• Title/Summary/Keyword: Interfacial structure

Search Result 422, Processing Time 0.034 seconds

Current Characteristics at p-GaP Semiconductor Interfaces (p형 GaP 반도체 계면의 전류 특성)

  • 김은익;천장호
    • Journal of the Korean Institute of Telematics and Electronics
    • /
    • v.26 no.9
    • /
    • pp.1369-1374
    • /
    • 1989
  • Electrical characteristics at the p-GaP semiconductor/CsNO3 electrolyte interfaces were investigated. It is found that such interfacial phenomena are well analyzed by semiconductor-semiconductor pn junction diode models and image charge effects of semiconductor-vacuum interfaces. The formation processes of electrical double layers and their potential variations are verified using cyclic voltammetric methods. The interfacial current are influenced by Cs+ ion coverage onto the semiconductor electrode surface and structure of electrical double layer.

  • PDF

Interfacial and Pull-out Properties of PVA and PET Fiber with UV Irradiation in Cementitious Composites (시멘트 복합체 내에서 UV처리에 따른 PVA 및 PET섬유의 계면 및 매입인발특성)

  • Jeon, Esther;Lee, Sang-Soo;Yun, Hyun-Do
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2006.05b
    • /
    • pp.401-404
    • /
    • 2006
  • Much of requirements to the civil and building structures have been changed in accordance with the social and economic progress. Ductility of high performance fiber reinforced cementitious composites(HPFRCCs), which exhibit strain hardening and multiple crackling characteristics under the uniaxial tensile stress is drastically improved. In HPFRCC application, PVA fiber has been dominantly used as a reinforcement because of its excellent alkali resistant nature as well as high strength. But the inherent strong hydrophilicity of PVA fiber promotes the moisture absorption in cement matrix and thus it may cause the corrosion of steel structure. Therefore, it is necessary to control the interfacial adhesion of cement composites. In present study, to control the interfacial adhesion of the cementitious composites reinforced by PVA fiber, UV irradiation of the PVA fiber were performed and their effects on the adhesion property and general characteristics were investigated extensively.

  • PDF

Solution-processed electrophosphorescent devices with a thin fluoropolymer at the hole transport interfacial layer

  • Park, Jae-Kyun;Hwang, Gyoung-Seok;Lee, Tae-Woo;Chin, Byung-Doo
    • Journal of Information Display
    • /
    • v.12 no.4
    • /
    • pp.223-227
    • /
    • 2011
  • Electrophosphorescent devices with ionomer-type hole transport layers were investigated. On top of the 3,4-ethylenedioxy thiophene:poly(4-styrene sulfonate) [PEDOT:PSS] structures, fluoropolymer interfacial layers (FPIs) with different side chain lengths were introduced. Both for the PEDOT:PSS/FPI (layered) and PEDOT:PSS (mixed) structures with soluble phosphorescent emitters, the short-side-chain FPIs showed higher efficiency. The difference in the electrical properties of the two FPIs for bipolar (light-emitting) devices was not clear, but the hole-only device clearly showed the favored hole injection at the PEDOT:PSS/FPI structure with a shorter side chain, a copolymer of tetrafluoroethylene and sulfonyl fluoride vinyl ether.

CNTs Electric Field Enhancement of CIGS Solar Cells

  • Han, Seong-Hwan
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.08a
    • /
    • pp.67-67
    • /
    • 2011
  • Compound semiconductor/CNTs composites have shown considerably improved efficiency improvement in photovoltaic devices, which is often attributed to two different factors. One is the formation of efficient electronic energy cascade structures. The other effect of CNTs on the performance of photovoltaic devices is the decrement of interfacial resistance. The interfacial resistances at n-type/ p-type materials and/or n-type materials/TCO electrode are reduced by an outstanding electrical property of CNTs. In addition to the effects of CNTs, we report the third reason for increment of efficiency in photovoltaic devices by CNT's well-known electrical field enhancement effects. The improved ${\beta}$ values in reverse-FE currents of CIGS electrode with SWNTs layers indicate the enhancement of electrical field in photovoltaic devices, which implies the acceleration of the electron transfer rate in the cell. Due to the formation of an efficient electronic energy cascade structure and the decrease of the interfacial resistance as well as the improvement of the electrical field in the photovoltaic devices, the power conversion efficiency of electrochemically deposited superstrate-type CIGS solar cells was increased 24.3% in the presence of SWNTs and showed 10.40% conversion efficiency.

  • PDF

Positive Exchange Bias in Thin Film Multilayers Produced with Nano-oxide Layer

  • Jeon, Byeong-Seon;Hwang, Chan-Yong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.304-305
    • /
    • 2013
  • We report a positive exchange bias (HE) in thinmultilayered filmscontaining nano-oxide layer. The positive HE, obtained for our system results from an antiferromagnetic coupling between the ferromagnetic (FM) CoFe and the antiferromagnetic (AFM) CoO layers, which spontaneously form on top of the nano-oxide layer (NOL). The shift in the hysteresis loop along the direction of thecooling field and the change in the sign of exchange bias are evidence of antiferromagnetic interfacial exchange coupling between the CoO and CoFe layers. Our calculation indicates that uncompensated oxygen moments in the NOL results in antiferromagnetic interfacial exchange coupling between the CoO and CoFe layers. One of the interesting features observed with our system is that it displays the positive HE even above the bulk Neel temperature (TN) of CoO. Although the positive HEsystem has a different AFM/FM interfacial spin structure compare to that of the negative HE one, the results of the angular dependence measurements show that the magnetization reversal mechanism can be considered within the framework of the coherent rotation model.

  • PDF

Modelling of Grain Boundary in Polysilicon Film for Photodetector Through Current-Voltage Analysis (광검출기용 다결정 실리콘 박막의 전도특성 분석을 통한 결정립계의 모형화)

  • Lee, Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.33 no.4
    • /
    • pp.255-262
    • /
    • 2020
  • Grain boundaries play a major role in determining device performance, particularly of polysilicon-based photodetectors. Through the post-annealing of as-deposited polysilicon and then, the analysis of electric behavior for a metal-polysilicon-metal (MSM) photodetector, we were able to identify the influence of grain boundaries. A modified model of polysilicon grain boundaries in the MSM structure is presented, which uses a crystalline-interfacial layer-SiOx layer- interfacial layer-crystalline system that is similar to the Si-SiO2 system in MOS device. Hydrogen passivation was achieved through a hydrogen ion implantation process and was used to passivate the defects at both interfacial layers. The thin SiOx layer at the grain boundary can enhance the photosensitivity of an MSM photodetector by decreasing the dark current and increasing the light absorption.

High performance of inverted polymer solar cells

  • Lee, Hsin-Ying;Lee, Ching-Ting;Huang, Hung-Lin
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2015.08a
    • /
    • pp.61.2-61.2
    • /
    • 2015
  • In the past decades, green energy, such as solar energy, wind power, hydropower, biomass energy, geothermal energy, and so on, has been widely investigated and developed to solve energy shortage. Recently, organic solar cells have attracted much attention, because they have many advantages, including low-cost, flexibility, light weight, and easy fabrication [1-3]. Organic solar cells are as a potential candidate of the next generation solar cells. In this abstract, to improve the power conversion efficiency and the stability, the inverted polymer solar cells with various structures were developed [4-6]. The novel cell structures included the P3HT:PCBM inverted polymer solar cells with AZO nanorods array, with pentacene-doped active layer, and with extra P3HT interfacial layer and PCBM interfacial layer. These three difference structures could respectively improve the performance of the P3HT:PCBM inverted polymer solar cells. For the inverted polymer solar cells with AZO nanorods array as the electronic transportation layer, by using the nanorod structure, the improvement of carrier collection and carrier extraction capabilities could be expected due to an increase in contact area between the nanorod array and the active layer. For the inverted polymer solar cells with pentacene-doped active layer, the hole-electron mobility in the active layer could be balanced by doping pentacene contents. The active layer with the balanced hole-electron mobility could reduce the carrier recombination in the active layers to enhance the photocurrent of the resulting inverted polymer solar cells. For the inverted polymer solar cells with extra P3HT and PCBM interfacial layers, the extra PCBM and P3HT interfacial layers could respectively improve the electron transport and hole transport. The extra PCBM interfacial layer served another function was that led more P3HT moving to the top side of the absorption layer, which reduced the non-continuous pathways of P3HT. It indicated that the recombination centers could be further reduced in the absorption layer. The extra P3HT interfacial layer could let the hole be more easily transported to the MoO3 hole transport layer. The high performance of the novel P3HT:PCBM inverted polymer solar cells with various structures were obtained.

  • PDF

A Study on the Mechanical Properties of Interfacial Transition Zone (ITZ) of Lightweight High Strength Concrete Via Nanoindentation (나노 인덴테이션을 통한 경량 고강도 콘크리트 Interfacial Transition Zone (ITZ)의 역학적 특성에 관한 연구)

  • Im, Su-Min;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.8 no.4
    • /
    • pp.537-544
    • /
    • 2020
  • The interfacial transition zone(ITZ) which is the boundary layer between cement composites and aggregates is considered to be the region of gradual transition, heterogeneous, and the weakest part of concrete. For the development of lightweight high strength concrete, it is essential to evaluate the mechanical properties of ITZ between high strength concrete with low water-binder ratio and lightweight aggregates. However, the mechanical properties of ITZ are not well established due to its high porosity and complex structure. Furthermore, the properties of ITZ in concrete using lightweight aggregates are dominated by more various variations (e.g. water-binder ratio, water absorption capacity of aggregate, curing conditions) than normal-weight aggregate concrete. This study aims to elucidate the mechanical properties of ITZ in lightweight high-strength cement composites according to the types of aggregates and the aggregate sizes. Nanoindentation analysis was used to evaluate the elastic modulus of ITZ between high strength cement composites with the water-binder ratio of 0.2 and normal sand, lightweight aggregate with different aggregate siz es of 2mm and 5mm in this study.

Interfacial bond properties and comparison of various interfacial bond stress calculation methods of steel and steel fiber reinforced concrete

  • Wu, Kai;Zheng, Huiming;Lin, Junfu;Li, Hui;Zhao, Jixiang
    • Computers and Concrete
    • /
    • v.26 no.6
    • /
    • pp.515-531
    • /
    • 2020
  • Due to the construction difficulties of steel reinforced concrete (SRC), a new composite structure of steel and steel fiber reinforced concrete (SSFRC) is proposed for solving construction problems of SRC. This paper aims to investigate the bond properties and composition of interfacial bond stress between steel and steel fiber reinforced concrete. Considering the design parameters of section type, steel fiber ratio, interface embedded length and concrete cover thickness, a total of 36 specimens were fabricated. The bond properties of specimens were studied, and three different methods of calculating interfacial bond stress were analyzed. The results show: relative slip first occurs at the free end; Bearing capacity of specimens increases with the increase of interface embedded length. While the larger interface embedded length is, the smaller the average bond strength is. The average bond strength increases with the increase of concrete cover thickness and steel fiber ratio. And calculation method 3 proposed in this paper can not only reasonably explain the hardening stage after the loading end curve yielding, but also can be applied to steel reinforced high-strength concrete (SRHC) and steel reinforced recycled coarse aggregate concrete (SRRAC).

Improvement of the mechanical properties of titanium carbonitride-metal composites by modification of interfaces (계면 개선을 통한 타이타늄 탄/질화물 금속 복합재료의 기계적 물성 향상)

  • Kwon, Hanjung
    • Ceramist
    • /
    • v.23 no.2
    • /
    • pp.114-131
    • /
    • 2020
  • Fracture in the titanium carbonitride-metal composites occurs by crack propagation through the carbonitride grains or in the interfaces. Thus, intrinsic properties of the carbonitride need to be enhanced and the interfaces should be also modified to coherent structure to strengthen the composites. Especially, interfacial structure can be the main factor to determine the mechanical properties of titanium carbonitride-metal composites because the interfaces between carbonitride grains and metallic phase are weak parts due to heterogeneous nature of carbonitride and metallic phase. In this paper, methodologies for improving the interfacial structure of titanium carbonitride-metal composites are suggested. Total area of the interfaces can be reduced using solid solution type carbonitrides as raw materials instead of a mixture of various carbonitrides in the composites. Also, synthesis of titanium carbonitride-metal composite powders and the low-temperature sintering of the composite powders for short time can be the way for formation of coherent interfaces. The sintering of the composite powders for short time at low temperature can reduce the potential of formation of interfaces by dissolution and precipitation of carbonitride in the liquid metal. As a result of formation of coherent boundaries due to low-temperature and short-time sintering, interfaces between titanium carbonitride grains and metallic phase have the favorable structure for the enhanced fracture toughness. It is believed that the low-temperature sintering of solid solution type composite powders for short time can be the way to improve the low toughness of the titanium carbonitride-metal composites.