914
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• 2010

A novel catalytic kinetic method is proposed for the determination of Se(IV), Se(VI) and total inorganic selenium in water based on the catalytic effect of Se(IV) on the reduction of bromate by p-nitrophenylhydrazine at pH 3.0. The generated bromine, $Br_2$ or $Cl_2$ plus $Br_2$ in 0.1 M NaCl (or NaBr) environment efficiently decolorized Calmagite and the reaction was monitored spectrophotometrically at 523 nm as a function of time. In this indicator reaction, bromide acted as an activator for the catalysis of selenium (IV) and a reducing agent for selenium (VI) at pH 3.0, which allowed the determination of total selenium. The fixed time method was adopted for the determination and speciation of inorganic selenium. Under the optimum conditions, the calibration graph are linear in the range 1 - 35 ${\mu}gL^{-1}$ of Se(IV) for the fixed time method at $25^{\circ}C$. The detection limit based on statistical $3S_{blank}$/m-criterion was 0.215 ${\mu}gL^{-1}$ for the fixed time method (7 min). All of the variables that affect the sensitivity at 523 nm were investigated, and the optimum conditions were established. The interference effect of various cations and anions on the Se (IV) determination was also studied. The selectivity of the selenium determination was greatly improved with the use of the strongly cation exchange resin such as Amberlite IR120 plus. The proposed kinetic method was validated statistically and through recovery studies in natural water samples. The RSDs for ten replicate measurements of 5, 15 and 25 ${\mu}gL^{-1}$ of Se(IV) and Se(VI) was changed between 2.1 - 4.85%. Analyses of a certified standard reference material (NIST SRM 1643e) for selenium using the fixed-time method showed that the proposed kinetic method has good accuracy. Se(IV), Se(VI) and total inorganic selenium in environmental water samples have been successfully determined by this method after selective reduction of Se(VI) to Se(IV).

• 대한전자공학회논문지SD
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• 제47권10호
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• pp.7-13
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• 2010

본 논문에서는 전자기파 장애(EMI)의 감소를 위한 위상 보간기 기반의 새로운 스프레드 스펙트럼 클락 발생기(SSCG)를 제시한다. 제안하는 SSCG는 낮은 설계 복잡도와 저전력 및 작은 칩면적을 갖으며 삼각 주파수 변조를 이루기 위해 디지털적으로 조절 가능한 위상 보간 방식을 사용하였다. 이 새로운 SSCG는 듀티 싸이클 왜곡 없이 200MHz에서 ${\pm}2%$의 센터-스프레드 스펙트럼 범위를 갖는 시스템 클락을 발생시킬 수 있다. 이 위상 보간기 기반의 SSCG 회로는 200MHz에서 약 5.0 mW의 전력을 소모하고, 0.18-um 1.8-V CMOS 공정을 사용하여 설계하여 검증하였으며 $0.092mm^2$의 칩 면적을 차지한다.

• 마이크로전자및패키징학회지
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• 제24권4호
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• pp.19-22
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• 2017

본 논문에서는 방대한 양의 데이터를 전송하기 위한 고분자 광도파로를 기반으로 한 집적 평면형 다중모드 $1{\times}N$ 광 분배소자의 구조를 제안하였다. 두 개의 상이한 모양의 테이퍼 형 광도파로를 이용하여 광의 모드 변환 특성을 분석하고, 넓은 파장 영역에도 동작이 가능한 광분배기 구조를 설계하였다. 일반적인 광 분배기 구조는 Y-branch를 나열하는 형태와 Mach-Zehnder 및 커플러 형태로 제작되고 있으나, 분기부가 반복되면서 광 손실이 증가하는 문제가 있다. 해결 방안으로 본 연구에서 제안되는 구조는 Y-branch를 배열하지 않는 구조를 제안하여 분기부에 대한 손실을 줄이고, 출력단의 광의 세기가 균일하게 출력되는 해결방안을 제안하였다.

• 대한기계학회논문집
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• 제10권3호
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• pp.343-348
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• 1986

본 연구는 이와 같은 필요성에 의해 빛의 간섭현상을 이용하여 액체막이 부차 적인 유동을 일으키기 이전에 용착성장속도를 정량적으로 측정할 수 있었고, 터어빈 날개의 부식에 직접적으로 문제를 일으키는 황산나트륨과 황산칼륨의 용착성장속도를 측정하였다. 본 연구는 종래 액체막의 성장속도만을 빛의 간섭현상을 이용하여 측정 해오던 측정범위를 광원으로 사용된 레이저의 편광상태, 굴절율, 입사각등의 변화에 따른 간섭신호의 비교연구를 통해 고체상태막의 성장속도 및 막이 기화되어 증발되는 현상도 측정하였다. 따라서 증기상태의 무기염이 금속표면에 용착될 때 적용해온 Rosner의 이론을 실험결과와 비교할 수 있었고 응축된 상태로 증기에 표함되어 있는 경우와 이슬점(dew point:표면에 더 이상 용착이 일어나지 못하는 표면온도)의 해석에 보다 확장된 개념들을 도입할 수 있었다.

• 대한화학회지
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• 제51권4호
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• pp.331-338
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• 2007

분석 시약으로 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone (HMBATSC)를 사용하여 코발트 (II) 정량을 위하여 빠르고 간단하고 민감한 분광광도법을 개발하였다. 액상에서 금속이온이 pH 6.0에서 HMBATSC와 갈색의 착물을 형성하였다. 이 착물은 375 nm와 390 nm에서 두 개의 최대 흡수 피크를 보였다. 375 nm에서 많은 흡 수를 보였고, 반면 390 nm에서는 분명한 흡수를 보이지 않았다. Beer's 법칙에서 Co(II)는 0.059-2.357 μg ml-1 범위를 보였다. 이 방법의 몰 흡수와 Sandall's 민감도는 각각 2.74×104 l mol-1 cm-1와 0.0024 μg cm-2 였다. 여러 가지 다른 이온들에 간섭에 대해서도 연구하였다. 화학양론적으로 착체는 1:2 [Co(II)- HMBATSC] 이 였다. 이차 유도 분광광도 법에 의한 Co(II)의 정량방법에 대해서도 제안하였다. 제안된 방법을 alloy steels, 비타민 B12와 생물학 시료에 있는 Co(II)의 정량에 적용하였다.

• 한국광학회지
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• 제8권4호
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• pp.333-339
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• 1997

클래딩 지름이 다른 광섬유 브래그 격자를 용융 접착하여 스트레인과 온도를 분리하여 측정할 수 있는 센서를 구성하였다. 굵기차에 의해서 스트레인에 대한 각 브래그 파장 변화량은 서로 다르며, 동일한 모재(perform)에서 생산된 광섬유를 사용하였으므로 온도에 대한 파장 변화량은 같았다. 두 브래그 파장의 변화량을 측정하고 잘 정의된 행렬함수에 대입하여, 가해진 스트레인과 온도의 양을 분리하여, 계산할 수 있었다. 0-1500 .mu.strain, 20-100.deg. C 범위의 스트레인과 온도 변화를 가하면서 제작된 센서의 특성을 관측하였고, 브래그 파장 변화를 측정하여 계산한 결과, 온도계와 마이크로미터 값에 비하여 10% 이내의 측정오차를 얻을 수 있었다. 스트레인의 측정 정일도를 높이기 위해서 일정한 광경로차를 갖는 마하젠더 간섭계를 이용하여 두 격자의 상대 파장변화를 간섭 신호의 크기변화로 변환하는 새로운 방법을 제안하였으며, 시스템을 구축하여 실험한 결과로 온도에 무관하게 분광분석기에 비항 80배 이상 향상된 스트레인 측정 정밀도를 얻을 수 있었다.

• 한국식품영양과학회지
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• 제23권6호
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• pp.1032-1037
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• 1994

A simple, reproducible , and accurate enzymatic method using a cholesterol assay kit was developed to quantify total cholesterol content in egg yolk. Total egg yolk lipid was extracted with hexane : isopropanol(3 : 2, v/v) mixture. Samples containing various amount of the total lipid(0-3mg) in optically identifical culture tubes were reacted for 10 min in a water bath (37$^{\circ}C$) with the enzyme solution (5ml) from the cholesterol assay kit. Cholesterol content of the reaction mixturesin culture tubes was spectrophotometrically determined by two different ways : (1) using the culture tube as a curvette(designate culture tube method ; CTM) and (2) the quartz cvette containing the reaction mixture transferred from the culture tube (designate standard cvette method, SCM). CTM revealed lower cholesterol content in 0.1-1.0mg lipid sample range that SCM did, but not significant. For more than 2.0mg lipid sample, CTM gave significantly (p<0.01) lower cholesterol content relative to that by SCM, suggesting that SCM give a false positive result from the sample containing more than 2 mg lipid due to the interference of absorbance by lipid dispersed in the reaction solution . Cholesterol content of less than 1.0mg lipid sample by CTM was proportional to the amount of lipid used, but its linear relationship was not seen in more than 2mg lipid sample. Thus, to determine the appropriate lipid amounts (mg) analyzed . A constant level (41$\mu\textrm{g}$/mg) of cholesterol concentration was observed from the sample containing 0.1-1mg lipid. after which the cholesterol level was dropped to less than 41$\mu\textrm{g}$ /mg. Cholesterol concentration in egg yolk samples quantified by CTM was in accordance with that by GC method. These results suggest that CTM is an useful method for the quantification of cholesterol in egg yolk lipid and other lipids as well.

• Journal of Electrochemical Science and Technology
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• 제10권4호
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• pp.416-423
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• 2019

A novel non-enzymatic oxalic acid (OA) sensor based on the platinum/carbon black-nickel-reduced graphene oxide (Pt/CBNi-rGO) nanocomposite is reported. The nanocomposites were prepared by the ethylene glycol reduction method. Their morphology and chemical composition were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM). The results clearly demonstrated the formation of the Pt/CB-Ni-rGO nanocomposite. The electrocatalytic activity of the Pt/CB-Ni-rGO electrode was investigated by cyclic voltammetry. It was determined that the appropriate amount of Pt enhanced the catalytic activity of Pt for oxalic acid electro-oxidation. Moreover, the modified electrode was determined to be highly selective for oxalic acid without interference from compounds commonly found in urine including uric acid and ascorbic acid. The chronoamperometric signal gave a wide linearity range of 20 μM-60 mM and the detection limit (3σ) was found to be 2.35 μM. The proposed method showed high selectivity, stability, and good reproducibility and could be used with micro-volumes of sample for the detection of oxalic acid. Finally, the oxalic acid content in artificial and control urine samples were successfully determined by our proposed electrode.