• Title/Summary/Keyword: Interfacial property

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Electrical Characterization of $HfO_2$/Hf/Si(sub) Films Grown by Atomic Layer Deposition (ALD방법으로 성장된 $HfO_2$/Hf/Si 박막의 전기적 특성)

  • Lee, Dae-Gab;Do, Seung-Woo;Lee, Jae-Sung;Lee, Yong-Hyun
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.565-566
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    • 2006
  • In this work, We study electrical characterization of $HfO_2$/Hf/Si films grown by Atomic Layer Deposition(ALD). Through AES(Auger Electron Spectroscopy), capacitance-voltage(C-V) and current-voltage(I-V) analysis, the role of Hf layer for the better $HfO_2$/Si interface property was investigated. We found that Hf metal layer in our structure effectively suppressed the generation of interfacial $SiO_2$ layer between $HfO_2$ film and silicon substrate.

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Influence of water saturation on fracture toughness in woven natural fiber reinforced composites

  • Kim, Hyo-Jin;Seo, Do-Won
    • Advanced Composite Materials
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    • v.16 no.2
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    • pp.83-94
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    • 2007
  • Woven sisal textile fiber reinforced composites were used to evaluate fracture toughness, tensile and three-point bending. The water absorption testing of all specimens was repeated five times in this study. All specimens were immersed in pure water during 9 days at room temperature, and dried in 1 day at $50^{\circ}C$. Two kinds of polymer matrices such as epoxy and vinyl-ester were used. Fractured surfaces were taken to study the failure mechanism and fiber/matrix interfacial adhesion. It is shown that it can be enhanced to improve their mechanical performance to reveal the relationship between fracture toughness and water absorption fatigue according to different polymer matrices. Water uptake of the epoxy composites was found to increase with cycle times. Mechanical properties are dramatically affected by the water absorption cycles. Water-absorbed samples showed poor mechanical properties, such as lower values of maximum strength and extreme elongation. The $K_{IC}$ values demonstrated a decrease in inclination with increasing cyclic times of wetting and drying for the epoxy and vinyl-ester.

Study on nanoemulsion using various lecithins and oils

  • Park, Byung-Gyu;Lee, Sung-Won;Chai, Hee-Gil;Eom, Sang-Yong;Kim, Jong-Heon;Ji, Hong-Geun
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.379-391
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    • 2003
  • Nanoemulsions have many specific characters compared with general emulsions in aspect of stability, rheological property, uniformity, high interfacial tension and so on. Therefore we study on nanoemulsions with changing various lecithins and oils using microfluidizer. As lecithins, we used saturated lecithin, unsaturated lecithin and hydrogenated phosphatidylcholine. Caprylic capric triglyceride, Squalane, Macadamia nut oil, Liquid paraffins, Dimethicone, and Cyclomethicone were used as oils. To identify nanoemulsions, we measured paticle size, zeta potential, turbidity and transmission electron microscope.

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Wear Characteristics of Coated $Si_3N_4$-TiC Ceramic Tool (Coated $Si_3N_4$-TiC Ceramic 공구의 마모 특성)

  • 김동원;권오관;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.44-51
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    • 1988
  • Titanium carbide(TiC), Titanium nitride(TiN), and Titanium carbonnitride(Ti(C,N)) films were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$, $TiCl_4-N_2-H_2$, and $TiCl_4-CH_4-N_2-H_2$ gas mixtures, respectively. The experimental results indicate that TiC coatings compared with TiN coatings on $Si_3N_4$ -TiC ceramic have an improved microstructural property, good thermal shock resistance, and good interfacial bonding. However TiN coatings compared with TiC coatings have a low friction coefficient with steel and good chemical stability. It is found by cutting test that coated insert compared with $Si_3N_4$-TiC ceramic have a superior flank and crater wear resistance. And multilayer coating compared with monolayer coating shows a improved wear resistance.

Cold Roll Bonding of (Ag-10% Ni)/Cu Clad Metals ((Ag-10 % Ni)/Cu 접점재의 냉간압연접합)

  • 김종헌;김성일;박상용
    • Transactions of Materials Processing
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    • v.6 no.2
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    • pp.136-144
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    • 1997
  • (Ag-10%Ni)/Cu clad metals for electric contact switch were fabricated by cold-roll bonding process. 2 or 3 passes of cold-rolling was carried out for each process to investigate the effect of the rolling passes on the bonding property. The effect of the annealing temperature of copper before the cold-roll bonding on the bond strength was also studied. The specimen bonded with copper annealed below 30$0^{\circ}C$ before roll bonding showed good bond strength. This is because high stored energy in copper promoted the short range diffusion and the grain refinement of copper by the static recrystallization increased the degree of the interfacial coherency. The maximum peel strength of clad metals bonded with Cu annealed below 30$0^{\circ}C$ was 120N.

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Comparative Study of Mass Transfer and Bubble Hydrodynamic Parameters in Bubble Column Reactor: Physical Configurations and Operating Conditions

  • Sastaravet, Prajak;Chuenchaem, Chomthisa;Thaphet, Nawaporn;Chawaloesphonsiya, Nattawin;Painmanakul, Pisut
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.345-354
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    • 2014
  • In this paper, effects of physical configurations and operating conditions on bubble column performance were analyzed in terms of bubble hydrodynamic and mass transfer parameters. Bubble column with 3 different dimensions and 7 gas diffusers (single / multiple orifice and rigid / flexible orifice) were applied. High speed camera and image analysis program were used for analyzing the bubble hydrodynamic parameters. The local liquid-side mass transfer coefficient ($k_L$) was estimated from the volumetric mass transfer coefficient ($k_La$) and the interfacial area (a), which was deduced from the bubble diameter ($D_B$) and the terminal bubble rising velocity ($U_B$). The result showed that the values of kLa and a increased with the superficial gas velocity (Vg) and the size of bubble column. Influences of gas diffuser physical property (orifice size, thickness and orifice number) can be proven on the generated bubble size and the mass transfer performance in bubble column. Concerning the variation of $k_L$ coefficients with bubble size, 3 zones (Zone A, B and C) can be observed. For Zone A and Zone C, a good agreement between the experimental and the predicted $K_L$ coefficients was obtained (average difference of ${\pm}15%$), whereas the inaccuracy result (of ${\pm}40%$) was found in Zone B. To enhance the high $k_La$ coefficient and absorption efficiency in bubble column, it was unnecessary to generate numerous fine bubbles at high superficial gas velocity since it causes high power consumption with the great decrease of $k_L$ coefficients.

Interfacial Evaluation and Hydrophobicity of Multifunctional Hybrid Nanocomposites for Self-sensing and Actuation (자체 감지능 및 작동기용 다기능 하이브리드 나노복합재료의 계면 특성 및 소수성 표면 연구)

  • Wang, Zuo-Jia;GnidaKouong, Joel;Jang, Jung-Hoon;Kim, Myung-Soo;Park, Joung-Man
    • Composites Research
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    • v.23 no.2
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    • pp.24-30
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    • 2010
  • Interfacial evaluation and hydrophobicity of Ni-nanopowder/epoxy composites were investigated for self-sensing and actuation. Contact resistance and resistivity were measured using gradient micro-specimens. The actuation of the composites in the electromagnetic field was studied with three wave functions, i.e., sine, triangle and square functions. Due tothe presence of hydrophobic domains on the heterogeneous surface, the static contact angle of Ni-nanopowder/epoxy nanocomposite wasabout $100^{\circ}$, which was rather lower than that for super-hydrophobicity. The dynamic contact angle showed the similar trend of static contact angle. Ni-nanopowder/epoxy composite was responded wellfor both self-sensing and actuation in electromagnetic field due to the intrinsic metal property of Ni-nanopowder. Displacement of the actuator of Ni-nanopowder/epoxy composite was evaluated to obtain the maximum and the optimum performance using laser displacement sensor as functions of the wave type, frequency, and voltage. Actuation of Ni-nanopowder/epoxy composites also increased as functions of applied frequency and voltage. Actuated strain increased more rapidly at sine wave with increasing voltage compared to those of triangle or rectangular waves.

Evaluation of Mechanical Property of Carbon Fiber/Polypropylene Composite According to Carbon Fiber Surface Treatment (탄소섬유 표면처리에 따른 탄소섬유/폴리프로필렌 복합재료의 기계적 물성 평가)

  • Han, Song Hee;Oh, Hyun Ju;Kim, Seong Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.6
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    • pp.791-796
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    • 2013
  • In this study, the mechanical properties of a carbon fiber/polypropylene composite were evaluated according to the carbon fiber surface treatment. Carbon fiber surface treatments such as silane coupling agents and plasma treatment were performed to enhance the interfacial strength between carbon fibers and polypropylene. The treated carbon fiber surface was characterized by XPS, SEM, and single-filament tensile test. The interlaminar shear strength (ILSS) of the composite with respect to the surface treatment was determined by a short beam shear test. The test results showed that the ILSS of the plasma-treated specimen increased with the treatment time. The ILSS of the specimen treated with a silane coupling agent after plasma treatment increased by 48.7% compared to that of the untreated specimen.

Effect of Support Membrane Property on Performance of Forward Osmosis Membrane (지지체 특성이 정삼투막 성능에 미치는 영향)

  • Jeong, Bo-Reum;Kim, Jong-Hak;Kim, Beom-Sik;Park, Yoo-In;Song, Du-Hyun;Kim, In-Chul
    • Membrane Journal
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    • v.20 no.3
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    • pp.235-240
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    • 2010
  • The aim of this paper is to evaluate and compare the performances of forward osmosis (FO) membranes using different materials. The FO membranes were synthesized using interfacial polymerization method on hydrophobic polysulfone (PSf) and relatively hydrophilic polyethersulfone (PES) supports. The FO performance such as flux and back diffusion was measured. The resulting fluxes of PSf and PES FO membranes were $4.3\;L/m^2hr$ and $17.8\;L/m^2hr$, respectively. The flux of the PES FO membrane was higher than that of the PSf FO membrane. The results indicated that hydrophillictity of the support membrane is important for increasing flux in FO process. Moreover, with decreasing the support layer thickness, flux increased considerably.

Discussion on the Mechanical Alloying Process of Ni-20Cr alloy (Ni-20 Cr계 분말의 기계적 합금화 과정에 대한 고찰)

  • Yoo, Myoung Ki;Choi, Ju
    • Analytical Science and Technology
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    • v.6 no.2
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    • pp.197-205
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    • 1993
  • Blends of elemental Ni and 20 weight % Cr powder were milled for different period in a laboratory attritor. Powder size distribution, microstructure and X-ray diffraction characteristics were investigated as a function of processing period. Saturated magnetization, Ms and coercive force, Hc we also measured and compared with plasma melted ingot to confirm the mechanically alloyed states. Mechanical alloying occurred as a consequence of the partition of powders and the increase of interfacial area driving diffusing of Cr into Ni. However, magnetic properties of chemically homogeneous solid solution like melted ingot has not been observed even though steady state of submicron grain size has been achieved after milling over 15 hrs. Further mechanical alloying period gave refinement of grain size, which resulted in the increase of alloyed layer. It is concluded that homogenization should be controlled by the increase of interfacial area between constitutive powders caused by plastic particle deformation and by the diffusion of Cr within the alloyed phase into Ni-rich phase through lattice defects.

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